JPS6160853B2 - - Google Patents
Info
- Publication number
- JPS6160853B2 JPS6160853B2 JP53133098A JP13309878A JPS6160853B2 JP S6160853 B2 JPS6160853 B2 JP S6160853B2 JP 53133098 A JP53133098 A JP 53133098A JP 13309878 A JP13309878 A JP 13309878A JP S6160853 B2 JPS6160853 B2 JP S6160853B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- carbon atoms
- group
- mol
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002647 polyamide Polymers 0.000 claims description 49
- 239000004952 Polyamide Substances 0.000 claims description 48
- 125000004432 carbon atom Chemical group C* 0.000 claims description 40
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 36
- 125000000217 alkyl group Chemical group 0.000 claims description 25
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 22
- 150000004985 diamines Chemical class 0.000 claims description 21
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 17
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical group OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- 238000010521 absorption reaction Methods 0.000 description 25
- 150000003839 salts Chemical class 0.000 description 20
- 239000000203 mixture Chemical group 0.000 description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 17
- -1 aromatic aminocarboxylic acid nitrile Chemical group 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000009835 boiling Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 9
- 150000001408 amides Chemical class 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000012230 colorless oil Substances 0.000 description 7
- 238000006068 polycondensation reaction Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000006482 condensation reaction Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- ZOLLIQAKMYWTBR-RYMQXAEESA-N cyclododecatriene Chemical group C/1C\C=C\CC\C=C/CC\C=C\1 ZOLLIQAKMYWTBR-RYMQXAEESA-N 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- FZUWIRGHKCUMTH-UHFFFAOYSA-N 2,13-dimethyltetradecane-3,12-diamine Chemical compound CC(C)C(N)CCCCCCCCC(N)C(C)C FZUWIRGHKCUMTH-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- HPGJOUYGWKFYQW-UHFFFAOYSA-N diphenyl benzene-1,4-dicarboxylate Chemical compound C=1C=C(C(=O)OC=2C=CC=CC=2)C=CC=1C(=O)OC1=CC=CC=C1 HPGJOUYGWKFYQW-UHFFFAOYSA-N 0.000 description 3
- WHGYJUPJEFDRHW-UHFFFAOYSA-N dotriacontane-12,21-diamine Chemical compound CCCCCCCCCCCC(N)CCCCCCCCC(N)CCCCCCCCCCC WHGYJUPJEFDRHW-UHFFFAOYSA-N 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- MMCQGZHYFCKPJP-UHFFFAOYSA-N octacosane-10,19-diamine Chemical compound CCCCCCCCCC(N)CCCCCCCCC(N)CCCCCCCCC MMCQGZHYFCKPJP-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- TTZVHRJRFBJCRU-UHFFFAOYSA-N 1,10-dicyclohexyldecane-1,10-diamine Chemical compound C1CCCCC1C(N)CCCCCCCCC(N)C1CCCCC1 TTZVHRJRFBJCRU-UHFFFAOYSA-N 0.000 description 2
- DAGLNKUWJGMCHW-UHFFFAOYSA-N 2,15-dimethylhexadecane-4,13-diamine Chemical compound CC(C)CC(N)CCCCCCCCC(N)CC(C)C DAGLNKUWJGMCHW-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000005263 alkylenediamine group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- UXWHXEQADOLPLB-UHFFFAOYSA-N docosane-7,16-diamine Chemical compound CCCCCCC(N)CCCCCCCCC(N)CCCCCC UXWHXEQADOLPLB-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- YNVQYOQLKGNUBZ-UHFFFAOYSA-N octadecane-1,1-diamine Chemical compound CCCCCCCCCCCCCCCCCC(N)N YNVQYOQLKGNUBZ-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000009489 vacuum treatment Methods 0.000 description 2
- SXIFNAOBIAIYJO-SXVCMZJPSA-N (1E,3E,7E)-cyclododeca-1,3,7-triene Chemical compound C/1=C\CCCC\C=C\C=C\CC\1 SXIFNAOBIAIYJO-SXVCMZJPSA-N 0.000 description 1
- JWAGOKOJCIHYQM-UHFFFAOYSA-N 1,2-diazacyclododeca-1,5,9-triene Chemical group C1CC=CCCN=NCCC=C1 JWAGOKOJCIHYQM-UHFFFAOYSA-N 0.000 description 1
- AZCPJRSLLFDOJD-UHFFFAOYSA-N 1,2-diazacyclododecane Chemical compound C1CCCCCNNCCCC1 AZCPJRSLLFDOJD-UHFFFAOYSA-N 0.000 description 1
- FFOFRYBBHNBDPT-UHFFFAOYSA-N 2,15-dimethylhexadecane Chemical compound CC(C)CCCCCCCCCCCCC(C)C FFOFRYBBHNBDPT-UHFFFAOYSA-N 0.000 description 1
- DPQHRXRAZHNGRU-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,6-diamine Chemical compound NCC(C)CC(C)(C)CCN DPQHRXRAZHNGRU-UHFFFAOYSA-N 0.000 description 1
- FZZMTSNZRBFGGU-UHFFFAOYSA-N 2-chloro-7-fluoroquinazolin-4-amine Chemical compound FC1=CC=C2C(N)=NC(Cl)=NC2=C1 FZZMTSNZRBFGGU-UHFFFAOYSA-N 0.000 description 1
- YJQFWWYXQJWYGY-UHFFFAOYSA-N 3,12-bis(2-methylpropyl)-1,2-diazacyclododeca-1,5,9-triene Chemical compound CC(C)CC1CC=CCCC=CCC(CC(C)C)N=N1 YJQFWWYXQJWYGY-UHFFFAOYSA-N 0.000 description 1
- HREWWBVVWTYGHO-UHFFFAOYSA-N 3,12-di(pentan-2-yl)-1,2-diazacyclododeca-1,5,9-triene Chemical compound CCCC(C)C1CC=CCCC=CCC(C(C)CCC)N=N1 HREWWBVVWTYGHO-UHFFFAOYSA-N 0.000 description 1
- ZCBKEPFTNJHENF-UHFFFAOYSA-N 3,12-di(undecyl)-1,2-diazacyclododeca-1,5,9-triene Chemical compound CCCCCCCCCCCC1CC=CCCC=CCC(CCCCCCCCCCC)N=N1 ZCBKEPFTNJHENF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000012696 Interfacial polycondensation Methods 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004955 Trogamid T Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- XCIXKGXIYUWCLL-UHFFFAOYSA-N cyclopentanol Chemical compound OC1CCCC1 XCIXKGXIYUWCLL-UHFFFAOYSA-N 0.000 description 1
- OWEZJUPKTBEISC-UHFFFAOYSA-N decane-1,1-diamine Chemical compound CCCCCCCCCC(N)N OWEZJUPKTBEISC-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000004427 diamine group Chemical group 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- RBMTXFLUVLIQGN-UHFFFAOYSA-N dodecane-1,10-diamine Chemical class CCC(N)CCCCCCCCCN RBMTXFLUVLIQGN-UHFFFAOYSA-N 0.000 description 1
- CBLAIDIBZHTGLV-UHFFFAOYSA-N dodecane-2,11-diamine Chemical compound CC(N)CCCCCCCCC(C)N CBLAIDIBZHTGLV-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- MIHXSBPXSQUTAE-UHFFFAOYSA-N hexadecane-4,13-diamine Chemical compound CCCC(N)CCCCCCCCC(N)CCC MIHXSBPXSQUTAE-UHFFFAOYSA-N 0.000 description 1
