JPS6228455B2 - - Google Patents
Info
- Publication number
- JPS6228455B2 JPS6228455B2 JP54016341A JP1634179A JPS6228455B2 JP S6228455 B2 JPS6228455 B2 JP S6228455B2 JP 54016341 A JP54016341 A JP 54016341A JP 1634179 A JP1634179 A JP 1634179A JP S6228455 B2 JPS6228455 B2 JP S6228455B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver
- layer
- component
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 claims description 62
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 36
- 229920000642 polymer Polymers 0.000 claims description 31
- 239000003638 chemical reducing agent Substances 0.000 claims description 21
- 239000011941 photocatalyst Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 76
- -1 silver halide Chemical class 0.000 description 51
- 229910052709 silver Inorganic materials 0.000 description 41
- 239000004332 silver Substances 0.000 description 41
- 150000003378 silver Chemical class 0.000 description 30
- 239000000243 solution Substances 0.000 description 17
- VFJYIHQDILEQNR-UHFFFAOYSA-M trimethylsulfanium;iodide Chemical compound [I-].C[S+](C)C VFJYIHQDILEQNR-UHFFFAOYSA-M 0.000 description 17
- 239000000203 mixture Substances 0.000 description 15
- 239000000123 paper Substances 0.000 description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 239000000126 substance Substances 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000011229 interlayer Substances 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 7
- 125000003545 alkoxy group Chemical group 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 7
- 239000000975 dye Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- FUGYGGDSWSUORM-UHFFFAOYSA-N 4-hydroxystyrene Chemical compound OC1=CC=C(C=C)C=C1 FUGYGGDSWSUORM-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 125000004423 acyloxy group Chemical group 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 5
- 125000004104 aryloxy group Chemical group 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 125000001841 imino group Chemical group [H]N=* 0.000 description 5
- 235000013824 polyphenols Nutrition 0.000 description 5
- AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 235000021357 Behenic acid Nutrition 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000002390 adhesive tape Substances 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 229940116226 behenic acid Drugs 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 150000008442 polyphenolic compounds Chemical class 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 206010070834 Sensitisation Diseases 0.000 description 3
- 241001061127 Thione Species 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 3
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 239000004815 dispersion polymer Substances 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 125000001624 naphthyl group Chemical group 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 230000008313 sensitization Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 125000003396 thiol group Chemical group [H]S* 0.000 description 3
- FYADHXFMURLYQI-UHFFFAOYSA-N 1,2,4-triazine Chemical class C1=CN=NC=N1 FYADHXFMURLYQI-UHFFFAOYSA-N 0.000 description 2
- UXTZUUVTGMDXNG-UHFFFAOYSA-N 1,2-benzoxazine-3,4-dione Chemical class C1=CC=C2C(=O)C(=O)NOC2=C1 UXTZUUVTGMDXNG-UHFFFAOYSA-N 0.000 description 2
- AVRPFRMDMNDIDH-UHFFFAOYSA-N 1h-quinazolin-2-one Chemical class C1=CC=CC2=NC(O)=NC=C21 AVRPFRMDMNDIDH-UHFFFAOYSA-N 0.000 description 2
- JESXATFQYMPTNL-UHFFFAOYSA-N 2-ethenylphenol Chemical compound OC1=CC=CC=C1C=C JESXATFQYMPTNL-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920001747 Cellulose diacetate Polymers 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 2
- LQZMLBORDGWNPD-UHFFFAOYSA-N N-iodosuccinimide Chemical compound IN1C(=O)CCC1=O LQZMLBORDGWNPD-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 2
- 150000001785 cerium compounds Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910001502 inorganic halide Inorganic materials 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N iodoform Chemical compound IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 2
- YSZIOXAEADAJLX-UHFFFAOYSA-N phthalazine-1,4-dione Chemical class C1=CC=C2C(=O)N=NC(=O)C2=C1 YSZIOXAEADAJLX-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 125000005543 phthalimide group Chemical class 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- CVYDEWKUJFCYJO-UHFFFAOYSA-M sodium;docosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O CVYDEWKUJFCYJO-UHFFFAOYSA-M 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- PPTXVXKCQZKFBN-UHFFFAOYSA-N (S)-(-)-1,1'-Bi-2-naphthol Chemical group C1=CC=C2C(C3=C4C=CC=CC4=CC=C3O)=C(O)C=CC2=C1 PPTXVXKCQZKFBN-UHFFFAOYSA-N 0.000 description 1
- GVTLFGJNTIRUEG-ZHACJKMWSA-N (e)-n-(3-methoxyphenyl)-3-phenylprop-2-enamide Chemical compound COC1=CC=CC(NC(=O)\C=C\C=2C=CC=CC=2)=C1 GVTLFGJNTIRUEG-ZHACJKMWSA-N 0.000 description 1
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical class O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- UOJUPXODQRLOBQ-UHFFFAOYSA-N 1-(2-hydroxy-6-nitronaphthalen-1-yl)-6-nitronaphthalen-2-ol Chemical group [O-][N+](=O)C1=CC=C2C(C3=C4C=CC(=CC4=CC=C3O)[N+]([O-])=O)=C(O)C=CC2=C1 UOJUPXODQRLOBQ-UHFFFAOYSA-N 0.000 description 1
- ZPANWZBSGMDWON-UHFFFAOYSA-N 1-[(2-hydroxynaphthalen-1-yl)methyl]naphthalen-2-ol Chemical compound C1=CC=C2C(CC3=C4C=CC=CC4=CC=C3O)=C(O)C=CC2=C1 ZPANWZBSGMDWON-UHFFFAOYSA-N 0.000 description 1
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- SHRGFZRBJZPBFT-UHFFFAOYSA-N 1-bromo-1,2,4-triazolidine-3,5-dione Chemical compound BrN1NC(=O)NC1=O SHRGFZRBJZPBFT-UHFFFAOYSA-N 0.000 description 1
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
- FSIZEHNSBFCXPM-UHFFFAOYSA-N 1-oxophthalazine-2-carboxamide Chemical compound C1=CC=C2C(=O)N(C(=O)N)N=CC2=C1 FSIZEHNSBFCXPM-UHFFFAOYSA-N 0.000 description 1
- KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- JFZFRIKFAXTVMP-UHFFFAOYSA-N 2,4-bis(3-tert-butyl-2-hydroxy-5-methylphenyl)-3-methylbicyclo[3.1.1]hepta-1,3,5-trien-6-ol Chemical compound C1C2=C(C1=C(C(=C2C1=C(C(=CC(=C1)C)C(C)(C)C)O)C)C1=C(C(=CC(=C1)C)C(C)(C)C)O)O JFZFRIKFAXTVMP-UHFFFAOYSA-N 0.000 description 1
- ROKOECFNTZMAGR-UHFFFAOYSA-N 2,4-ditert-butyl-6-[(3,5-ditert-butyl-2-hydroxyphenyl)-phenylmethyl]phenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(C(C=2C=CC=CC=2)C=2C(=C(C=C(C=2)C(C)(C)C)C(C)(C)C)O)=C1O ROKOECFNTZMAGR-UHFFFAOYSA-N 0.000 description 1
- LXWZXEJDKYWBOW-UHFFFAOYSA-N 2,4-ditert-butyl-6-[(3,5-ditert-butyl-2-hydroxyphenyl)methyl]phenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)C)C(C)(C)C)O)=C1O LXWZXEJDKYWBOW-UHFFFAOYSA-N 0.000 description 1
- QHPKIUDQDCWRKO-UHFFFAOYSA-N 2,6-ditert-butyl-4-[2-(3,5-ditert-butyl-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(C(C)(C)C=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 QHPKIUDQDCWRKO-UHFFFAOYSA-N 0.000 description 1
- DUUBQTCYVNKWFW-UHFFFAOYSA-N 2-(1-hydroxy-4-methoxynaphthalen-2-yl)-4-methoxynaphthalen-1-ol Chemical group C1=CC=CC2=C(O)C(C=3C=C(C4=CC=CC=C4C=3O)OC)=CC(OC)=C21 DUUBQTCYVNKWFW-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- PSMWHAYJHHEURK-UHFFFAOYSA-N 2-[(2-hydroxy-3,5-dimethylphenyl)-phenylmethyl]-4,6-dimethylphenol Chemical compound CC1=CC(C)=C(O)C(C(C=2C=CC=CC=2)C=2C(=C(C)C=C(C)C=2)O)=C1 PSMWHAYJHHEURK-UHFFFAOYSA-N 0.000 description 1
- SZAQZZKNQILGPU-UHFFFAOYSA-N 2-[1-(2-hydroxy-3,5-dimethylphenyl)-2-methylpropyl]-4,6-dimethylphenol Chemical compound C=1C(C)=CC(C)=C(O)C=1C(C(C)C)C1=CC(C)=CC(C)=C1O SZAQZZKNQILGPU-UHFFFAOYSA-N 0.000 description 1
- PZTWFIMBPRYBOD-UHFFFAOYSA-N 2-acetylphthalazin-1-one Chemical compound C1=CC=C2C(=O)N(C(=O)C)N=CC2=C1 PZTWFIMBPRYBOD-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- LDLCZOVUSADOIV-UHFFFAOYSA-N 2-bromoethanol Chemical compound OCCBr LDLCZOVUSADOIV-UHFFFAOYSA-N 0.000 description 1
- MARXMDRWROUXMD-UHFFFAOYSA-N 2-bromoisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(Br)C(=O)C2=C1 MARXMDRWROUXMD-UHFFFAOYSA-N 0.000 description 1
- MLMGJTAJUDSUKA-UHFFFAOYSA-N 2-ethenyl-1h-imidazole Chemical class C=CC1=NC=CN1 MLMGJTAJUDSUKA-UHFFFAOYSA-N 0.000 description 1
- JXPDNDHCMMOJPC-UHFFFAOYSA-N 2-hydroxybutanedinitrile Chemical class N#CC(O)CC#N JXPDNDHCMMOJPC-UHFFFAOYSA-N 0.000 description 1
- FLFWJIBUZQARMD-UHFFFAOYSA-N 2-mercapto-1,3-benzoxazole Chemical class C1=CC=C2OC(S)=NC2=C1 FLFWJIBUZQARMD-UHFFFAOYSA-N 0.000 description 1
- UIQPERPLCCTBGX-UHFFFAOYSA-N 2-phenylacetic acid;silver Chemical compound [Ag].OC(=O)CC1=CC=CC=C1 UIQPERPLCCTBGX-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- OBAVEFZNJPQRRC-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)-phenylmethyl]-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(C(C=2C=CC=CC=2)C=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O OBAVEFZNJPQRRC-UHFFFAOYSA-N 0.000 description 1
- GHNLJDPNIAIWOQ-UHFFFAOYSA-N 2h-1$l^{6},2-benzothiazine 1,1-dioxide Chemical class C1=CC=C2S(=O)(=O)NC=CC2=C1 GHNLJDPNIAIWOQ-UHFFFAOYSA-N 0.000 description 1
- DABNZWMZHPDHFD-UHFFFAOYSA-N 3-bromo-2h-1,3-oxazole Chemical compound BrN1COC=C1 DABNZWMZHPDHFD-UHFFFAOYSA-N 0.000 description 1
- NHLAPJMCARJFOG-UHFFFAOYSA-N 3-methyl-1,4-dihydropyrazol-5-one Chemical compound CC1=NNC(=O)C1 NHLAPJMCARJFOG-UHFFFAOYSA-N 0.000 description 1
- RLLNOZZVLWEBBI-UHFFFAOYSA-N 4-methyl-3h-quinazolin-2-one Chemical compound C1=CC=CC2=C(C)NC(=O)N=C21 RLLNOZZVLWEBBI-UHFFFAOYSA-N 0.000 description 1
- PUGUFBAPNSPHHY-UHFFFAOYSA-N 4-phenyl-1h-1,2,4-triazole-5-thione Chemical class SC1=NN=CN1C1=CC=CC=C1 PUGUFBAPNSPHHY-UHFFFAOYSA-N 0.000 description 1
- OORIFUHRGQKYEV-UHFFFAOYSA-N 6-bromo-1-(6-bromo-2-hydroxynaphthalen-1-yl)naphthalen-2-ol Chemical group BrC1=CC=C2C(C3=C4C=CC(Br)=CC4=CC=C3O)=C(O)C=CC2=C1 OORIFUHRGQKYEV-UHFFFAOYSA-N 0.000 description 1
