JPS6223640B2 - - Google Patents

Info

Publication number: JPS6223640B2
Authority: JP; Japan
Prior art keywords: scale; hydroxyethylacrylamide; scale inhibitor; methylolmethacrylamide; methyl
Prior art date: 1981-05-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP8279781A

Other languages

English (en)

Japanese (ja)

Other versions

JPS57197097A (en

Inventor

Yoshinari Kawasaki

Kenji Hanno

Sakae Katayama

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

KATAYAMA KAGAKU KOGYO KENKYUSHO KK

Original Assignee

KATAYAMA KAGAKU KOGYO KENKYUSHO KK

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-05-29

Filing date

1981-05-29

Publication date

1987-05-25

1981-05-29 Application filed by KATAYAMA KAGAKU KOGYO KENKYUSHO KK filed Critical KATAYAMA KAGAKU KOGYO KENKYUSHO KK

1981-05-29 Priority to JP8279781A priority Critical patent/JPS57197097A/ja

1982-12-03 Publication of JPS57197097A publication Critical patent/JPS57197097A/ja

1987-05-25 Publication of JPS6223640B2 publication Critical patent/JPS6223640B2/ja

Status Granted legal-status Critical Current

Links

239000002455 scale inhibitor Substances 0.000 claims description 21
150000001875 compounds Chemical class 0.000 claims description 12
229920001577 copolymer Polymers 0.000 claims description 10
229920001519 homopolymer Polymers 0.000 claims description 6
239000004480 active ingredient Substances 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims description 4
BSCJIBOZTKGXQP-UHFFFAOYSA-N n-(2-hydroxyethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCCO BSCJIBOZTKGXQP-UHFFFAOYSA-N 0.000 claims description 4
UUORTJUPDJJXST-UHFFFAOYSA-N n-(2-hydroxyethyl)prop-2-enamide Chemical compound OCCNC(=O)C=C UUORTJUPDJJXST-UHFFFAOYSA-N 0.000 claims description 4
DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 claims description 4
DTLHKFMXQMLMPY-UHFFFAOYSA-N n-ethyl-n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CCN(CO)C(=O)C(C)=C DTLHKFMXQMLMPY-UHFFFAOYSA-N 0.000 claims description 4
125000002947 alkylene group Chemical group 0.000 claims description 3
IIXYEVUNJFXWEB-UHFFFAOYSA-N n-hydroxy-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NO IIXYEVUNJFXWEB-UHFFFAOYSA-N 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
VYHUMZYFJVMWRC-UHFFFAOYSA-N n-(2-hydroxyethyl)-n-methylprop-2-enamide Chemical compound OCCN(C)C(=O)C=C VYHUMZYFJVMWRC-UHFFFAOYSA-N 0.000 claims description 2
OWMJBTZUVCDOSF-UHFFFAOYSA-N n-(2-hydroxyethyl)-n-propylprop-2-enamide Chemical compound CCCN(CCO)C(=O)C=C OWMJBTZUVCDOSF-UHFFFAOYSA-N 0.000 claims description 2
ZTUGCJNAJJDKDC-UHFFFAOYSA-N n-(3-hydroxypropyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCCCO ZTUGCJNAJJDKDC-UHFFFAOYSA-N 0.000 claims description 2
ZEMHQYNMVKDBFJ-UHFFFAOYSA-N n-(3-hydroxypropyl)prop-2-enamide Chemical compound OCCCNC(=O)C=C ZEMHQYNMVKDBFJ-UHFFFAOYSA-N 0.000 claims description 2
QALQIBQJEQZNTE-UHFFFAOYSA-N n-(hydroxymethyl)-n,2-dimethylprop-2-enamide Chemical compound OCN(C)C(=O)C(C)=C QALQIBQJEQZNTE-UHFFFAOYSA-N 0.000 claims description 2
AUCNMQYOQYTGPE-UHFFFAOYSA-N n-(hydroxymethyl)-n-methylprop-2-enamide Chemical compound OCN(C)C(=O)C=C AUCNMQYOQYTGPE-UHFFFAOYSA-N 0.000 claims description 2
PTSPHFGZMBDNJN-UHFFFAOYSA-N n-ethyl-n-(2-hydroxyethyl)prop-2-enamide Chemical compound OCCN(CC)C(=O)C=C PTSPHFGZMBDNJN-UHFFFAOYSA-N 0.000 claims description 2
BKBSLWLWFYNAND-UHFFFAOYSA-N n-hydroxy-3-methyl-2-methylidenebutanamide Chemical compound CC(C)C(=C)C(=O)NO BKBSLWLWFYNAND-UHFFFAOYSA-N 0.000 claims description 2
WMJIEXXHUGKGQQ-UHFFFAOYSA-N n-hydroxy-n-methylprop-2-enamide Chemical compound CN(O)C(=O)C=C WMJIEXXHUGKGQQ-UHFFFAOYSA-N 0.000 claims description 2
YERGJESCBQEIQT-UHFFFAOYSA-N N-hydroxy-2,4-dimethylpent-2-enamide Chemical compound ONC(C(=CC(C)C)C)=O YERGJESCBQEIQT-UHFFFAOYSA-N 0.000 claims 1
HQVFKSDWNYVAQD-UHFFFAOYSA-N n-hydroxyprop-2-enamide Chemical compound ONC(=O)C=C HQVFKSDWNYVAQD-UHFFFAOYSA-N 0.000 claims 1
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
229920000642 polymer Polymers 0.000 description 9
229910000019 calcium carbonate Inorganic materials 0.000 description 6
239000007788 liquid Substances 0.000 description 6
238000006116 polymerization reaction Methods 0.000 description 6
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 5
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
229910001424 calcium ion Inorganic materials 0.000 description 5
239000001506 calcium phosphate Substances 0.000 description 5
229910000389 calcium phosphate Inorganic materials 0.000 description 5
235000011010 calcium phosphates Nutrition 0.000 description 5
239000012085 test solution Substances 0.000 description 5
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 5
229910052725 zinc Inorganic materials 0.000 description 5
239000011701 zinc Substances 0.000 description 5
230000000694 effects Effects 0.000 description 4
239000003112 inhibitor Substances 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
229910001209 Low-carbon steel Inorganic materials 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
239000011575 calcium Substances 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
238000005260 corrosion Methods 0.000 description 3
230000007797 corrosion Effects 0.000 description 3
239000008235 industrial water Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
238000003756 stirring Methods 0.000 description 3
229920001059 synthetic polymer Polymers 0.000 description 3
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000000034 method Methods 0.000 description 2
ZJAOAACCNHFJAH-UHFFFAOYSA-N phosphonoformic acid Chemical compound OC(=O)P(O)(O)=O ZJAOAACCNHFJAH-UHFFFAOYSA-N 0.000 description 2
230000002265 prevention Effects 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000004220 aggregation Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001339 alkali metal compounds Chemical class 0.000 description 1
150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
229960005102 foscarnet Drugs 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
239000003456 ion exchange resin Substances 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229920005610 lignin Polymers 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
229940045641 monobasic sodium phosphate Drugs 0.000 description 1
229910000403 monosodium phosphate Inorganic materials 0.000 description 1
235000019799 monosodium phosphate Nutrition 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920001444 polymaleic acid Polymers 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1