- QNTIPRAMJVCLOP-UHFFFAOYSA-N icosane-1,1-diamine Chemical compound CCCCCCCCCCCCCCCCCCCC(N)N QNTIPRAMJVCLOP-UHFFFAOYSA-N 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KVHGRNNYXUQOHE-UHFFFAOYSA-N octadecane-5,14-diamine Chemical compound CCCCC(N)CCCCCCCCC(N)CCCC KVHGRNNYXUQOHE-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003503 terephthalic acid derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Description
æ¬çºæã¯æ°èŠéæããªã¢ããããã®è£œé æ¹æ³ã
ããã³ãã®æ圢å補é ã®ããã®çšéã«é¢ããã ãã€ãç¹èš±æ现æžç¬¬745029å·ã«ã第ïŒçŽãŸãã¯
第ïŒçŽã®èèªæãè³éŠæã¢ããã«ã«ãã³é žãããª
ã«ãããã¯èèªæãŸãã¯è³éŠæãžãããªã«æ··åç©
ãšçŽçéã®ç¬¬ïŒçŽãŸãã¯ç¬¬ïŒçŽãžã¢ãã³ããå å§
äžã§æ°Žã®ååšãšãšãã«150âãªãã300âã«å ç±ã
ãããšã«ãããé«ååããªã¢ããã®è£œé æ¹æ³ãé
瀺ãããŠããã é©åœãªãžã¢ãã³ãšããŠã¯ãç¹ã«ïŒïŒ10âãžã¢ã
ãâïŒïŒ10âãžã¡ãã«ãã«ã³ããããããŠããã
ãã©ã³ã¹ç¹èš±æ现æžç¬¬867384å·ã«ããã°ãäŸãã°
ïŒïŒ®âãžãã«ãã«âïŒïŒ10âãžã¡ãã«âïŒïŒ10
âãžã¢ãããã«ã³ã®æ§ãªãã«ã ã¢ããããŸããã
ãªã¢ãã補é ã®ããã®éçž®åææãšããŠäœ¿çšã§ã
ããæåŸã«ããã€ãå ¬éå ¬å ±ç¬¬1720513å·ã§ã¯ã
è³éŠæãžã«ã«ãã³é žãšãé眮æãããã¯äž¡ç«¯ã®ç
çŽ ã®ãã¡å°ããšãïŒåãççŽ ååæ°ïŒãªããïŒã®
ã¢ã«ãã«åºã§ã¢ã«ãã«çœ®æãããéå ã«ïŒãªãã
10åã®ççŽ ååãå«ãã¢ã«ãã¬ã³ãžã¢ãã³ããåŸ
ãããäžè¬çã«èç ®æ²žæ§ã®éæããªã¢ãããèšèŒ
ããŠããã ããããªããããã®å ¬éå ¬å ±ã®å ·äœçé瀺ã¯ã
è³éŠæãžã«ã«ãã³é žãšéäžã«ççŽ ååãïŒå以äž
ã¯å«ãŸãªãäžèšã®çš®é¡ã®ã¢ã«ãã¬ã³ãžã¢ãã³ãã
åŸãããéæããªã¢ããã«éå®ãããŠãããè³éŠ
æãžã«ã«ãã³é žãŸãã¯ãã®èªå°äœãšãïŒïŒ10âãž
ã¢ã«ãã«â眮æïŒïŒ10âãžã¢ããããã«ã³ããåŸ
ãããããªã¢ããã®äŸã«ã€ããŠã¯ã以äžã«æ²ãã
ãã®ä»ã®ãã¥ãã®åèæç®ã«ãæèšãããŠããª
ãã è³éŠæãžã«ã«ãã³é žãšãã®èªå°äœãããã³é眮
æãŸãã¯ã¢ã«ãã«çœ®æé·éãžã¢ãã³ããåŸããã
ããªã¢ãããããªãã¡ããã«ç€ºããåŸæ¥ã®æè¡æ
ç®ã«ç€ºãããŠããããªã¢ããã䞊ã³ã«ãããã¬ã
ãïŒTrogamid ïŒããªãåæšã§ç¥ããããã
ã¬ãã¿ã«é žãšïŒïŒïŒïŒïŒâããã³ïŒïŒïŒïŒïŒâã
ãªã¡ãã«ãããµã¡ãã¬ã³ãžã¢ãã³ã®ç°æ§äœæ··åç©
ããåŸãããçž®åçæç©ã¯ãåžæ°Žæ§ãèå æ°Žå解
æ§ããã³ïŒãŸãã¯æ¹¿åºŠååšäžã§ã®å¯žæ³å®å®æ§ç
ããå®å šã«æºè¶³ãã¹ããã®ã§ã¯ãªãããã®ããã
ããã®ããªã¢ããã®ç©ççããã³é»æ°çæ§è³ªããŸ
ãäžå åã§ãããããã«ãŸãããããã®ããªã¢ã
ãã¯ã沞ç¹æ°Žäžã§éæ床ãæ¥éã«å€±ãªãããã®ç
æç©ã®ã¬ã©ã¹è»¢ç§»æž©åºŠã湿床ã«å€§ããå·Šå³ãã
ãã 以äžã®çç±ã«ãããæ¬çºæã®ç®çã¯ãåžæ°Žæ§ã
äœããèå æ°Žå解æ§ãå¢å ãã湿床ååšäžã§ã®å¯ž
æ³å®å®æ§ãé«ããããã«ãšããªããç©ççããã³
ç¹ã«é»æ°çæ§è³ªãæ¹è¯ããããéæã§èç ®æ²žæ§ã®
æ°èŠããªã¢ãããæäŸããããšã«ããã æ¬çºæã®æ°èŠããªã¢ããã¯ã25âã«ããã0.5
ïŒ ããªã¢ããã®ïœâã¯ã¬ãŸãŒã«æº¶æ¶²ãšããŠæž¬å®ã
ãå Žåãå°ãªããšã0.4dlïŒïœã奜ãŸããã¯0.4
dlïŒïœãªããçŽïŒdlïŒïœããã奜ãŸããã¯çŽ0.6
dlïŒïœããçŽïŒdlïŒïœã®æç®æ¯ç²åºŠãæãããã
㊠äžè¬åŒïŒ ãåŒäžã X1ã¯æ¬¡åŒïŒ ïŒåŒäžã R1ãšR3ã¯äºãã«ç¬ç«ããŠããããæ°ŽçŽ ååãŸ
ãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šã
ããR2ãšR4ã¯äºãã«ç¬ç«ããŠããããççŽ åå
æ°ïŒãªãã12ã®ã¢ã«ãã«åºãè¡šãããïŒã®åºãè¡š
ãããã ã§è¡šããããç¹°è¿ãæ§é åäœãæããå Žåã«ãã€
ãŠã¯ äžè¬åŒïŒ ãåŒäžã X2ã¯æ¬¡åŒïŒ ïŒåŒäžã R5ãšR7ã¯äºãã«ç¬ç«ããŠãããããççŽ åå
æ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šãããR6ãšR8ã¯
äºãã«ç¬ç«ããŠãããããççŽ ååæ°ïŒãªãã10
ã®ã¢ã«ãã«åºãè¡šãããããããã¯R3ãšR6ãã
ã³ïŒãŸãã¯R7ãšR8ã¯ãããçãçµåããŠããç
çŽ ååãšäžç·ã«ãªã€ãŠççŽ ååæ°ïŒãªãã12ã®ã·
ã¯ãã¢ã«ãã«åºãè¡šãããïŒã®åºãè¡šãããã ã§è¡šããããç¹°è¿ãæ§é åäœãæããäžè¬åŒã
ãã³äžè¬åŒã«ãããŠãåã ã®å Žåãååšããå š
ãã³ãŒã³ãžã«ã«ãã³é žåºã«å¯ŸããŠã«ã«ããã«åºã
ãã®ãã³ãŒã³ç°ã®ïŒïŒïŒâéšäœã«ã100ãªãã50
ã¢ã«ïŒ ãïŒïŒïŒâéšäœã«ïŒãªãã50ã¢ã«ïŒ ã®å²å
ã§çµåãããžã¢ãã³æåã¯ååšããå šãžã¢ãã³æ
åã«å¯ŸããŠãåŒâNHâX1âNHâã§è¡šãããã
æåã100ãªãã25ã¢ã«ïŒ ãå ããåŒâNHâX2
âNHâã§è¡šããããæåããïŒãªãã75ã¢ã«ïŒ
ãå ãããŸããžã¢ãã³æåâNHâX1âNHâã®
ã¢ã«ïŒ ã§è¡šããããéã¯ãã¬ãã¿ã«é žæåéãšç
éããã以äžã§ããããšãããªããR1ãªããR8
ã®åºã§è¡šããããã¢ã«ãã«åºã¯çŽéã§ãæåãé
ã§ãè¯ãããçŽéã®æ¹ã奜ãŸãããããã«å®çŸ©ã
ããã¢ã«ãã«åºã®äŸãšããŠã¯ãã¡ãã«ïŒãšãã«ïŒ
ïœâãããã«ïŒã€ãœãããã«ïŒïœâããã«ïŒç¬¬ïŒ
ããã«ïŒïœâãã³ãã«ïŒïœâããã·ã«ïŒïœâãªã¯
ãã«ïŒïœâãã·ã«ïŒïœâãŠã³ãã·ã«ïŒããã³ïœâ
ããã·ã«ã®ååºãããããããR5ãšR6ãããã¯
R7ãšR8ãããããã®çµåããŠããççŽ ååãšäž
ç·ã«ãªã€ãŠåœ¢æããã·ã¯ãã¢ã«ãã«ç°ã¯ãäŸãã°
ã·ã¯ããã³ãã«ïŒã·ã¯ãããã·ã«ïŒã·ã¯ããªã¯ã
ã«ãŸãã¯ã·ã¯ãããã·ã«ã®ç°ã§ããã R1ãšR3ã®å¯ŸãR2ãšR4ã®å¯Ÿããªãã³ã«R5ãšR7ã®
察ã®åã ã«ãããŠã察ããªã眮æåºã¯å¥œãŸããã¯
åäžã®åºãè¡šããããŸãã¯R5ãšR6ãªãã³ã«R7ãš
R8ã®å¯Ÿã¯åã ããããããçµåããŠããççŽ å
åãšäžç·ã«ãªã€ãŠãåäžã®ã·ã¯ãã¢ã«ãã«åºã圢
æããŠããäºã奜ãŸããã 奜ãŸããããªã¢ãããšããŠã¯ãR1ãšR3ããã
ããæ°ŽçŽ ååãè¡šãããR2ãšR4ãããããççŽ
ååæ°ïŒãªããïŒç¹ã«ïŒãªããïŒã®ã¢ã«ãã«åºã
è¡šãããããããã¯R1ãšR3ãããããã¡ãã«åº
ãè¡šãããR2ãšR4ã®ãããããççŽ ååæ°ïŒãª
ããïŒç¹ã«ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šããã
R5ãšR7ã®ããããããççŽ ååæ°ïŒãªããïŒã®
ã¢ã«ãã«åºãè¡šãããR6ãšR8ã®ãããããççŽ
ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šããããŸãã¯
R5ãšR6ããã³R7ãšR8ã®ããããããããã®çµå
ããŠããççŽ ååãšäžç·ã«ãªã€ãŠãã·ã¯ããã³ã
ã«åºãŸãã¯ã·ã¯ãããã·ã«åºã圢æããŠããåå
ç©ããããããã æã奜ãŸããããªã¢ããã¯ãR1ãšR3ãããã
ãæ°ŽçŽ ååããR2ãšR4ãããããã¡ãã«åºãŸã
ã¯ãšãã«åºããã³ç¹ã«ïœâãããã«åºãŸãã¯ïœâ
ããã«åºãè¡šãããäžè¬åŒã®æ§é ã®ç¹°è¿ãåäœ
ã®ã¿ããæ§æãããããªã¢ããã§ããã æ¬çºæã®ä»ã®å¥œãŸããããªã¢ããã¯ã以äžã«ç€º
ãäžçš®é¡ã®ç¹å¥ãªçµæãæã€ãã®ã§ããã (1) åŒïŒ ã®ç¹°è¿ãæ§é åäœãããªãã奜ãŸããã¯çŽïŒ
dlïŒïœã®æç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸ
ãŒã«äžã«0.5ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæãã
ããªã¢ããã (2) åŒïŒ ã®ç¹°è¿ãæ§é åäœãããªãã奜ãŸããã¯çŽïŒ
dlïŒïœã®æç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸ
ãŒã«äžã«0.5ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæãã
ããªã¢ããã (3) åŒïŒ ã®ç¹°è¿ãæ§é åäœãããªãã奜ãŸããã¯çŽïŒ
dlïŒïœã®æç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸ
ãŒã«äžã«0.5ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæãã
ããªã¢ããã æ¬çºæã®ããªã¢ããã¯ãã¬ãã¿ã«é žãŸãã¯ãã®
ã¢ãã圢ææ§èªå°äœ100ãªãã50ã¢ã«ïŒ ãšãã€ãœ
ãã¿ã«é žãŸãã¯ãã®ã¢ãã圢ææ§èªå°äœïŒãªãã
50ã¢ã«ïŒ ãã åŒïŒ H2NâX1âNH2 ïŒïŒ ïŒåŒäžãX1ã¯åŒã«å®çŸ©ãããã®ãšåããïŒã§
è¡šãããããžã¢ãã³100ãªãã25ã¢ã«ïŒ ãš åŒïŒ H2NâX2âNH2 ïŒïŒ ïŒåŒäžãX2ã¯åŒã«å®çŸ©ãããã®ãšåããïŒã§
è¡šãããããžã¢ãã³ïŒãªãã75ã¢ã«ïŒ ãšããåŒ
ã§è¡šãããããžã¢ãã³ã®ã¢ã«ïŒ ã§è¡šããããé
ãããã¬ãã¿ã«é žãŸãã¯ãã®ã¢ãã圢ææ§èªå°äœ
ãšåéãããã¯ãã以äžã«ããŠåå¿ãããŠåŸãã
ãããã¬ãã¿ã«é žãŸãã¯ã€ãœãã¿ã«é žã®ã¢ãã圢
ææ§èªå°äœãšããŠã¯ãäŸãã°çžåœãããžãã©ã€
ããç¹ã«ãžã¯ãã©ã€ãããžãããªã«ããžã¢ã«ãã«
ãŸãã¯ãžã¢ãªã«ãšã¹ãã«ããšãããåã¢ã«ãã«éš
åã«ïŒãªããïŒã®ççŽ ååãæãããžã¢ã«ãã«ãš
ã¹ãã«ãããã³ãžããšãã«ãšã¹ãã«ã䜿çšããã
ãšãã§ããã æ¬çºæã®ããªã¢ããã¯ã奜ãŸããã¯æ°æ®µéã®æº¶
èéçž®ååå¿éçšã«ãã€ãŠåŸãããããã®éçšã«
ãããŠæ±ºããããå²åã®åå¿äœãããªãã¡å¥œãŸã
ãã¯ã€ãœãã¿ã«é žããã³ïŒãŸãã¯ãã¬ãã¿ã«é žã
ãã³åŒã«ããè¡šãããããžã¢ãã³ãããªãå¡©ã
ãã³ãå Žåã«ãã€ãŠã¯ã€ãœãã¿ã«é žããã³ïŒãã