- SHVCSCWHWMSGTE-UHFFFAOYSA-N 6-methyluracil Chemical class CC1=CC(=O)NC(=O)N1 SHVCSCWHWMSGTE-UHFFFAOYSA-N 0.000 description 1
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical group CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- AXVCDCGTJGNMKM-UHFFFAOYSA-L C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] Chemical compound C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] AXVCDCGTJGNMKM-UHFFFAOYSA-L 0.000 description 1
- HIJJMXBSLCYHBI-UHFFFAOYSA-M C(CCCCCCCCCCCCCCCCCCCCCCCCCCC)(=O)[O-].[Ag+] Chemical compound C(CCCCCCCCCCCCCCCCCCCCCCCCCCC)(=O)[O-].[Ag+] HIJJMXBSLCYHBI-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 150000000996 L-ascorbic acids Chemical class 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical group [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 229920001986 Vinylidene chloride-vinyl chloride copolymer Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
- NZHXEWZGTQSYJM-UHFFFAOYSA-N [bromo(diphenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Br)C1=CC=CC=C1 NZHXEWZGTQSYJM-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229940051880 analgesics and antipyretics pyrazolones Drugs 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229940045985 antineoplastic platinum compound Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 150000007656 barbituric acids Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- UBNQPQUDOHAIGE-UHFFFAOYSA-N benzenesulfonamide;naphthalen-1-ol Chemical compound NS(=O)(=O)C1=CC=CC=C1.C1=CC=C2C(O)=CC=CC2=C1 UBNQPQUDOHAIGE-UHFFFAOYSA-N 0.000 description 1
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical class C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- UUZYBYIOAZTMGC-UHFFFAOYSA-M benzyl(trimethyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)CC1=CC=CC=C1 UUZYBYIOAZTMGC-UHFFFAOYSA-M 0.000 description 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- KDPAWGWELVVRCH-UHFFFAOYSA-N bromoacetic acid Chemical compound OC(=O)CBr KDPAWGWELVVRCH-UHFFFAOYSA-N 0.000 description 1
- 229950005228 bromoform Drugs 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000004744 butyloxycarbonyl group Chemical group 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- VXIVSQZSERGHQP-UHFFFAOYSA-N chloroacetamide Chemical group NC(=O)CCl VXIVSQZSERGHQP-UHFFFAOYSA-N 0.000 description 1
- 125000002668 chloroacetyl group Chemical group ClCC(=O)* 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229920001688 coating polymer Polymers 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002508 contact lithography Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- OPTDDWCXQQYKGU-UHFFFAOYSA-N diphenyldichloromethane Chemical compound C=1C=CC=CC=1C(Cl)(Cl)C1=CC=CC=C1 OPTDDWCXQQYKGU-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- VUFOSBDICLTFMS-UHFFFAOYSA-M ethyl-hexadecyl-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CC VUFOSBDICLTFMS-UHFFFAOYSA-M 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002344 gold compounds Chemical class 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 150000002443 hydroxylamines Chemical class 0.000 description 1
- JJIKCECWEYPAGR-UHFFFAOYSA-N icosanoic acid;silver Chemical compound [Ag].CCCCCCCCCCCCCCCCCCCC(O)=O JJIKCECWEYPAGR-UHFFFAOYSA-N 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 150000002731 mercury compounds Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- OTVPURYEWXIAKH-UHFFFAOYSA-N n,n-dibromobenzenesulfonamide Chemical compound BrN(Br)S(=O)(=O)C1=CC=CC=C1 OTVPURYEWXIAKH-UHFFFAOYSA-N 0.000 description 1
- DLJMSHXCPBXOKX-UHFFFAOYSA-N n,n-dibutylprop-2-enamide Chemical compound CCCCN(C(=O)C=C)CCCC DLJMSHXCPBXOKX-UHFFFAOYSA-N 0.000 description 1
- SQARMCGNIUBXAJ-UHFFFAOYSA-N n-(2-hydroxyphenyl)benzenesulfonamide Chemical compound OC1=CC=CC=C1NS(=O)(=O)C1=CC=CC=C1 SQARMCGNIUBXAJ-UHFFFAOYSA-N 0.000 description 1
- KFPBEVFQCXRYIR-UHFFFAOYSA-N n-(3,5-dichloro-4-hydroxyphenyl)benzenesulfonamide Chemical compound C1=C(Cl)C(O)=C(Cl)C=C1NS(=O)(=O)C1=CC=CC=C1 KFPBEVFQCXRYIR-UHFFFAOYSA-N 0.000 description 1
- WHZPMLXZOSFAKY-UHFFFAOYSA-N n-(4-hydroxyphenyl)benzenesulfonamide Chemical compound C1=CC(O)=CC=C1NS(=O)(=O)C1=CC=CC=C1 WHZPMLXZOSFAKY-UHFFFAOYSA-N 0.000 description 1
- FWLGGSWAIHNLLW-UHFFFAOYSA-N n-bromo-n-phenylacetamide Chemical compound CC(=O)N(Br)C1=CC=CC=C1 FWLGGSWAIHNLLW-UHFFFAOYSA-N 0.000 description 1
- VBTQNRFWXBXZQR-UHFFFAOYSA-N n-bromoacetamide Chemical compound CC(=O)NBr VBTQNRFWXBXZQR-UHFFFAOYSA-N 0.000 description 1
- YRVUCYWJQFRCOB-UHFFFAOYSA-N n-butylprop-2-enamide Chemical compound CCCCNC(=O)C=C YRVUCYWJQFRCOB-UHFFFAOYSA-N 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- KPCHOCIEAXFUHZ-UHFFFAOYSA-N oxadiazole-4-thiol Chemical class SC1=CON=N1 KPCHOCIEAXFUHZ-UHFFFAOYSA-N 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 150000001475 oxazolidinediones Chemical class 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 150000002941 palladium compounds Chemical class 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical group CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- CWMRFSSMSXQUJC-UHFFFAOYSA-N pyrrole-2-thione Chemical class S=C1C=CC=N1 CWMRFSSMSXQUJC-UHFFFAOYSA-N 0.000 description 1
- 150000003236 pyrrolines Chemical class 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010187 selection method Methods 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- LMEWRZSPCQHBOB-UHFFFAOYSA-M silver;2-hydroxypropanoate Chemical compound [Ag+].CC(O)C([O-])=O LMEWRZSPCQHBOB-UHFFFAOYSA-M 0.000 description 1
- CLDWGXZGFUNWKB-UHFFFAOYSA-M silver;benzoate Chemical compound [Ag+].[O-]C(=O)C1=CC=CC=C1 CLDWGXZGFUNWKB-UHFFFAOYSA-M 0.000 description 1
- LKSDDVCOLMJDNV-UHFFFAOYSA-L silver;bromosilver;docosanoate Chemical compound [Ag+].[Ag]Br.CCCCCCCCCCCCCCCCCCCCCC([O-])=O LKSDDVCOLMJDNV-UHFFFAOYSA-L 0.000 description 1
- MNMYRUHURLPFQW-UHFFFAOYSA-M silver;dodecanoate Chemical compound [Ag+].CCCCCCCCCCCC([O-])=O MNMYRUHURLPFQW-UHFFFAOYSA-M 0.000 description 1
- BDAZBZUQNUAZTB-UHFFFAOYSA-M silver;hexacosanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O BDAZBZUQNUAZTB-UHFFFAOYSA-M 0.000 description 1
- LTYHQUJGIQUHMS-UHFFFAOYSA-M silver;hexadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCC([O-])=O LTYHQUJGIQUHMS-UHFFFAOYSA-M 0.000 description 1
- ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 1
- FCXSOSQMZSSZMU-UHFFFAOYSA-M silver;pentacosanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O FCXSOSQMZSSZMU-UHFFFAOYSA-M 0.000 description 1
- LPYHADGLCYWDNC-UHFFFAOYSA-M silver;tetracosanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCCCC([O-])=O LPYHADGLCYWDNC-UHFFFAOYSA-M 0.000 description 1
- OHGHHPYRRURLHR-UHFFFAOYSA-M silver;tetradecanoate Chemical compound [Ag+].CCCCCCCCCCCCCC([O-])=O OHGHHPYRRURLHR-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- BUUPQKDIAURBJP-UHFFFAOYSA-N sulfinic acid Chemical compound OS=O BUUPQKDIAURBJP-UHFFFAOYSA-N 0.000 description 1
- 150000003455 sulfinic acids Chemical class 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- LIXPXSXEKKHIRR-UHFFFAOYSA-M tetraethylphosphanium;bromide Chemical compound [Br-].CC[P+](CC)(CC)CC LIXPXSXEKKHIRR-UHFFFAOYSA-M 0.000 description 1
- 125000003831 tetrazolyl group Chemical group 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000001467 thiazolidinediones Chemical class 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- GNMJFQWRASXXMS-UHFFFAOYSA-M trimethyl(phenyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)C1=CC=CC=C1 GNMJFQWRASXXMS-UHFFFAOYSA-M 0.000 description 1
- JBWKIWSBJXDJDT-UHFFFAOYSA-N triphenylmethyl chloride Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 JBWKIWSBJXDJDT-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/49836—Additives
- G03C1/49863—Inert additives, e.g. surfactants, binders
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/162—Protective or antiabrasion layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/165—Thermal imaging composition
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
æ¬çºæã¯ç±çŸåæå
ææã«é¢ãããã®ã§ããã
ç¹ã«éå±€æ§æãæããç±çŸåæå ææã®åå±€éã®
å¯çãæ¹è¯ãããç±çŸåæå ææã«é¢ãããã®ã§
ããã ç±çŸåæå ææã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3152904
å·åã³å第3457075å·åæ现æžã«èšèŒãããŠãã
ããã«ãããã³é žéãªã©ã®ææ©éå¡©ãææ©éå¡©ã®
ããã®éå å€åã³é²å ã«ãã該ææ©éå¡©ãšéå å€
ã®å ç±äžã§ã®åå¿ã®è§Šåªãšãªãç©è³ªãæŸåºããå
觊åªïŒäŸãã°ããã²ã³åéïŒãå¿ é ã®æ§æã åãš
ãã液åŠçãå šãå¿ èŠãšããªãå®å šä¹ŸåŒåŠçåã®
åçææã§ãããããªãã¡ããã®åçææã¯åžžæž©
ã«ãããŠã¯å®å®ã§ãããããããåé²å åŸã«é
åžžã枩床80â以äžã奜ãŸããã¯100â以äžã«å ç±
ãããšãæå å±€äžã®ææ©éå¡©ïŒé žåå€ïŒãšéå å€
ãšããã®è¿åã«ååšããé²å ãããå 觊åªã®è§Šåª
äœçšã«ãã€ãŠé žåéå åå¿ãããããŠéãçæ
ããããã«ãã€ãŠæå å±€ã®é²å éšåããã¿ããã«
é»åããŠæªé²å éšåïŒèæ¯ïŒãšã®éã«ã³ã³ãã©ã¹
ããçããŠç»åã圢æãããã®ã§ããã ç±çŸåæå ææã¯ãæãåçŽã«ã¯ãæ¯æäœäžã«
äžèšã®å¿ é æ§æã åã®å šãŠãïŒå±€ã«ãŸãšããŠå¡åž
ããããšã«ãã€ãŠæ§æãããããäžèšå¿ é æ§æã
åã©ããè¥ããã¯ä»ã®æ·»å å€ïŒäŸãã°è²èª¿å€ïŒãš
ã®æåå¿ãé²ãããã«åæåãå¥ã ã®å±€ã«åæ£ã
ãŠå€å±€ã«å¡åžãããããŸãã¯ç¹éæ53â87721å·
å ¬å ±ã«èšãããŠããããã«ç±ã«ããªãé²æ¢ããã
ãã«æ¯æäœãšäžèšã®å±€ã®éã«äžå¡ãå±€ãé 眮ãã
ããæŽã«ã¯ç¹éæ49â6917å·å ¬å ±ã«èšèŒãããŠã
ãããã«å¡èã®éæ床ãé«ããããçµæä¿åæ§ã
æ¹è¯ããããã«äžå¡ãããªããŒå±€ãèšãããªã©ã®
éå±€æ§æãæ¡çšããããšãå€ãã ãšãããããããéå±€æ§æã«ããå Žåãåå±€ã®
å¢çã«ãããå¯çã®æªãã«èµ·å ããæ¬ é¥ãçãã
åå±€ã¯ãã®å¢çé¢ã§å®¹æã«ã¯ãããŠããŸãïŒãã
ãèã¯ãããšããïŒãšããåé¡ãçããããšãçº
èŠãããããã®å±€éå¯çã®æªåã®åé¡ã¯ãäžè¬ã®
ãŒã©ãã³âããã²ã³åéåçæå ææã®åéã§ã¯
å€ãããç 究ãããŠããŠããããç±çŸåæå ææ
ã«ãããŠã¯æ°ããåé¡ã§ããããã®è§£æ±ºã瀺åã
ãå è¡æè¡ã¯ã»ãšãã©ãªãã ç±çŸåæå ææã«ãããèã¯ããã¯ç±çŸåæ©ã®
çŸåããŒã©ãŒã®æ±ãã«ããç±çŸåæã«çºçããã
ãšããããããŸãçŸåã®æžãã ç±çŸåæå ææã
æå§æ¥çããŒãã§å£ãªã©ã«ã¯ãã€ããŠãããåŸã
ã®æå§æ¥çããŒããã¯ãããšãã«çºçããããŸ
ããäžèšã®èã¯ããã¯ç±çŸåæå ææã®ã©ã®å±€ã®
éã§ãçºçããããç¹ã«äžå¡ãããªããŒå±€ãšãã®
äžã®å±€ã®éã§çããããããã®èã¯ãããçãã
ãšãè€ååãç Žå£ããããåã¯éåžžã«å€èªãã«ã
