JPS62149340A - ロジウム含有触媒の製法 - Google Patents

ロジウム含有触媒の製法

Info

Publication number: JPS62149340A
Authority: JP; Japan
Prior art keywords: pore; rhodium; volume; diameter; range
Prior art date: 1985-12-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP60289271A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0468976B2 (fr

Inventor

Kenichi Sano

健一佐野

Shinya Matsuhira

松比良　伸也

Tetsuo Nakajo

哲夫中條

Hiroko Noguchi

裕子野口

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-12-24

Filing date

1985-12-24

Publication date

1987-07-03

1985-12-24 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1985-12-24 Priority to JP60289271A priority Critical patent/JPS62149340A/ja

1987-07-03 Publication of JPS62149340A publication Critical patent/JPS62149340A/ja

1992-11-04 Publication of JPH0468976B2 publication Critical patent/JPH0468976B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 28
239000010948 rhodium Substances 0.000 title claims abstract description 21
229910052703 rhodium Inorganic materials 0.000 title claims abstract description 15
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title claims abstract description 14
238000004519 manufacturing process Methods 0.000 title claims description 5
239000011148 porous material Substances 0.000 claims abstract description 49
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 35
239000000377 silicon dioxide Substances 0.000 claims abstract description 17
238000000034 method Methods 0.000 claims abstract description 15
238000009826 distribution Methods 0.000 claims abstract description 9
238000002347 injection Methods 0.000 claims description 3
239000007924 injection Substances 0.000 claims description 3
238000000151 deposition Methods 0.000 abstract 1
239000007789 gas Substances 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 9
150000001875 compounds Chemical class 0.000 description 7
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
239000002245 particle Substances 0.000 description 6
238000003786 synthesis reaction Methods 0.000 description 6
-1 inorganic acid salts Chemical class 0.000 description 5
238000006722 reduction reaction Methods 0.000 description 5
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
239000003426 co-catalyst Substances 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
238000005470 impregnation Methods 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
239000000203 mixture Substances 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
239000002994 raw material Substances 0.000 description 2
SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 2
239000000126 substance Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
229910021380 Manganese Chloride Inorganic materials 0.000 description 1
GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
230000004913 activation Effects 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000004744 fabric Substances 0.000 description 1
238000010304 firing Methods 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
150000004674 formic acids Chemical class 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000010574 gas phase reaction Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
238000011068 loading method Methods 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
239000011565 manganese chloride Substances 0.000 description 1
229940099607 manganese chloride Drugs 0.000 description 1
235000002867 manganese chloride Nutrition 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000003891 oxalate salts Chemical class 0.000 description 1
239000010970 precious metal Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
150000003283 rhodium Chemical class 0.000 description 1
150000003284 rhodium compounds Chemical class 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP60289271A 1985-12-24 1985-12-24 ロジウム含有触媒の製法 Granted JPS62149340A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP60289271A JPS62149340A (ja)	1985-12-24	1985-12-24	ロジウム含有触媒の製法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP60289271A JPS62149340A (ja)	1985-12-24	1985-12-24	ロジウム含有触媒の製法

Publications (2)

Publication Number	Publication Date
JPS62149340A true JPS62149340A (ja)	1987-07-03
JPH0468976B2 JPH0468976B2 (fr)	1992-11-04

Family

ID=17740999

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP60289271A Granted JPS62149340A (ja)	1985-12-24	1985-12-24	ロジウム含有触媒の製法

Country Status (1)

Country	Link
JP (1)	JPS62149340A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0296573A (ja) *	1988-10-04	1990-04-09	Agency Of Ind Science & Technol	シクロヘキセン環を有する脂肪酸誘導体の製造法
US5352645A (en) *	1989-04-14	1994-10-04	E. I. Du Pont De Nemours And Company	Silica microspheres, method of improving attrition resistance and use
JP2021065837A (ja) *	2019-10-23	2021-04-30	国立大学法人秋田大学	排気ガス浄化用触媒

1985
- 1985-12-24 JP JP60289271A patent/JPS62149340A/ja active Granted

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0296573A (ja) *	1988-10-04	1990-04-09	Agency Of Ind Science & Technol	シクロヘキセン環を有する脂肪酸誘導体の製造法
US5352645A (en) *	1989-04-14	1994-10-04	E. I. Du Pont De Nemours And Company	Silica microspheres, method of improving attrition resistance and use
JP2021065837A (ja) *	2019-10-23	2021-04-30	国立大学法人秋田大学	排気ガス浄化用触媒

Also Published As

Publication number	Publication date
JPH0468976B2 (fr)	1992-11-04

Legal Events

Date	Code	Title	Description
2005-12-24	EXPY	Cancellation because of completion of term

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JPS62149340A - ロジウム含有触媒の製法 - Google Patents

Info

Links

Classifications

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=17740999

Family Applications (1)

Country Status (1)

Cited By (3)

Cited By (3)

Also Published As

Similar Documents

Legal Events