ãã¯ãã¬ãã¿ã«é žããã³åŒã«ããè¡šãããããž
ã¢ãã³ãããªãå¡©ã溶èç¶æ ã§çŽ220âãªãã300
âã®éã®æž©åºŠã§ããã奜ãŸããã¯çªçŽ ã®æ§ãªäžæŽ»
æ§æ°äœé°å²æ°äžã§å å§ããªããåæçž®åãããã
åæçž®åã«çšããããå¡©ã¯ãå®è³ªçã«ååŠéè«ç
å²åã®ã€ãœãã¿ã«é žããã³ïŒãããã¯ãã¬ãã¿ã«
é žããã³åŒã«ããè¡šãããããžã¢ãã³ããŸãã¯
ã€ãœãã¿ã«é žããã³ïŒãããã¯ãã¬ãã¿ã«é žãã
ã³åŒããè¡šãããããžã¢ãã³ãããé©åœãªäžæŽ»
æ§ææ©æº¶åªäžã§åã ã«éœåè¯ãåæããããé©åœ
ãªäžæŽ»æ§ææ©æº¶åªãšã¯ãäŸãã°ã·ã¯ããã³ã¿ããŒ
ã«ãã·ã¯ããããµããŒã«ã®æ§ãªèç°åŒã¢ã«ã³ãŒã«
ããã³ç¹ã«ã¡ã¿ããŒã«ïŒãšã¿ããŒã«ïŒïœâããã
ããŒã«ïŒãã¿ããŒã«ïŒãã³ã¿ããŒã«ïŒãããµããŒ
ã«çã®æ§ã«ãççŽ ååæ°ïŒä»¥äžã®èèªæã¢ã«ã³ãŒ
ã«ãããã³ä»¥äžã«ããã溶åªãšæ°Žã®æ··åç©ãã
ããç¶ããŠåæçž®åç©ããçŽ220âãã300âã®é
ã®æž©åºŠåžžå§äžã§ããã奜ãŸããã¯ãã®å ŽåãäžæŽ»
æ§æ°äœé°å²æ°äžã§ãããªã¢ããã圢æããããŸã§
æŽã«çž®ååå¿ããããããå Žåã«ã¯ããªã¢ããã®
ã¬ã¹ãè¿œãåºããããéçž®åã®çµäºæã«æžå§åŠç
ãè¡ãªããšå¥œçµæãåŸãããã æ¬çºæã®ããªã¢ããã¯ãåŒããã³ïŒãŸãã¯åŒ
ã«ããè¡šãããããžã¢ãã³ããå®è³ªçã«ååŠé
è«çéã®æŽ»æ§åãããã¬ãã¿ã«é žãšã¹ãã«ãšå Žå
ã«ãã€ãŠã¯ã€ãœãã¿ã«é žãšã¹ãã«ãšæº¶èéçž®åã
ããããšã«ãã€ãŠãåŸãããã 掻æ§åãããšã¹ãã«ã®é©åœãªãã®ãšããŠã¯ãç¹
ã«ããããã®ãžããšãã«ãšã¹ãã«ããããããã äžè¬ã«åå¿æž©åºŠã¯ãçŽ230âãã300âã®éã®ç¯
å²ã§ããã æåŸã«æ¬çºæã®ããªã¢ããã¯ã溶èéçž®åãã
ãã¯çé¢éçž®åãšããŠç¥ãããŠããæ¹æ³ã«ãã€ãŠ
ãåŸãããšãã§ããã åŒããã³åŒã«ããè¡šãããããžã¢ãã³ã¯ã
å ¬ç¥ã§ãããå ¬ç¥ã®æ¹æ³ãäŸãã°äžæŽ»æ§ææ©æº¶åª
ã®ååšäžã§ãïŒïŒ12âéšäœãåŒããã³åŒã«å¿
ããŠçœ®æããïŒïŒïŒâãžã¢ã¶âïŒïŒïŒïŒïŒâã·ã¯
ãããã«ããªãšã³ãŸãã¯ïŒïŒïŒâãžã¢ã¶âã·ã¯ã
ããã«ã³ãæ¥è§Šéå ããããšã«ããã調補ããã
ãšãã§ããã æ¬çºæã®ããªã¢ããã¯ãç¡è²éæãªå€èŠ³ãå
ãã沞隰氎ã«èæ§ã瀺ããå®è³ªçã«æ¹¿åºŠã«ç¡é¢ä¿
ãªé«ãã¬ã©ã¹è»¢ç§»æž©åºŠãšãããæ¹è¯ãããç©ç
çãç¹ã«é»æ°çæ§è³ªãšåæã«ãäœãåžæ°Žæ§ãè¯å¥œ
ãªèå æ°Žå解æ§ããã³ïŒãããã¯ã湿床ã®ååšäž
ã§ã®è¯å¥œãªå¯žæ³å®å®æ§ãæããäºãç¹ã«ç¹åŸŽãšã
ãŠãããæ¬ããªã¢ããã¯ãäŸãã°å°åºæ圢æ³ãã
ãã¯æŒåºæ³ãšããŠç¥ãããŠããæ¹æ³ã«ãããéåžž
ã«åºç¯ãªçš®é¡ã®éææ圢åã«å å·¥ããããšãã§ã
ããæ¬çºæã以äžã®å®æœäŸã«åºããŠèª¬æããã å®æœäŸ ïŒ æ°Ž120mlããã³ãšã¿ããŒã«400mlæ··å液äžã«ãã¬
ãã¿ã«é ž16.6ïœãå ããæ¹æè£ çœ®ã滎äžæŒæãã
ã³éæµå·åŽè£ 眮ãåããäžžåºãã©ã¹ã³äžã§ãæ¹æ
ãã€ã€50âã«å ç±ããã滎äžæŒæããïŒïŒ15âãž
ã¢ãããšã€ã³ãµã³31.26ïœã滎å ããçããæ··å
ç©ãPHãçŽ7.5ã«ãªããŸã§éæµããïŒçŽïŒæéã
èŠãããïŒã次ã«åå¿æ··ååç©ãïŒâã«å·åŽããç
ããå¡©ãå¥ããŠéã80âã§ç空也ç¥ãããåç
ã¯46ïœã§çè«éã®97ïŒ ã§ãã€ãã åŸãããå¡©15ïœããçªçŽ é°å²æ°äžã§èå§å®¹åš
ïŒbomb tubeïŒäžã«è解ã280âã«å ç±ãããïŒæ
éåŸæº¶èç©ãå·åŽããåºåããåæçž®åç©ã容åš
ããåãåºãçªçŽ å°å ¥æ段ãåããçž®ååå¿ç®¡äž
ã«ç§»ãããåæçž®åç©ãçªçŽ é°å²æ°äžã§270âã§
è解ããçªçŽ ãéããªãã10æéãã®æž©åºŠã«ä¿ã€
ãããã®æº¶è§£ç©ãå·åŽãããšãåºåããŠç¡è²éæ
ã®åºãŸããšãªã€ããçããããªã¢ãããã25âã«
ãŠïœâã¯ã¬ãŸãŒã«ã®0.5ïŒ ããªã¢ãã溶液ãšããŠ
枬å®ããæç®æ¯ç²åºŠã¯ã0.96dlïŒïœã§ãã€ããã
ã®ããªã¢ãããé»æ°çã«å ç±ããæ²¹å§æ©ã«ããã
250âã§å å§ãïŒæã®ã·ãŒãã«ãããã·ãŒãïŒã¯
也ç¥æ¡ä»¶äžã«ãã·ãŒãïŒã¯å®€æž©ïŒ20âãªãã25
âïŒã§65ïŒ çžå¯Ÿæ¹¿åºŠæ¡ä»¶äžã«ãããã«ã·ãŒãïŒã¯
æ°Žäžã«ä¿åãããïŒé±éåŸã·ãŒãïŒã¯0.4ééïŒ
ã®æ°Žããã·ãŒãïŒã¯0.6ééïŒ ã®æ°Žãåžåããã
ããã«é·æéä¿åããåŸããäžèšã®æ¡ä»¶ã§ãã以
äžã®æ°Žååžåã¯èªããããªãã€ããäžèšã®åŠçã®
åŸã·ãŒãïŒãªããïŒã®ã¬ã©ã¹è»¢ç§»æž©åºŠã瀺差ç±å
ææ³ã«ãã枬å®ãã以äžã®å€ãåŸãã ã·ãŒãïŒïŒ126âãã·ãŒãïŒïŒ114âã ã·ãŒãïŒïŒ114âã å®æœäŸïŒãªããïŒ ãã¬ãã¿ã«é žãšããã§å®çŸ©ãããžã¢ãã³ããåŸ
ãããä»ã®ããªã¢ããããå®æœäŸïŒã«èšèŒããæ¹
æ³ã§äœããã·ãŒãã«ããã å®æœäŸïŒãªããïŒã§ã¯ããã¬ãã¿ã«é žãšçš®ã ã®
ãžã¢ãã³ãããªãïŒçš®é¡ã®å¡©ã®æ··åç©ã䜿çšãã
éçž®åãããŠãããããã®å ±éåã¢ããã«ããã
䜿çšããåå¿ææããã³ãåå¿ã«ããåŸãããã
ãªã¢ããã®æ§è³ªïŒå®æœäŸïŒã«èšèŒããæ¹æ³ã§æž¬
å®ïŒã¯è¡šïŒã«ç€ºãã å®æœäŸ ïŒ 10ïŒ19âãžã¢ãããªã¯ã¿ã³ãµã³4.183ïœããã³
ãžããšãã«ãã¬ãã¿ã¬ãŒã3.071ïœããçªçŽ å°å ¥
æ段ãåããçž®ååå¿ç®¡äžã«å ¥ããçªçŽ é°å²æ°äž
ã§220âã«ïŒæéä¿ã€ãã次ã«æž©åºŠãåŸã ã«250â
ã«äžæããããïŒæéåŸç空åŠçãæœããããã
å解ããããšããŒã«ã¯ïŒæéãããŠçå»ãããå·
åŽã«ãã溶解ç©ã¯åºåãç¡è²éæãªåºãŸããšãªã€
ããåŸãããããªã¢ããã¯25âã«ãŠïœâã¯ã¬ãŸãŒ
ã«ã®0.5ïŒ ããªã¢ãã溶液ãšããŠæž¬å®ããå Žåã
æç®æ¯ç²åºŠã0.53dlïŒïœã§ãã€ããã¬ã©ã¹è»¢ç§»æž©
床ã¯112âã65ïŒ çžå¯Ÿæ¹¿åºŠå®€æž©æ¡ä»¶äžã§ã®ïŒé±é
åŸã®åžæ°Žéã¯0.3ééïŒ ã§ãã€ãã å®æœäŸ ïŒ ãžããšãã«ã»ãã¬ãã¿ã¬ãŒããã12ïŒ21âãžã¢
ãããããªã¢ã³ã³ã¿ã³ãšå®æœäŸïŒã«èšèŒããæ¹æ³
ã§åå¿ããããåŸãããããªã¢ããã®æ§è³ªã¯ãå®
æœäŸïŒã§èª¿è£œããããªã¢ããã®æ§è³ªãšå®è³ªçã«å
æ§ã§ãã€ãã å®æœäŸ 10 ãžããšãã«ã»ãã¬ãã¿ã¬ãŒãããååŠéè«çé
ã®ïŒïŒ13âãžã¢ããâïŒïŒ15âãžã¡ãã«ãããµã
ã«ã³ãšå®æœäŸïŒã«èšèŒããæ¹æ³ã§åå¿ããããåŸ
ãããããªã¢ããã®æ§è³ªã¯è¡šïŒã«ç€ºãã å®æœäŸ 11 ãã¬ãã¿ã«é ž11.72ïœãããšã¿ããŒã«250mlãšæ°Ž
90mlã®æ··åç©ã«å ããæ¹æè£ çœ®ãéæµå·åŽè£ 眮ã
ãã³æ»ŽäžæŒæãåããåå¿å®¹åšäžã§éæµãéå§ã
ã枩床ã«å ç±ãã次ãã§ïŒïŒ10âãžã¢ããâïŒïŒ
10âãžã·ã¯ãããã·ã«ãã«ã³24ïœã滎äžæŒæãã
滎å ãããåå¿æ··åç©ãéæµãã€ã€48æéæ¹æ
ãã次ãã§å®€æž©ïŒ20âãªãã25âïŒã«å·åŽããã
çããå¡©ãå¥ããŠéãã100âã§ç空也ç¥ã
ããåçã¯34.8ïœã§çè«éã®98ïŒ ã§ãã€ããåŸã
ããå¡©7.5ïœãšãã¬ãã¿ã«é žãšïŒïŒ13âãžã¢ãã
ãããµãã«ã³ãããªãå¡©ïŒå®æœäŸïŒã®æ¹æ³ã«åŸã€
ãŠèª¿è£œããïŒ7.5ïœãæ··åããŠèå§å®¹åšã«å ¥ãã
çªçŽ é°å²æ°äžã§æº¶èããããã®å¡©ã®æ··åç©ã280
âã§æº¶èããïŒæéãã®æž©åºŠã«ä¿ã€ããåæçž®å
ç©ãå·åŽãã次ãã§çž®ååå¿å®¹åšã«ç§»ãé£ç¶çã«
çªçŽ ãéããªããã溶èç¶æ ã§280âïŒæééçž®
åããããå·åŽã«ããå ±éåã¢ãããåºåããç¡
è²éæãªåºãŸããšãªã€ããåŸãããå ±éåã¢ãã
ããæ²¹å§æ©ã«ãã280âã§åã0.2mmã®ã·ãŒããšã
ãããã®å ±éåã¢ããã®æ§è³ªã¯ã第ïŒè¡šã«ç€ºãã å®æœäŸ 12 å®æœäŸ11ã«èšèŒããäŸãšåæ§ã«ããŠãåå®æœäŸ
ã®ç¬¬ïŒæ®µç®ã®åå¿ã«ããåŸãããå¡©ïŒïœãšããã¬
ãã¿ã«é žãšïŒïŒ16âãžã¢ãããã³ãµã³ãããªãå¡©
ïŒå®æœäŸïŒã®æ¹æ³ã«åŸã€ãŠèª¿è£œããïŒïŒïœãéçž®
åããã·ãŒãç¶ã«ãã¬ã¹ãããåŸãããå ±éåã¢
ããã®æ§è³ªã¯ãè¡šïŒã«ç€ºãã å®æœäŸ 13 ïŒïŒ12âãžã¢ããâïŒïŒ13âãžã¡ãã«ããã©ã
ã«ã³11.83ïœããæ¹æè£ çœ®ãåããããŒã«ãŒäžã§
ãšã¿ããŒã«150mlã«æº¶èãã溶液ã50âã«å ç±ã
ãããã®æº¶æ¶²ã«ã€ãœãã¿ã«é ž7.66ïœãäžåºŠã«å
ããããŒã«ãŒããšã¿ããŒã«30mlã§ãããã ãçºç±
åå¿ã«ç¶ããŠæº¶æ¶²ãåŸããããå·åŽã«ããåå¿æ··
å液ããå¡©ãæ²æŸ±ãããæ²æŸ±ãå¥ããŠéãã90
âã§ç空也ç¥ãããåçã¯15.8ïœã§çè«éã®81ïŒ
ã§ãã€ããçããå¡©ïŒïœãšããã¬ãã¿ã«é žãšïŒïŒ
14âãžã¢ãããªã¯ã¿ãã«ã³ãããªãå¡©ïŒå®æœäŸïŒ
ã®æ¹æ³ã«åŸã€ãŠèª¿è£œããïŒïŒïœãæ··åããèå§å
å¿å®¹åšäžã§270âïŒæéåæçž®åããããéçž®å
ã¯çž®ååå¿å®¹åšäžã§çªçŽ ãéãã€ã€270âïŒæé
è¡ãªããããåŸãããç¡è²éæã®åºãŸãããæ²¹å§
æ©ã«ãã270âã§ãã¬ã¹ããŠã·ãŒãã«ãããå ±é
åã¢ããã®æ§è³ªã¯è¡šïŒã«ç€ºãã å®æœäŸ 14 ã€ãœãã¿ã«é ž12.27ïœã沞隰ãšã¿ããŒã«380mläž
ã«æº¶è§£ãããïŒïŒ10âãžã¢ããâïŒïŒ10âãžã·ã¯
ãããã·ã«ãã«ã³25ïœãïŒåºŠã«å ããããã«ãšã¿
ããŒã«75mlãå ãããæ°ç§åŸã«å¡©ãæ²æ®¿ãããå
å¿æ··åç©ãïŒâã«å·åŽããå¡©ãå¥ããŠéã100
âã§ç空也ç¥ãããåçã¯36.1ïœã§çè«éã®97ïŒ
ã§ãã€ãããã®å¡©ïŒïœãšããã¬ãã¿ã«é žãšïŒïŒ15
âãžã¢ãããšã€ã³ãµã³ãããªãå¡©ïŒå®æœäŸïŒã®æ¹
æ³ã«åŸã€ãŠèª¿è£œããïŒïŒïœããå®æœäŸ13ã«èšèŒã
ãæ¡ä»¶ã§éçž®åããŠå ±éåã¢ãããšãã次ãã§é
æã·ãŒãã«å å·¥ãããåŸãããå ±éåã¢ããã®æ§
質ã¯ãè¡šïŒã«ç€ºãã å®æœäŸ 15 ãã¬ãã¿ã«é ž13.98ïœããæ°Ž100mlãšãšã¿ããŒã«