ããªãã åŸã€ãŠãæ¬çºæã®ç®çã¯éå±€æ§æãæããç±çŸ
åæå ææã®åå±€éã®å¯çãæ¹è¯ããèã¯ããã
é²æ¢ãããç±çŸåæå ææãæäŸããããšã«ã
ããæ¬çºæã®ç®çã¯ç¹ã«äžå¡ãå±€ãæããç±çŸå
æå ææã®äžå¡ãããªããŒå±€ãšãã®äžã®å±€ã®éã®
èã¯ãããé²æ¢ãããç±çŸåæå ææãæäŸãã
ããšã«ããã æ¬çºæã®ç®çã¯ä»ã®åçç¹æ§ã«æªåœ±é¿ãåãŒã
ãªãæ段ã«ãã€ãŠäžèšæ¬ é¥ãé²æ¢ãããç±çŸåæ
å ææãæäŸããããšã«ããã ãããè«žç®çãéæããæ¬çºæã¯æ¬¡ã®åŠãæè¡
çæ§æãæãããã®ã§ãããå³ã¡æ¬çºæã¯ãæ¯æ
äœäžã«ïŒå±€ä»¥äžã®éå±€ãæãã該éå±€ã®ïŒå±€åã¯
ïŒå±€ä»¥äžã«ããã€ãŠå°ãªããšã(a)ææ©éå¡©ã(b)å
觊åªåã³(c)éå å€ãå«æããŠãªãç±çŸåæå ææ
ã«ãããŠã該éå±€ã®å°ãªããšãïŒå±€ã«(d)äžèšäžè¬
åŒã§è¡šããããåäœãæããéåäœãå«æããã
ãããšãç¹åŸŽãšããç±çŸåæå ææã§ããã ããã ããããã§ïŒ²ã¯æ°ŽçŽ åååã¯äœçŽã¢ã«ã
ã«åºãè¡šãããã¯æ°ŽçŽ ååãåã¯ããã²ã³å
åããããåºãã·ã¢ãåºãã¢ã«ãã«åºãã¢ã«ã³ã
ã·åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ãã«ã¹ã«ã
ãã«åºãã¢ãªãŒã«ãªãã·åºãã¢ã·ã«åºãã¢ã·ã«ãª
ãã·åºåã³ã¢ã·ã«ã¢ããåºãããªã矀ããéžã°ã
ãïŒãïŒåã®åºãè¡šãããã æ¬çºæã«çšããããæå(a)ã®ææ©éå¡©ã¯ãåžžæ
ã§ã¯ç¡è²ãçœè²åã¯æ·¡è²ã§ããããé²å ãããå
觊åªïŒåŸè¿°ïŒã®ååšã®äžã«ã80â以äžã«å ç±ãã
ããšãã«éå å€ïŒåŸè¿°ïŒãšåå¿ããŠéïŒåïŒãç
ãããã®ã§ãã€ãŠãç±çŸåæå ææã«ãããŠç»å
圢ææåãšããŠã®æ©èœãæããã®ã§ãããããã
ææ©éå¡©ãšããŠã¯ã€ããåºãã¡ã«ã«ããåºãããª
ã³åºåã¯ã«ã«ããã·ã«åºãæããææ©ååç©ã®é
å¡©ãç¥ãããŠããããã®å ·äœäŸãšããŠã¯æ¬¡ã®ãã
ãªãã®ãããã (1) ã€ããåºãæããææ©ååç©ã®éå¡©ã®äŸãšã
ãŠã¯ããã³ãŸããªã¢ãŸãŒã«é¡ã®éå¡©ããã¿ã©ãž
ãã³é¡ã®éå¡©ããã³ãŸãªããµãžã³ãžãªã³é¡ã®é
å¡©ãã€ãããŸãŒã«é¡ã®éå¡©ãããã©ã¢ã¶ã€ã³ã
ã³é¡ã®éå¡©ããã³ã¿ã¢ã¶ã€ã³ãã³é¡ã®éå¡©ãª
ã©ã (2) ã¡ã«ã«ããåºåã¯ããªã³åºãæããææ©åå
ç©ã®éå¡©ã®äŸãšããŠã¯ãïŒâã¡ã«ã«ãããã³ãŸ
ãªããµãŸãŒã«é¡ã®éå¡©ãã¡ã«ã«ãããªããµãžã¢
ãŸãŒã«é¡ã®éå¡©ãïŒâã¡ã«ã«ãããã³ãŸãã¢ãŸ
ãŒã«é¡ã®éå¡©ãïŒâã¡ã«ã«ãããã³ãŸã€ãããŸ
ãŒã«é¡ã®éå¡©ãïŒâã¡ã«ã«ããâïŒâããšãã«
âïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«é¡ã®éå¡©ãªã©ã (3) ã«ã«ããã·ã«åºãæããææ©ååç©ã®éå¡©ã®
äŸãšããŠã¯ãèèªæã«ã«ãã³é žé¡ã®éå¡©ãè³éŠ
æã«ã«ãã³é žé¡ã®éå¡©ïŒäŸãã°å®æ¯éŠé žéãã
ã¿ã«é žéãããšãã«é ¢é žéã4â²âïœâãªã¯ã¿ã
ã·ã«ãªãã·ãžããšãã«âïŒâã«ã«ãã³é žã®éå¡©
ãªã©ïŒãªã©ã ãããã®ææ©éå¡©ã®æŽã«è©³ããå ·äœäŸåã³ãã
ã«èšãã以å€ã®ææ©éå¡©ã®äŸã«ã€ããŠã¯ãäŸãã°
ç±³åœç¹èš±ç¬¬3457075å·ãå第3549379å·ãå第
3785830å·ãå第3933507å·ãå第4009039å·åã³
è±åœç¹èš±ç¬¬1230642å·åæ现æžãåã¯ç¹éæ50â
93139å·ãå50â99719å·ãå51â22431å·ãå52
â141222å·åã³å53â36224å·åå ¬å ±ã®èšèŒã«ã
ã€ãŠå ¬ç¥ã§ãããæ¬çºæã«ãããŠãããããã®å ¬
ç¥ã®ææ©éå¡©ã®äžããé©å®éžæããŠæå(a)ãšããŠ
䜿çšããããšãã§ãããäŸãã°ãå 觊åªãšããŠã
ãã²ã³åéåã¯éè²çŽ æå æ§ã³ã³ãã¬ãã¯ã¹ã䜿
çšããå Žåã«ã¯ãäžèšã®å ¬ç¥ã®ææ©éå¡©ã®äžãã
å ã«æ¯èŒçå®å®ãªãã®ãéžæããŠçšããããã®å¥œ
ãŸããäŸãšããŠã¯ççŽ æ°10ä¹è³40ãç¹ã«18ä¹è³33
ã®é·éèèªæã«ã«ãã³é žã®éå¡©ãæããããå ·äœ
çã«ã¯ã©ãŠãªã³é žéãããªã¹ãã³é žéããã«ãã
ã³é žéãã¹ãã¢ãªã³é žéãã¢ã©ããžã³é žéããã
ã³é žéããªã°ãã»ãªã³é žéããã³ã¿ã³ãµã³é žéã
ã»ããã³é žéãããã¿ã³ãµã³é žéãã¢ã³ã¿ã³é ž
éãã¡ãªã·ã³é žéãã©ã¯ã»ã«é žéãªã©ãäŸç€ºãã
ããšãã§ããã ãããææ©éå¡©ã®åæã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3457075å·ãå第3458544å·ãå第3700458å·ãå
第3839049å·ãå第3960908å·ãè±åœç¹èš±ç¬¬
1173426å·åæ现æžåã¯ç¹éæ49â52626å·ãå51
â122011å·ãå52â14122å·åå ¬å ±ã«èšèŒããã
å ¬ç¥ã®çš®ã ã®æ¹æ³ã«ãã€ãŠéæããããç¹ã«ãæ
æ©é塩圢ææã«ç±³åœç¹èš±ç¬¬3700458å·æ现æžåã¯
ç¹éæ53â32015å·å ¬å ±ã«èšèŒãããããªããŒé¡
ããç±³åœç¹èš±ç¬¬3887597å·æ现æžç¹éæ49â13224
å·åã¯å51â41317å·åå ¬å ±ã«èšèŒãããå«éå±
ååç©ãååšãããŠãããšãææ©éå¡©ã®ç²å圢
æ ãç²åãµã€ãºåã³ïŒåã¯åçæ§ãæ¹è¯ã§ããã®
ã§å¥œãŸããããããã®å ±åæåã®äœ¿çšéã®å¥œãŸã
ãç¯å²ã¯ãçæãããææ©éå¡©ïŒã¢ã«ã«å¯ŸããŠã
ããªããŒé¡ã®å ŽåçŽ0.1ïœä¹è³çŽ1000ïœç¹ã«çŽïŒ
ïœä¹è³çŽ500ïœãå«éå±ååç©ã®å ŽåçŽ10-6ã¢ã«
ä¹è³10-1ã¢ã«ã§ããã äžèšã®ããšãããŠèª¿è£œãããææ©éå¡©ã®äžã§
ããé·åŸãçŽ0.01ãã¯ãã³ä¹è³çŽ10ãã¯ãã³ãç¹
ã«çŽ0.1ãã¯ãã³ä¹è³çŽïŒãã¯ãã³ã®ç²åãµã€ãº
ãæãããã®ã奜ãŸãã䜿çšãããã æ¬çºæã«ãããŠæå(a)ã®ææ©éå¡©ã¯ãæ¯æäœïŒ
m2åœãééã«æç®ããŠçŽ0.1ïœä¹è³çŽïŒïœã奜ãŸ
ããã¯çŽ0.2ïœä¹è³çŽ2.5ïœã®ç¯å²ã§çšããããã
ããã¯ãé©åºŠãªç»åæ¿åºŠãäžããã«å¿ èŠååãªé
ã®ç¯å²ã§ãã€ãŠããã®ç¯å²ããå°ãçšãããšç»å
æ¿åºŠãäžè¶³ã«ãªããããŸããã®ç¯å²ããå€ãçšã
ãŠãç»åæ¿åºŠã¯å¢å ãããããã€ãŠã³ã¹ãé«ã«ãª
ãã æ¬çºæã«çšããããæå(b)ã®å 觊åªã¯ãé»ç£æŸ
å°ç·ã®ç §å°ãåããããšã«ãã€ãŠãæå(a)ã®ææ©
éå¡©ãšæå(c)ã®éå å€ãšã®80â以äžã®å ç±äžã§ã®
éïŒåïŒåœ¢æåå¿ã觊åªããç©è³ªã«å€åãããè¥
ããã¯ãã®ãããªç©è³ªãæŸåºããèœåãæããã
ã®ã§ãã€ãŠãç±çŸåæå ææã«ãããŠæå æåå
ã³äžèšéïŒåïŒåœ¢æåå¿ã®è§ŠåªæåãšããŠæ©èœã
ããã®ã§ããããããå 觊åªãšããŠã¯ãé žåäºé
ãé žåãã¿ã³ãªã©ã®ç¡æ©å å°é»æ§ç©è³ªïŒç±³åœç¹èš±
第3152904å·æ现æžã«èšãããŠããééå±ãšãžã¢
ãŸã¹ã«ãã³é žè¥ããã¯ã¹ã«ãã€ã³é žãšã®å¡©ïŒå
ã³ïŒåã¯ç¹å ¬æ49â25498å·ãç¹éæ46â4728å·
å ¬å ±è¥ããã¯ç±³åœç¹èš±ç¬¬3933507å·æ现æžã«èšèŒ
ãããéãšè²çŽ ã®æå æ§ã³ã³ãã¬ãã¹ãç±³åœç¹èš±
第3457075å·æ现æžã«èšèŒãããæå æ§ããã²ã³
åéãªã©ã®æå æ§éå¡©ãªã©ããããéåžžææ©éå¡©
ïŒã¢ã«åœãçŽ0.001ä¹è³çŽ10ã¢ã«ã奜ãŸããã¯çŽ
0.01ä¹è³çŽïŒã¢ã«ã®ç¯å²ã§çšããããã ãããã®å 觊åªã®äžã§æ¬çºæã«çšããã®ã«æã
é©ããŠãããã®ã¯æå æ§ããã²ã³åéãäŸãã°å¡©
åéãèåéãæ²åéãå¡©èæ²åéãå¡©èåéã
å¡©æ²åéãæ²èåéåã¯ãããã®æ··åç©ã§ããã
æå æ§ããã²ã³åéã®å¥œãŸããç²åãµã€ãºã¯çŽ
0.001ãã¯ãã³ä¹è³çŽïŒãã¯ãã³ãç¹ã«çŽ0.01ã
ã¯ãã³ä¹è³çŽ0.5ãã¯ãã³ã§ããããŸãããã®äœ¿
çšéã®ç¯å²ã¯ãææ©éå¡©ïŒã¢ã«ã«å¯Ÿãã0.001ã¢
ã«ä¹è³0.7ã¢ã«ã奜ãŸããã¯çŽ0.01ã¢ã«ä¹è³çŽ0.5
ã¢ã«ã§ããã æå æ§ããã²ã³åéã¯ãã·ã³ã°ã«ãžãšããæ³è¥
ããã¯ããã«ãžãšããæ³ãªã©ã®åçæè¡ã®åéã§
å ¬ç¥ã®ä»»æã®æ¹æ³ã«ãããäŸãã°ãªãããã³ä¹³
å€ãã¢ã³ã¢ãã¢æ³ä¹³å€ãããªã·ã¢ããŒãåã¯ããª
ãšãŒãã«çæä¹³å€ãªã©ã®ä¹³å€ãšããŠäºãã調補
ãã次ãã§æ¬çºæã®ä»ã®æåãšæ··åããŠæ¬çºæã«
çšããçµæç©äžã«å°å ¥ããããšãã§ããããã®å Ž
åã«æ床ãé«ããç®çã§ææ©éå¡©ãšæå æ§ããã²
ã³åéã®æ¥è§Šãååã«è¡ãªããããããäŸãã°ã
æå æ§ããã²ã³åéä¹³å€ãäœãæã®ä¿è·ããªããŒ
ãšããŠç±³åœç¹èš±ç¬¬3706564å·ãå第3706565å·ãå
第3713833å·ãå第3748143å·ãè±åœç¹èš±ç¬¬
1362970å·åæ现æžã«èšèŒãããããªããã«ã¢ã»
ã¿ãŒã«é¡ãªã©ã®ãŒã©ãã³ä»¥å€ã®ããªããŒãçšãã
æ段ããè±åœç¹èš±ç¬¬1354186å·æ现æžã«èšãããŠ
ããããã«æå æ§ããã²ã³åéä¹³å€ã®ãŒã©ãã³ã
é µçŽ å解ããæ段åã¯ç±³åœç¹èš±ç¬¬4076539å·æ现
æžã«èšãããŠããããã«æå æ§ããã²ã³åéç²å
ãçé¢æŽ»æ§å€ã®ååšåã§èª¿è£œããããšã«ãã€ãŠä¿
è·ããªããŒã®äœ¿çšãçç¥ããæ段ãªã©ã®åæ段ã
é©çšããããšãã§ããã æ¬çºæã«äœ¿çšãããæå æ§ããã²ã³åéã¯ãŸã
è±åœç¹èš±ç¬¬1447454å·æ现æžã«èšèŒãããŠããã
ãã«ãããã²ã³åå€ãšææ©é塩圢ææ§æåïŒäŸã
ã°ããã³é žãããªãŠã å¡©ãªã©ïŒãšãå ±åãããæ··
å液ã«éã€ãªã³æº¶æ¶²ãæ³šå ¥ããããšã«ãã€ãŠææ©
éå¡©ã®çæãšã»ãŒåæã«çæãããããšãã§ã
ãã æŽã«ä»ã®æ¹æ³ãšããŠã¯ãäºãã調補ãããææ©
éå¡©ã®æº¶æ¶²è¥ããã¯åæ£æ¶²åã¯ææ©éå¡©ãå«ãã·
ãŒãææã«æå æ§ããã²ã³åé圢ææåãäœçšã
ããŠãææ©éå¡©ã®äžéšãæå æ§ããã²ã³åéã«å€
æãããããšãã§ããããã®ããã«ããŠåœ¢æãã
ãæå æ§ããã²ã³åéã¯ææ©éå¡©ãšæå¹ã«æ¥è§Šã
ãŠããŠå¥œãŸããäœçšãåãããäžèšã®æå æ§ãã
ã²ã³åé圢ææåãšã¯ææ©éå¡©ãšåå¿ããŠæå æ§
ããã²ã³åéãçæãããååç©ã§ãããã©ã®ã
ããªååç©ãããã«è©²åœãæå¹ã§ãããã¯æ¬¡ã®ã
ãšãç°¡åãªè©Šéšã§å€å¥ããããšãã§ãããããªã
ã¡ãææ©éå¡©ãšè©Šéšãããã¹ãååç©ãšãæ··åã
å¿ èŠãªãã°å ç±ããåŸã«ïŒžç·åææ³ã«ããããã²
ã³åéã«ç¹æã®åæããŒã¯ãããããšã調ã¹ãã®
ã§ããããããè©Šéšã«ãã€ãŠæå¹ã§ããããšã確
ãããããæå æ§ããã²ã³åé圢ææåãšããŠ
ã¯ãç¡æ©ããã²ã³åç©ããªããŠã ãã©ã€ãé¡ãã
ãã²ã³åçåæ°ŽçŽ é¡ãâããã²ã³ååç©ããã®
ä»ã®å«ããã²ã³ååç©ãããããã®å ·äœäŸã«ã€ã
ãŠã¯ç±³åœç¹èš±ç¬¬4009039å·ãå第3457075å·ãå第
4003749å·ãè±åœç¹èš±ç¬¬1498956å·ãå第1498956
å·åæ现æžåã³ç¹éæ53â27027å·ãå53â25420
å·åå ¬å ±ã«è©³èª¬ãããŠãããäžã«ãã®äžäŸã瀺
ãã (1) ç¡æ©ããã²ã³åç©ïŒäŸãã°MXnã§è¡šããã
ãããã²ã³åç©ïŒããã§ïŒã¯ããNH4åã³é
å±ååãè¡šãããã¯ClãBråã³ãè¡šã
ããïœã¯ïŒãåã³NH4ã®æã¯ïŒããïŒãéå±
ååã®æã¯ãã®åå䟡ãè¡šãããéå±ååãšã
ãŠã¯ããªããŠã ããããªãŠã ãã«ãªãŠã ãã»ã·
ãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãã¹ããã³ã
ãŠã ãããªãŠã ãäºéãã«ãããŠã ãæ°Žéã
é«ãã¢ã³ãã¢ã³ãã¯ãã ããã³ã¬ã³ãéãã³ã
ã«ããããã±ã«ãããžãŠã ãã»ãªãŠã ãªã©ãã
ãïŒã (2) ãªããŠã ãã©ã€ãé¡ïŒäŸãã°ããªã¡ãã«ããš
ãã«ã¢ã³ã¢ããŠã ãããã€ããã»ãã«ãšãã«ãž
ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããããªã¡ãã«ã
ã³ãžã«ã¢ã³ã¢ããŠã ãããã€ãã®ãããªã第ïŒ
çŽã¢ã³ã¢ããŠã ãã©ã€ãïŒããã©ãšãã«ããªã¹
ããªããŠã ãããã€ãã®ãããªç¬¬ïŒçŽããªã¹ã
ãªããŠã ãã©ã€ãïŒããªã¡ãã«ã¹ã«ãããŠã ã¢
ã€ãªãã€ãã®ãããªç¬¬ïŒçŽã¹ã«ãããŠã ãã©ã€
ããªã©ãããã (3) ããã²ã³åçåæ°ŽçŽ é¡ïŒäŸãã°ãšãŒããã«
ã ãããã¢ãã«ã ãåèåççŽ ãïŒâããã â
ïŒâã¡ãã«ãããã³ãªã©ãããã (4) âããã²ã³ååç©ïŒäŸãã°ïŒ®âã¯ãããã¯
ãé žã€ãããâããã ãã¯ãé žã€ãããâ
ããã ãã¿ã«ã€ãããâããã ã¢ã»ãã¢ã
ããâãšãŒããã¯ãé žã€ãããâããã ã
ã¿ã©ãŸã³ãâããã ãªããµãŸãªã³ãâã¯ã
ããã¿ã©ãŸã³ãâããã¢ã¢ã»ãã¢ããªãã
ïŒïŒ®âãžããã¢ãã³ãŒã³ã¹ã«ãã³ã¢ããã
âããã¢ââã¡ãã«ãã³ãŒã³ã¹ã«ãã³ã¢ã
ããïŒïŒïŒâãžããã¢âïŒïŒïŒâãžã¡ãã«ãã
ã³ãã€ã³ãâããã¢ãŠã©ãŸãŒã«ãªã©ãããã (5) ãã®ä»ã®å«ããã²ã³ååç©ïŒäŸãã°å¡©åããª
ããšãã«ã¡ãã«ãèåããªããšãã«ã¡ãã«ãïŒ
âããã é ¢é žãïŒâããã ãšã¿ããŒã«ãäºå¡©å
ãã³ãŸããšãã³ãªã©ãããã ãããã®æå æ§ããã²ã³åé圢ææåã¯ææ©é
å¡©ã«å¯ŸãååŠéè«çå°éçšãããããéåžžãã®ç¯
å²ã¯ææ©éå¡©ïŒã¢ã«ã«å¯ŸãçŽ0.0001ã¢ã«ä¹è³çŽ
0.7ã¢ã«ã奜ãŸããã¯çŽ0.01ã¢ã«ä¹è³çŽ0.5ã¢ã«ã«
èšå®ããããæå æ§ããã²ã³åé圢ææåã¯äžèš
ã®ç¯å²ã®äžã§ïŒçš®ä»¥äžäœµçšãããŠããããæå æ§
ããã²ã³åé圢ææåãçšããŠææ©éå¡©ã®äžéšã
æå æ§ããã²ã³åéã«å€æãããå·¥çšã®åå¿æž©
床ãåå¿æéãåå¿å§åçã®è«žæ¡ä»¶ã¯åºãç¯å²ã®
äžãããäœè£œã®ç®çã«åãããŠé©å®éžæãèšå®ã
ãããšãã§ããããéåžžãã®åå¿æž©åºŠã¯çŽâ20â
ä¹è³çŽ70âããã®åå¿æéã¯çŽ0.1ç§ä¹è³çŽ72æ
éããã®åå¿å§åã¯å€§æ°å§ã«èšå®ãããã®ã奜ãŸ
ããããŸãããã®åå¿ã¯åŸè¿°ããçµåå€ãšããŠäœ¿
çšãããããªããŒã®ååšäžã«è¡ãããããšã奜ãŸ
ããããã®éã®ããªããŒã®äœ¿çšéã¯ææ©éå¡©ïŒã¢
ã«åœã0.01ä¹è³100éééšã奜ãŸããã¯çŽ0.1ä¹è³
10éééšã§ããã äžèšããåçš®ã®æ¹æ³ã«ãã€ãŠèª¿è£œãããæå æ§
ããã²ã³åéã¯ãäŸãã°å«ç¡«é»ååç©ãéåå
ç©ãçœéååç©ããã©ãžãŠã ååç©ãéååç©ã
ã¹ãºååç©ãã¯ãã ååç©åã¯ãããã®çµåãã«
ãã€ãŠååŠå¢æããããšãã§ããããã®ååŠå¢æ
ã®æé ã«ã€ããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬4036650
å·ãè±åœç¹èš±ç¬¬1518850å·åæ现æžãç¹éæ51â
22430å·ãå51â78319å·ãå51â81124å·åå ¬å ±
ã«èšèŒãããŠããããŸãæå æ§ããã²ã³åé圢æ
æåã«ããææ©éå¡©ã®äžéšãæå æ§ããã²ã³åé
ã«å€æããæ æ§ã«ãããŠã¯ç±³åœç¹èš±ç¬¬3980482å·
æ现æžã«èšãããŠãããããªäœååéã®ã¢ããå
åç©ãå ±åãããŠããããšã«ãã€ãŠå¢æãéæã
ãããšãã§ããã æå(b)ã®å 觊åªãç¹ã«æå æ§ããã²ã³åéã¯
çš®ã ã®å ¬ç¥ã®è²çŽ ã«ãã€ãŠå åŠçã«å¢æããããš
ãã§ãããæå¹ãªå åŠå¢æè²çŽ ãšããŠã¯äŸãã°ã·
ã¢ãã³ãã¡ãã·ã¢ãã³ãããã·ã¢ãã³ãã³ã³ãã¬
ãã¯ã¹ïŒïŒæ žåã¯ïŒæ žã®ïŒã·ã¢ãã³è¥ããã¯ã¡ã
ã·ã¢ãã³ãããããŒã©ãŒã·ã¢ãã³ãã¹ããªã«ãã
ãã·ã¢ãã³ããªããœããŒã«ããããªããœããŒã«å
ã¯ããµã³ãã³ç³»ææãæãããããã·ã¢ãã³é¡ã®
è²çŽ ã®ãã¡ã§ãã¢ãŸãªã³æ žããªããµãŸãªã³æ žãã
ããªã³æ žãããªãžã³æ žããªããµãŸãŒã«æ žããã¢ãŸ
ãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸãŒã«æ žã®ãã
ãªå¡©åºæ§æ žãæãããã®ã奜ãŸããããŸãã¡ãã·
ã¢ãã³é¡ã®è²çŽ ã®ãã¡ã§ã¯äžèšã®å¡©åºæ§æ žãšå ±ã«
é žæ§æ žãšããŠããªããã³ãã€ã³æ žããããã³æ žã
ãªããµãŸãªãžã³ãžãªã³æ žããã¢ãŸãªãžã³ãžãªã³
æ žããã«ãããŒã«é žæ žããã¢ãŸãªã³ãªã³æ žããã
ã³ãããªã«æ žåã¯ãã©ãŸãã³æ žãæãããã®ã奜
ãŸãããç¹ã«äžèšã®ãã¡ã§ããã€ããåºåã¯ã«ã«
ããã·ã«åºãæããã·ã¢ãã³é¡åã³ã¡ãã·ã¢ãã³
é¡ã®è²çŽ ãæå¹ã§ãããå ·äœçã«ã¯ãäŸãã°ç±³åœ
ç¹èš±ç¬¬3761279å·ãå第3719495å·ãå第3877943
å·ãè±åœç¹èš±ç¬¬1466201å·ãå第1469117å·ãå第
1422057å·åæ现æžãç¹éæ51â27924å·ãå50â
156424å·å ¬å ±ãªã©ã«èšãããå ¬ç¥ã®è²çŽ ã®äžãã
é©å®éžæããäžèšå ¬ç¥äŸã®ææ³ã«åŸã€ãŠå 觊åªã®
è¿åã«äœçœ®ããããããšãã§ããããããã®å åŠ