Landscapes

Preventing Corrosion Or Incrustation Of Metals (AREA)

JP8279781A 1981-05-29 1981-05-29 Scale inhibitor Granted JPS57197097A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP8279781A JPS57197097A (en)	1981-05-29	1981-05-29	Scale inhibitor

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP8279781A JPS57197097A (en)	1981-05-29	1981-05-29	Scale inhibitor

Publications (2)

Publication Number	Publication Date
JPS57197097A JPS57197097A (en)	1982-12-03
JPS6223640B2 true JPS6223640B2 (de)	1987-05-25

Family

ID=13784391

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP8279781A Granted JPS57197097A (en)	1981-05-29	1981-05-29	Scale inhibitor

Country Status (1)

Country	Link
JP (1)	JPS57197097A (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP4645978B2 (ja) *	2001-01-24	2011-03-09	栗田工業株式会社	スケール防止剤

1981
- 1981-05-29 JP JP8279781A patent/JPS57197097A/ja active Granted

Also Published As

Publication number	Publication date
JPS57197097A (en)	1982-12-03

Publication	Publication Date	Title
US4469615A (en)	1984-09-04	Water treating compositions
US4207405A (en)	1980-06-10	Water-soluble phosphorus containing carboxylic polymers
US5980776A (en)	1999-11-09	Phosphonic acid polymers
CA1330390C (en)	1994-06-28	Cooling water corrosion inhibition method
US4209487A (en)	1980-06-24	Method for corrosion inhibition
US4317744A (en)	1982-03-02	Corrosion inhibitor
AU644480B2 (en)	1993-12-09	Inhibition of scale
US4692315A (en)	1987-09-08	Method of inhibiting corrosion in aqueous systems
US4744949A (en)	1988-05-17	Method for preventing corrosion in aqueous systems
NZ228752A (en)	1991-09-25	Composition for inhibiting corrosion in an aqueous system comprising a molybdate ion source and a polymer, a phosphonate or a polyphosphoric acid
US4033896A (en)	1977-07-05	Method of corrosion inhibition and compositions therefor
US4640818A (en)	1987-02-03	Corrosion inhibition of metals in water systems using aminophosphonic acid derivatives in combination with manganese
JPS63137799A (ja)	1988-06-09	ホスホン酸カルシウムスケール沈澱を防止する組成物および方法
GB2178023A (en)	1987-02-04	Corrosion inhibitor
US5093005A (en)	1992-03-03	Method for controlling scale
EP0277412B1 (de)	1992-05-06	Korrosionsinhibierung von Eisenmetallen
US4432884A (en)	1984-02-21	Scale inhibiting agent
US4401587A (en)	1983-08-30	Aminomethylphosphonic acid and polymaleic anhydride combinations for treating corrosion
JPH0146593B2 (de)	1989-10-09
JPS602918B2 (ja)	1985-01-24	スケ−ル防止剤
US4963631A (en)	1990-10-16	Polymers
JPH0630785B2 (ja)	1994-04-27	水性系の腐食、及びスケールの形成及び析出を抑制する方法
JPS6260000B2 (de)	1987-12-14
US5180790A (en)	1993-01-19	Water soluble complexing agent for metallic cations
US4886617A (en)	1989-12-12	Water soluble phosphonated polymers