340mlã®æ··åç©äžã«å ããæ¹æè£ çœ®ãéæµå·åŽç®¡
ããã³æ»ŽäžæŒæãåããåå¿å®¹åšäžã§ã60âã«å
ç±ãã次ãã§ïŒïŒ14âãžã¢ããâïŒïŒ15âãžã¡ã
ã«ãªã¯ã¿ãã«ã³26.3ïœãå ãããæžæ¿æ¶²ãéæµã
ã€ã€ãPHãçŽ7.5ã«ãªããŸã§æ¹æããïŒçŽïŒæé
èŠãããïŒã宀枩ã«å·åŽåŸãå¡©ãå¥ããŠéã90â
ã§ç空也ç¥ãããåçã¯38.3ïœã§çè«éã®95ïŒ ã§
ãã€ãããã®å¡©ïŒïœãããã¬ãã¿ã«é žãšïŒïŒ14â
ãžã¢ãããªã¯ã¿ãã«ã³ãããªãå¡©ïŒå®æœäŸ13ã®æ¹
æ³ã«åŸã€ãŠèª¿è£œããïŒïŒïœãšæ··åããæ··åç©ãå®
æœäŸ13ã«èšèŒããæ¡ä»¶äžã§éçž®åããå ±éåã¢ã
ããšãããåŸãããå ±éåã¢ããã®æ§è³ªã¯è¡šïŒã«
瀺ãã
ããã³ãã®æ圢å補é ã®ããã®çšéã«é¢ããã ãã€ãç¹èš±æ现æžç¬¬745029å·ã«ã第ïŒçŽãŸãã¯
第ïŒçŽã®èèªæãè³éŠæã¢ããã«ã«ãã³é žãããª
ã«ãããã¯èèªæãŸãã¯è³éŠæãžãããªã«æ··åç©
ãšçŽçéã®ç¬¬ïŒçŽãŸãã¯ç¬¬ïŒçŽãžã¢ãã³ããå å§
äžã§æ°Žã®ååšãšãšãã«150âãªãã300âã«å ç±ã
ãããšã«ãããé«ååããªã¢ããã®è£œé æ¹æ³ãé
瀺ãããŠããã é©åœãªãžã¢ãã³ãšããŠã¯ãç¹ã«ïŒïŒ10âãžã¢ã
ãâïŒïŒ10âãžã¡ãã«ãã«ã³ããããããŠããã
ãã©ã³ã¹ç¹èš±æ现æžç¬¬867384å·ã«ããã°ãäŸãã°
ïŒïŒ®âãžãã«ãã«âïŒïŒ10âãžã¡ãã«âïŒïŒ10
âãžã¢ãããã«ã³ã®æ§ãªãã«ã ã¢ããããŸããã
ãªã¢ãã補é ã®ããã®éçž®åææãšããŠäœ¿çšã§ã
ããæåŸã«ããã€ãå ¬éå ¬å ±ç¬¬1720513å·ã§ã¯ã
è³éŠæãžã«ã«ãã³é žãšãé眮æãããã¯äž¡ç«¯ã®ç
çŽ ã®ãã¡å°ããšãïŒåãççŽ ååæ°ïŒãªããïŒã®
ã¢ã«ãã«åºã§ã¢ã«ãã«çœ®æãããéå ã«ïŒãªãã
10åã®ççŽ ååãå«ãã¢ã«ãã¬ã³ãžã¢ãã³ããåŸ
ãããäžè¬çã«èç ®æ²žæ§ã®éæããªã¢ãããèšèŒ
ããŠããã ããããªããããã®å ¬éå ¬å ±ã®å ·äœçé瀺ã¯ã
è³éŠæãžã«ã«ãã³é žãšéäžã«ççŽ ååãïŒå以äž
ã¯å«ãŸãªãäžèšã®çš®é¡ã®ã¢ã«ãã¬ã³ãžã¢ãã³ãã
åŸãããéæããªã¢ããã«éå®ãããŠãããè³éŠ
æãžã«ã«ãã³é žãŸãã¯ãã®èªå°äœãšãïŒïŒ10âãž
ã¢ã«ãã«â眮æïŒïŒ10âãžã¢ããããã«ã³ããåŸ
ãããããªã¢ããã®äŸã«ã€ããŠã¯ã以äžã«æ²ãã
ãã®ä»ã®ãã¥ãã®åèæç®ã«ãæèšãããŠããª
ãã è³éŠæãžã«ã«ãã³é žãšãã®èªå°äœãããã³é眮
æãŸãã¯ã¢ã«ãã«çœ®æé·éãžã¢ãã³ããåŸããã
ããªã¢ãããããªãã¡ããã«ç€ºããåŸæ¥ã®æè¡æ
ç®ã«ç€ºãããŠããããªã¢ããã䞊ã³ã«ãããã¬ã
ãïŒTrogamid ïŒããªãåæšã§ç¥ããããã
ã¬ãã¿ã«é žãšïŒïŒïŒïŒïŒâããã³ïŒïŒïŒïŒïŒâã
ãªã¡ãã«ãããµã¡ãã¬ã³ãžã¢ãã³ã®ç°æ§äœæ··åç©
ããåŸãããçž®åçæç©ã¯ãåžæ°Žæ§ãèå æ°Žå解
æ§ããã³ïŒãŸãã¯æ¹¿åºŠååšäžã§ã®å¯žæ³å®å®æ§ç
ããå®å šã«æºè¶³ãã¹ããã®ã§ã¯ãªãããã®ããã
ããã®ããªã¢ããã®ç©ççããã³é»æ°çæ§è³ªããŸ
ãäžå åã§ãããããã«ãŸãããããã®ããªã¢ã
ãã¯ã沞ç¹æ°Žäžã§éæ床ãæ¥éã«å€±ãªãããã®ç
æç©ã®ã¬ã©ã¹è»¢ç§»æž©åºŠã湿床ã«å€§ããå·Šå³ãã
ãã 以äžã®çç±ã«ãããæ¬çºæã®ç®çã¯ãåžæ°Žæ§ã
äœããèå æ°Žå解æ§ãå¢å ãã湿床ååšäžã§ã®å¯ž
æ³å®å®æ§ãé«ããããã«ãšããªããç©ççããã³
ç¹ã«é»æ°çæ§è³ªãæ¹è¯ããããéæã§èç ®æ²žæ§ã®
æ°èŠããªã¢ãããæäŸããããšã«ããã æ¬çºæã®æ°èŠããªã¢ããã¯ã25âã«ããã0.5
ïŒ ããªã¢ããã®ïœâã¯ã¬ãŸãŒã«æº¶æ¶²ãšããŠæž¬å®ã
ãå Žåãå°ãªããšã0.4dlïŒïœã奜ãŸããã¯0.4
dlïŒïœãªããçŽïŒdlïŒïœããã奜ãŸããã¯çŽ0.6
dlïŒïœããçŽïŒdlïŒïœã®æç®æ¯ç²åºŠãæãããã
㊠äžè¬åŒïŒ ãåŒäžã X1ã¯æ¬¡åŒïŒ ïŒåŒäžã R1ãšR3ã¯äºãã«ç¬ç«ããŠããããæ°ŽçŽ ååãŸ
ãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šã
ããR2ãšR4ã¯äºãã«ç¬ç«ããŠããããççŽ åå
æ°ïŒãªãã12ã®ã¢ã«ãã«åºãè¡šãããïŒã®åºãè¡š
ãããã ã§è¡šããããç¹°è¿ãæ§é åäœãæããå Žåã«ãã€
ãŠã¯ äžè¬åŒïŒ ãåŒäžã X2ã¯æ¬¡åŒïŒ ïŒåŒäžã R5ãšR7ã¯äºãã«ç¬ç«ããŠãããããççŽ åå
æ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šãããR6ãšR8ã¯
äºãã«ç¬ç«ããŠãããããççŽ ååæ°ïŒãªãã10
ã®ã¢ã«ãã«åºãè¡šãããããããã¯R3ãšR6ãã
ã³ïŒãŸãã¯R7ãšR8ã¯ãããçãçµåããŠããç
çŽ ååãšäžç·ã«ãªã€ãŠççŽ ååæ°ïŒãªãã12ã®ã·
ã¯ãã¢ã«ãã«åºãè¡šãããïŒã®åºãè¡šãããã ã§è¡šããããç¹°è¿ãæ§é åäœãæããäžè¬åŒã
ãã³äžè¬åŒã«ãããŠãåã ã®å Žåãååšããå š
ãã³ãŒã³ãžã«ã«ãã³é žåºã«å¯ŸããŠã«ã«ããã«åºã
ãã®ãã³ãŒã³ç°ã®ïŒïŒïŒâéšäœã«ã100ãªãã50
ã¢ã«ïŒ ãïŒïŒïŒâéšäœã«ïŒãªãã50ã¢ã«ïŒ ã®å²å
ã§çµåãããžã¢ãã³æåã¯ååšããå šãžã¢ãã³æ
åã«å¯ŸããŠãåŒâNHâX1âNHâã§è¡šãããã
æåã100ãªãã25ã¢ã«ïŒ ãå ããåŒâNHâX2
âNHâã§è¡šããããæåããïŒãªãã75ã¢ã«ïŒ
ãå ãããŸããžã¢ãã³æåâNHâX1âNHâã®
ã¢ã«ïŒ ã§è¡šããããéã¯ãã¬ãã¿ã«é žæåéãšç
éããã以äžã§ããããšãããªããR1ãªããR8
ã®åºã§è¡šããããã¢ã«ãã«åºã¯çŽéã§ãæåãé
ã§ãè¯ãããçŽéã®æ¹ã奜ãŸãããããã«å®çŸ©ã
ããã¢ã«ãã«åºã®äŸãšããŠã¯ãã¡ãã«ïŒãšãã«ïŒ
ïœâãããã«ïŒã€ãœãããã«ïŒïœâããã«ïŒç¬¬ïŒ
ããã«ïŒïœâãã³ãã«ïŒïœâããã·ã«ïŒïœâãªã¯
ãã«ïŒïœâãã·ã«ïŒïœâãŠã³ãã·ã«ïŒããã³ïœâ
ããã·ã«ã®ååºãããããããR5ãšR6ãããã¯
R7ãšR8ãããããã®çµåããŠããççŽ ååãšäž
ç·ã«ãªã€ãŠåœ¢æããã·ã¯ãã¢ã«ãã«ç°ã¯ãäŸãã°
ã·ã¯ããã³ãã«ïŒã·ã¯ãããã·ã«ïŒã·ã¯ããªã¯ã
ã«ãŸãã¯ã·ã¯ãããã·ã«ã®ç°ã§ããã R1ãšR3ã®å¯ŸãR2ãšR4ã®å¯Ÿããªãã³ã«R5ãšR7ã®
察ã®åã ã«ãããŠã察ããªã眮æåºã¯å¥œãŸããã¯
åäžã®åºãè¡šããããŸãã¯R5ãšR6ãªãã³ã«R7ãš
R8ã®å¯Ÿã¯åã ããããããçµåããŠããççŽ å
åãšäžç·ã«ãªã€ãŠãåäžã®ã·ã¯ãã¢ã«ãã«åºã圢
æããŠããäºã奜ãŸããã 奜ãŸããããªã¢ãããšããŠã¯ãR1ãšR3ããã
ããæ°ŽçŽ ååãè¡šãããR2ãšR4ãããããççŽ
ååæ°ïŒãªããïŒç¹ã«ïŒãªããïŒã®ã¢ã«ãã«åºã
è¡šãããããããã¯R1ãšR3ãããããã¡ãã«åº
ãè¡šãããR2ãšR4ã®ãããããççŽ ååæ°ïŒãª
ããïŒç¹ã«ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šããã
R5ãšR7ã®ããããããççŽ ååæ°ïŒãªããïŒã®
ã¢ã«ãã«åºãè¡šãããR6ãšR8ã®ãããããççŽ
ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šããããŸãã¯
R5ãšR6ããã³R7ãšR8ã®ããããããããã®çµå
ããŠããççŽ ååãšäžç·ã«ãªã€ãŠãã·ã¯ããã³ã
ã«åºãŸãã¯ã·ã¯ãããã·ã«åºã圢æããŠããåå
ç©ããããããã æã奜ãŸããããªã¢ããã¯ãR1ãšR3ãããã
ãæ°ŽçŽ ååããR2ãšR4ãããããã¡ãã«åºãŸã
ã¯ãšãã«åºããã³ç¹ã«ïœâãããã«åºãŸãã¯ïœâ
ããã«åºãè¡šãããäžè¬åŒã®æ§é ã®ç¹°è¿ãåäœ
ã®ã¿ããæ§æãããããªã¢ããã§ããã æ¬çºæã®ä»ã®å¥œãŸããããªã¢ããã¯ã以äžã«ç€º
ãäžçš®é¡ã®ç¹å¥ãªçµæãæã€ãã®ã§ããã (1) åŒïŒ ã®ç¹°è¿ãæ§é åäœãããªãã奜ãŸããã¯çŽïŒ
dlïŒïœã®æç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸ
ãŒã«äžã«0.5ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæãã
ããªã¢ããã (2) åŒïŒ ã®ç¹°è¿ãæ§é åäœãããªãã奜ãŸããã¯çŽïŒ
dlïŒïœã®æç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸ
ãŒã«äžã«0.5ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæãã
ããªã¢ããã (3) åŒïŒ ã®ç¹°è¿ãæ§é åäœãããªãã奜ãŸããã¯çŽïŒ
dlïŒïœã®æç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸ
ãŒã«äžã«0.5ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæãã
ããªã¢ããã æ¬çºæã®ããªã¢ããã¯ãã¬ãã¿ã«é žãŸãã¯ãã®
ã¢ãã圢ææ§èªå°äœ100ãªãã50ã¢ã«ïŒ ãšãã€ãœ
ãã¿ã«é žãŸãã¯ãã®ã¢ãã圢ææ§èªå°äœïŒãªãã
50ã¢ã«ïŒ ãã åŒïŒ H2NâX1âNH2 ïŒïŒ ïŒåŒäžãX1ã¯åŒã«å®çŸ©ãããã®ãšåããïŒã§
è¡šãããããžã¢ãã³100ãªãã25ã¢ã«ïŒ ãš åŒïŒ H2NâX2âNH2 ïŒïŒ ïŒåŒäžãX2ã¯åŒã«å®çŸ©ãããã®ãšåããïŒã§
è¡šãããããžã¢ãã³ïŒãªãã75ã¢ã«ïŒ ãšããåŒ
ã§è¡šãããããžã¢ãã³ã®ã¢ã«ïŒ ã§è¡šããããé
ãããã¬ãã¿ã«é žãŸãã¯ãã®ã¢ãã圢ææ§èªå°äœ
ãšåéãããã¯ãã以äžã«ããŠåå¿ãããŠåŸãã
ãããã¬ãã¿ã«é žãŸãã¯ã€ãœãã¿ã«é žã®ã¢ãã圢
ææ§èªå°äœãšããŠã¯ãäŸãã°çžåœãããžãã©ã€
ããç¹ã«ãžã¯ãã©ã€ãããžãããªã«ããžã¢ã«ãã«
ãŸãã¯ãžã¢ãªã«ãšã¹ãã«ããšãããåã¢ã«ãã«éš
åã«ïŒãªããïŒã®ççŽ ååãæãããžã¢ã«ãã«ãš
ã¹ãã«ãããã³ãžããšãã«ãšã¹ãã«ã䜿çšããã
ãšãã§ããã æ¬çºæã®ããªã¢ããã¯ã奜ãŸããã¯æ°æ®µéã®æº¶
èéçž®ååå¿éçšã«ãã€ãŠåŸãããããã®éçšã«
ãããŠæ±ºããããå²åã®åå¿äœãããªãã¡å¥œãŸã
ãã¯ã€ãœãã¿ã«é žããã³ïŒãŸãã¯ãã¬ãã¿ã«é žã
ãã³åŒã«ããè¡šãããããžã¢ãã³ãããªãå¡©ã
ãã³ãå Žåã«ãã€ãŠã¯ã€ãœãã¿ã«é žããã³ïŒãã