å¢æè²çŽ ã¯æå(b)ã®å 觊åªïŒã¢ã«åœãçŽ10-4ã¢ã«
ä¹è³çŽïŒã¢ã«ã®ç¯å²ã§äœ¿çšãããã æ¬çºæã«çšããããæå(c)ã®éå å€ã¯ãé²å ã
ããå 觊åªã®äžã«80â以äžã«å ç±ãããæã«ææ©
éå¡©ãšåå¿ããŠãããéå ãããã®ã§ãã€ãŠãç±
çŸåæå ææã«ãããŠææ©éå¡©ãšå ±ã«é žåéå ç»
å圢ææ§çµæç©ãšããŠæ©èœãããã®ã§ãããé©åœ
ãªéå å€ã¯çšããããææ©éå¡©ã®çš®é¡ãæ§èœãç®
å®ã«ããŠæ±ºå®ããããäŸãã°éå ããé£ãææ©é
å¡©ã«å¯ŸããŠã¯åŒ·ãéå åãæããéå å€ãé©ããŠ
ãããéå ããæãææ©éå¡©ã«å¯ŸããŠã¯åŒ±ãéå
åãæããéå å€ãé©ããŠããã ç±çŸåæå ææã«çšããããéå å€ãšããŠäžè¬
ã«ç¥ãããŠãããã®ã«ã¯ãã¢ãããšããŒã«é¡ãïŒ
å以äžã®ããšããŒã«åºãæããããªããšããŒã«
é¡ãã¢ãããããŒã«é¡ããã¹ããããŒã«é¡ãïŒå
以äžã®æ°Žé žåºãæããããªããããã·ãã³ãŒã³
é¡ãïŒå以äžã®æ°Žé žåºãæããããªããããã·ã
ãã¿ã¬ã³é¡ãã¢ã¹ã³ã«ãã³é žé¡ãïŒâãã©ãŸãªã
ã³é¡ããã©ãŸãªã³âïŒâãªã³é¡ããã©ãŸãã³é¡ã
ããšãã¬ã³ãžã¢ãã³é¡ãéå æ§ç³é¡ãããããã·
ã«ã¢ãã³é¡ããã€ããããã³ã¢ããšãŒãã«é¡ãã
ãããªããµãã³é žé¡ãããã©ãžãé¡ãã¢ãããªã
ã·ã é¡ãâããããã·å°¿çŽ é¡ãªã©ããããæŽã«
詳ããã¯äŸãã°ç±³åœç¹èš±ç¬¬3615533å·ãå第
3679426å·ãå第3672904å·ãå第3751252å·ãå
第3782949å·ãå第3801321å·ãå第3794949å·ã
å第3801321å·ãå第3794488å·ãå第3893863
å·ãå第3887376å·ãå第3770448å·ãå第
3819382å·ãå第3773512å·ãå第3928686å·ãå
第3839048å·ãå第3887378å·ãå第4009039å·ã
å第4021249å·ãè±åœç¹èš±ç¬¬1486148å·è¥ããã¯ã
ã«ã®ãŒç¹èš±ç¬¬786086å·åæ现æžåã³ç¹éæ50â
36143å·ãå50â36110å·ãå50â116023å·ãå50
â99719å·ãå50â140113å·ãå51â51933å·ãå
51â23721å·ãå52â84727å·è¥ããã¯ç¹å ¬æ51â
35851å·åå ¬å ±ã«å ·äœçã«äŸç€ºãããéå å€ãã
ããæ¬çºæã®æå(c)ã¯ãã®ãããªå ¬ç¥ã®éå å€ã®
äžããé©å®éžæããããšãã§ãããéžææ¹æ³ãšã
ãŠã¯ãå®éã«ç±çŸåæå ææãäœã€ãŠã¿ãŠãã®å
çæ§ãè©äŸ¡ããããšã«ãã䜿çšããéå å€ã®åªå£
ã調ã¹ãæ¹æ³ãæãæçšã§ãããšèããããã äžèšããéå å€ã®äžã§ãææ©éå¡©ãšããŠèèªæ
ã«ã«ãã³é žéã䜿çšããå Žåã«å¥œãŸããéå å€ãš
ããŠã¯ãïŒå以äžã®ããšããŒã«åºãã¢ã«ãã¬ã³åº
åã¯ã€ãªãŠã«ãã€ãŠé£çµãããããªããšããŒã«
é¡ãç¹ã«è©²ããšããŒã«åºã®ããããã·ã«çœ®æäœçœ®
ã«é£ãªãïŒåã®çœ®æäœçœ®ã®å°ãªããšãã²ãšã€ã«ã¢
ã«ãã«åºïŒäŸãã°ã¡ãã«åºããšãã«åºããããã«
åºãïœâããã«åºãã·ã¯ãããã·ã«åºãªã©ïŒåã¯
ã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºãããããªãã«åºãª
ã©ïŒã眮æããããšããŒã«åºã®ïŒå以äžãã¢ã«ã
ã¬ã³åºåã¯ã€ãªãŠã«ãã€ãŠé£çµãããããªããšã
ãŒã«é¡ãäŸãã°ïŒïŒïŒâãã¹ïŒïŒâããããã·â
ïŒïŒïŒâãžã¡ãã«ããšãã«ïŒâïŒïŒïŒïŒïŒâããª
ã¡ãã«ãããµã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·
âïŒâïœâããã«âïŒâã¡ãã«ããšãã«ïŒã¡ã¿
ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒâãž
âïœâããã«ããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒâã¡ãã¬
ã³ãã¹ïŒïŒâããããã·âïŒâïœâããã«âïŒâ
ã¡ãã«ããšãã«ïŒâïŒâã¡ãã«ããšããŒã«ãïŒïŒ
6â²âãã³ãžãªãã³âãã¹ïŒïŒïŒïŒâãžâïœâãã
ã«ããšããŒã«ïŒãïŒïŒ6â²âãã³ãžãªãã³âãã¹
ïŒïŒâïœâããã«âïŒâã¡ãã«ããšããŒã«ïŒãïŒïŒ
6â²âãã³ãžãªãã³âãã¹ïŒïŒïŒïŒâãžã¡ãã«ããš
ããŒã«ïŒãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒ
ïŒâãžã¡ãã«ããšãã«ïŒâïŒâã¡ãã«ãããã³ã
ïŒïŒïŒïŒïŒïŒïŒâããã©ãã¹ïŒïŒâããããã·â
ïŒïŒïŒâãžã¡ãã«ããšãã«ïŒâïŒïŒïŒâãšãã«ã
ã³ã¿ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒ
âãžã¡ãã«ïŒãããã³ãïŒïŒïŒâãã¹ïŒïŒâãã
ããã·âïŒïŒïŒâãžâïœâããã«ããšãã«ïŒãã
ãã³ãªã©ã®ç±³åœç¹èš±ç¬¬3589903å·ãå第4021249å·
è¥ããã¯è±åœç¹èš±ç¬¬1486148å·åæ现æžåã³ç¹é
æ51â51933å·ãå50â36110å·ãå50â116023
å·ãå52â84727å·è¥ããã¯ç¹å ¬æ51â35727å·å
å ¬å ±ã«èšèŒãããããªããšããŒã«ååç©ãïŒç±³åœ
ç¹èš±ç¬¬3672904å·æ现æžã«èšèŒããããã¹âβâ
ããããŒã«é¡ãäŸãã°ïŒïŒ2â²âãžããããã·â
ïŒïŒ1â²âããããã«ãïŒïŒ6â²âãžããã¢ãŒïŒïŒ
2â²âãžããããã·âïŒïŒ1â²âããããã«ãïŒïŒ
6â²âãžãããâïŒïŒ2â²âãžããããã·âïŒïŒ1â²â
ããããã«ããã¹ïŒïŒâããããã·âïŒâããã
ã«ïŒã¡ã¿ã³ãïŒïŒ4â²âãžã¡ããã·âïŒïŒ1â²âãžã
ãããã·âïŒïŒ2â²âããããã«ãªã©ãïŒç±³åœç¹èš±
第3801321å·æ现æžã«èšãããŠãããããªã¹ã«ã
ã³ã¢ããããšããŒã«åã¯ã¹ã«ãã³ã¢ããããããŒ
ã«é¡ïŒäŸãã°ïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããšã
ãŒã«ãïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããšããŒã«ã
ïŒïŒïŒâãžã¯ããâïŒâãã³ãŒã³ã¹ã«ãã³ã¢ãã
ããšããŒã«ãïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããã
ãŒã«ãªã©ïŒãæããããšãã§ããã æ¬çºæã«äœ¿çšãããéå å€ã®éã¯ãææ©éå¡©ã
éå å€ã®çš®é¡ããã®ä»ã®æ·»å å€ã«ãã€ãŠçš®ã å€å
ããããäžè¬çã«ã¯ææ©éå¡©ïŒã¢ã«åœãçŽ0.05ã¢
ã«ãçŽ10ã¢ã«ã奜ãŸããã¯çŽ0.1ãçŽïŒã¢ã«ãé©
åœã§ããããŸããã®éã®ç¯å²å ã«ãããŠãäžè¿°ã
ãéå å€ã¯ïŒçš®ä»¥äžäœµçšãããŠãããã äžèšããæå(a)ïŒ(b)åã³ïŒåã¯(c)ãåæ£ãå±€ã
æ§æããããã«çšããããçµåå€ãšããŠã¯ãç±çŸ
åæå ææã®åéã§çµåå€ãšããŠå ¬ç¥ã®åçš®é«å
åææãçšããããšãã§ãããäŸãã°ããŒã©ãã³
ã®åŠãèçœè³ªãã»ã«ããŒã¹èªå°äœãããã¹ãã©ã³
ã®åŠãããªãµãã«ã©ã€ãåã¯ã¢ã©ãã¢ãŽã ãªã©ã®
倩ç¶é«ååææããç±³åœç¹èš±ç¬¬4009039å·æ现æž
åã¯ç¹éæ50â126408å·ãå51â29126å·ãå51
â19525å·åã¯å49â84443å·åå ¬å ±ã«èšè¿°ãããŠ
ããåæé«ååææïŒäŸãã°ããªããã«ããã©ãŒ
ã«ãããªé ¢é žããã«ããšãã«ã»ã«ããŒã¹ãå¡©åã
ããªãã³ãŒå¡©åããã«ã³ããªããŒãããªã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒããå¡©åããã«âé ¢é žããã«ã³ããªã
ãŒãã»ã«ããŒã¹ã¢ã»ããŒãããã¬ãŒãåã¯ããªã
ãã«ã¢ã«ã³ãŒã«ãªã©ïŒãæãããããããã®äžã§
ãçæ°Žæ§ã®åæé«ååææãç¹ã«å¥œãŸããã ãããé«ååææã¯ããã®äžã«åæ£ããããæ
åãæ æããããã«ååãªéå³ã¡çµåå€ãšããŠæ
å¹ãªéã®ç¯å²ã§çšããããããã®ç¯å²ã¯åœæ¥è ã«
ãšã€ãŠé©å®æ±ºå®ã§ãããã®ã§ããããäžäŸãšããŠ
å°ãªããšãææ©éå¡©ãåæ£æ æããããå Žåã¯ã
ææ©éå¡©ã«å¯Ÿãééæ¯ã§çŽ10察ïŒä¹è³ïŒå¯Ÿ10ãç¹
ã«çŽïŒå¯Ÿä¹è³ïŒå¯ŸïŒã®ç¯å²ã§çšããããã æå(a)ã(c)ã¯äžèšã®çµåå€äžã«åã ã«åæ£ã
åã å¥ã ã®ïŒå±€ã«å¡åžããŠãããããã ããæ床
ãé«ãããããã«ã¯æå(a)ãš(b)ãäºãã«å¯æ¥ã«æ¥
觊ããŠããªããã°ãªããªãã®ã§ãå°ãªããšãæå
(a)ãš(b)ã¯åäžå±€å ã«å«æãããããšã奜ãŸããã
ãã®å Žåãæå(c)ã¯æå(a)ãš(b)ãå«æããå±€ã«å ±
ã«å«æãããŠãããããæå(a)ãš(b)ãå«æããå±€
ã«é£ç¶ããå¥ã®å±€ã«å«æãããŠãããã æå(a)ãš(b)ãå«æããå±€ãšæå(c)ãå«æããå±€
ã®éå±€æ§æããšã€ãå Žåãæ¬çºæã®æå(d)ããã®
äž¡å±€ã®å°ãªããšãäžæ¹ã«å«æããããããšã«ãã
äž¡å±€ã®å¯çãæ¹è¯ãããã ãŸããæå(a)ã(c)ãåäžå±€ã«å«æãããå Žåã
æ¬çºæã®æå(d)ããã®å±€ãšãã®å±€ã«é£æ¥ããè£å©
å±€ïŒäŸãã°ç±³åœç¹èš±ç¬¬4021229å·æ现æžã«èšèŒã
ããäžå¡ãå±€åã¯ç±³åœç¹èš±ç¬¬3933508å·æ现æžã«
èšèŒãããäžå¡ãããªããŒå±€ïŒã®å°ãªããšãäžæ¹
ã«å«æããããããšã«ããäž¡å±€ã®éã®å¯çãæ¹è¯
ãããäžå¡ãå±€ã¯äžèšã«åŒçšããç¹èš±æ现æžã«è©³
説ãããŠããããã«ãæå(a)ã(c)ãå«æããå±€ãš
æ¯æäœã®éã«èšããããé«ååç©è³ªãããªãå±€ã§
ãã€ãŠãäŸãã°ããªé ¢é žããã«ãã»ã«ããŒã¹ã¢ã»
ããŒããé ¢é žãã³ããªããŒãå¡©åããã«âå¡©åã
ããªãã³ã³ããªããŒãããªããã«ã¢ã«ã³ãŒã«ãªã©
ã®é«ååç©è³ªãçšãããéåžžïŒä¹è³20ãã¯ãã³ã®
åã¿ã§æ¯æäœäžã«èšããããã æ¬çºæã®æå(d)ã«ããå±€éå¯çæ¹è¯å¹æã¯ç¹ã«
æå(a)ã(c)ãå«ãå±€ãšäžå¡ãããªããŒå±€ãšã®éã§
ç¹ã«é¡èã«ç¢ºèªããããäžå¡ãããªããŒå±€ã¯äŸã
ã°ããªå¡©åããã«ãããªé ¢é žããã«ãå¡©é ¢ãã³ã
ãªããŒãå¡©åããã«âå¡©åãããªãã³ã³ããªã
ãŒãã«ã«ããã·ããªãšã¹ãã«é¡ãå¡©åãããªã
ã³ãããªã¹ãã¬ã³ãã¡ãã«ã»ã«ããŒã¹ããšãã«ã»
ã«ããŒã¹ãäºé ¢é žã»ã«ããŒã¹ãã»ã«ããŒã¹ã¢ã»ã
ãŒãããã¬ãŒãããŒã©ãã³ãããªããã«ã¢ã«ã³ãŒ
ã«çã®ç±³åœç¹èš±ç¬¬3933508å·åã¯å第3856526å·å
æ现æžã«èšèŒãããåçš®é«ååç©è³ªãæå(a)ã(c)
ãå«æããå±€ã®äžã«å¥œãŸããã¯çŽïŒã20ãã¯ãã³
ã®åã¿ã§èšãããã®ã§ãããäžå¡ãããªããŒå±€ã
æ§æããããã®é«ååç©è³ªã®äžã§ãçæ°Žæ§ã®é«å
åç©è³ªã奜ãŸããçšããããããªããæå(a)ãš(b)
ãå«ãå±€ãšã¯å¥ã«æå(c)ãå«ãå±€ãèšããå Žåã«
ããæå(c)ãå«ãå±€ãæ§æããé«ååç©è³ªãšããŠ
ã¯äžè¿°ããäžå¡ãããªããŒå±€ã«çšããã«å¥œé©ãªé«
ååç©è³ªã®äžããéžæãããã®ã奜ãŸããã åŸã€ãŠãæ¬çºæã®ç¹ã«å¥œãŸããå®æœæ æ§ãéå±€
æ§æã®é¢ããæããã°ã (1) æ¯æäœäžã«ãæå(a)ãš(b)ãå«æããå±€ãšæå
(c)ãå«æããå±€ãæãããã€è©²äž¡å±€ã®å°ãªããš
ãäžæ¹ã«æå(d)ãå«æããããç±çŸåæå æ
æã (2) æ¯æäœäžã«ãæå(a)ã(c)ãå«æããããå±€ãš
äžå¡ãããªããŒå±€ãæãããã€è©²äž¡å±€ã®å°ãªã
ãšãäžæ¹ã«æå(d)ãå«æããããç±çŸåæå æ
æãåã³ (3) äžèš(1)åã¯(2)ã«ãããŠæ¯æäœãšãã®äžã®å±€ã®
éã«äžå¡ãå±€ãèšããç±çŸåæå ææãã§ã
ãã äžèšããåå±€éã®å¯çæ¹è¯å¹æã¯ãæ¬çºæã®æ
å(d)ãå«æãããã¹ãå±€ãæ§æããçµåå€ã«å¯Ÿ
ããæ¬çºæã®æå(d)ã0.01ééïŒ ã100ééïŒ å«
æãããããšã«ãã€ãŠåçŸæ§ããåŸãããã奜ãŸ
ããã¯ãæå(d)ã¯è©²çµåå€ã«å¯Ÿã0.1ééïŒ ã10
ééïŒ ã®ç¯å²ã§å«æããããããããŸããäžèšã®
å±€éå¯çæ¹è¯ã®å¹æã¯æå(d)ã®å«æã®ããæ¹ã«ã
ã€ãŠåœ±é¿ãããããšã¯ãªãããæå(d)ã¯å¥œãŸãã
ã¯å¡åžåã«å¡åžæ¶²äžã«æ·»å ãããã æ¬çºæã®æå(d)ã¯ãç±çŸåæå ææã«èšããã
ãå±€ïŒäŸãã°æå æç±å±€ãšäžå¡ãå±€ãæå æç±å±€
ãšäžå¡ãå±€ïŒã®éã®å¯çã匷ããèã¯ãããé²æ¢
ããã®ã«èå¹ãããããããä»ã®åçç¹æ§ã«æªåœ±
é¿ããããŒãããšããªãã ãã®æå(d)ã®éåäœãæ§æããäžèšäžè¬åŒã§è¡š
ããããåäœã«ã€ãæŽã«å ·äœçã«èª¬æããã°ã
ç¹ã«éå±€æ§æãæããç±çŸåæå ææã®åå±€éã®
å¯çãæ¹è¯ãããç±çŸåæå ææã«é¢ãããã®ã§
ããã ç±çŸåæå ææã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3152904
å·åã³å第3457075å·åæ现æžã«èšèŒãããŠãã
ããã«ãããã³é žéãªã©ã®ææ©éå¡©ãææ©éå¡©ã®
ããã®éå å€åã³é²å ã«ãã該ææ©éå¡©ãšéå å€
ã®å ç±äžã§ã®åå¿ã®è§Šåªãšãªãç©è³ªãæŸåºããå
觊åªïŒäŸãã°ããã²ã³åéïŒãå¿ é ã®æ§æã åãš
ãã液åŠçãå šãå¿ èŠãšããªãå®å šä¹ŸåŒåŠçåã®
åçææã§ãããããªãã¡ããã®åçææã¯åžžæž©
ã«ãããŠã¯å®å®ã§ãããããããåé²å åŸã«é
åžžã枩床80â以äžã奜ãŸããã¯100â以äžã«å ç±
ãããšãæå å±€äžã®ææ©éå¡©ïŒé žåå€ïŒãšéå å€
ãšããã®è¿åã«ååšããé²å ãããå 觊åªã®è§Šåª
äœçšã«ãã€ãŠé žåéå åå¿ãããããŠéãçæ
ããããã«ãã€ãŠæå å±€ã®é²å éšåããã¿ããã«
é»åããŠæªé²å éšåïŒèæ¯ïŒãšã®éã«ã³ã³ãã©ã¹
ããçããŠç»åã圢æãããã®ã§ããã ç±çŸåæå ææã¯ãæãåçŽã«ã¯ãæ¯æäœäžã«
äžèšã®å¿ é æ§æã åã®å šãŠãïŒå±€ã«ãŸãšããŠå¡åž
ããããšã«ãã€ãŠæ§æãããããäžèšå¿ é æ§æã
åã©ããè¥ããã¯ä»ã®æ·»å å€ïŒäŸãã°è²èª¿å€ïŒãš
ã®æåå¿ãé²ãããã«åæåãå¥ã ã®å±€ã«åæ£ã
ãŠå€å±€ã«å¡åžãããããŸãã¯ç¹éæ53â87721å·
å ¬å ±ã«èšãããŠããããã«ç±ã«ããªãé²æ¢ããã
ãã«æ¯æäœãšäžèšã®å±€ã®éã«äžå¡ãå±€ãé 眮ãã
ããæŽã«ã¯ç¹éæ49â6917å·å ¬å ±ã«èšèŒãããŠã
ãããã«å¡èã®éæ床ãé«ããããçµæä¿åæ§ã
æ¹è¯ããããã«äžå¡ãããªããŒå±€ãèšãããªã©ã®
éå±€æ§æãæ¡çšããããšãå€ãã ãšãããããããéå±€æ§æã«ããå Žåãåå±€ã®
å¢çã«ãããå¯çã®æªãã«èµ·å ããæ¬ é¥ãçãã
åå±€ã¯ãã®å¢çé¢ã§å®¹æã«ã¯ãããŠããŸãïŒãã
ãèã¯ãããšããïŒãšããåé¡ãçããããšãçº
èŠãããããã®å±€éå¯çã®æªåã®åé¡ã¯ãäžè¬ã®
ãŒã©ãã³âããã²ã³åéåçæå ææã®åéã§ã¯
å€ãããç 究ãããŠããŠããããç±çŸåæå ææ
ã«ãããŠã¯æ°ããåé¡ã§ããããã®è§£æ±ºã瀺åã
ãå è¡æè¡ã¯ã»ãšãã©ãªãã ç±çŸåæå ææã«ãããèã¯ããã¯ç±çŸåæ©ã®
çŸåããŒã©ãŒã®æ±ãã«ããç±çŸåæã«çºçããã
ãšããããããŸãçŸåã®æžãã ç±çŸåæå ææã
æå§æ¥çããŒãã§å£ãªã©ã«ã¯ãã€ããŠãããåŸã
ã®æå§æ¥çããŒããã¯ãããšãã«çºçããããŸ
ããäžèšã®èã¯ããã¯ç±çŸåæå ææã®ã©ã®å±€ã®
éã§ãçºçããããç¹ã«äžå¡ãããªããŒå±€ãšãã®
äžã®å±€ã®éã§çããããããã®èã¯ãããçãã
ãšãè€ååãç Žå£ããããåã¯éåžžã«å€èªãã«ã
ããªãã åŸã€ãŠãæ¬çºæã®ç®çã¯éå±€æ§æãæããç±çŸ
åæå ææã®åå±€éã®å¯çãæ¹è¯ããèã¯ããã
é²æ¢ãããç±çŸåæå ææãæäŸããããšã«ã
ããæ¬çºæã®ç®çã¯ç¹ã«äžå¡ãå±€ãæããç±çŸå
æå ææã®äžå¡ãããªããŒå±€ãšãã®äžã®å±€ã®éã®
èã¯ãããé²æ¢ãããç±çŸåæå ææãæäŸãã
ããšã«ããã æ¬çºæã®ç®çã¯ä»ã®åçç¹æ§ã«æªåœ±é¿ãåãŒã
ãªãæ段ã«ãã€ãŠäžèšæ¬ é¥ãé²æ¢ãããç±çŸåæ
å ææãæäŸããããšã«ããã ãããè«žç®çãéæããæ¬çºæã¯æ¬¡ã®åŠãæè¡
çæ§æãæãããã®ã§ãããå³ã¡æ¬çºæã¯ãæ¯æ
äœäžã«ïŒå±€ä»¥äžã®éå±€ãæãã該éå±€ã®ïŒå±€åã¯
ïŒå±€ä»¥äžã«ããã€ãŠå°ãªããšã(a)ææ©éå¡©ã(b)å
觊åªåã³(c)éå å€ãå«æããŠãªãç±çŸåæå ææ
ã«ãããŠã該éå±€ã®å°ãªããšãïŒå±€ã«(d)äžèšäžè¬
åŒã§è¡šããããåäœãæããéåäœãå«æããã
ãããšãç¹åŸŽãšããç±çŸåæå ææã§ããã ããã ããããã§ïŒ²ã¯æ°ŽçŽ åååã¯äœçŽã¢ã«ã
ã«åºãè¡šãããã¯æ°ŽçŽ ååãåã¯ããã²ã³å
åããããåºãã·ã¢ãåºãã¢ã«ãã«åºãã¢ã«ã³ã
ã·åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ãã«ã¹ã«ã
ãã«åºãã¢ãªãŒã«ãªãã·åºãã¢ã·ã«åºãã¢ã·ã«ãª
ãã·åºåã³ã¢ã·ã«ã¢ããåºãããªã矀ããéžã°ã
ãïŒãïŒåã®åºãè¡šãããã æ¬çºæã«çšããããæå(a)ã®ææ©éå¡©ã¯ãåžžæ
ã§ã¯ç¡è²ãçœè²åã¯æ·¡è²ã§ããããé²å ãããå
觊åªïŒåŸè¿°ïŒã®ååšã®äžã«ã80â以äžã«å ç±ãã
ããšãã«éå å€ïŒåŸè¿°ïŒãšåå¿ããŠéïŒåïŒãç
ãããã®ã§ãã€ãŠãç±çŸåæå ææã«ãããŠç»å
圢ææåãšããŠã®æ©èœãæããã®ã§ãããããã
ææ©éå¡©ãšããŠã¯ã€ããåºãã¡ã«ã«ããåºãããª
ã³åºåã¯ã«ã«ããã·ã«åºãæããææ©ååç©ã®é
å¡©ãç¥ãããŠããããã®å ·äœäŸãšããŠã¯æ¬¡ã®ãã
ãªãã®ãããã (1) ã€ããåºãæããææ©ååç©ã®éå¡©ã®äŸãšã
ãŠã¯ããã³ãŸããªã¢ãŸãŒã«é¡ã®éå¡©ããã¿ã©ãž
ãã³é¡ã®éå¡©ããã³ãŸãªããµãžã³ãžãªã³é¡ã®é
å¡©ãã€ãããŸãŒã«é¡ã®éå¡©ãããã©ã¢ã¶ã€ã³ã
ã³é¡ã®éå¡©ããã³ã¿ã¢ã¶ã€ã³ãã³é¡ã®éå¡©ãª
ã©ã (2) ã¡ã«ã«ããåºåã¯ããªã³åºãæããææ©åå
ç©ã®éå¡©ã®äŸãšããŠã¯ãïŒâã¡ã«ã«ãããã³ãŸ
ãªããµãŸãŒã«é¡ã®éå¡©ãã¡ã«ã«ãããªããµãžã¢
ãŸãŒã«é¡ã®éå¡©ãïŒâã¡ã«ã«ãããã³ãŸãã¢ãŸ
ãŒã«é¡ã®éå¡©ãïŒâã¡ã«ã«ãããã³ãŸã€ãããŸ
ãŒã«é¡ã®éå¡©ãïŒâã¡ã«ã«ããâïŒâããšãã«
âïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«é¡ã®éå¡©ãªã©ã (3) ã«ã«ããã·ã«åºãæããææ©ååç©ã®éå¡©ã®
äŸãšããŠã¯ãèèªæã«ã«ãã³é žé¡ã®éå¡©ãè³éŠ
æã«ã«ãã³é žé¡ã®éå¡©ïŒäŸãã°å®æ¯éŠé žéãã
ã¿ã«é žéãããšãã«é ¢é žéã4â²âïœâãªã¯ã¿ã
ã·ã«ãªãã·ãžããšãã«âïŒâã«ã«ãã³é žã®éå¡©
ãªã©ïŒãªã©ã ãããã®ææ©éå¡©ã®æŽã«è©³ããå ·äœäŸåã³ãã
ã«èšãã以å€ã®ææ©éå¡©ã®äŸã«ã€ããŠã¯ãäŸãã°
ç±³åœç¹èš±ç¬¬3457075å·ãå第3549379å·ãå第
3785830å·ãå第3933507å·ãå第4009039å·åã³
è±åœç¹èš±ç¬¬1230642å·åæ现æžãåã¯ç¹éæ50â
93139å·ãå50â99719å·ãå51â22431å·ãå52
â141222å·åã³å53â36224å·åå ¬å ±ã®èšèŒã«ã
ã€ãŠå ¬ç¥ã§ãããæ¬çºæã«ãããŠãããããã®å ¬
ç¥ã®ææ©éå¡©ã®äžããé©å®éžæããŠæå(a)ãšããŠ
䜿çšããããšãã§ãããäŸãã°ãå 觊åªãšããŠã
ãã²ã³åéåã¯éè²çŽ æå æ§ã³ã³ãã¬ãã¯ã¹ã䜿
çšããå Žåã«ã¯ãäžèšã®å ¬ç¥ã®ææ©éå¡©ã®äžãã
å ã«æ¯èŒçå®å®ãªãã®ãéžæããŠçšããããã®å¥œ
ãŸããäŸãšããŠã¯ççŽ æ°10ä¹è³40ãç¹ã«18ä¹è³33
ã®é·éèèªæã«ã«ãã³é žã®éå¡©ãæããããå ·äœ
çã«ã¯ã©ãŠãªã³é žéãããªã¹ãã³é žéããã«ãã
ã³é žéãã¹ãã¢ãªã³é žéãã¢ã©ããžã³é žéããã
ã³é žéããªã°ãã»ãªã³é žéããã³ã¿ã³ãµã³é žéã
ã»ããã³é žéãããã¿ã³ãµã³é žéãã¢ã³ã¿ã³é ž
éãã¡ãªã·ã³é žéãã©ã¯ã»ã«é žéãªã©ãäŸç€ºãã
ããšãã§ããã ãããææ©éå¡©ã®åæã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3457075å·ãå第3458544å·ãå第3700458å·ãå
第3839049å·ãå第3960908å·ãè±åœç¹èš±ç¬¬
1173426å·åæ现æžåã¯ç¹éæ49â52626å·ãå51
â122011å·ãå52â14122å·åå ¬å ±ã«èšèŒããã
å ¬ç¥ã®çš®ã ã®æ¹æ³ã«ãã€ãŠéæããããç¹ã«ãæ
æ©é塩圢ææã«ç±³åœç¹èš±ç¬¬3700458å·æ现æžåã¯
ç¹éæ53â32015å·å ¬å ±ã«èšèŒãããããªããŒé¡
ããç±³åœç¹èš±ç¬¬3887597å·æ现æžç¹éæ49â13224
å·åã¯å51â41317å·åå ¬å ±ã«èšèŒãããå«éå±
ååç©ãååšãããŠãããšãææ©éå¡©ã®ç²å圢
æ ãç²åãµã€ãºåã³ïŒåã¯åçæ§ãæ¹è¯ã§ããã®
ã§å¥œãŸããããããã®å ±åæåã®äœ¿çšéã®å¥œãŸã
ãç¯å²ã¯ãçæãããææ©éå¡©ïŒã¢ã«ã«å¯ŸããŠã
ããªããŒé¡ã®å ŽåçŽ0.1ïœä¹è³çŽ1000ïœç¹ã«çŽïŒ
ïœä¹è³çŽ500ïœãå«éå±ååç©ã®å ŽåçŽ10-6ã¢ã«
ä¹è³10-1ã¢ã«ã§ããã äžèšã®ããšãããŠèª¿è£œãããææ©éå¡©ã®äžã§
ããé·åŸãçŽ0.01ãã¯ãã³ä¹è³çŽ10ãã¯ãã³ãç¹
ã«çŽ0.1ãã¯ãã³ä¹è³çŽïŒãã¯ãã³ã®ç²åãµã€ãº
ãæãããã®ã奜ãŸãã䜿çšãããã æ¬çºæã«ãããŠæå(a)ã®ææ©éå¡©ã¯ãæ¯æäœïŒ
m2åœãééã«æç®ããŠçŽ0.1ïœä¹è³çŽïŒïœã奜ãŸ
ããã¯çŽ0.2ïœä¹è³çŽ2.5ïœã®ç¯å²ã§çšããããã
ããã¯ãé©åºŠãªç»åæ¿åºŠãäžããã«å¿ èŠååãªé
ã®ç¯å²ã§ãã€ãŠããã®ç¯å²ããå°ãçšãããšç»å
æ¿åºŠãäžè¶³ã«ãªããããŸããã®ç¯å²ããå€ãçšã
ãŠãç»åæ¿åºŠã¯å¢å ãããããã€ãŠã³ã¹ãé«ã«ãª
ãã æ¬çºæã«çšããããæå(b)ã®å 觊åªã¯ãé»ç£æŸ
å°ç·ã®ç §å°ãåããããšã«ãã€ãŠãæå(a)ã®ææ©
éå¡©ãšæå(c)ã®éå å€ãšã®80â以äžã®å ç±äžã§ã®
éïŒåïŒåœ¢æåå¿ã觊åªããç©è³ªã«å€åãããè¥
ããã¯ãã®ãããªç©è³ªãæŸåºããèœåãæããã
ã®ã§ãã€ãŠãç±çŸåæå ææã«ãããŠæå æåå
ã³äžèšéïŒåïŒåœ¢æåå¿ã®è§ŠåªæåãšããŠæ©èœã
ããã®ã§ããããããå 觊åªãšããŠã¯ãé žåäºé
ãé žåãã¿ã³ãªã©ã®ç¡æ©å å°é»æ§ç©è³ªïŒç±³åœç¹èš±
第3152904å·æ现æžã«èšãããŠããééå±ãšãžã¢
ãŸã¹ã«ãã³é žè¥ããã¯ã¹ã«ãã€ã³é žãšã®å¡©ïŒå
ã³ïŒåã¯ç¹å ¬æ49â25498å·ãç¹éæ46â4728å·
å ¬å ±è¥ããã¯ç±³åœç¹èš±ç¬¬3933507å·æ现æžã«èšèŒ
ãããéãšè²çŽ ã®æå æ§ã³ã³ãã¬ãã¹ãç±³åœç¹èš±
第3457075å·æ现æžã«èšèŒãããæå æ§ããã²ã³
åéãªã©ã®æå æ§éå¡©ãªã©ããããéåžžææ©éå¡©
ïŒã¢ã«åœãçŽ0.001ä¹è³çŽ10ã¢ã«ã奜ãŸããã¯çŽ
0.01ä¹è³çŽïŒã¢ã«ã®ç¯å²ã§çšããããã ãããã®å 觊åªã®äžã§æ¬çºæã«çšããã®ã«æã
é©ããŠãããã®ã¯æå æ§ããã²ã³åéãäŸãã°å¡©
åéãèåéãæ²åéãå¡©èæ²åéãå¡©èåéã
å¡©æ²åéãæ²èåéåã¯ãããã®æ··åç©ã§ããã
æå æ§ããã²ã³åéã®å¥œãŸããç²åãµã€ãºã¯çŽ
0.001ãã¯ãã³ä¹è³çŽïŒãã¯ãã³ãç¹ã«çŽ0.01ã
ã¯ãã³ä¹è³çŽ0.5ãã¯ãã³ã§ããããŸãããã®äœ¿
çšéã®ç¯å²ã¯ãææ©éå¡©ïŒã¢ã«ã«å¯Ÿãã0.001ã¢
ã«ä¹è³0.7ã¢ã«ã奜ãŸããã¯çŽ0.01ã¢ã«ä¹è³çŽ0.5
ã¢ã«ã§ããã æå æ§ããã²ã³åéã¯ãã·ã³ã°ã«ãžãšããæ³è¥
ããã¯ããã«ãžãšããæ³ãªã©ã®åçæè¡ã®åéã§
å ¬ç¥ã®ä»»æã®æ¹æ³ã«ãããäŸãã°ãªãããã³ä¹³
å€ãã¢ã³ã¢ãã¢æ³ä¹³å€ãããªã·ã¢ããŒãåã¯ããª
ãšãŒãã«çæä¹³å€ãªã©ã®ä¹³å€ãšããŠäºãã調補
ãã次ãã§æ¬çºæã®ä»ã®æåãšæ··åããŠæ¬çºæã«
çšããçµæç©äžã«å°å ¥ããããšãã§ããããã®å Ž
åã«æ床ãé«ããç®çã§ææ©éå¡©ãšæå æ§ããã²
ã³åéã®æ¥è§Šãååã«è¡ãªããããããäŸãã°ã
æå æ§ããã²ã³åéä¹³å€ãäœãæã®ä¿è·ããªããŒ
ãšããŠç±³åœç¹èš±ç¬¬3706564å·ãå第3706565å·ãå
第3713833å·ãå第3748143å·ãè±åœç¹èš±ç¬¬
1362970å·åæ现æžã«èšèŒãããããªããã«ã¢ã»
ã¿ãŒã«é¡ãªã©ã®ãŒã©ãã³ä»¥å€ã®ããªããŒãçšãã
æ段ããè±åœç¹èš±ç¬¬1354186å·æ现æžã«èšãããŠ
ããããã«æå æ§ããã²ã³åéä¹³å€ã®ãŒã©ãã³ã
é µçŽ å解ããæ段åã¯ç±³åœç¹èš±ç¬¬4076539å·æ现
æžã«èšãããŠããããã«æå æ§ããã²ã³åéç²å
ãçé¢æŽ»æ§å€ã®ååšåã§èª¿è£œããããšã«ãã€ãŠä¿
è·ããªããŒã®äœ¿çšãçç¥ããæ段ãªã©ã®åæ段ã
é©çšããããšãã§ããã æ¬çºæã«äœ¿çšãããæå æ§ããã²ã³åéã¯ãŸã
è±åœç¹èš±ç¬¬1447454å·æ现æžã«èšèŒãããŠããã
ãã«ãããã²ã³åå€ãšææ©é塩圢ææ§æåïŒäŸã
ã°ããã³é žãããªãŠã å¡©ãªã©ïŒãšãå ±åãããæ··
å液ã«éã€ãªã³æº¶æ¶²ãæ³šå ¥ããããšã«ãã€ãŠææ©
éå¡©ã®çæãšã»ãŒåæã«çæãããããšãã§ã
ãã æŽã«ä»ã®æ¹æ³ãšããŠã¯ãäºãã調補ãããææ©
éå¡©ã®æº¶æ¶²è¥ããã¯åæ£æ¶²åã¯ææ©éå¡©ãå«ãã·
ãŒãææã«æå æ§ããã²ã³åé圢ææåãäœçšã
ããŠãææ©éå¡©ã®äžéšãæå æ§ããã²ã³åéã«å€
æãããããšãã§ããããã®ããã«ããŠåœ¢æãã
ãæå æ§ããã²ã³åéã¯ææ©éå¡©ãšæå¹ã«æ¥è§Šã
ãŠããŠå¥œãŸããäœçšãåãããäžèšã®æå æ§ãã
ã²ã³åé圢ææåãšã¯ææ©éå¡©ãšåå¿ããŠæå æ§
ããã²ã³åéãçæãããååç©ã§ãããã©ã®ã
ããªååç©ãããã«è©²åœãæå¹ã§ãããã¯æ¬¡ã®ã
ãšãç°¡åãªè©Šéšã§å€å¥ããããšãã§ãããããªã
ã¡ãææ©éå¡©ãšè©Šéšãããã¹ãååç©ãšãæ··åã
å¿ èŠãªãã°å ç±ããåŸã«ïŒžç·åææ³ã«ããããã²
ã³åéã«ç¹æã®åæããŒã¯ãããããšã調ã¹ãã®
ã§ããããããè©Šéšã«ãã€ãŠæå¹ã§ããããšã確
ãããããæå æ§ããã²ã³åé圢ææåãšããŠ
ã¯ãç¡æ©ããã²ã³åç©ããªããŠã ãã©ã€ãé¡ãã
ãã²ã³åçåæ°ŽçŽ é¡ãâããã²ã³ååç©ããã®
ä»ã®å«ããã²ã³ååç©ãããããã®å ·äœäŸã«ã€ã
ãŠã¯ç±³åœç¹èš±ç¬¬4009039å·ãå第3457075å·ãå第
4003749å·ãè±åœç¹èš±ç¬¬1498956å·ãå第1498956
å·åæ现æžåã³ç¹éæ53â27027å·ãå53â25420
å·åå ¬å ±ã«è©³èª¬ãããŠãããäžã«ãã®äžäŸã瀺
ãã (1) ç¡æ©ããã²ã³åç©ïŒäŸãã°MXnã§è¡šããã
ãããã²ã³åç©ïŒããã§ïŒã¯ããNH4åã³é
å±ååãè¡šãããã¯ClãBråã³ãè¡šã
ããïœã¯ïŒãåã³NH4ã®æã¯ïŒããïŒãéå±
ååã®æã¯ãã®åå䟡ãè¡šãããéå±ååãšã
ãŠã¯ããªããŠã ããããªãŠã ãã«ãªãŠã ãã»ã·
ãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãã¹ããã³ã
ãŠã ãããªãŠã ãäºéãã«ãããŠã ãæ°Žéã
é«ãã¢ã³ãã¢ã³ãã¯ãã ããã³ã¬ã³ãéãã³ã
ã«ããããã±ã«ãããžãŠã ãã»ãªãŠã ãªã©ãã
ãïŒã (2) ãªããŠã ãã©ã€ãé¡ïŒäŸãã°ããªã¡ãã«ããš
ãã«ã¢ã³ã¢ããŠã ãããã€ããã»ãã«ãšãã«ãž
ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããããªã¡ãã«ã
ã³ãžã«ã¢ã³ã¢ããŠã ãããã€ãã®ãããªã第ïŒ
çŽã¢ã³ã¢ããŠã ãã©ã€ãïŒããã©ãšãã«ããªã¹
ããªããŠã ãããã€ãã®ãããªç¬¬ïŒçŽããªã¹ã
ãªããŠã ãã©ã€ãïŒããªã¡ãã«ã¹ã«ãããŠã ã¢
ã€ãªãã€ãã®ãããªç¬¬ïŒçŽã¹ã«ãããŠã ãã©ã€
ããªã©ãããã (3) ããã²ã³åçåæ°ŽçŽ é¡ïŒäŸãã°ãšãŒããã«
ã ãããã¢ãã«ã ãåèåççŽ ãïŒâããã â
ïŒâã¡ãã«ãããã³ãªã©ãããã (4) âããã²ã³ååç©ïŒäŸãã°ïŒ®âã¯ãããã¯
ãé žã€ãããâããã ãã¯ãé žã€ãããâ
ããã ãã¿ã«ã€ãããâããã ã¢ã»ãã¢ã
ããâãšãŒããã¯ãé žã€ãããâããã ã
ã¿ã©ãŸã³ãâããã ãªããµãŸãªã³ãâã¯ã
ããã¿ã©ãŸã³ãâããã¢ã¢ã»ãã¢ããªãã
ïŒïŒ®âãžããã¢ãã³ãŒã³ã¹ã«ãã³ã¢ããã
âããã¢ââã¡ãã«ãã³ãŒã³ã¹ã«ãã³ã¢ã
ããïŒïŒïŒâãžããã¢âïŒïŒïŒâãžã¡ãã«ãã
ã³ãã€ã³ãâããã¢ãŠã©ãŸãŒã«ãªã©ãããã (5) ãã®ä»ã®å«ããã²ã³ååç©ïŒäŸãã°å¡©åããª
ããšãã«ã¡ãã«ãèåããªããšãã«ã¡ãã«ãïŒ
âããã é ¢é žãïŒâããã ãšã¿ããŒã«ãäºå¡©å
ãã³ãŸããšãã³ãªã©ãããã ãããã®æå æ§ããã²ã³åé圢ææåã¯ææ©é
å¡©ã«å¯ŸãååŠéè«çå°éçšãããããéåžžãã®ç¯
å²ã¯ææ©éå¡©ïŒã¢ã«ã«å¯ŸãçŽ0.0001ã¢ã«ä¹è³çŽ
0.7ã¢ã«ã奜ãŸããã¯çŽ0.01ã¢ã«ä¹è³çŽ0.5ã¢ã«ã«
èšå®ããããæå æ§ããã²ã³åé圢ææåã¯äžèš
ã®ç¯å²ã®äžã§ïŒçš®ä»¥äžäœµçšãããŠããããæå æ§
ããã²ã³åé圢ææåãçšããŠææ©éå¡©ã®äžéšã
æå æ§ããã²ã³åéã«å€æãããå·¥çšã®åå¿æž©
床ãåå¿æéãåå¿å§åçã®è«žæ¡ä»¶ã¯åºãç¯å²ã®
äžãããäœè£œã®ç®çã«åãããŠé©å®éžæãèšå®ã
ãããšãã§ããããéåžžãã®åå¿æž©åºŠã¯çŽâ20â
ä¹è³çŽ70âããã®åå¿æéã¯çŽ0.1ç§ä¹è³çŽ72æ
éããã®åå¿å§åã¯å€§æ°å§ã«èšå®ãããã®ã奜ãŸ
ããããŸãããã®åå¿ã¯åŸè¿°ããçµåå€ãšããŠäœ¿
çšãããããªããŒã®ååšäžã«è¡ãããããšã奜ãŸ
ããããã®éã®ããªããŒã®äœ¿çšéã¯ææ©éå¡©ïŒã¢
ã«åœã0.01ä¹è³100éééšã奜ãŸããã¯çŽ0.1ä¹è³
10éééšã§ããã äžèšããåçš®ã®æ¹æ³ã«ãã€ãŠèª¿è£œãããæå æ§
ããã²ã³åéã¯ãäŸãã°å«ç¡«é»ååç©ãéåå
ç©ãçœéååç©ããã©ãžãŠã ååç©ãéååç©ã
ã¹ãºååç©ãã¯ãã ååç©åã¯ãããã®çµåãã«
ãã€ãŠååŠå¢æããããšãã§ããããã®ååŠå¢æ
ã®æé ã«ã€ããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬4036650
å·ãè±åœç¹èš±ç¬¬1518850å·åæ现æžãç¹éæ51â
22430å·ãå51â78319å·ãå51â81124å·åå ¬å ±
ã«èšèŒãããŠããããŸãæå æ§ããã²ã³åé圢æ
æåã«ããææ©éå¡©ã®äžéšãæå æ§ããã²ã³åé
ã«å€æããæ æ§ã«ãããŠã¯ç±³åœç¹èš±ç¬¬3980482å·
æ现æžã«èšãããŠãããããªäœååéã®ã¢ããå
åç©ãå ±åãããŠããããšã«ãã€ãŠå¢æãéæã
ãããšãã§ããã æå(b)ã®å 觊åªãç¹ã«æå æ§ããã²ã³åéã¯
çš®ã ã®å ¬ç¥ã®è²çŽ ã«ãã€ãŠå åŠçã«å¢æããããš
ãã§ãããæå¹ãªå åŠå¢æè²çŽ ãšããŠã¯äŸãã°ã·
ã¢ãã³ãã¡ãã·ã¢ãã³ãããã·ã¢ãã³ãã³ã³ãã¬
ãã¯ã¹ïŒïŒæ žåã¯ïŒæ žã®ïŒã·ã¢ãã³è¥ããã¯ã¡ã
ã·ã¢ãã³ãããããŒã©ãŒã·ã¢ãã³ãã¹ããªã«ãã
ãã·ã¢ãã³ããªããœããŒã«ããããªããœããŒã«å
ã¯ããµã³ãã³ç³»ææãæãããããã·ã¢ãã³é¡ã®
è²çŽ ã®ãã¡ã§ãã¢ãŸãªã³æ žããªããµãŸãªã³æ žãã
ããªã³æ žãããªãžã³æ žããªããµãŸãŒã«æ žããã¢ãŸ
ãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸãŒã«æ žã®ãã
ãªå¡©åºæ§æ žãæãããã®ã奜ãŸããããŸãã¡ãã·
ã¢ãã³é¡ã®è²çŽ ã®ãã¡ã§ã¯äžèšã®å¡©åºæ§æ žãšå ±ã«
é žæ§æ žãšããŠããªããã³ãã€ã³æ žããããã³æ žã
ãªããµãŸãªãžã³ãžãªã³æ žããã¢ãŸãªãžã³ãžãªã³
æ žããã«ãããŒã«é žæ žããã¢ãŸãªã³ãªã³æ žããã
ã³ãããªã«æ žåã¯ãã©ãŸãã³æ žãæãããã®ã奜
ãŸãããç¹ã«äžèšã®ãã¡ã§ããã€ããåºåã¯ã«ã«
ããã·ã«åºãæããã·ã¢ãã³é¡åã³ã¡ãã·ã¢ãã³
é¡ã®è²çŽ ãæå¹ã§ãããå ·äœçã«ã¯ãäŸãã°ç±³åœ
ç¹èš±ç¬¬3761279å·ãå第3719495å·ãå第3877943
å·ãè±åœç¹èš±ç¬¬1466201å·ãå第1469117å·ãå第
1422057å·åæ现æžãç¹éæ51â27924å·ãå50â
156424å·å ¬å ±ãªã©ã«èšãããå ¬ç¥ã®è²çŽ ã®äžãã
é©å®éžæããäžèšå ¬ç¥äŸã®ææ³ã«åŸã€ãŠå 觊åªã®
è¿åã«äœçœ®ããããããšãã§ããããããã®å åŠ
å¢æè²çŽ ã¯æå(b)ã®å 觊åªïŒã¢ã«åœãçŽ10-4ã¢ã«
ä¹è³çŽïŒã¢ã«ã®ç¯å²ã§äœ¿çšãããã æ¬çºæã«çšããããæå(c)ã®éå å€ã¯ãé²å ã
ããå 觊åªã®äžã«80â以äžã«å ç±ãããæã«ææ©
éå¡©ãšåå¿ããŠãããéå ãããã®ã§ãã€ãŠãç±
çŸåæå ææã«ãããŠææ©éå¡©ãšå ±ã«é žåéå ç»
å圢ææ§çµæç©ãšããŠæ©èœãããã®ã§ãããé©åœ
ãªéå å€ã¯çšããããææ©éå¡©ã®çš®é¡ãæ§èœãç®
å®ã«ããŠæ±ºå®ããããäŸãã°éå ããé£ãææ©é
å¡©ã«å¯ŸããŠã¯åŒ·ãéå åãæããéå å€ãé©ããŠ
ãããéå ããæãææ©éå¡©ã«å¯ŸããŠã¯åŒ±ãéå
åãæããéå å€ãé©ããŠããã ç±çŸåæå ææã«çšããããéå å€ãšããŠäžè¬
ã«ç¥ãããŠãããã®ã«ã¯ãã¢ãããšããŒã«é¡ãïŒ
å以äžã®ããšããŒã«åºãæããããªããšããŒã«
é¡ãã¢ãããããŒã«é¡ããã¹ããããŒã«é¡ãïŒå
以äžã®æ°Žé žåºãæããããªããããã·ãã³ãŒã³
é¡ãïŒå以äžã®æ°Žé žåºãæããããªããããã·ã
ãã¿ã¬ã³é¡ãã¢ã¹ã³ã«ãã³é žé¡ãïŒâãã©ãŸãªã
ã³é¡ããã©ãŸãªã³âïŒâãªã³é¡ããã©ãŸãã³é¡ã
ããšãã¬ã³ãžã¢ãã³é¡ãéå æ§ç³é¡ãããããã·
ã«ã¢ãã³é¡ããã€ããããã³ã¢ããšãŒãã«é¡ãã
ãããªããµãã³é žé¡ãããã©ãžãé¡ãã¢ãããªã
ã·ã é¡ãâããããã·å°¿çŽ é¡ãªã©ããããæŽã«
詳ããã¯äŸãã°ç±³åœç¹èš±ç¬¬3615533å·ãå第
3679426å·ãå第3672904å·ãå第3751252å·ãå