ãã¯ãã¬ãã¿ã«é žããã³åŒã«ããè¡šãããããž
ã¢ãã³ãããªãå¡©ã溶èç¶æ ã§çŽ220âãªãã300
âã®éã®æž©åºŠã§ããã奜ãŸããã¯çªçŽ ã®æ§ãªäžæŽ»
æ§æ°äœé°å²æ°äžã§å å§ããªããåæçž®åãããã
åæçž®åã«çšããããå¡©ã¯ãå®è³ªçã«ååŠéè«ç
å²åã®ã€ãœãã¿ã«é žããã³ïŒãããã¯ãã¬ãã¿ã«
é žããã³åŒã«ããè¡šãããããžã¢ãã³ããŸãã¯
ã€ãœãã¿ã«é žããã³ïŒãããã¯ãã¬ãã¿ã«é žãã
ã³åŒããè¡šãããããžã¢ãã³ãããé©åœãªäžæŽ»
æ§ææ©æº¶åªäžã§åã ã«éœåè¯ãåæããããé©åœ
ãªäžæŽ»æ§ææ©æº¶åªãšã¯ãäŸãã°ã·ã¯ããã³ã¿ããŒ
ã«ãã·ã¯ããããµããŒã«ã®æ§ãªèç°åŒã¢ã«ã³ãŒã«
ããã³ç¹ã«ã¡ã¿ããŒã«ïŒãšã¿ããŒã«ïŒïœâããã
ããŒã«ïŒãã¿ããŒã«ïŒãã³ã¿ããŒã«ïŒãããµããŒ
ã«çã®æ§ã«ãççŽ ååæ°ïŒä»¥äžã®èèªæã¢ã«ã³ãŒ
ã«ãããã³ä»¥äžã«ããã溶åªãšæ°Žã®æ··åç©ãã
ããç¶ããŠåæçž®åç©ããçŽ220âãã300âã®é
ã®æž©åºŠåžžå§äžã§ããã奜ãŸããã¯ãã®å ŽåãäžæŽ»
æ§æ°äœé°å²æ°äžã§ãããªã¢ããã圢æããããŸã§
æŽã«çž®ååå¿ããããããå Žåã«ã¯ããªã¢ããã®
ã¬ã¹ãè¿œãåºããããéçž®åã®çµäºæã«æžå§åŠç
ãè¡ãªããšå¥œçµæãåŸãããã æ¬çºæã®ããªã¢ããã¯ãåŒããã³ïŒãŸãã¯åŒ
ã«ããè¡šãããããžã¢ãã³ããå®è³ªçã«ååŠé
è«çéã®æŽ»æ§åãããã¬ãã¿ã«é žãšã¹ãã«ãšå Žå
ã«ãã€ãŠã¯ã€ãœãã¿ã«é žãšã¹ãã«ãšæº¶èéçž®åã
ããããšã«ãã€ãŠãåŸãããã 掻æ§åãããšã¹ãã«ã®é©åœãªãã®ãšããŠã¯ãç¹
ã«ããããã®ãžããšãã«ãšã¹ãã«ããããããã äžè¬ã«åå¿æž©åºŠã¯ãçŽ230âãã300âã®éã®ç¯
å²ã§ããã æåŸã«æ¬çºæã®ããªã¢ããã¯ã溶èéçž®åãã
ãã¯çé¢éçž®åãšããŠç¥ãããŠããæ¹æ³ã«ãã€ãŠ
ãåŸãããšãã§ããã åŒããã³åŒã«ããè¡šãããããžã¢ãã³ã¯ã
å ¬ç¥ã§ãããå ¬ç¥ã®æ¹æ³ãäŸãã°äžæŽ»æ§ææ©æº¶åª
ã®ååšäžã§ãïŒïŒ12âéšäœãåŒããã³åŒã«å¿
ããŠçœ®æããïŒïŒïŒâãžã¢ã¶âïŒïŒïŒïŒïŒâã·ã¯
ãããã«ããªãšã³ãŸãã¯ïŒïŒïŒâãžã¢ã¶âã·ã¯ã
ããã«ã³ãæ¥è§Šéå ããããšã«ããã調補ããã
ãšãã§ããã æ¬çºæã®ããªã¢ããã¯ãç¡è²éæãªå€èŠ³ãå
ãã沞隰氎ã«èæ§ã瀺ããå®è³ªçã«æ¹¿åºŠã«ç¡é¢ä¿
ãªé«ãã¬ã©ã¹è»¢ç§»æž©åºŠãšãããæ¹è¯ãããç©ç
çãç¹ã«é»æ°çæ§è³ªãšåæã«ãäœãåžæ°Žæ§ãè¯å¥œ
ãªèå æ°Žå解æ§ããã³ïŒãããã¯ã湿床ã®ååšäž
ã§ã®è¯å¥œãªå¯žæ³å®å®æ§ãæããäºãç¹ã«ç¹åŸŽãšã
ãŠãããæ¬ããªã¢ããã¯ãäŸãã°å°åºæ圢æ³ãã
ãã¯æŒåºæ³ãšããŠç¥ãããŠããæ¹æ³ã«ãããéåžž
ã«åºç¯ãªçš®é¡ã®éææ圢åã«å å·¥ããããšãã§ã
ããæ¬çºæã以äžã®å®æœäŸã«åºããŠèª¬æããã å®æœäŸ ïŒ æ°Ž120mlããã³ãšã¿ããŒã«400mlæ··å液äžã«ãã¬
ãã¿ã«é ž16.6ïœãå ããæ¹æè£ çœ®ã滎äžæŒæãã
ã³éæµå·åŽè£ 眮ãåããäžžåºãã©ã¹ã³äžã§ãæ¹æ
ãã€ã€50âã«å ç±ããã滎äžæŒæããïŒïŒ15âãž
ã¢ãããšã€ã³ãµã³31.26ïœã滎å ããçããæ··å
ç©ãPHãçŽ7.5ã«ãªããŸã§éæµããïŒçŽïŒæéã
èŠãããïŒã次ã«åå¿æ··ååç©ãïŒâã«å·åŽããç
ããå¡©ãå¥ããŠéã80âã§ç空也ç¥ãããåç
ã¯46ïœã§çè«éã®97ïŒ ã§ãã€ãã åŸãããå¡©15ïœããçªçŽ é°å²æ°äžã§èå§å®¹åš
ïŒbomb tubeïŒäžã«è解ã280âã«å ç±ãããïŒæ
éåŸæº¶èç©ãå·åŽããåºåããåæçž®åç©ã容åš
ããåãåºãçªçŽ å°å ¥æ段ãåããçž®ååå¿ç®¡äž
ã«ç§»ãããåæçž®åç©ãçªçŽ é°å²æ°äžã§270âã§
è解ããçªçŽ ãéããªãã10æéãã®æž©åºŠã«ä¿ã€
ãããã®æº¶è§£ç©ãå·åŽãããšãåºåããŠç¡è²éæ
ã®åºãŸããšãªã€ããçããããªã¢ãããã25âã«
ãŠïœâã¯ã¬ãŸãŒã«ã®0.5ïŒ ããªã¢ãã溶液ãšããŠ
枬å®ããæç®æ¯ç²åºŠã¯ã0.96dlïŒïœã§ãã€ããã
ã®ããªã¢ãããé»æ°çã«å ç±ããæ²¹å§æ©ã«ããã
250âã§å å§ãïŒæã®ã·ãŒãã«ãããã·ãŒãïŒã¯
也ç¥æ¡ä»¶äžã«ãã·ãŒãïŒã¯å®€æž©ïŒ20âãªãã25
âïŒã§65ïŒ çžå¯Ÿæ¹¿åºŠæ¡ä»¶äžã«ãããã«ã·ãŒãïŒã¯
æ°Žäžã«ä¿åãããïŒé±éåŸã·ãŒãïŒã¯0.4ééïŒ
ã®æ°Žããã·ãŒãïŒã¯0.6ééïŒ ã®æ°Žãåžåããã
ããã«é·æéä¿åããåŸããäžèšã®æ¡ä»¶ã§ãã以
äžã®æ°Žååžåã¯èªããããªãã€ããäžèšã®åŠçã®
åŸã·ãŒãïŒãªããïŒã®ã¬ã©ã¹è»¢ç§»æž©åºŠã瀺差ç±å
ææ³ã«ãã枬å®ãã以äžã®å€ãåŸãã ã·ãŒãïŒïŒ126âãã·ãŒãïŒïŒ114âã ã·ãŒãïŒïŒ114âã å®æœäŸïŒãªããïŒ ãã¬ãã¿ã«é žãšããã§å®çŸ©ãããžã¢ãã³ããåŸ
ãããä»ã®ããªã¢ããããå®æœäŸïŒã«èšèŒããæ¹
æ³ã§äœããã·ãŒãã«ããã å®æœäŸïŒãªããïŒã§ã¯ããã¬ãã¿ã«é žãšçš®ã ã®
ãžã¢ãã³ãããªãïŒçš®é¡ã®å¡©ã®æ··åç©ã䜿çšãã
éçž®åãããŠãããããã®å ±éåã¢ããã«ããã
䜿çšããåå¿ææããã³ãåå¿ã«ããåŸãããã
ãªã¢ããã®æ§è³ªïŒå®æœäŸïŒã«èšèŒããæ¹æ³ã§æž¬
å®ïŒã¯è¡šïŒã«ç€ºãã å®æœäŸ ïŒ 10ïŒ19âãžã¢ãããªã¯ã¿ã³ãµã³4.183ïœããã³
ãžããšãã«ãã¬ãã¿ã¬ãŒã3.071ïœããçªçŽ å°å ¥
æ段ãåããçž®ååå¿ç®¡äžã«å ¥ããçªçŽ é°å²æ°äž
ã§220âã«ïŒæéä¿ã€ãã次ã«æž©åºŠãåŸã ã«250â
ã«äžæããããïŒæéåŸç空åŠçãæœããããã
å解ããããšããŒã«ã¯ïŒæéãããŠçå»ãããå·
åŽã«ãã溶解ç©ã¯åºåãç¡è²éæãªåºãŸããšãªã€
ããåŸãããããªã¢ããã¯25âã«ãŠïœâã¯ã¬ãŸãŒ
ã«ã®0.5ïŒ ããªã¢ãã溶液ãšããŠæž¬å®ããå Žåã
æç®æ¯ç²åºŠã0.53dlïŒïœã§ãã€ããã¬ã©ã¹è»¢ç§»æž©
床ã¯112âã65ïŒ çžå¯Ÿæ¹¿åºŠå®€æž©æ¡ä»¶äžã§ã®ïŒé±é
åŸã®åžæ°Žéã¯0.3ééïŒ ã§ãã€ãã å®æœäŸ ïŒ ãžããšãã«ã»ãã¬ãã¿ã¬ãŒããã12ïŒ21âãžã¢
ãããããªã¢ã³ã³ã¿ã³ãšå®æœäŸïŒã«èšèŒããæ¹æ³
ã§åå¿ããããåŸãããããªã¢ããã®æ§è³ªã¯ãå®
æœäŸïŒã§èª¿è£œããããªã¢ããã®æ§è³ªãšå®è³ªçã«å
æ§ã§ãã€ãã å®æœäŸ 10 ãžããšãã«ã»ãã¬ãã¿ã¬ãŒãããååŠéè«çé
ã®ïŒïŒ13âãžã¢ããâïŒïŒ15âãžã¡ãã«ãããµã
ã«ã³ãšå®æœäŸïŒã«èšèŒããæ¹æ³ã§åå¿ããããåŸ
ãããããªã¢ããã®æ§è³ªã¯è¡šïŒã«ç€ºãã å®æœäŸ 11 ãã¬ãã¿ã«é ž11.72ïœãããšã¿ããŒã«250mlãšæ°Ž
90mlã®æ··åç©ã«å ããæ¹æè£ çœ®ãéæµå·åŽè£ 眮ã
ãã³æ»ŽäžæŒæãåããåå¿å®¹åšäžã§éæµãéå§ã
ã枩床ã«å ç±ãã次ãã§ïŒïŒ10âãžã¢ããâïŒïŒ
10âãžã·ã¯ãããã·ã«ãã«ã³24ïœã滎äžæŒæãã
滎å ãããåå¿æ··åç©ãéæµãã€ã€48æéæ¹æ
ãã次ãã§å®€æž©ïŒ20âãªãã25âïŒã«å·åŽããã
çããå¡©ãå¥ããŠéãã100âã§ç空也ç¥ã
ããåçã¯34.8ïœã§çè«éã®98ïŒ ã§ãã€ããåŸã
ããå¡©7.5ïœãšãã¬ãã¿ã«é žãšïŒïŒ13âãžã¢ãã
ãããµãã«ã³ãããªãå¡©ïŒå®æœäŸïŒã®æ¹æ³ã«åŸã€
ãŠèª¿è£œããïŒ7.5ïœãæ··åããŠèå§å®¹åšã«å ¥ãã
çªçŽ é°å²æ°äžã§æº¶èããããã®å¡©ã®æ··åç©ã280
âã§æº¶èããïŒæéãã®æž©åºŠã«ä¿ã€ããåæçž®å
ç©ãå·åŽãã次ãã§çž®ååå¿å®¹åšã«ç§»ãé£ç¶çã«
çªçŽ ãéããªããã溶èç¶æ ã§280âïŒæééçž®
åããããå·åŽã«ããå ±éåã¢ãããåºåããç¡
è²éæãªåºãŸããšãªã€ããåŸãããå ±éåã¢ãã
ããæ²¹å§æ©ã«ãã280âã§åã0.2mmã®ã·ãŒããšã
ãããã®å ±éåã¢ããã®æ§è³ªã¯ã第ïŒè¡šã«ç€ºãã å®æœäŸ 12 å®æœäŸ11ã«èšèŒããäŸãšåæ§ã«ããŠãåå®æœäŸ
ã®ç¬¬ïŒæ®µç®ã®åå¿ã«ããåŸãããå¡©ïŒïœãšããã¬
ãã¿ã«é žãšïŒïŒ16âãžã¢ãããã³ãµã³ãããªãå¡©
ïŒå®æœäŸïŒã®æ¹æ³ã«åŸã€ãŠèª¿è£œããïŒïŒïœãéçž®
åããã·ãŒãç¶ã«ãã¬ã¹ãããåŸãããå ±éåã¢
ããã®æ§è³ªã¯ãè¡šïŒã«ç€ºãã å®æœäŸ 13 ïŒïŒ12âãžã¢ããâïŒïŒ13âãžã¡ãã«ããã©ã
ã«ã³11.83ïœããæ¹æè£ çœ®ãåããããŒã«ãŒäžã§
ãšã¿ããŒã«150mlã«æº¶èãã溶液ã50âã«å ç±ã
ãããã®æº¶æ¶²ã«ã€ãœãã¿ã«é ž7.66ïœãäžåºŠã«å
ããããŒã«ãŒããšã¿ããŒã«30mlã§ãããã ãçºç±
åå¿ã«ç¶ããŠæº¶æ¶²ãåŸããããå·åŽã«ããåå¿æ··
å液ããå¡©ãæ²æŸ±ãããæ²æŸ±ãå¥ããŠéãã90
âã§ç空也ç¥ãããåçã¯15.8ïœã§çè«éã®81ïŒ
ã§ãã€ããçããå¡©ïŒïœãšããã¬ãã¿ã«é žãšïŒïŒ
14âãžã¢ãããªã¯ã¿ãã«ã³ãããªãå¡©ïŒå®æœäŸïŒ
ã®æ¹æ³ã«åŸã€ãŠèª¿è£œããïŒïŒïœãæ··åããèå§å
å¿å®¹åšäžã§270âïŒæéåæçž®åããããéçž®å
ã¯çž®ååå¿å®¹åšäžã§çªçŽ ãéãã€ã€270âïŒæé
è¡ãªããããåŸãããç¡è²éæã®åºãŸãããæ²¹å§
æ©ã«ãã270âã§ãã¬ã¹ããŠã·ãŒãã«ãããå ±é
åã¢ããã®æ§è³ªã¯è¡šïŒã«ç€ºãã å®æœäŸ 14 ã€ãœãã¿ã«é ž12.27ïœã沞隰ãšã¿ããŒã«380mläž
ã«æº¶è§£ãããïŒïŒ10âãžã¢ããâïŒïŒ10âãžã·ã¯
ãããã·ã«ãã«ã³25ïœãïŒåºŠã«å ããããã«ãšã¿
ããŒã«75mlãå ãããæ°ç§åŸã«å¡©ãæ²æ®¿ãããå
å¿æ··åç©ãïŒâã«å·åŽããå¡©ãå¥ããŠéã100
âã§ç空也ç¥ãããåçã¯36.1ïœã§çè«éã®97ïŒ
ã§ãã€ãããã®å¡©ïŒïœãšããã¬ãã¿ã«é žãšïŒïŒ15
âãžã¢ãããšã€ã³ãµã³ãããªãå¡©ïŒå®æœäŸïŒã®æ¹
æ³ã«åŸã€ãŠèª¿è£œããïŒïŒïœããå®æœäŸ13ã«èšèŒã
ãæ¡ä»¶ã§éçž®åããŠå ±éåã¢ãããšãã次ãã§é
æã·ãŒãã«å å·¥ãããåŸãããå ±éåã¢ããã®æ§
質ã¯ãè¡šïŒã«ç€ºãã å®æœäŸ 15 ãã¬ãã¿ã«é ž13.98ïœããæ°Ž100mlãšãšã¿ããŒã«