第3782949å·ãå第3801321å·ãå第3794949å·ã
å第3801321å·ãå第3794488å·ãå第3893863
å·ãå第3887376å·ãå第3770448å·ãå第
3819382å·ãå第3773512å·ãå第3928686å·ãå
第3839048å·ãå第3887378å·ãå第4009039å·ã
å第4021249å·ãè±åœç¹èš±ç¬¬1486148å·è¥ããã¯ã
ã«ã®ãŒç¹èš±ç¬¬786086å·åæ现æžåã³ç¹éæ50â
36143å·ãå50â36110å·ãå50â116023å·ãå50
â99719å·ãå50â140113å·ãå51â51933å·ãå
51â23721å·ãå52â84727å·è¥ããã¯ç¹å ¬æ51â
35851å·åå ¬å ±ã«å ·äœçã«äŸç€ºãããéå å€ãã
ããæ¬çºæã®æå(c)ã¯ãã®ãããªå ¬ç¥ã®éå å€ã®
äžããé©å®éžæããããšãã§ãããéžææ¹æ³ãšã
ãŠã¯ãå®éã«ç±çŸåæå ææãäœã€ãŠã¿ãŠãã®å
çæ§ãè©äŸ¡ããããšã«ãã䜿çšããéå å€ã®åªå£
ã調ã¹ãæ¹æ³ãæãæçšã§ãããšèããããã äžèšããéå å€ã®äžã§ãææ©éå¡©ãšããŠèèªæ
ã«ã«ãã³é žéã䜿çšããå Žåã«å¥œãŸããéå å€ãš
ããŠã¯ãïŒå以äžã®ããšããŒã«åºãã¢ã«ãã¬ã³åº
åã¯ã€ãªãŠã«ãã€ãŠé£çµãããããªããšããŒã«
é¡ãç¹ã«è©²ããšããŒã«åºã®ããããã·ã«çœ®æäœçœ®
ã«é£ãªãïŒåã®çœ®æäœçœ®ã®å°ãªããšãã²ãšã€ã«ã¢
ã«ãã«åºïŒäŸãã°ã¡ãã«åºããšãã«åºããããã«
åºãïœâããã«åºãã·ã¯ãããã·ã«åºãªã©ïŒåã¯
ã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºãããããªãã«åºãª
ã©ïŒã眮æããããšããŒã«åºã®ïŒå以äžãã¢ã«ã
ã¬ã³åºåã¯ã€ãªãŠã«ãã€ãŠé£çµãããããªããšã
ãŒã«é¡ãäŸãã°ïŒïŒïŒâãã¹ïŒïŒâããããã·â
ïŒïŒïŒâãžã¡ãã«ããšãã«ïŒâïŒïŒïŒïŒïŒâããª
ã¡ãã«ãããµã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·
âïŒâïœâããã«âïŒâã¡ãã«ããšãã«ïŒã¡ã¿
ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒâãž
âïœâããã«ããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒâã¡ãã¬
ã³ãã¹ïŒïŒâããããã·âïŒâïœâããã«âïŒâ
ã¡ãã«ããšãã«ïŒâïŒâã¡ãã«ããšããŒã«ãïŒïŒ
6â²âãã³ãžãªãã³âãã¹ïŒïŒïŒïŒâãžâïœâãã
ã«ããšããŒã«ïŒãïŒïŒ6â²âãã³ãžãªãã³âãã¹
ïŒïŒâïœâããã«âïŒâã¡ãã«ããšããŒã«ïŒãïŒïŒ
6â²âãã³ãžãªãã³âãã¹ïŒïŒïŒïŒâãžã¡ãã«ããš
ããŒã«ïŒãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒ
ïŒâãžã¡ãã«ããšãã«ïŒâïŒâã¡ãã«ãããã³ã
ïŒïŒïŒïŒïŒïŒïŒâããã©ãã¹ïŒïŒâããããã·â
ïŒïŒïŒâãžã¡ãã«ããšãã«ïŒâïŒïŒïŒâãšãã«ã
ã³ã¿ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒ
âãžã¡ãã«ïŒãããã³ãïŒïŒïŒâãã¹ïŒïŒâãã
ããã·âïŒïŒïŒâãžâïœâããã«ããšãã«ïŒãã
ãã³ãªã©ã®ç±³åœç¹èš±ç¬¬3589903å·ãå第4021249å·
è¥ããã¯è±åœç¹èš±ç¬¬1486148å·åæ现æžåã³ç¹é
æ51â51933å·ãå50â36110å·ãå50â116023
å·ãå52â84727å·è¥ããã¯ç¹å ¬æ51â35727å·å
å ¬å ±ã«èšèŒãããããªããšããŒã«ååç©ãïŒç±³åœ
ç¹èš±ç¬¬3672904å·æ现æžã«èšèŒããããã¹âβâ
ããããŒã«é¡ãäŸãã°ïŒïŒ2â²âãžããããã·â
ïŒïŒ1â²âããããã«ãïŒïŒ6â²âãžããã¢ãŒïŒïŒ
2â²âãžããããã·âïŒïŒ1â²âããããã«ãïŒïŒ
6â²âãžãããâïŒïŒ2â²âãžããããã·âïŒïŒ1â²â
ããããã«ããã¹ïŒïŒâããããã·âïŒâããã
ã«ïŒã¡ã¿ã³ãïŒïŒ4â²âãžã¡ããã·âïŒïŒ1â²âãžã
ãããã·âïŒïŒ2â²âããããã«ãªã©ãïŒç±³åœç¹èš±
第3801321å·æ现æžã«èšãããŠãããããªã¹ã«ã
ã³ã¢ããããšããŒã«åã¯ã¹ã«ãã³ã¢ããããããŒ
ã«é¡ïŒäŸãã°ïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããšã
ãŒã«ãïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããšããŒã«ã
ïŒïŒïŒâãžã¯ããâïŒâãã³ãŒã³ã¹ã«ãã³ã¢ãã
ããšããŒã«ãïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããã
ãŒã«ãªã©ïŒãæããããšãã§ããã æ¬çºæã«äœ¿çšãããéå å€ã®éã¯ãææ©éå¡©ã
éå å€ã®çš®é¡ããã®ä»ã®æ·»å å€ã«ãã€ãŠçš®ã å€å
ããããäžè¬çã«ã¯ææ©éå¡©ïŒã¢ã«åœãçŽ0.05ã¢
ã«ãçŽ10ã¢ã«ã奜ãŸããã¯çŽ0.1ãçŽïŒã¢ã«ãé©
åœã§ããããŸããã®éã®ç¯å²å ã«ãããŠãäžè¿°ã
ãéå å€ã¯ïŒçš®ä»¥äžäœµçšãããŠãããã äžèšããæå(a)ïŒ(b)åã³ïŒåã¯(c)ãåæ£ãå±€ã
æ§æããããã«çšããããçµåå€ãšããŠã¯ãç±çŸ
åæå ææã®åéã§çµåå€ãšããŠå ¬ç¥ã®åçš®é«å
åææãçšããããšãã§ãããäŸãã°ããŒã©ãã³
ã®åŠãèçœè³ªãã»ã«ããŒã¹èªå°äœãããã¹ãã©ã³
ã®åŠãããªãµãã«ã©ã€ãåã¯ã¢ã©ãã¢ãŽã ãªã©ã®
倩ç¶é«ååææããç±³åœç¹èš±ç¬¬4009039å·æ现æž
åã¯ç¹éæ50â126408å·ãå51â29126å·ãå51
â19525å·åã¯å49â84443å·åå ¬å ±ã«èšè¿°ãããŠ
ããåæé«ååææïŒäŸãã°ããªããã«ããã©ãŒ
ã«ãããªé ¢é žããã«ããšãã«ã»ã«ããŒã¹ãå¡©åã
ããªãã³ãŒå¡©åããã«ã³ããªããŒãããªã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒããå¡©åããã«âé ¢é žããã«ã³ããªã
ãŒãã»ã«ããŒã¹ã¢ã»ããŒãããã¬ãŒãåã¯ããªã
ãã«ã¢ã«ã³ãŒã«ãªã©ïŒãæãããããããã®äžã§
ãçæ°Žæ§ã®åæé«ååææãç¹ã«å¥œãŸããã ãããé«ååææã¯ããã®äžã«åæ£ããããæ
åãæ æããããã«ååãªéå³ã¡çµåå€ãšããŠæ
å¹ãªéã®ç¯å²ã§çšããããããã®ç¯å²ã¯åœæ¥è ã«
ãšã€ãŠé©å®æ±ºå®ã§ãããã®ã§ããããäžäŸãšããŠ
å°ãªããšãææ©éå¡©ãåæ£æ æããããå Žåã¯ã
ææ©éå¡©ã«å¯Ÿãééæ¯ã§çŽ10察ïŒä¹è³ïŒå¯Ÿ10ãç¹
ã«çŽïŒå¯Ÿä¹è³ïŒå¯ŸïŒã®ç¯å²ã§çšããããã æå(a)ã(c)ã¯äžèšã®çµåå€äžã«åã ã«åæ£ã
åã å¥ã ã®ïŒå±€ã«å¡åžããŠãããããã ããæ床
ãé«ãããããã«ã¯æå(a)ãš(b)ãäºãã«å¯æ¥ã«æ¥
觊ããŠããªããã°ãªããªãã®ã§ãå°ãªããšãæå
(a)ãš(b)ã¯åäžå±€å ã«å«æãããããšã奜ãŸããã
ãã®å Žåãæå(c)ã¯æå(a)ãš(b)ãå«æããå±€ã«å ±
ã«å«æãããŠãããããæå(a)ãš(b)ãå«æããå±€
ã«é£ç¶ããå¥ã®å±€ã«å«æãããŠãããã æå(a)ãš(b)ãå«æããå±€ãšæå(c)ãå«æããå±€
ã®éå±€æ§æããšã€ãå Žåãæ¬çºæã®æå(d)ããã®
äž¡å±€ã®å°ãªããšãäžæ¹ã«å«æããããããšã«ãã
äž¡å±€ã®å¯çãæ¹è¯ãããã ãŸããæå(a)ã(c)ãåäžå±€ã«å«æãããå Žåã
æ¬çºæã®æå(d)ããã®å±€ãšãã®å±€ã«é£æ¥ããè£å©
å±€ïŒäŸãã°ç±³åœç¹èš±ç¬¬4021229å·æ现æžã«èšèŒã
ããäžå¡ãå±€åã¯ç±³åœç¹èš±ç¬¬3933508å·æ现æžã«
èšèŒãããäžå¡ãããªããŒå±€ïŒã®å°ãªããšãäžæ¹
ã«å«æããããããšã«ããäž¡å±€ã®éã®å¯çãæ¹è¯
ãããäžå¡ãå±€ã¯äžèšã«åŒçšããç¹èš±æ现æžã«è©³
説ãããŠããããã«ãæå(a)ã(c)ãå«æããå±€ãš
æ¯æäœã®éã«èšããããé«ååç©è³ªãããªãå±€ã§
ãã€ãŠãäŸãã°ããªé ¢é žããã«ãã»ã«ããŒã¹ã¢ã»
ããŒããé ¢é žãã³ããªããŒãå¡©åããã«âå¡©åã
ããªãã³ã³ããªããŒãããªããã«ã¢ã«ã³ãŒã«ãªã©
ã®é«ååç©è³ªãçšãããéåžžïŒä¹è³20ãã¯ãã³ã®
åã¿ã§æ¯æäœäžã«èšããããã æ¬çºæã®æå(d)ã«ããå±€éå¯çæ¹è¯å¹æã¯ç¹ã«
æå(a)ã(c)ãå«ãå±€ãšäžå¡ãããªããŒå±€ãšã®éã§
ç¹ã«é¡èã«ç¢ºèªããããäžå¡ãããªããŒå±€ã¯äŸã
ã°ããªå¡©åããã«ãããªé ¢é žããã«ãå¡©é ¢ãã³ã
ãªããŒãå¡©åããã«âå¡©åãããªãã³ã³ããªã
ãŒãã«ã«ããã·ããªãšã¹ãã«é¡ãå¡©åãããªã
ã³ãããªã¹ãã¬ã³ãã¡ãã«ã»ã«ããŒã¹ããšãã«ã»
ã«ããŒã¹ãäºé ¢é žã»ã«ããŒã¹ãã»ã«ããŒã¹ã¢ã»ã
ãŒãããã¬ãŒãããŒã©ãã³ãããªããã«ã¢ã«ã³ãŒ
ã«çã®ç±³åœç¹èš±ç¬¬3933508å·åã¯å第3856526å·å
æ现æžã«èšèŒãããåçš®é«ååç©è³ªãæå(a)ã(c)
ãå«æããå±€ã®äžã«å¥œãŸããã¯çŽïŒã20ãã¯ãã³
ã®åã¿ã§èšãããã®ã§ãããäžå¡ãããªããŒå±€ã
æ§æããããã®é«ååç©è³ªã®äžã§ãçæ°Žæ§ã®é«å
åç©è³ªã奜ãŸããçšããããããªããæå(a)ãš(b)
ãå«ãå±€ãšã¯å¥ã«æå(c)ãå«ãå±€ãèšããå Žåã«
ããæå(c)ãå«ãå±€ãæ§æããé«ååç©è³ªãšããŠ
ã¯äžè¿°ããäžå¡ãããªããŒå±€ã«çšããã«å¥œé©ãªé«
ååç©è³ªã®äžããéžæãããã®ã奜ãŸããã åŸã€ãŠãæ¬çºæã®ç¹ã«å¥œãŸããå®æœæ æ§ãéå±€
æ§æã®é¢ããæããã°ã (1) æ¯æäœäžã«ãæå(a)ãš(b)ãå«æããå±€ãšæå
(c)ãå«æããå±€ãæãããã€è©²äž¡å±€ã®å°ãªããš
ãäžæ¹ã«æå(d)ãå«æããããç±çŸåæå æ
æã (2) æ¯æäœäžã«ãæå(a)ã(c)ãå«æããããå±€ãš
äžå¡ãããªããŒå±€ãæãããã€è©²äž¡å±€ã®å°ãªã
ãšãäžæ¹ã«æå(d)ãå«æããããç±çŸåæå æ
æãåã³ (3) äžèš(1)åã¯(2)ã«ãããŠæ¯æäœãšãã®äžã®å±€ã®
éã«äžå¡ãå±€ãèšããç±çŸåæå ææãã§ã
ãã äžèšããåå±€éã®å¯çæ¹è¯å¹æã¯ãæ¬çºæã®æ
å(d)ãå«æãããã¹ãå±€ãæ§æããçµåå€ã«å¯Ÿ
ããæ¬çºæã®æå(d)ã0.01ééïŒ ã100ééïŒ å«
æãããããšã«ãã€ãŠåçŸæ§ããåŸãããã奜ãŸ
ããã¯ãæå(d)ã¯è©²çµåå€ã«å¯Ÿã0.1ééïŒ ã10
ééïŒ ã®ç¯å²ã§å«æããããããããŸããäžèšã®
å±€éå¯çæ¹è¯ã®å¹æã¯æå(d)ã®å«æã®ããæ¹ã«ã
ã€ãŠåœ±é¿ãããããšã¯ãªãããæå(d)ã¯å¥œãŸãã
ã¯å¡åžåã«å¡åžæ¶²äžã«æ·»å ãããã æ¬çºæã®æå(d)ã¯ãç±çŸåæå ææã«èšããã
ãå±€ïŒäŸãã°æå æç±å±€ãšäžå¡ãå±€ãæå æç±å±€
ãšäžå¡ãå±€ïŒã®éã®å¯çã匷ããèã¯ãããé²æ¢
ããã®ã«èå¹ãããããããä»ã®åçç¹æ§ã«æªåœ±
é¿ããããŒãããšããªãã ãã®æå(d)ã®éåäœãæ§æããäžèšäžè¬åŒã§è¡š
ããããåäœã«ã€ãæŽã«å ·äœçã«èª¬æããã°ã
ãåŒãã«ãããŠãã¯æ°ŽçŽ ååãå
ã¯ã¡ãã«åºããšãã«åºããããã«åºãªã©ã®ççŽ å
åæ°ïŒä»¥äžã®äœçŽã¢ã«ãã«åºãè¡šããã ã¯æ°ŽçŽ ååãåã¯æ¬¡ã®çŸ€ããéžã°ããïŒãïŒ
åã®çœ®æåºãè¡šãããããªãã¡ ããã²ã³ååïŒäŸãã°å¡©çŽ ãèçŽ åã¯æ²
çŽ ïŒïŒ ãããåºïŒ ã·ã¢ãåºïŒ ã¢ã«ãã«åºãç¹ã«ççŽ ååæ°18以äžã®ã¢ã«ã
ã«åºïŒäŸãã°ãïœâããã«åºãïŒïŒïŒïŒïŒâã
ãªã¡ãã«ããã·ã«åºãïŒâã¡ãã«ãŠã³ãã·ã«
åºïŒïŒ ã¢ã«ã³ãã·åºãç¹ã«ççŽ ååæ°12以äžã®ã¢ã«
ã³ãã·åºããã®ã¢ã«ã³ãã·åºã¯ããšãã«åºåã¯
ãããã«åºãªã©ã®ã¢ãªãŒã«åºãããããã·åºå
ã³ïŒåã¯ããã²ã³ååã§çœ®æãããŠããŠããã
ïŒäŸãã°ãã¡ããã·åºããšããã·åºãããã«ãª
ãã·åºããã³ãžã«ãªãã·åºãïŒâã¯ããâïŒâ
ããããã·ããããã·åºïŒïŒ ã¢ã«ã³ãã·ã«ã«ããã«åºãç¹ã«ççŽ ååæ°12
以äžã®ã¢ã«ã³ãã·ã«ã«ããã«åºããã®åºã¯ããš
ãã«åºåã¯ãããã«åºãªã©ã®ã¢ãªãŒã«åºã§çœ®æ
ãããŠããŠãããïŒäŸãã°ãã¡ããã·ã«ã«ãã
ã«åºããšããã·ã«ã«ããã«åºããããã·ã«ã«ã
ãã«åºïŒïŒ ã¢ã«ãã«ã¹ã«ããã«åºãç¹ã«ççŽ ååæ°ïŒä»¥
äžã®ã¢ã«ãã«ã¹ã«ããã«åºïŒäŸãã°ãã¡ãã«ã¹
ã«ããã«åºããããã«ã¹ã«ããã«åºãããã«ã¹
ã«ããã«åºïŒïŒ ã¢ãªãŒã«ãªãã·åºãç¹ã«ççŽ ååæ°12以äžã®
ã¢ãªãŒã«ãªãã·åºïŒäŸãã°ãããšããã·åºãã
ãããã·åºïŒïŒ ã¢ã·ã«åºãç¹ã«ççŽ ååæ°12以äžã®ã¢ã·ã«
åºããã®åºã¯ããã²ã³åååã¯ããšãã«åºåã¯
ãããã«åºãªã©ã®ã¢ãªãŒã«åºã§çœ®æãããŠããŠ
ãããïŒäŸãã°ãã¡ããã·åºãããããªãã«
åºãã¯ããã¢ã»ãã«åºããã³ãŸã€ã«åºïŒïŒ ã¢ã·ã«ãªãã·åºãç¹ã«äžèšããã¢ã·ã«åºã«å¯Ÿ
å¿ããã¢ã·ã«ãªãã·åºïŒäŸãã°ãã¢ã»ãã«ãªã
ã·åºãããããªãã«ãªãã·åºãã¯ããã¢ã»ãã«
ãªãã·åºããã³ãŸã€ã«ãªãã·åºïŒïŒåã³ ã¢ã·ã«ã¢ããåºãç¹ã«äžèšããã¢ã·ã«åºã«
察å¿ããã¢ã·ã«ã¢ããåºïŒäŸãã°ãã¢ã»ãã«ã¢
ããåºãããããªãã«ã¢ããåºãã¯ããã¢ã»ã
ã«ã¢ããåºïŒïŒ äžèšããïŒãïŒã®åºã®äžã§ã¯ãç¹ã«ãã
ã²ã³ååããããåºãã¢ã«ãã«åºåã¯ã¢ã«ã³ãã·
åºãå ¥æãæãã®ã§å¥œãŸããããæã奜ãŸããæ
å(d)ã¯ïŒžãæ°ŽçŽ ååãè¡šããã°ããã§ããã åè¿°ããèã¯ããé²æ¢ã®å¹æã¯ãäžèšã®äžè¬åŒ
ã§è¡šããããåäœãå°ãªããšãïŒåå«æããéå
äœã«ã€ããŠåžžã«åŸããããã®ã§ãããã該åäœã®
æ°ãå€ãããŠãã€ãŠãäžèšå¹æããã»ã©èšççã«
å€åããããšã¯ãªãã®ã§ã該åäœã®å«ææ°ã®äžé
ã¯éåäœã®å ¥æè¥ããã¯åæã®ãæããåãæ±ã
ã®å®¹æããšãã€ã芳ç¹ãã決å®ããŠããããã®ç¹
ããããã°ãäžèšäžè¬åŒã§è¡šããããåäœãïŒã
çŽ200å«æããéåäœãå®çšäžå¥œãŸãããã®ãšã
ãããšãã§ããããŸãããã奜ãŸããç¯å²ã¯ïŒã
60ã§ããããªããã®å«ææ°ã¯å¹³åå€ã§ãã€ãŠãã
ã®ç¯å²ã®å«ææ°ãæã€éåäœã®ä»ã«å€å°ã®ã¢ãã
ãŒãïŒéäœãå«ãŸããŠãæ¬çºæã®å¹æã«ã¯åœ±é¿ã
ãªãã æ¬çºæã®æå(d)ã¯ãäžè¬åŒã§è¡šããããåäœã
æããéåäœã®äžéšã®æ°Žé žåºãå€æ§ãããã®ãå«
æãããå³ã¡äžè¬åŒã§è¡šããããåäœãæããé
åäœã®äžéšã®æ°Žé žåºã¯ã¢ã«ã³ãã·åºãã¢ãªãŒã«ãª
ãã·åºãã¢ã·ã«ãªãã·åºãªã©ã«å€æ§ãããŠããŠã
ãããããã§ã¢ã«ã³ãã·åºãã¢ãªãŒã«ãªãã·åºã
ã¢ã·ã«ãªãã·åºã¯ãåè¿°ãããšããŠã®ïŒã
ïŒãïŒãšåãæå³ã®ãã®ã§ããã æ¬çºæã®æå(d)ã¯äžèšåäœãšå ±ã«ãä»ã®å ±éå
æåãæããéåäœããå«æãããå ±éåæåã¯
åºãç¯å²ããéžã¶ããšãã§ãããäŸãã°ã¢ã¯ãªã«
é žïŒã¡ã¿ã¯ãªã«é žïŒã¢ã¯ãªã«é žè¥ããã¯ã¡ã¿ã¯ãª
ã«é žã®ãšã¹ãã«ïŒäŸãã°ã¢ã¯ãªã«é žã¡ãã«ãã¡ã¿
ã¯ãªã«é žãšãã«ãã¢ã¯ãªã«é žããã«ãã¡ã¿ã¯ãªã«
é žâïŒâãšãã«ããã·ã«ãšã¹ãã«ïŒïŒã¢ã¯ãªã«é ž
è¥ããã¯ã¡ã¿ã¯ãªã«é žã®ã¢ããïŒäŸãã°ã¢ã¯ãªã«
ã¢ãããã¡ã¿ã¯ãªã«ã¢ãããâããã«ã¢ã¯ãªã«
ã¢ãããïŒïŒ®âãžããã«ã¢ã¯ãªã«ã¢ããïŒïŒç¡
æ°Žãã¬ã€ã³é žïŒç¡æ°Žãã¬ã€ã³é žã®ããŒããšã¹ã
ã«ããžãšã¹ãã«ãããŒãã¢ããããžã¢ããè¥ãã
ã¯ã€ããïŒã¹ãã¬ã³é¡ïŒããã«ã€ãããŸãŒã«é¡ïŒ
ã¢ã¯ãªããããªã«ïŒãã¿ãžãšã³ãªã©ãããã ãããå ±éåæåã®ïŒçš®åã¯ïŒçš®ä»¥äžãæãã
å ±éåäœã®ãã¡ã§ããåèšäžè¬åŒã§è¡šããããå
äœã®å ±éåæ¯ãå°ãªããšãïŒã¢ã«ïŒ 以äžã®ãã®ã
奜ãŸãããç¹ã«30ã¢ã«ïŒ 以äžã®ãã®ãæãŸããã
ãŸããã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¹ãã¬ã³ã¹ã«
ãã³é žãªã©ã®é žæåãå«ãå ±éåæåãå«æãã
å ±éåäœã«ãã€ãŠã¯ãè©²é žæ§å ±éåæåã®å ±éå
æ¯ã30ã¢ã«ïŒ ãè¶ããªãå ±éåäœããã奜ãŸã
ãã æ¬çºæã®æå(d)ãšããŠçšããã«å¥œãŸããéåäœ
ã®å ·äœäŸã®ããã€ããäžèšã«åèšããïŒãã ãã
äžèšã«ãããŠMwã¯å¹³åååéãè¡šããïŒã äžè¿°ããéåäœã®åææ³ã¯å ¬ç¥ã§ãã€ãŠãäŸã
ã°ããžã€ãŒãã« ãªã ãªã«ã¬ãã㯠ã±ãã¹ã
ãªãŒïŒJournal of Organic ChemistryïŒïŒç¬¬23
å·»ã第544ã é ïŒ1958幎ïŒçã«ããåææ³ã
ç¥ãããŠããã¢ãããŒãçšãããžã€ãŒãã« ãªã
ããªã㌠ãµã€ãšã³ã¹ïŒJournal of Polymer
ScienceïŒïŒïŒ¡âïŒã第ïŒå·»ç¬¬2175é åã³ç¬¬2405é
ïŒ1969幎ïŒçã«èšèŒãããéåæ³ã«ãã€ãŠå®¹æã«
åæããããšãã§ããããŸããäžèšã®éåäœã®äž
ã«ã¯åžè²©åãšããŠå ¥æããããšã®å¯èœãªãã®ãã