340mlã®æ··åç©äžã«å ããæ¹æè£ çœ®ãéæµå·åŽç®¡
ããã³æ»ŽäžæŒæãåããåå¿å®¹åšäžã§ã60âã«å
ç±ãã次ãã§ïŒïŒ14âãžã¢ããâïŒïŒ15âãžã¡ã
ã«ãªã¯ã¿ãã«ã³26.3ïœãå ãããæžæ¿æ¶²ãéæµã
ã€ã€ãPHãçŽ7.5ã«ãªããŸã§æ¹æããïŒçŽïŒæé
èŠãããïŒã宀枩ã«å·åŽåŸãå¡©ãå¥ããŠéã90â
ã§ç空也ç¥ãããåçã¯38.3ïœã§çè«éã®95ïŒ ã§
ãã€ãããã®å¡©ïŒïœãããã¬ãã¿ã«é žãšïŒïŒ14â
ãžã¢ãããªã¯ã¿ãã«ã³ãããªãå¡©ïŒå®æœäŸ13ã®æ¹
æ³ã«åŸã€ãŠèª¿è£œããïŒïŒïœãšæ··åããæ··åç©ãå®
æœäŸ13ã«èšèŒããæ¡ä»¶äžã§éçž®åããå ±éåã¢ã
ããšãããåŸãããå ±éåã¢ããã®æ§è³ªã¯è¡šïŒã«
瀺ãã
ãè¡šã
ïœ ïŒïŒ14âãžã¢ãããªã¯ã¿ãã«ã³
ïŒïŒ12âãžããã«âïŒïŒïŒâãžã¢ã¶âïŒïŒ
ïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãžã¢ã¹ãã¬ãª
ããŒæ··åç©ïŒ208ïœïŒ0.75ã¢ã«ïŒãããã³ããã«
å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåºçºãã
ïœïŒã«èšèŒããæ¹æ³ãç¹°è¿ããäž»åç»ã¯ïŒïŒ14
âãžã¢ãããªã¯ã¿ãã«ã³132.8ïœïŒçè«éã®
62.3ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããªãã ã沞ç¹149âïŒ0.001mmHgïŒïœïŒïŒ ïŒ1.4593ïŒ èµ€å€åžåïŒæ¶²ç¶ïŒã¯333ïŒ3267ïŒ1613cm-1ã®åž
åãã³ããæãããã ïœ ïŒïŒ15âãžã¢ãããšã€ã³ãµã³ ïŒïŒ12âãžããšãã«âïŒïŒïŒâãžã¢ã¶ã·ã¯ã
ããã«ã³ïŒãžã¢ã¹ãã¬ãªããŒæ··åç©ïŒã220ïœ
ïŒ0.71ã¢ã«ïŒãããã³ããã«å¿ããŠæžå°ããéã®
觊åªãšæº¶åªããåºçºããïœïŒã«èšèŒããæ¹æ³ã
ç¹°è¿ããäž»åç»ã¯ïŒïŒ15âãžã¢ãããšã€ã³ãµã³
136ïœïŒçè«éã®61.3ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããª
ãã ã沞ç¹167âãªãã170âïŒ0.001mmHgïŒ ïœïŒïŒ ïŒ1.4603ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯3289ããã³
1613cm-1ã®åžåãã³ããæãããã ïœ ïŒïŒ16âãžã¢ãããã³ãµã³ ïŒïŒ12âãžããã·ã«âïŒïŒïŒâãžã¢ã¶ã·ã¯ã
ããã«ã³ïŒãžã¢ã¹ãã¬ãªããŒæ··åç©ïŒ190ïœ
ïŒ0.56ã¢ã«ïŒãããã³ããã«å¿ããŠæžå°ããéã®
觊åªãšæº¶åªããåºçºããïœïŒã«èšèŒããæ¹æ³ã
ç¹°è¿ããäž»åç»ã¯ïŒïŒ16âãžã¢ãããã³ãµã³
130ïœïŒçè«éã®68ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããª
ãã ã沞ç¹184âïŒ0.02â0.005mmHgïŒ ïœïŒïŒ ïŒ1.4624ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯3355ïŒ
3278ïŒ1613cm-1ã®åžåãã³ããæãããã ïœ 10ïŒ19âãžã¢ãããªã¯ã¿ã³ãµã³ ç²ç²Ÿè£œïŒïŒ12âãžããã«âïŒïŒïŒâãžã¢ã¶â
ïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãžã¢ã¹ã
ã¬ãªããŒæ··åç©ïŒ100ïœïŒ0.24ã¢ã«ïŒããã³ã
ãã«å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåºçº
ããïœã«èšèŒããæ¹æ³ãç¹°è¿ãã10ïŒ19âãžã¢
ãããªã¯ã¿ã³ãµã³40.4ïœïŒçè«éã®40ïŒ ïŒãåŸ
ãããã ãèç¹33âãªãã37âïŒèµ€å€åžåã¯32.25ããã³
1582cm-1ã®åžåãã³ããæãããã ïœ 12ïŒ21âãžã¢ãããããªã¢ã³ã³ã¿ã³ 100ïœïŒ0.21ã¢ã«ïŒã®ç²ç²Ÿè£œïŒïŒ12âãžãŠã³
ãã·ã«âïŒïŒïŒâãžã¢ã¶âïŒïŒïŒïŒïŒâã·ã¯ã
ããã«ããªãšã³ïŒãžã¢ã¹ãã¬ãªããŒæ··åç©ïŒ
100ïœïŒ0.21ã¢ã«ïŒãããã³ããã«å¿ããŠæžå°ã
ãéã®è§Šåªãšæº¶åªããåºçºããïœã«èšèŒããæ¹
æ³ãç¹°è¿ãã12ïŒ21âãžã¢ãããããªã¢ã³ã³ã¿
ã³64.3ïœïŒçè«éã®64ïŒ ïŒãåŸãããã ãèç¹45âãªãã46âïŒèµ€å€åžåïŒæº¶åªïŒå¡©å
ã¡ãã¬ã³ïŒã¯3174ããã³1582cm-1ã®åžåãã³ã
ãæãããã ïœ ïŒïŒ12âãžã¢ããâïŒïŒ13âãžã¡ãã«ããã©
ãã«ã³ ïŒïŒ12âãžã€ãœãããã«âïŒïŒïŒâãžã¢ã¶â
ïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãžã¢ã¹ã
ã¬ãªããŒæ··åç©ïŒ250ïœïŒïŒã¢ã«ïŒãããã³ãã
ã«å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåºçºãã
ïœã«èšèŒããæ¹æ³ãç¹°è¿ããäž»åç»ã¯ïŒïŒ12â
ãžã¢ããâïŒïŒ13âãžã¡ãã«ããã©ãã«ã³238
ïœïŒçè«éã®92ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããªãã ã沞ç¹106âãªãã109âïŒ0.01mmHgïŒ ïœïŒïŒ ïŒ1.4600ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯ã3355ïŒ
3278ïŒããã³1613cm-1ã®åžåãã³ããæã
ããã ïœ ïŒïŒ14âãžã¢ããâïŒïŒ15âãžã¡ãã«ãªã¯ã¿
ãã«ã³ ïŒïŒ12âãžâïŒïŒâãã³ãã«ïŒâïŒïŒïŒâãž
ã¢ã¶âïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãž
ã¢ã¹ãã¬ãªããŒæ··åç©ïŒ61ïœïŒ0.2ã¢ã«ïŒããã
ã³ããã«å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåº
çºããïœã«èšèŒããæ¹æ³ãç¹°è¿ããäž»åç»ã¯ã
ïŒïŒ14âãžã¢ããâïŒïŒ15âãžã¡ãã«ãªã¯ã¿ã
ã«ã³48.4ïœïŒçè«éã®77ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãã
ãªãã ã沞ç¹155âãªãã159âïŒ0.03mmHgïŒ ïœïŒïŒ ïŒ1.4632ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯ã3246ãã
ã³1613cm-1ã®åžåãã³ããæãããã ïœ ïŒïŒ10âãžã¢ããâïŒïŒ10âãžã·ã¯ãããã·
ã«ãã«ã³ ïŒïŒ12âãžã·ã¯ãããã·ã«âïŒïŒïŒâãžã¢ã¶
âïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãžã¢ã¹
ãã¬ãªããŒæ··åç©ïŒ328.5ïœïŒïŒã¢ã«ïŒãããã³
ããã«å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåºçº
ããïœã«èšèŒããæ¹æ³ãç¹°è¿ããåŸãããäž»å
ç»ã¯ãïŒïŒ10âãžã¢ããâïŒïŒ10âãžã·ã¯ãã
ãã·ã«ãã«ã³304ïœïŒçè«éã®90ïŒ ïŒã®ç¡è²æ²¹
ç¶ç©ãããªãã ã沞ç¹190âãªãã193âïŒ0.05mmHgïŒ ïœïŒïŒ ïŒ1.4944ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯ã3355ïŒ
3278ïŒããã³1613cm-1ã®åžåãã³ããæã
ããã ïœ ïŒïŒ13âãžã¢ããâïŒïŒ15âãžã¡ãã«ãããµ
ãã«ã³ 400ïœïŒ1.45ã¢ã«ïŒã®ïŒïŒ12âãžã€ãœããã«
ïŒïŒïŒâãžã¢ã¶âïŒïŒïŒïŒïŒâã·ã¯ãããã«ã
ãªãšã³ïŒãžã¢ã¹ãã¬ãªããŒæ··åç©ïŒ400ïœ
ïŒ1.45ã¢ã«ïŒãããã³ããã«å¿ããŠæžå°ããéã®
觊åªãšæº¶åªããåºçºããïœã«èšèŒããæ¹æ³ãç¹°
è¿ããåŸãããäž»åç»ã¯ïŒïŒ13âãžã¢ããâ
ïŒïŒ15âãžã¡ãã«ãããµãã«ã³261ïœïŒçè«é
ã®63ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããªãã ã沞ç¹168âãªãã172âïŒ0.04mmHgïŒ ïœïŒïŒ ïŒ1.4561ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯3289ïŒ
3205ïŒ1600cm-1ã®åžåãã³ããæãããã åºçºææãšããŠäœ¿çšãããïŒïŒïŒâãžã¢ã¶â
ïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ããã³ïŒïŒïŒ
âãžã¢ã¶ã·ã¯ãããã«ã³ã¯ããã€ãå ¬éå ¬å ±ç¬¬
2330087å·ããã³ç¬¬2549403å·ã«èšèŒãããæ¹æ³ã«
ããåŸãããšãã§ããã
ïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãžã¢ã¹ãã¬ãª
ããŒæ··åç©ïŒ208ïœïŒ0.75ã¢ã«ïŒãããã³ããã«
å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåºçºãã
ïœïŒã«èšèŒããæ¹æ³ãç¹°è¿ããäž»åç»ã¯ïŒïŒ14
âãžã¢ãããªã¯ã¿ãã«ã³132.8ïœïŒçè«éã®
62.3ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããªãã ã沞ç¹149âïŒ0.001mmHgïŒïœïŒïŒ ïŒ1.4593ïŒ èµ€å€åžåïŒæ¶²ç¶ïŒã¯333ïŒ3267ïŒ1613cm-1ã®åž
åãã³ããæãããã ïœ ïŒïŒ15âãžã¢ãããšã€ã³ãµã³ ïŒïŒ12âãžããšãã«âïŒïŒïŒâãžã¢ã¶ã·ã¯ã
ããã«ã³ïŒãžã¢ã¹ãã¬ãªããŒæ··åç©ïŒã220ïœ
ïŒ0.71ã¢ã«ïŒãããã³ããã«å¿ããŠæžå°ããéã®
觊åªãšæº¶åªããåºçºããïœïŒã«èšèŒããæ¹æ³ã
ç¹°è¿ããäž»åç»ã¯ïŒïŒ15âãžã¢ãããšã€ã³ãµã³
136ïœïŒçè«éã®61.3ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããª
ãã ã沞ç¹167âãªãã170âïŒ0.001mmHgïŒ ïœïŒïŒ ïŒ1.4603ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯3289ããã³
1613cm-1ã®åžåãã³ããæãããã ïœ ïŒïŒ16âãžã¢ãããã³ãµã³ ïŒïŒ12âãžããã·ã«âïŒïŒïŒâãžã¢ã¶ã·ã¯ã
ããã«ã³ïŒãžã¢ã¹ãã¬ãªããŒæ··åç©ïŒ190ïœ
ïŒ0.56ã¢ã«ïŒãããã³ããã«å¿ããŠæžå°ããéã®
觊åªãšæº¶åªããåºçºããïœïŒã«èšèŒããæ¹æ³ã
ç¹°è¿ããäž»åç»ã¯ïŒïŒ16âãžã¢ãããã³ãµã³
130ïœïŒçè«éã®68ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããª
ãã ã沞ç¹184âïŒ0.02â0.005mmHgïŒ ïœïŒïŒ ïŒ1.4624ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯3355ïŒ
3278ïŒ1613cm-1ã®åžåãã³ããæãããã ïœ 10ïŒ19âãžã¢ãããªã¯ã¿ã³ãµã³ ç²ç²Ÿè£œïŒïŒ12âãžããã«âïŒïŒïŒâãžã¢ã¶â
ïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãžã¢ã¹ã
ã¬ãªããŒæ··åç©ïŒ100ïœïŒ0.24ã¢ã«ïŒããã³ã
ãã«å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåºçº
ããïœã«èšèŒããæ¹æ³ãç¹°è¿ãã10ïŒ19âãžã¢
ãããªã¯ã¿ã³ãµã³40.4ïœïŒçè«éã®40ïŒ ïŒãåŸ
ãããã ãèç¹33âãªãã37âïŒèµ€å€åžåã¯32.25ããã³
1582cm-1ã®åžåãã³ããæãããã ïœ 12ïŒ21âãžã¢ãããããªã¢ã³ã³ã¿ã³ 100ïœïŒ0.21ã¢ã«ïŒã®ç²ç²Ÿè£œïŒïŒ12âãžãŠã³
ãã·ã«âïŒïŒïŒâãžã¢ã¶âïŒïŒïŒïŒïŒâã·ã¯ã
ããã«ããªãšã³ïŒãžã¢ã¹ãã¬ãªããŒæ··åç©ïŒ
100ïœïŒ0.21ã¢ã«ïŒãããã³ããã«å¿ããŠæžå°ã
ãéã®è§Šåªãšæº¶åªããåºçºããïœã«èšèŒããæ¹
æ³ãç¹°è¿ãã12ïŒ21âãžã¢ãããããªã¢ã³ã³ã¿
ã³64.3ïœïŒçè«éã®64ïŒ ïŒãåŸãããã ãèç¹45âãªãã46âïŒèµ€å€åžåïŒæº¶åªïŒå¡©å
ã¡ãã¬ã³ïŒã¯3174ããã³1582cm-1ã®åžåãã³ã
ãæãããã ïœ ïŒïŒ12âãžã¢ããâïŒïŒ13âãžã¡ãã«ããã©
ãã«ã³ ïŒïŒ12âãžã€ãœãããã«âïŒïŒïŒâãžã¢ã¶â
ïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãžã¢ã¹ã
ã¬ãªããŒæ··åç©ïŒ250ïœïŒïŒã¢ã«ïŒãããã³ãã
ã«å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåºçºãã
ïœã«èšèŒããæ¹æ³ãç¹°è¿ããäž»åç»ã¯ïŒïŒ12â
ãžã¢ããâïŒïŒ13âãžã¡ãã«ããã©ãã«ã³238
ïœïŒçè«éã®92ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããªãã ã沞ç¹106âãªãã109âïŒ0.01mmHgïŒ ïœïŒïŒ ïŒ1.4600ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯ã3355ïŒ
3278ïŒããã³1613cm-1ã®åžåãã³ããæã
ããã ïœ ïŒïŒ14âãžã¢ããâïŒïŒ15âãžã¡ãã«ãªã¯ã¿
ãã«ã³ ïŒïŒ12âãžâïŒïŒâãã³ãã«ïŒâïŒïŒïŒâãž
ã¢ã¶âïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãž
ã¢ã¹ãã¬ãªããŒæ··åç©ïŒ61ïœïŒ0.2ã¢ã«ïŒããã
ã³ããã«å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåº
çºããïœã«èšèŒããæ¹æ³ãç¹°è¿ããäž»åç»ã¯ã
ïŒïŒ14âãžã¢ããâïŒïŒ15âãžã¡ãã«ãªã¯ã¿ã
ã«ã³48.4ïœïŒçè«éã®77ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãã
ãªãã ã沞ç¹155âãªãã159âïŒ0.03mmHgïŒ ïœïŒïŒ ïŒ1.4632ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯ã3246ãã
ã³1613cm-1ã®åžåãã³ããæãããã ïœ ïŒïŒ10âãžã¢ããâïŒïŒ10âãžã·ã¯ãããã·
ã«ãã«ã³ ïŒïŒ12âãžã·ã¯ãããã·ã«âïŒïŒïŒâãžã¢ã¶
âïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ïŒãžã¢ã¹
ãã¬ãªããŒæ··åç©ïŒ328.5ïœïŒïŒã¢ã«ïŒãããã³
ããã«å¿ããŠæžå°ããéã®è§Šåªãšæº¶åªããåºçº
ããïœã«èšèŒããæ¹æ³ãç¹°è¿ããåŸãããäž»å
ç»ã¯ãïŒïŒ10âãžã¢ããâïŒïŒ10âãžã·ã¯ãã
ãã·ã«ãã«ã³304ïœïŒçè«éã®90ïŒ ïŒã®ç¡è²æ²¹
ç¶ç©ãããªãã ã沞ç¹190âãªãã193âïŒ0.05mmHgïŒ ïœïŒïŒ ïŒ1.4944ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯ã3355ïŒ
3278ïŒããã³1613cm-1ã®åžåãã³ããæã
ããã ïœ ïŒïŒ13âãžã¢ããâïŒïŒ15âãžã¡ãã«ãããµ
ãã«ã³ 400ïœïŒ1.45ã¢ã«ïŒã®ïŒïŒ12âãžã€ãœããã«
ïŒïŒïŒâãžã¢ã¶âïŒïŒïŒïŒïŒâã·ã¯ãããã«ã
ãªãšã³ïŒãžã¢ã¹ãã¬ãªããŒæ··åç©ïŒ400ïœ
ïŒ1.45ã¢ã«ïŒãããã³ããã«å¿ããŠæžå°ããéã®
觊åªãšæº¶åªããåºçºããïœã«èšèŒããæ¹æ³ãç¹°
è¿ããåŸãããäž»åç»ã¯ïŒïŒ13âãžã¢ããâ
ïŒïŒ15âãžã¡ãã«ãããµãã«ã³261ïœïŒçè«é
ã®63ïŒ ïŒã®ç¡è²æ²¹ç¶ç©ãããªãã ã沞ç¹168âãªãã172âïŒ0.04mmHgïŒ ïœïŒïŒ ïŒ1.4561ïŒèµ€å€åžåïŒæ¶²ç¶ïŒã¯3289ïŒ
3205ïŒ1600cm-1ã®åžåãã³ããæãããã åºçºææãšããŠäœ¿çšãããïŒïŒïŒâãžã¢ã¶â
ïŒïŒïŒïŒïŒâã·ã¯ãããã«ããªãšã³ããã³ïŒïŒïŒ
âãžã¢ã¶ã·ã¯ãããã«ã³ã¯ããã€ãå ¬éå ¬å ±ç¬¬
2330087å·ããã³ç¬¬2549403å·ã«èšèŒãããæ¹æ³ã«
ããåŸãããšãã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžè¬åŒïŒ ãåŒäžã X1ã¯æ¬¡åŒïŒ ïŒåŒäžã R1åã³R3ã¯äºãã«ç¬ç«ããŠããããæ°ŽçŽ åå
ãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šã
ããR2åã³R4ã¯äºãã«ç¬ç«ããŠããããççŽ å
åæ°ïŒãªãã12ã®ã¢ã«ãã«åºãè¡šãããïŒ ã®åºãè¡šãããã ã§è¡šããããç¹°è¿ãæ§é åäœãæããå Žåã«ãã€
ãŠã¯ äžè¬åŒïŒ ãåŒäžã X2ã¯æ¬¡åŒïŒ ïŒåŒäžã R5ãšR7ã¯äºãã«ç¬ç«ããŠããããççŽ ååæ°
ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šãããR6ãšR8ã¯äº
ãã«ç¬ç«ããŠããããççŽ ååæ°ïŒãªãã10ã®ã¢
ã«ãã«åºãè¡šãããããããã¯R5ããã³R6ãã
ã³ïŒãŸãã¯R7ããã³R8ã¯ãããçãçµåããŠã
ãççŽ ååãšäžç·ã«ãªã€ãŠççŽ ååæ°ïŒãªãã12
ã®ã·ã¯ãã¢ã«ãã«åºãè¡šãããïŒ ã®åºãè¡šãããã ã§è¡šããããç¹°è¿ãæ§é åäœãæãããããŠäžè¬
åŒããã³äžè¬åŒã«ãããŠãåã ã®å Žåååšã
ãå šãã³ãŒã³ãžã«ã«ãã³é žåºã«å¯ŸããŠã«ã«ããã«
åºããã®ãã³ãŒã³ç°ã®ïŒïŒïŒâéšäœã«ã100ãªã
ã50ã¢ã«ïŒ ãïŒïŒïŒâéšäœã«ïŒãªãã50ã¢ã«ïŒ ã®
å²åã§çµåãããžã¢ãã³æåã¯ååšããå šãžã¢ã
ã³æåã«å¯ŸããŠãåŒâNHâX1âNHâã§è¡šãã
ããæåã100ãªãã25ã¢ã«ïŒ ãå ããåŒâNHâ
X2âNHâã§è¡šããããæåãïŒãªãã75ã¢ã«ïŒ
ãå ãããŸããžã¢ãã³æåâNHâX1âNHâã®
ã¢ã«ïŒ ã§è¡šããããéã¯ãã¬ãã¿ã«é žæåéãšç
éããã以äžã§ããããšãããªãããªã¢ããã§ã
ã€ãŠã25âã«ãŠïœâã¯ã¬ãŸãŒã«ã®0.5ïŒ æº¶æ¶²ãšã
ãŠæž¬å®ããå Žåãå°ããšã0.4dlïŒïœã®æç®æ¯ç²
床ãæããéæããªã¢ããã ïŒ R1ãšR3ïŒR2ãšR4ïŒR5ãšR7ããã³R6ãšR8ã®
åã ã«ãããŠã察ããªã眮æåºã¯åäžã®åºãè¡šã
ããããããã¯R5ãšR6ã®å¯Ÿããã³R7ãšR8ã®å¯Ÿã
åã ããããããçµåããŠããççŽ ååãšäžç·ã«
ãªã€ãŠãåäžã®ã·ã¯ãã¢ã«ãã«åºã圢æããŠãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ããªã¢ããã ïŒ R1ãšR3ãããããæ°ŽçŽ ååãè¡šãããR2ãš
R4ãããããççŽ ååæ°ïŒãªããïŒç¹ã«ïŒãªã
ãïŒã®ã¢ã«ãã«åºãè¡šãããããããã¯R1ãšR3
ãããããã¡ãã«åºãè¡šãããR2ãšR4ã®ããã
ããççŽ ååæ°ïŒãªããïŒç¹ã«ïŒãªããïŒã®ã¢ã«
ãã«åºãè¡šãããR5ãšR7ã®ãããããççŽ åå
æ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šãããR6ãšR8ã®
ãããããççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºã
è¡šããããããã¯R5ãšR6ããã³R7ãšR8ãããã
ãçµåããŠããççŽ ååãšäžç·ã«ãªã€ãŠã·ã¯ãã
ã³ãã«åºãŸãã¯ã·ã¯ãããã·ã«åºã圢æããŠãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ããªã¢ããã ïŒ R1ãšR3ãããããæ°ŽçŽ ååããR2ãšR4ãã
ãããã¡ãã«åºãŸãã¯ãšãã«åºããã³ç¹ã«ïœâã
ããã«åºãŸãã¯ïœâããã«åºãè¡šãããäžè¬åŒ
ã®ç¹°è¿ãæ§é åäœã®ã¿ããæ§æãããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®ããªã¢ããã ïŒ åŒïŒ ãç¹°è¿ãæ§æåäœãšãã奜ãŸããã¯ïŒdlïŒïœã®æ
ç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸãŒã«äžã«0.5
ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®ããªã¢ããã ïŒ åŒïŒ ã®ç¹°è¿ãæ§é åäœãããªãã奜ãŸããã¯ïŒdlïŒïœ
ã®æç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸãŒã«äžã«
0.5ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®ããªã¢ããã ïŒ åŒïŒ ã®ç¹°è¿ãæ§é åäœãããªãã奜ãŸããã¯ïŒdlïŒïœ
ã®æç®æ¯ç²åºŠïŒ25âã«ãããŠïœâã¯ã¬ãŸãŒã«äžã«
0.5ïŒ æ¿åºŠã«æº¶è§£ããŠæž¬å®ïŒãæããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®ããªã¢ããã ïŒ ãã¬ãã¿ã«é žãŸãã¯ãã®ã¢ãã圢ææ§èªå°äœ
100ãªãã50ã¢ã«ïŒ ããã³ã€ãœãã¿ã«é žãŸãã¯ã
ã®ã¢ãã圢ææ§èªå°äœïŒãªãã50ã¢ã«ïŒ ãåŒïŒ H2NâX1âNH2 ïŒïŒ ïŒåŒäžãX1ã¯äžèšã®åŒã«å®çŸ©ãããã®ãšå
ããïŒ ã§è¡šãããããžã¢ãã³100ãªãã25ã¢ã«ïŒ ããã³
åŒïŒ H2NâX2âNH2 ïŒïŒ ïŒåŒäžãX2ã¯äžèšã®åŒã«å®çŸ©ãããã®ãšå
ããïŒ ã§è¡šãããããžã¢ãã³ïŒãªãã75ã¢ã«ïŒ ãšããåŒ
ã§è¡šãããããžã¢ãã³ã®ã¢ã«ïŒ ã§è¡šããããé
ãããã¬ãã¿ã«é žãŸãã¯ãã®ã¢ãã圢ææ§èªå°äœ
éããå°ãªãããããã¯çããããŠåå¿ãããŠåŸ
ããã äžè¬åŒïŒ ãåŒäžã X1ã¯æ¬¡åŒïŒ ïŒåŒäžã R1ãšR3ã¯äºãã«ç¬ç«ããŠããããæ°ŽçŽ ååãŸ
ãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šã