ããäŸãã°ãåè¿°ã®å ·äœäŸïŒã«ç€ºããéåäœã¯äžž
åç³æ²¹(æ ª)ãããã¬ãžã³ïŒããªãåååã§ãæŽã«å ·
äœäŸïŒã«ç€ºããéåäœã¯å瀟ãããã¬ãžã³MBã
ãªãåååã§çºå£²ãããŠããããã®ãããªåžè²©å
ã䜿ã€ãŠæ¬çºæã®ç®çãéæããããšãã§ããã äžè¿°ããåæåãšå ±ã«è²èª¿å€ãè²èª¿ä»äžå€è¥ã
ãã¯è³ŠæŽ»å€ããŒããŒãšç§°ããããæ·»å å€ïŒä»¥äžè²
調å€ãšåŒã¶ïŒã䜿çšãããããšãæãŸãããè²èª¿
å€ã¯ææ©éå¡©ãšéå å€ã®é žåéå éïŒåïŒçæå
å¿ã®éçšã«é¢äžããŠãçããç»åãæ¿è²ç¹ã«é»è²
ã«ããæ©èœãæãããè²èª¿å€ãšããŠã¯ãæ¢ã«ãã
ããŠå€çš®ã®ååç©ãå ¬ç¥ã§ãããããã®ã»ãšãã©
ã®ãã®ã¯ã€ããåºãã¡ã«ã«ããåºåã¯ããªã³åºã
æããååç©ã§ããããã®äžããã䜿çšããææ©
éå¡©åã³éå å€ã®çš®é¡ã«ããããŠé©åœãªè²èª¿å€ã
éžæããã®ã§ããããæ¬çºæã«ãããŠå¥œãŸããè²
調å¹æãäžãããã®ãšããŠã¯ãç±³åœç¹èš±ç¬¬
3152904å·ãå第3844797å·åã¯å第4076534å·å
æ现æžã«èšèŒããããã¿ã©ãžãã³é¡ïŒäŸãã°ãã¿
ã©ãžãã³ãïŒâã¢ã»ãã«ãã¿ã©ãžãã³ãïŒâã«ã«
ãã¢ã€ã«ãã¿ã©ãžãã³ãªã©ïŒãç±³åœç¹èš±ç¬¬3846136
å·æ现æžã«èšèŒãããïŒâãã©ãŸãªã³âïŒâãªã³
é¡ïŒäŸãã°ïŒâã¡ãã«âïŒâãã©ãŸãªã³âïŒâãª
ã³ãªã©ïŒè¥ããã¯ãããŸãªãã³é¡ïŒäŸãã°ãããŸ
ãªãã³ãïŒâã¡ãã«ãããŸãªãã³ãªã©ïŒãç±³åœç¹
蚱第4030930å·æ现æžã«èšèŒãããããªããžã³é¡
ïŒäŸãã°ïŒâã¡ãã«âïŒïŒïŒâãžããããã·ããª
ããžã³é¡ãªã©ïŒè¥ããã¯ïŒïŒïŒïŒïŒâããªã¢ãžã³
é¡ïŒäŸãã°ïŒâã¡ãã«âïŒïŒïŒâãžããããã·â
ïŒïŒïŒïŒïŒâããªã¢ãžã³ãªã©ïŒãç¹å ¬æ53â36774
å·å ¬å ±ã«èšèŒããããã¿ã©ãžã³ãžãªã³é¡ïŒäŸãã°
ãã¿ã©ãžã³ãžãªã³ãªã©ïŒãç°ç¶ã€ããé¡ïŒäŸãã°
ç±³åœç¹èš±ç¬¬3846136å·æ现æžåã¯ç¹éæ53â55115
å·å ¬å ±ã«èšèŒããããµã¯ã·ã³ã€ããé¡ããã¿ã«ã€
ããé¡åã¯ãŠã©ãŸãŒã«é¡ãç±³åœç¹èš±ç¬¬3951660å·
åã¯å第3885967å·åæ现æžã«èšèŒããããã³ãŸ
ãªããµãžã³ãžãªã³é¡ãç¹éæ53â76020å·å ¬å ±ã«
èšèŒããããã³ãŸãã¢ãžã³ãžãªã³é¡ãç±³åœç¹èš±ç¬¬
3782941å·æ现æžã«èšèŒãããããã¿ã«ã€ãã
é¡ïŒãªã©ã®ã€ããåºãæããè€çŽ ç°åŒååç©ãæ
ããããããããã®è²èª¿å€ã¯ïŒçš®ä»¥äžäœµçšããŠã
ãããäŸãã°ç¹éæ53â1020å·åã³å53â55115
å·åå ¬å ±ã«èšèŒãããŠããããã«ããã¿ã©ãžãã³
é¡ãšçµåããŠãã³ãŸãªããµãžã³ãžãªã³é¡ããã³ãŸ
ãã¢ãžã³ãžãªã³é¡è¥ããã¯ãã¿ã«ã€ããé¡ã䜵çš
ããããšã«ããé«æž©é«æ¹¿äžã§ã®è²¯èµã«ç±æ¥ããè²
調å¹æã®å£åãé²æ¢ããããšãã§ããã ãŸããç±³åœç¹èš±ç¬¬3847612å·åã³å第3994732å·
åæ现æžã«èšèŒãããŠããããã«ãã¿ã«é žããã
ããšé žè¥ããã¯ãã¿ã«ã¢ããé žãšã€ãããŸãŒã«é¡
è¥ããã¯ãã¿ã©ãŸã³é¡ã䜵çšããŠè²èª¿å€ãšããŠçš
ããããšãã§ããã è²èª¿å€ãçšããå Žåããã®äœ¿çšéã¯ææ©éå¡©ïŒ
ã¢ã«åœãçŽ0.0001ã¢ã«ä¹è³çŽïŒã¢ã«ãç¹ã«çŽ
0.0005ã¢ã«ä¹è³çŽïŒã¢ã«ã®ç¯å²ã奜é©ã§ããããŸ
ãè²èª¿å€ãæ·»å ããå±€ã¯ä»»æã§ããããç¹ã«æå
(a)ãš(b)ãå«ãå±€ãè¥ããã¯æå(a)ã(c)ãå«ãå±€ã«
æ·»å ããã®ã奜ãŸããã æ¬çºæã®ç±çŸåæå ææã®åæåãšå ±ã«ããã®
åéã§å ¬ç¥ã®åŠçæžã®ææã®å ã«ããå€è²ãé²æ¢
ããã®ã«æå¹ãªååç©ã䜿çšããŠããããäŸãã°
ç±³åœç¹èš±ç¬¬3839041å·æ现æžã«èšèŒãããŠããã
ããªã¢ãŸãŒã«ããªãšãŒãã«ããããã¯ãããã¢ãŸ
ãŒã«ããªã³é¡ã®åŠãå®å®å€ããªã«ãŒãµãŒãç±³åœç¹
蚱第3700457å·æ现æžã«èšèŒãããŠãããããªã
ãã©ãŸãªã«ååç©åã¯ãã®ããªã«ãŒãµãŒãç±³åœç¹
蚱第3707377å·ãå第3874946å·ãå第3955982å·
åæ现æžã«èšãããŠãããããªå«ããã²ã³åå
ç©ããã®ä»ç¹éæ51â26019å·å ¬å ±ã«èšãããã€
ãªãŠåäœãªã©ãããããããã䜵çšããŠãããã ãŸããç±çŸåæã«æªé²å éšã«çããã«ããªïŒç±
ã«ããªãšããïŒãé²æ¢ããã®ã«æå¹ãªååç©ã䜿
çšã§ããããããç±ã«ããªé²æ¢å€ãšããŠã¯æ¢ã«å€
ãã®ååç©ãå ¬ç¥ã§ãããäŸãã°ç±³åœç¹èš±ç¬¬
3589903å·æ现æžã«èšèŒãããæ°Žéååç©ãç±³åœ
ç¹èš±ç¬¬3957493å·æ现æžã«èšèŒãããâããã²
ãååç©ãç¹éæ51â78227å·å ¬å ±ã«èšãããŠã
ããããªãã³ãŒã³ããªã¹ã«ãã³éžé¡ãç¹éæ51â
122430å·å ¬å ±ã«èšãããŠãããããªã¹ã«ãã€ã³é ž
é¡ãç¹éæ52â24520å·å ¬å ±ã«èšãããŠãããã
ãªã»ãªãŠã ååç©ãªã©ã®ä»ãç¹éæ50â101019
å·ãå50â116024å·ãå50â123331å·ãå50â
134421å·ãå51â47419å·ãå51â42529å·ãå51
â51323å·ãå51â57435å·ãå51â104338å·ãå
53â32015å·ãå51â22431å·ãå51â54428å·ã
å51â75433å·ãå51â122430å·ãå53â1020
å·ãå53â19825å·ãå53â28417å·åå ¬å ±ã«èšèŒ
ãããç±ã«ããªé²æ¢å€ãåç¬åã¯äœµçšããŠäœ¿çšã
ãŠãããã æ¬çºæã®åæåãå«æããå±€åã¯åè£å©å±€ã«ã¯
ç±çŸåæå ææã®åéã§å ¬ç¥ã®æ·»å å€ãäŸãã°å¯
å¡å€ããããå€ãçé¢æŽ»æ§å€ãå¢æå€ãå¢çœå€ã
åžå æ§ç©è³ªããã€ã«ã¿ãŒææããã¬ãŒã·ãšã³é²æ¢
ææãã«ã©ãŒã«ãã©ãŒã硬èå€ã最æ»å€ãçŸåä¿
é²å€ãªã©ãå«æãããããšãã§ããããããã®æ·»
å å€ã®å ·äœçå称åã³ãã®äœ¿çšæ æ§ã«ã€ããŠã¯
Product Licensing Indexèªã第92å·»ïŒ1971幎12
æå·ïŒNo.9232第107é ãç¹éæ53â33615å·ãå50
â119623å·ãå50â57619å·ãå51â27923å·åå ¬
å ±åã¯ç±³åœç¹èš±ç¬¬3769019å·ãå第3821001å·ãå
第3667959å·ãå第3871887å·ãå第3885965å·ã
å第4021250å·ãå第4036650å·ãå第3531286
å·ãå第3764328å·åæ现æžã«èšèŒãããŠããã æ¬çºæã®éå±€æ§æãä¿æããããã«äœ¿çšããã
æ¯æäœã®çŽ æãšããŠã¯åçš®é«ååææãã¬ã©ã¹ã
ãŠãŒã«åžãã³ããã³åžãçŽãéå±ïŒäŸãã°ã¢ã«ã
ããŠã ïŒãªã©ãæããããããæ å ±èšé²ææãšã
ãŠã®åæ±äžå¯ææ§ã®ããã·ãŒãåã¯ããŒã«ã«å å·¥
ã§ãããã®ã奜é©ã§ãããåŸã€ãŠãæ¬çºæã«ãã
ãæ¯æäœãšããŠã¯ããã©ã¹ããã¯ãã€ã«ã ïŒäŸã
ã°ã»ã«ããŒã¹ã¢ã»ããŒããã€ã«ã ãããªãšã¹ãã«
ãã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã ãããªã¢ãããã€ã«ã ãããªã€ãããã€ã«ã ã
ããªã¢ã»ããŒããã€ã«ã åã¯ããªã«ãŒãããŒãã
ã€ã«ã ïŒåã¯çŽïŒäžè¬ã®çŽã®ä»ã«ãäŸãã°åççš
åçŽãã³ãŒãçŽè¥ããã¯ã¢ãŒãçŽã®ãããªå°å·çš
åçŽããã©ã€ã¿çŽãã¬ãžã³ã³ãŒãã€ãçŽããã«ã®
ãŒç¹èš±ç¬¬784615å·æ现æžã«èšãããŠãããããªã
ãªãµãã«ã©ã€ããªã©ã§ãµã€ãžã³ã°ãããçŽãäºé ž
åãã¿ã³ãªã©ã®é¡æãå«æãããã°ã¡ã³ãçŽãã
ãªããã«ã¢ã«ã³ãŒã«ããµã€ãžã³ã°ããçŽïŒãç¹ã«
奜ãŸããã ãããæ¯æäœäžãžã®åå±€ã®å¡åžã¯åŸæ¥å ¬ç¥ã®æ
段ãäŸãã°æµžæŒ¬æ³ããšã¢ãã€ãæ³ãããããŒå¡åž
æ³ãã«ãŒãã³å¡åžæ³ãªã©ã«ãã€ãŠïŒå±€ãã€åã¯ïŒ
局以äžãåæã«å¡åžããããšã«ãã€ãŠéæãã
ãã ãã®ããã«ããŠäœãããç±çŸåæå ææã¯äœ¿çš
ã«é©ãããµã€ãºã«è£æãããåŸãç»åé²å ãã
ããå¿ èŠãªãã°é²å åã«äºç±ïŒ80âã140âïŒã
äžããŠããããç»åé²å ã«é©ããå æºãšããŠã¯ã¿
ã³ã°ã¹ãã³ã©ã³ããäž»ãšããŠãžã¢ãŸæå ææã®é²
å ã«äœ¿çšãããŠãããããªè€åçšè¢å ã©ã³ããæ°Ž
éç¯ããšãŒãã©ã³ãããã»ãã³ã©ã³ããCTRå
æºãã¬ãŒã¶ãŒå æºãªã©åçš®å æºãæãããããå
çš¿ã«ã¯ã補å³ãªã©ã®ç·ç»åã¯å¿è«ã®ããšãé調ã
æããåçç»åã§ããããåã«ã¡ã©ãçšããŠäººç©
ã颚æ¯åãæ®åœ±ããããšãå¯èœã§ãããçŒä»æ³ãš
ããŠã¯åçš¿ãšéããŠå¯ççŒä»ããŠããããåå°çŒ
ä»ãããŠããããååŒäŒžãçŒä»ãããŠãããã é²å éã¯ææã®æ床ã«ãã€ãŠç°ãªãããé«æ床
ã®ãã®ã§ã¯çŽ10ã«ã¯ã¹ç§ãäœæ床ã®ãã®ã§ã¯çŽ
103ã«ã¯ã¹ç§ãèŠãããããããŠç»åé²å ããã
ææã¯ãå ç±ïŒçŽ180âã奜ãŸããã¯ãçŽ100âã
çŽ150âïŒãããã ãã§çŸåããè¯å¥œãªã³ã³ãã©
ã¹ããæããéç»åãåŸããããå ç±æéã¯ïŒç§
ã60ç§ãªã©ä»»æã«èª¿ç¯ããããããã¯å ç±æž©åºŠãš
ã®é¢ä¿ã§æ±ºå®ããããéåžžã¯ã120âã§çŽïŒç§ã
çŽ40ç§ã130âã§çŽïŒç§ãçŽ20ç§ã140âã§çŽïŒç§
ãçŽ10ç§ãé©åœã§ãããå ç±ããæ段ãšããŠã¯å
çš®ãããäŸãã°ææãç°¡åãªå ç±ããããã¬ãŒã
ã«æ¥è§ŠããããŠãããããå ç±ããããã©ã ã«æ¥
觊ããããŠããããå Žåã«ãã€ãŠã¯å ç±ããã空
éå ãééãããŠããããåé«åšæ³¢å ç±ãã¬ãŒã¶
ãŒããŒã ã«ããå ç±ãè¡ã€ãŠãããã æ¬çºæã®ç±çŸåæå ææã¯æå(d)ã®äœçšã«ãã€
ãŠåå±€éã®å¯çãæ¹è¯ãããä¿åæãç±çŸåæå
ã¯åŠçåŸã®äœ¿çšæã«èã¯ãããçããããšããªã
ã®ã§åžžã«ããããªè€åé¢ãæãããã®ã§ãã極ã
ãŠæçšã§ããã 以äžå®æœäŸãæ²ãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æã
ãã å®æœäŸ ïŒ ããã³é ž34ïœãšæ°Ž500mlãæ··åããŠ85âã«å ç±
ããŠããã³é žãè解ãããã85âã§è解ãããã
ã³é žãšæ°Žã®æ··åç©ã1800r.p.m.ã§æ¹æããªããã
ããã«æ°Žé žåãããªãŠã 氎溶液ïŒæ°Žé žåãããªãŠ
ã 2.0ïœïŒæ°Ž50c.c.ïŒïŒ25âïŒãïŒåéã§æ·»å ããŠã
ãã³é žãããªãŠã ãšããã³é žã®æ··åç©ãäœãã次
ã«1800r.p.m.ã§æ¹æããªãã枩床ã85âãã30â
ã«äžããã 次ã«æ¹æãç¶ããªããããã«ç¡é žé氎溶液ïŒç¡
é žé8.5ïœïŒæ°Ž50c.c.ïŒïŒ25âïŒãïŒåéã§æ·»å ã
ãŠãããã«90åéæ¹æãããããã«é ¢é žã€ãœã¢ã
ã«200c.c.ãæ·»å ããŠçæããããã³é žéç²åãå
åããåŸãããªããã«ããã©ãŒã«ã®ã€ãœãããã
ãŒã«æº¶æ¶²ïŒãã³ã«ããã©ãŒã«4000âïŒïŒé»æ°ååŠ
(æ ª)補25ïœïŒã€ãœãããããŒã«200c.c.ïŒã«ãã¢ãžã
ã€ã¶ãŒã§åæ£ããŠïŒ25âïŒ3000r.p.m.30åïŒãã
ãã³é žéã®ããªããŒåæ£æ¶²ã調補ããã 次ã®ãã®ããã³é žéã®ããªããŒåæ£æ¶²ã50âã«
ä¿ã¡500r.p.m.ã§æ¹æããªãããâããã ã³ã
ã¯é žã€ããã®ã¢ã»ãã³æº¶æ¶²ïŒïŒ®âããã ã³ãã¯é ž
ã€ãã1.4ïœïŒã¢ã»ãã³100c.c.ïŒïŒ25âïŒã40åé
ã§æ·»å ããåŸããã«60åéæ¹æããŠç±çŸåæå æ
æçšçµæç©ïŒèåéâããã³é žéããªããŒåæ£
液ïŒïŒ¡ã調補ããã äžèšã®ç±çŸåæå ææçšçµæç©ïŒ¡ã1/12éïŒ1/
ïŒïŒïŒã¢ã«ïŒæ¡åããŠã30âã«ä¿ã¡200r.p.m.ã§æ¹æ
ããªããäžèšæåãïŒåééã§æ·»å ããŠå¡åžæ¶²ïŒ¡
ã調補ããã
åæ°ïŒä»¥äžã®äœçŽã¢ã«ãã«åºãè¡šããã ã¯æ°ŽçŽ ååãåã¯æ¬¡ã®çŸ€ããéžã°ããïŒãïŒ
åã®çœ®æåºãè¡šãããããªãã¡ ããã²ã³ååïŒäŸãã°å¡©çŽ ãèçŽ åã¯æ²
çŽ ïŒïŒ ãããåºïŒ ã·ã¢ãåºïŒ ã¢ã«ãã«åºãç¹ã«ççŽ ååæ°18以äžã®ã¢ã«ã
ã«åºïŒäŸãã°ãïœâããã«åºãïŒïŒïŒïŒïŒâã
ãªã¡ãã«ããã·ã«åºãïŒâã¡ãã«ãŠã³ãã·ã«
åºïŒïŒ ã¢ã«ã³ãã·åºãç¹ã«ççŽ ååæ°12以äžã®ã¢ã«
ã³ãã·åºããã®ã¢ã«ã³ãã·åºã¯ããšãã«åºåã¯
ãããã«åºãªã©ã®ã¢ãªãŒã«åºãããããã·åºå
ã³ïŒåã¯ããã²ã³ååã§çœ®æãããŠããŠããã
ïŒäŸãã°ãã¡ããã·åºããšããã·åºãããã«ãª
ãã·åºããã³ãžã«ãªãã·åºãïŒâã¯ããâïŒâ
ããããã·ããããã·åºïŒïŒ ã¢ã«ã³ãã·ã«ã«ããã«åºãç¹ã«ççŽ ååæ°12
以äžã®ã¢ã«ã³ãã·ã«ã«ããã«åºããã®åºã¯ããš
ãã«åºåã¯ãããã«åºãªã©ã®ã¢ãªãŒã«åºã§çœ®æ
ãããŠããŠãããïŒäŸãã°ãã¡ããã·ã«ã«ãã
ã«åºããšããã·ã«ã«ããã«åºããããã·ã«ã«ã
ãã«åºïŒïŒ ã¢ã«ãã«ã¹ã«ããã«åºãç¹ã«ççŽ ååæ°ïŒä»¥
äžã®ã¢ã«ãã«ã¹ã«ããã«åºïŒäŸãã°ãã¡ãã«ã¹
ã«ããã«åºããããã«ã¹ã«ããã«åºãããã«ã¹
ã«ããã«åºïŒïŒ ã¢ãªãŒã«ãªãã·åºãç¹ã«ççŽ ååæ°12以äžã®
ã¢ãªãŒã«ãªãã·åºïŒäŸãã°ãããšããã·åºãã
ãããã·åºïŒïŒ ã¢ã·ã«åºãç¹ã«ççŽ ååæ°12以äžã®ã¢ã·ã«
åºããã®åºã¯ããã²ã³åååã¯ããšãã«åºåã¯
ãããã«åºãªã©ã®ã¢ãªãŒã«åºã§çœ®æãããŠããŠ
ãããïŒäŸãã°ãã¡ããã·åºãããããªãã«
åºãã¯ããã¢ã»ãã«åºããã³ãŸã€ã«åºïŒïŒ ã¢ã·ã«ãªãã·åºãç¹ã«äžèšããã¢ã·ã«åºã«å¯Ÿ
å¿ããã¢ã·ã«ãªãã·åºïŒäŸãã°ãã¢ã»ãã«ãªã
ã·åºãããããªãã«ãªãã·åºãã¯ããã¢ã»ãã«
ãªãã·åºããã³ãŸã€ã«ãªãã·åºïŒïŒåã³ ã¢ã·ã«ã¢ããåºãç¹ã«äžèšããã¢ã·ã«åºã«
察å¿ããã¢ã·ã«ã¢ããåºïŒäŸãã°ãã¢ã»ãã«ã¢
ããåºãããããªãã«ã¢ããåºãã¯ããã¢ã»ã
ã«ã¢ããåºïŒïŒ äžèšããïŒãïŒã®åºã®äžã§ã¯ãç¹ã«ãã
ã²ã³ååããããåºãã¢ã«ãã«åºåã¯ã¢ã«ã³ãã·
åºãå ¥æãæãã®ã§å¥œãŸããããæã奜ãŸããæ
å(d)ã¯ïŒžãæ°ŽçŽ ååãè¡šããã°ããã§ããã åè¿°ããèã¯ããé²æ¢ã®å¹æã¯ãäžèšã®äžè¬åŒ
ã§è¡šããããåäœãå°ãªããšãïŒåå«æããéå
äœã«ã€ããŠåžžã«åŸããããã®ã§ãããã該åäœã®
æ°ãå€ãããŠãã€ãŠãäžèšå¹æããã»ã©èšççã«
å€åããããšã¯ãªãã®ã§ã該åäœã®å«ææ°ã®äžé
ã¯éåäœã®å ¥æè¥ããã¯åæã®ãæããåãæ±ã
ã®å®¹æããšãã€ã芳ç¹ãã決å®ããŠããããã®ç¹
ããããã°ãäžèšäžè¬åŒã§è¡šããããåäœãïŒã
çŽ200å«æããéåäœãå®çšäžå¥œãŸãããã®ãšã
ãããšãã§ããããŸãããã奜ãŸããç¯å²ã¯ïŒã
60ã§ããããªããã®å«ææ°ã¯å¹³åå€ã§ãã€ãŠãã
ã®ç¯å²ã®å«ææ°ãæã€éåäœã®ä»ã«å€å°ã®ã¢ãã
ãŒãïŒéäœãå«ãŸããŠãæ¬çºæã®å¹æã«ã¯åœ±é¿ã
ãªãã æ¬çºæã®æå(d)ã¯ãäžè¬åŒã§è¡šããããåäœã
æããéåäœã®äžéšã®æ°Žé žåºãå€æ§ãããã®ãå«
æãããå³ã¡äžè¬åŒã§è¡šããããåäœãæããé
åäœã®äžéšã®æ°Žé žåºã¯ã¢ã«ã³ãã·åºãã¢ãªãŒã«ãª
ãã·åºãã¢ã·ã«ãªãã·åºãªã©ã«å€æ§ãããŠããŠã
ãããããã§ã¢ã«ã³ãã·åºãã¢ãªãŒã«ãªãã·åºã
ã¢ã·ã«ãªãã·åºã¯ãåè¿°ãããšããŠã®ïŒã
ïŒãïŒãšåãæå³ã®ãã®ã§ããã æ¬çºæã®æå(d)ã¯äžèšåäœãšå ±ã«ãä»ã®å ±éå
æåãæããéåäœããå«æãããå ±éåæåã¯
åºãç¯å²ããéžã¶ããšãã§ãããäŸãã°ã¢ã¯ãªã«
é žïŒã¡ã¿ã¯ãªã«é žïŒã¢ã¯ãªã«é žè¥ããã¯ã¡ã¿ã¯ãª
ã«é žã®ãšã¹ãã«ïŒäŸãã°ã¢ã¯ãªã«é žã¡ãã«ãã¡ã¿
ã¯ãªã«é žãšãã«ãã¢ã¯ãªã«é žããã«ãã¡ã¿ã¯ãªã«
é žâïŒâãšãã«ããã·ã«ãšã¹ãã«ïŒïŒã¢ã¯ãªã«é ž
è¥ããã¯ã¡ã¿ã¯ãªã«é žã®ã¢ããïŒäŸãã°ã¢ã¯ãªã«
ã¢ãããã¡ã¿ã¯ãªã«ã¢ãããâããã«ã¢ã¯ãªã«
ã¢ãããïŒïŒ®âãžããã«ã¢ã¯ãªã«ã¢ããïŒïŒç¡
æ°Žãã¬ã€ã³é žïŒç¡æ°Žãã¬ã€ã³é žã®ããŒããšã¹ã
ã«ããžãšã¹ãã«ãããŒãã¢ããããžã¢ããè¥ãã
ã¯ã€ããïŒã¹ãã¬ã³é¡ïŒããã«ã€ãããŸãŒã«é¡ïŒ
ã¢ã¯ãªããããªã«ïŒãã¿ãžãšã³ãªã©ãããã ãããå ±éåæåã®ïŒçš®åã¯ïŒçš®ä»¥äžãæãã
å ±éåäœã®ãã¡ã§ããåèšäžè¬åŒã§è¡šããããå
äœã®å ±éåæ¯ãå°ãªããšãïŒã¢ã«ïŒ 以äžã®ãã®ã
奜ãŸãããç¹ã«30ã¢ã«ïŒ 以äžã®ãã®ãæãŸããã
ãŸããã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¹ãã¬ã³ã¹ã«
ãã³é žãªã©ã®é žæåãå«ãå ±éåæåãå«æãã
å ±éåäœã«ãã€ãŠã¯ãè©²é žæ§å ±éåæåã®å ±éå
æ¯ã30ã¢ã«ïŒ ãè¶ããªãå ±éåäœããã奜ãŸã
ãã æ¬çºæã®æå(d)ãšããŠçšããã«å¥œãŸããéåäœ