ããR2ãšR4ã¯äºãã«ç¬ç«ããŠããããççŽ åå
æ°ïŒãªãã12ã®ã¢ã«ãã«åºãè¡šãããïŒã®åºãè¡š
ãããã ã§è¡šããããç¹°è¿ãæ§é åäœãæããå Žåã«ãã€
ãŠã¯ äžè¬åŒïŒ ãåŒäžã X2ã¯æ¬¡åŒïŒ ïŒåŒäžã R5ãšR7ã¯äºãã«ç¬ç«ããŠããããççŽ ååæ°
ïŒãªããïŒã®ã¢ã«ãã«åºãè¡šããR6ãšR8ã¯äºã
ã«ç¬ç«ããŠããããççŽ ååæ°ïŒãªãã10ã®ã¢ã«
ãã«åºãè¡šãããããããã¯R5ãšR6ããã³ïŒãŸ
ãã¯R7ãšR8ã¯ãããçãçµåããŠããççŽ åå
ãšäžç·ã«ãªã€ãŠççŽ ååæ°ïŒãªãã12ã®ã·ã¯ãã¢
ã«ãã«åºãè¡šãããïŒã®åºãè¡šãããã ã§è¡šããããç¹°è¿ãæ§é åäœãæããäžè¬åŒã
ãã³äžè¬åŒã«ãããŠãåã ã®å Žåååšããå šã
ã³ãŒã³ãžã«ã«ãã³é žåºã«å¯ŸããŠã«ã«ããã«åºãã
ã®ãã³ãŒã³ç°ã®ïŒïŒïŒâéšäœã«ã100ãªãã50ã¢
ã«ïŒ ãïŒïŒïŒâéšäœã«ïŒãªãã50ã¢ã«ïŒ ã®å²åã§
çµåãããžã¢ãã³æåã¯ååšããå šãžã¢ãã³æå
ã«å¯ŸããŠãåŒâNHâX1âNHâã§è¡šããããæ
åã100ãªãã25ã¢ã«ïŒ ãå ããåŒâNHâX2â
NHâã§è¡šããããæåããïŒãªãã75ã¢ã«ïŒ ã
å ãããŸããžã¢ãã³æåâNHâX1âNHâã®ã¢
ã«ïŒ ã§è¡šããããéã¯ãã¬ãã¿ã«é žæåéãšçé
ããã以äžã§ããããšãããªãããªã¢ããã§ãã€
ãŠã25âã«ãŠïœâã¯ã¬ãŸãŒã«ã®0.5ïŒ æº¶æ¶²ãšããŠ
枬å®ããå Žåãå°ãªããšã0.4dlïŒïœã®æç®æ¯ç²
床ãæããéæããªã¢ããã®è£œé æ¹æ³ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1314977A CH631191A5 (de) | 1977-10-28 | 1977-10-28 | Verfahren zur herstellung von neuen transparenten polyamiden. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5471193A JPS5471193A (en) | 1979-06-07 |
| JPS6160853B2 true JPS6160853B2 (ja) | 1986-12-23 |
Family
ID=4389760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13309878A Granted JPS5471193A (en) | 1977-10-28 | 1978-10-28 | Transparent polyamide and method of making same |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4210743A (ja) |
| JP (1) | JPS5471193A (ja) |
| CA (1) | CA1120195A (ja) |
| CH (1) | CH631191A5 (ja) |
| DE (1) | DE2846501A1 (ja) |
| FR (1) | FR2407228A1 (ja) |
| GB (1) | GB2006796B (ja) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3360070D1 (en) * | 1982-01-29 | 1985-04-18 | Ciba Geigy Ag | 1,10-substituted 10-amino-deca-3,7-diene-nitriles and method for their preparation |
| DE3366159D1 (en) * | 1982-01-29 | 1986-10-23 | Ciba Geigy Ag | Transparent, cross-linkable polyamides |
| CA1242045A (en) * | 1984-07-24 | 1988-09-13 | Ag Ciba-Geigy | Polyamides, processes for producing them, and their use |
| US4722963A (en) * | 1985-12-20 | 1988-02-02 | Henkel Corporation | Aromatic dicarboxylic acid polyamide having acid value greater than 35 |
| GB2195690B (en) * | 1986-10-08 | 1990-04-25 | Anthony Green | Cat door |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL264738A (ja) * | 1959-10-29 | |||
| US3563959A (en) * | 1966-06-25 | 1971-02-16 | Dynamit Nobel Ag | Process for the production of transparent polyamides which are resistant to boiling |
| DE1720513A1 (de) * | 1967-11-02 | 1971-07-01 | Dynamit Nobel Ag | Verfahren zur Herstellung transparenter,kochbestaendiger Polyamide |
| FR1588130A (ja) * | 1967-11-02 | 1970-04-03 | ||
| GB1251520A (ja) | 1968-11-04 | 1971-10-27 | ||
| NL7108318A (ja) | 1970-07-04 | 1972-01-06 | ||
| US3839295A (en) * | 1972-03-13 | 1974-10-01 | Phillips Petroleum Co | Production of polyamides from aqueous slurry of 5-methyl-1,9-nonanediamine and terephthalic acid |
| CH570389A5 (ja) * | 1972-06-16 | 1975-12-15 | Ciba Geigy Ag |
-
1977
- 1977-10-28 CH CH1314977A patent/CH631191A5/de not_active IP Right Cessation
-
1978
- 1978-10-25 DE DE19782846501 patent/DE2846501A1/de active Granted
- 1978-10-26 US US05/954,809 patent/US4210743A/en not_active Expired - Lifetime
- 1978-10-27 FR FR7830566A patent/FR2407228A1/fr active Granted
- 1978-10-27 GB GB7842312A patent/GB2006796B/en not_active Expired
- 1978-10-28 JP JP13309878A patent/JPS5471193A/ja active Granted
- 1978-10-30 CA CA000314684A patent/CA1120195A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2846501C2 (ja) | 1989-02-02 |
| FR2407228A1 (fr) | 1979-05-25 |
| CH631191A5 (de) | 1982-07-30 |
| US4210743A (en) | 1980-07-01 |
| CA1120195A (en) | 1982-03-16 |
| GB2006796A (en) | 1979-05-10 |
| DE2846501A1 (de) | 1979-05-03 |
| JPS5471193A (en) | 1979-06-07 |
| FR2407228B1 (ja) | 1983-04-01 |
| GB2006796B (en) | 1982-07-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2626717B2 (ja) | ç¡æ°Žç©ã³ããªããŒã®è£œé æ¹æ³ | |
| US4393192A (en) | Crystalline copolymers prepared from N,N'-terephthaloyldi-beta-alanine and a glycol | |
| KR970002525B1 (ko) | í¬ëª íŽëŠ¬ì믞ë, ê·žì ì ì¡°ë°©ë² | |
| JP3190373B2 (ja) | ç¡å®åœ¢ã³ããªã¢ããããã®è£œæ³åã³æ圢éšæã®è£œæ³ | |
| US4207411A (en) | Copolyamide of branched C10 diamine, bis(4-aminocyclohexyl)-alkane, isophthalic acid and terephthalic acid | |
| JPS5847403B2 (ja) | ããªãšã¹ãã«ã¢ããã®è£œæ³ | |
| US4567249A (en) | Melt preparation of polyamide by amide ester interchange | |
| JPH0841183A (ja) | ããµã³ãã³ããªããŒããã³ããµã³ãã³ã³ããªããŒãªãã³ã«ãããã®è£œæ³ | |
| JPS6026140B2 (ja) | éæãªã³ããªã¢ãã | |
| US4210743A (en) | Transparent polyamides from branched chain diamines | |
| US4210742A (en) | Transparent polyamides from branched chain diamine | |
| CA1186845A (en) | Transparent polyamides, process for producing them and their use for the manufacture of shaped articles | |
| US4195165A (en) | Aliphatic polyamide from disubstituted decane diamine | |
| CA1120190A (en) | Crystalline polyamides | |
| CA1163043A (en) | Transparent copolyamides and their use for the production of mouldings | |
| CA2028304A1 (en) | Process for the preparation of a thermoplastically processable aromatic polyamide | |
| US5686556A (en) | Process for the preparation of an α-amino Ï-ester monoamide and process for the manufacture of a polyamide | |
| JPS6120579B2 (ja) | ||
| US4258176A (en) | Transparent copolyamide from 1,10-disubstituted C11 diamine | |
| JPS63146926A (ja) | éæããªã¢ããããã³ãã®è£œé æ¹æ³ | |
| CA1186844A (en) | Transparent polyamides, processes for producing them and their use for the manufacture of shaped articles | |
| US4202961A (en) | Transparent polyamide from aromatic dicarboxylic acid and disubstituted decane diamine | |
| CA1120192A (en) | Aliphatic polyamides | |
| US4258177A (en) | Transparent copolyamide from 1,10-disubstituted C10 diamine | |
| CA1120191A (en) | Transparent polyamides |