ã®å ·äœäŸã®ããã€ããäžèšã«åèšããïŒãã ãã
äžèšã«ãããŠMwã¯å¹³åååéãè¡šããïŒã äžè¿°ããéåäœã®åææ³ã¯å ¬ç¥ã§ãã€ãŠãäŸã
ã°ããžã€ãŒãã« ãªã ãªã«ã¬ãã㯠ã±ãã¹ã
ãªãŒïŒJournal of Organic ChemistryïŒïŒç¬¬23
å·»ã第544ã é ïŒ1958幎ïŒçã«ããåææ³ã
ç¥ãããŠããã¢ãããŒãçšãããžã€ãŒãã« ãªã
ããªã㌠ãµã€ãšã³ã¹ïŒJournal of Polymer
ScienceïŒïŒïŒ¡âïŒã第ïŒå·»ç¬¬2175é åã³ç¬¬2405é
ïŒ1969幎ïŒçã«èšèŒãããéåæ³ã«ãã€ãŠå®¹æã«
åæããããšãã§ããããŸããäžèšã®éåäœã®äž
ã«ã¯åžè²©åãšããŠå ¥æããããšã®å¯èœãªãã®ãã
ããäŸãã°ãåè¿°ã®å ·äœäŸïŒã«ç€ºããéåäœã¯äžž
åç³æ²¹(æ ª)ãããã¬ãžã³ïŒããªãåååã§ãæŽã«å ·
äœäŸïŒã«ç€ºããéåäœã¯å瀟ãããã¬ãžã³MBã
ãªãåååã§çºå£²ãããŠããããã®ãããªåžè²©å
ã䜿ã€ãŠæ¬çºæã®ç®çãéæããããšãã§ããã äžè¿°ããåæåãšå ±ã«è²èª¿å€ãè²èª¿ä»äžå€è¥ã
ãã¯è³ŠæŽ»å€ããŒããŒãšç§°ããããæ·»å å€ïŒä»¥äžè²
調å€ãšåŒã¶ïŒã䜿çšãããããšãæãŸãããè²èª¿
å€ã¯ææ©éå¡©ãšéå å€ã®é žåéå éïŒåïŒçæå
å¿ã®éçšã«é¢äžããŠãçããç»åãæ¿è²ç¹ã«é»è²
ã«ããæ©èœãæãããè²èª¿å€ãšããŠã¯ãæ¢ã«ãã
ããŠå€çš®ã®ååç©ãå ¬ç¥ã§ãããããã®ã»ãšãã©
ã®ãã®ã¯ã€ããåºãã¡ã«ã«ããåºåã¯ããªã³åºã
æããååç©ã§ããããã®äžããã䜿çšããææ©
éå¡©åã³éå å€ã®çš®é¡ã«ããããŠé©åœãªè²èª¿å€ã
éžæããã®ã§ããããæ¬çºæã«ãããŠå¥œãŸããè²
調å¹æãäžãããã®ãšããŠã¯ãç±³åœç¹èš±ç¬¬
3152904å·ãå第3844797å·åã¯å第4076534å·å
æ现æžã«èšèŒããããã¿ã©ãžãã³é¡ïŒäŸãã°ãã¿
ã©ãžãã³ãïŒâã¢ã»ãã«ãã¿ã©ãžãã³ãïŒâã«ã«
ãã¢ã€ã«ãã¿ã©ãžãã³ãªã©ïŒãç±³åœç¹èš±ç¬¬3846136
å·æ现æžã«èšèŒãããïŒâãã©ãŸãªã³âïŒâãªã³
é¡ïŒäŸãã°ïŒâã¡ãã«âïŒâãã©ãŸãªã³âïŒâãª
ã³ãªã©ïŒè¥ããã¯ãããŸãªãã³é¡ïŒäŸãã°ãããŸ
ãªãã³ãïŒâã¡ãã«ãããŸãªãã³ãªã©ïŒãç±³åœç¹
蚱第4030930å·æ现æžã«èšèŒãããããªããžã³é¡
ïŒäŸãã°ïŒâã¡ãã«âïŒïŒïŒâãžããããã·ããª
ããžã³é¡ãªã©ïŒè¥ããã¯ïŒïŒïŒïŒïŒâããªã¢ãžã³
é¡ïŒäŸãã°ïŒâã¡ãã«âïŒïŒïŒâãžããããã·â
ïŒïŒïŒïŒïŒâããªã¢ãžã³ãªã©ïŒãç¹å ¬æ53â36774
å·å ¬å ±ã«èšèŒããããã¿ã©ãžã³ãžãªã³é¡ïŒäŸãã°
ãã¿ã©ãžã³ãžãªã³ãªã©ïŒãç°ç¶ã€ããé¡ïŒäŸãã°
ç±³åœç¹èš±ç¬¬3846136å·æ现æžåã¯ç¹éæ53â55115
å·å ¬å ±ã«èšèŒããããµã¯ã·ã³ã€ããé¡ããã¿ã«ã€
ããé¡åã¯ãŠã©ãŸãŒã«é¡ãç±³åœç¹èš±ç¬¬3951660å·
åã¯å第3885967å·åæ现æžã«èšèŒããããã³ãŸ
ãªããµãžã³ãžãªã³é¡ãç¹éæ53â76020å·å ¬å ±ã«
èšèŒããããã³ãŸãã¢ãžã³ãžãªã³é¡ãç±³åœç¹èš±ç¬¬
3782941å·æ现æžã«èšèŒãããããã¿ã«ã€ãã
é¡ïŒãªã©ã®ã€ããåºãæããè€çŽ ç°åŒååç©ãæ
ããããããããã®è²èª¿å€ã¯ïŒçš®ä»¥äžäœµçšããŠã
ãããäŸãã°ç¹éæ53â1020å·åã³å53â55115
å·åå ¬å ±ã«èšèŒãããŠããããã«ããã¿ã©ãžãã³
é¡ãšçµåããŠãã³ãŸãªããµãžã³ãžãªã³é¡ããã³ãŸ
ãã¢ãžã³ãžãªã³é¡è¥ããã¯ãã¿ã«ã€ããé¡ã䜵çš
ããããšã«ããé«æž©é«æ¹¿äžã§ã®è²¯èµã«ç±æ¥ããè²
調å¹æã®å£åãé²æ¢ããããšãã§ããã ãŸããç±³åœç¹èš±ç¬¬3847612å·åã³å第3994732å·
åæ现æžã«èšèŒãããŠããããã«ãã¿ã«é žããã
ããšé žè¥ããã¯ãã¿ã«ã¢ããé žãšã€ãããŸãŒã«é¡
è¥ããã¯ãã¿ã©ãŸã³é¡ã䜵çšããŠè²èª¿å€ãšããŠçš
ããããšãã§ããã è²èª¿å€ãçšããå Žåããã®äœ¿çšéã¯ææ©éå¡©ïŒ
ã¢ã«åœãçŽ0.0001ã¢ã«ä¹è³çŽïŒã¢ã«ãç¹ã«çŽ
0.0005ã¢ã«ä¹è³çŽïŒã¢ã«ã®ç¯å²ã奜é©ã§ããããŸ
ãè²èª¿å€ãæ·»å ããå±€ã¯ä»»æã§ããããç¹ã«æå
(a)ãš(b)ãå«ãå±€ãè¥ããã¯æå(a)ã(c)ãå«ãå±€ã«
æ·»å ããã®ã奜ãŸããã æ¬çºæã®ç±çŸåæå ææã®åæåãšå ±ã«ããã®
åéã§å ¬ç¥ã®åŠçæžã®ææã®å ã«ããå€è²ãé²æ¢
ããã®ã«æå¹ãªååç©ã䜿çšããŠããããäŸãã°
ç±³åœç¹èš±ç¬¬3839041å·æ现æžã«èšèŒãããŠããã
ããªã¢ãŸãŒã«ããªãšãŒãã«ããããã¯ãããã¢ãŸ
ãŒã«ããªã³é¡ã®åŠãå®å®å€ããªã«ãŒãµãŒãç±³åœç¹
蚱第3700457å·æ现æžã«èšèŒãããŠãããããªã
ãã©ãŸãªã«ååç©åã¯ãã®ããªã«ãŒãµãŒãç±³åœç¹
蚱第3707377å·ãå第3874946å·ãå第3955982å·
åæ现æžã«èšãããŠãããããªå«ããã²ã³åå
ç©ããã®ä»ç¹éæ51â26019å·å ¬å ±ã«èšãããã€
ãªãŠåäœãªã©ãããããããã䜵çšããŠãããã ãŸããç±çŸåæã«æªé²å éšã«çããã«ããªïŒç±
ã«ããªãšããïŒãé²æ¢ããã®ã«æå¹ãªååç©ã䜿
çšã§ããããããç±ã«ããªé²æ¢å€ãšããŠã¯æ¢ã«å€
ãã®ååç©ãå ¬ç¥ã§ãããäŸãã°ç±³åœç¹èš±ç¬¬
3589903å·æ现æžã«èšèŒãããæ°Žéååç©ãç±³åœ
ç¹èš±ç¬¬3957493å·æ现æžã«èšèŒãããâããã²
ãååç©ãç¹éæ51â78227å·å ¬å ±ã«èšãããŠã
ããããªãã³ãŒã³ããªã¹ã«ãã³éžé¡ãç¹éæ51â
122430å·å ¬å ±ã«èšãããŠãããããªã¹ã«ãã€ã³é ž
é¡ãç¹éæ52â24520å·å ¬å ±ã«èšãããŠãããã
ãªã»ãªãŠã ååç©ãªã©ã®ä»ãç¹éæ50â101019
å·ãå50â116024å·ãå50â123331å·ãå50â
134421å·ãå51â47419å·ãå51â42529å·ãå51
â51323å·ãå51â57435å·ãå51â104338å·ãå
53â32015å·ãå51â22431å·ãå51â54428å·ã
å51â75433å·ãå51â122430å·ãå53â1020
å·ãå53â19825å·ãå53â28417å·åå ¬å ±ã«èšèŒ
ãããç±ã«ããªé²æ¢å€ãåç¬åã¯äœµçšããŠäœ¿çšã
ãŠãããã æ¬çºæã®åæåãå«æããå±€åã¯åè£å©å±€ã«ã¯
ç±çŸåæå ææã®åéã§å ¬ç¥ã®æ·»å å€ãäŸãã°å¯
å¡å€ããããå€ãçé¢æŽ»æ§å€ãå¢æå€ãå¢çœå€ã
åžå æ§ç©è³ªããã€ã«ã¿ãŒææããã¬ãŒã·ãšã³é²æ¢
ææãã«ã©ãŒã«ãã©ãŒã硬èå€ã最æ»å€ãçŸåä¿
é²å€ãªã©ãå«æãããããšãã§ããããããã®æ·»
å å€ã®å ·äœçå称åã³ãã®äœ¿çšæ æ§ã«ã€ããŠã¯
Product Licensing Indexèªã第92å·»ïŒ1971幎12
æå·ïŒNo.9232第107é ãç¹éæ53â33615å·ãå50
â119623å·ãå50â57619å·ãå51â27923å·åå ¬
å ±åã¯ç±³åœç¹èš±ç¬¬3769019å·ãå第3821001å·ãå
第3667959å·ãå第3871887å·ãå第3885965å·ã
å第4021250å·ãå第4036650å·ãå第3531286
å·ãå第3764328å·åæ现æžã«èšèŒãããŠããã æ¬çºæã®éå±€æ§æãä¿æããããã«äœ¿çšããã
æ¯æäœã®çŽ æãšããŠã¯åçš®é«ååææãã¬ã©ã¹ã
ãŠãŒã«åžãã³ããã³åžãçŽãéå±ïŒäŸãã°ã¢ã«ã
ããŠã ïŒãªã©ãæããããããæ å ±èšé²ææãšã
ãŠã®åæ±äžå¯ææ§ã®ããã·ãŒãåã¯ããŒã«ã«å å·¥
ã§ãããã®ã奜é©ã§ãããåŸã€ãŠãæ¬çºæã«ãã
ãæ¯æäœãšããŠã¯ããã©ã¹ããã¯ãã€ã«ã ïŒäŸã
ã°ã»ã«ããŒã¹ã¢ã»ããŒããã€ã«ã ãããªãšã¹ãã«
ãã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã ãããªã¢ãããã€ã«ã ãããªã€ãããã€ã«ã ã
ããªã¢ã»ããŒããã€ã«ã åã¯ããªã«ãŒãããŒãã
ã€ã«ã ïŒåã¯çŽïŒäžè¬ã®çŽã®ä»ã«ãäŸãã°åççš
åçŽãã³ãŒãçŽè¥ããã¯ã¢ãŒãçŽã®ãããªå°å·çš
åçŽããã©ã€ã¿çŽãã¬ãžã³ã³ãŒãã€ãçŽããã«ã®
ãŒç¹èš±ç¬¬784615å·æ现æžã«èšãããŠãããããªã
ãªãµãã«ã©ã€ããªã©ã§ãµã€ãžã³ã°ãããçŽãäºé ž
åãã¿ã³ãªã©ã®é¡æãå«æãããã°ã¡ã³ãçŽãã
ãªããã«ã¢ã«ã³ãŒã«ããµã€ãžã³ã°ããçŽïŒãç¹ã«
奜ãŸããã ãããæ¯æäœäžãžã®åå±€ã®å¡åžã¯åŸæ¥å ¬ç¥ã®æ
段ãäŸãã°æµžæŒ¬æ³ããšã¢ãã€ãæ³ãããããŒå¡åž
æ³ãã«ãŒãã³å¡åžæ³ãªã©ã«ãã€ãŠïŒå±€ãã€åã¯ïŒ
局以äžãåæã«å¡åžããããšã«ãã€ãŠéæãã
ãã ãã®ããã«ããŠäœãããç±çŸåæå ææã¯äœ¿çš
ã«é©ãããµã€ãºã«è£æãããåŸãç»åé²å ãã
ããå¿ èŠãªãã°é²å åã«äºç±ïŒ80âã140âïŒã
äžããŠããããç»åé²å ã«é©ããå æºãšããŠã¯ã¿
ã³ã°ã¹ãã³ã©ã³ããäž»ãšããŠãžã¢ãŸæå ææã®é²
å ã«äœ¿çšãããŠãããããªè€åçšè¢å ã©ã³ããæ°Ž
éç¯ããšãŒãã©ã³ãããã»ãã³ã©ã³ããCTRå
æºãã¬ãŒã¶ãŒå æºãªã©åçš®å æºãæãããããå
çš¿ã«ã¯ã補å³ãªã©ã®ç·ç»åã¯å¿è«ã®ããšãé調ã
æããåçç»åã§ããããåã«ã¡ã©ãçšããŠäººç©
ã颚æ¯åãæ®åœ±ããããšãå¯èœã§ãããçŒä»æ³ãš
ããŠã¯åçš¿ãšéããŠå¯ççŒä»ããŠããããåå°çŒ
ä»ãããŠããããååŒäŒžãçŒä»ãããŠãããã é²å éã¯ææã®æ床ã«ãã€ãŠç°ãªãããé«æ床
ã®ãã®ã§ã¯çŽ10ã«ã¯ã¹ç§ãäœæ床ã®ãã®ã§ã¯çŽ
103ã«ã¯ã¹ç§ãèŠãããããããŠç»åé²å ããã
ææã¯ãå ç±ïŒçŽ180âã奜ãŸããã¯ãçŽ100âã
çŽ150âïŒãããã ãã§çŸåããè¯å¥œãªã³ã³ãã©
ã¹ããæããéç»åãåŸããããå ç±æéã¯ïŒç§
ã60ç§ãªã©ä»»æã«èª¿ç¯ããããããã¯å ç±æž©åºŠãš
ã®é¢ä¿ã§æ±ºå®ããããéåžžã¯ã120âã§çŽïŒç§ã
çŽ40ç§ã130âã§çŽïŒç§ãçŽ20ç§ã140âã§çŽïŒç§
ãçŽ10ç§ãé©åœã§ãããå ç±ããæ段ãšããŠã¯å
çš®ãããäŸãã°ææãç°¡åãªå ç±ããããã¬ãŒã
ã«æ¥è§ŠããããŠãããããå ç±ããããã©ã ã«æ¥
觊ããããŠããããå Žåã«ãã€ãŠã¯å ç±ããã空
éå ãééãããŠããããåé«åšæ³¢å ç±ãã¬ãŒã¶
ãŒããŒã ã«ããå ç±ãè¡ã€ãŠãããã æ¬çºæã®ç±çŸåæå ææã¯æå(d)ã®äœçšã«ãã€
ãŠåå±€éã®å¯çãæ¹è¯ãããä¿åæãç±çŸåæå
ã¯åŠçåŸã®äœ¿çšæã«èã¯ãããçããããšããªã
ã®ã§åžžã«ããããªè€åé¢ãæãããã®ã§ãã極ã
ãŠæçšã§ããã 以äžå®æœäŸãæ²ãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æã
ãã å®æœäŸ ïŒ ããã³é ž34ïœãšæ°Ž500mlãæ··åããŠ85âã«å ç±
ããŠããã³é žãè解ãããã85âã§è解ãããã
ã³é žãšæ°Žã®æ··åç©ã1800r.p.m.ã§æ¹æããªããã
ããã«æ°Žé žåãããªãŠã 氎溶液ïŒæ°Žé žåãããªãŠ
ã 2.0ïœïŒæ°Ž50c.c.ïŒïŒ25âïŒãïŒåéã§æ·»å ããŠã
ãã³é žãããªãŠã ãšããã³é žã®æ··åç©ãäœãã次
ã«1800r.p.m.ã§æ¹æããªãã枩床ã85âãã30â
ã«äžããã 次ã«æ¹æãç¶ããªããããã«ç¡é žé氎溶液ïŒç¡
é žé8.5ïœïŒæ°Ž50c.c.ïŒïŒ25âïŒãïŒåéã§æ·»å ã
ãŠãããã«90åéæ¹æãããããã«é ¢é žã€ãœã¢ã
ã«200c.c.ãæ·»å ããŠçæããããã³é žéç²åãå
åããåŸãããªããã«ããã©ãŒã«ã®ã€ãœãããã
ãŒã«æº¶æ¶²ïŒãã³ã«ããã©ãŒã«4000âïŒïŒé»æ°ååŠ
(æ ª)補25ïœïŒã€ãœãããããŒã«200c.c.ïŒã«ãã¢ãžã
ã€ã¶ãŒã§åæ£ããŠïŒ25âïŒ3000r.p.m.30åïŒãã
ãã³é žéã®ããªããŒåæ£æ¶²ã調補ããã 次ã®ãã®ããã³é žéã®ããªããŒåæ£æ¶²ã50âã«
ä¿ã¡500r.p.m.ã§æ¹æããªãããâããã ã³ã
ã¯é žã€ããã®ã¢ã»ãã³æº¶æ¶²ïŒïŒ®âããã ã³ãã¯é ž
ã€ãã1.4ïœïŒã¢ã»ãã³100c.c.ïŒïŒ25âïŒã40åé
ã§æ·»å ããåŸããã«60åéæ¹æããŠç±çŸåæå æ
æçšçµæç©ïŒèåéâããã³é žéããªããŒåæ£
液ïŒïŒ¡ã調補ããã äžèšã®ç±çŸåæå ææçšçµæç©ïŒ¡ã1/12éïŒ1/
ïŒïŒïŒã¢ã«ïŒæ¡åããŠã30âã«ä¿ã¡200r.p.m.ã§æ¹æ
ããªããäžèšæåãïŒåééã§æ·»å ããŠå¡åžæ¶²ïŒ¡
ã調補ããã
ãè¡šã
éã0.3ïœã«ãªãããã«å¡åžããŠç±çŸåæå
ææ
(A)ãäœè£œããã ç±çŸåæå ææã«å¯Ÿãäžå¡ãããªããŒå±€ïŒä»¥
äžä¿è·å±€ãšããïŒãšããŠé ¢é žç¶¿æº¶æ¶²ïŒäºé ¢é žã»ã«
ããŒã¹ïŒïŒïœãã¢ã»ãã³ïŒ200c.c.ïŒ200c.c.ã«å¯Ÿãã
æå(d)ãšããŠããªãŒïœâããã«ããšããŒã«ïŒäžžå
ç³æ²¹è£œãã¬ãžã³ïŒïŒ0.5ïœãæ·»å ãã溶液ã40
mlïŒm2ãšãªãããã«å¡åžããŠãç±çŸåæå ææ(B)
ãäœè£œããã æ¯èŒã®çºã«ãäžèšé ¢é žç¶¿æº¶æ¶²ã ããåæ§ã«40
mlïŒm2ãšãªãããã«å¡åžããŠç±çŸåæå ææ(C)ã
äœè£œããã ãã®ããã«ããŠäœè£œããç±çŸåæå ææ(B)åã³
(C)ã«ãå æ¥ãéããŠã¿ã³ã°ã¹ãã³ã©ã³ãã§é²å ã
äžããã次ã«130âã§ïŒç§éç±æ¿ã«æ¥è§ŠãããŠå
ç±ããããšã«ãã€ãŠçŸåãããã ãããã®ãµã³ãã«ã®å±€éå¯çæ§ã調ã¹ãçºã«ã
ç±çŸåæžã¿ãµã³ãã«è¡šé¢ã«ç²çããŒãïŒæ¥æ±é»å·¥
補ãããªãšã¹ãã«ç²çããŒãïŒãã匵ãä»ããŠã
180ãã®è§åºŠæ¹åã«ããã®ç²çããŒããåŒåŒµãã
ãšã«ãããç²çããŒãã«ä»çããŠæ¥ãé ¢é žç¶¿ã®é¢
ç©ãèšæž¬ããããšã«ãããå±€éå¯ç床åãã調ã¹
ãã
(A)ãäœè£œããã ç±çŸåæå ææã«å¯Ÿãäžå¡ãããªããŒå±€ïŒä»¥
äžä¿è·å±€ãšããïŒãšããŠé ¢é žç¶¿æº¶æ¶²ïŒäºé ¢é žã»ã«
ããŒã¹ïŒïŒïœãã¢ã»ãã³ïŒ200c.c.ïŒ200c.c.ã«å¯Ÿãã
æå(d)ãšããŠããªãŒïœâããã«ããšããŒã«ïŒäžžå
ç³æ²¹è£œãã¬ãžã³ïŒïŒ0.5ïœãæ·»å ãã溶液ã40
mlïŒm2ãšãªãããã«å¡åžããŠãç±çŸåæå ææ(B)
ãäœè£œããã æ¯èŒã®çºã«ãäžèšé ¢é žç¶¿æº¶æ¶²ã ããåæ§ã«40
mlïŒm2ãšãªãããã«å¡åžããŠç±çŸåæå ææ(C)ã
äœè£œããã ãã®ããã«ããŠäœè£œããç±çŸåæå ææ(B)åã³
(C)ã«ãå æ¥ãéããŠã¿ã³ã°ã¹ãã³ã©ã³ãã§é²å ã
äžããã次ã«130âã§ïŒç§éç±æ¿ã«æ¥è§ŠãããŠå
ç±ããããšã«ãã€ãŠçŸåãããã ãããã®ãµã³ãã«ã®å±€éå¯çæ§ã調ã¹ãçºã«ã
ç±çŸåæžã¿ãµã³ãã«è¡šé¢ã«ç²çããŒãïŒæ¥æ±é»å·¥
補ãããªãšã¹ãã«ç²çããŒãïŒãã匵ãä»ããŠã
180ãã®è§åºŠæ¹åã«ããã®ç²çããŒããåŒåŒµãã
ãšã«ãããç²çããŒãã«ä»çããŠæ¥ãé ¢é žç¶¿ã®é¢
ç©ãèšæž¬ããããšã«ãããå±€éå¯ç床åãã調ã¹
ãã
ãè¡šã
以äžã®ããšã«ããæ¬çºæã®æå(d)ã§ããããªâ
ïœâããã«ããšããŒã«ã¯å±€éå¯çã®äœçšã«æå¹ã§
ããããšãå€æããã å®æœäŸ ïŒ å®æœäŸïŒã®æå(d)ãšããŠããã åããªâïœâã
ãã«ããšããŒã«ïŒäžžåç³æ²¹è£œãã¬ãžã³MBïŒãå®
æœäŸïŒãšåäžåŠæ¹ã§çšããŠãç±çŸåæå ææ(D)ã
äœè£œãåæ§ã®æ¯èŒè©Šéšãè¡ã€ãã
ïœâããã«ããšããŒã«ã¯å±€éå¯çã®äœçšã«æå¹ã§
ããããšãå€æããã å®æœäŸ ïŒ å®æœäŸïŒã®æå(d)ãšããŠããã åããªâïœâã
ãã«ããšããŒã«ïŒäžžåç³æ²¹è£œãã¬ãžã³MBïŒãå®
æœäŸïŒãšåäžåŠæ¹ã§çšããŠãç±çŸåæå ææ(D)ã
äœè£œãåæ§ã®æ¯èŒè©Šéšãè¡ã€ãã
ãè¡šã
以äžã®çµæããæ¬çºæã®æåã§ãããå±€éå¯
çã®äœçšã«æå¹ã§ããããšãå€æããã å®æœäŸ ïŒ å®æœäŸïŒã®ç±çŸåæå ææçšçµæç©ïŒ¡ã1/12é
ïŒ1/240ã¢ã«ïŒæ¡åããŠã30âã«ä¿ã¡200r.p.m.ã§
æ¹æããªããå®æœäŸïŒã«æŒãã(i)ã(iv)ã®æåãïŒ
åééã§æ·»å ããªãããæŽã«ã(v)ãšããŠããªâïœ
âããã«ããšããŒã«ïŒ10ééïŒ ã€ãœãããã«ã¢
ã«ã³ãŒã«æ¶²ïŒïŒmlãæ·»å ããŠå¡åžæ¶²ïŒ¥ã調液ã
ãŠãæ¯æäœçŽïŒããªããã«ã¢ã«ã³ãŒã«ãäžå¡ãã
ãæå§çŽçšåçŽïŒäžã«ãïŒm2åœãã®å¡åžééã
0.3ïœã«ãªãããã«å¡åžããŠç±çŸåæå ææ(E)ã
äœè£œããã æ¯èŒã®çºã«ç±çŸåæå ææ(A)ãäœè£œãã(E)åã³
(A)ã«å®æœäŸïŒã®é ¢é žç¶¿åç¬æº¶æ¶²ã40mlïŒm2ãšãªã
ããã«å¡åžããŠç±çŸåæå ææ(E)åã³(C)ãäœè£œ
ããå®æœäŸïŒïŒïŒãšåæ§ã®è©Šéšãè¡ã€ãã
çã®äœçšã«æå¹ã§ããããšãå€æããã å®æœäŸ ïŒ å®æœäŸïŒã®ç±çŸåæå ææçšçµæç©ïŒ¡ã1/12é
ïŒ1/240ã¢ã«ïŒæ¡åããŠã30âã«ä¿ã¡200r.p.m.ã§
æ¹æããªããå®æœäŸïŒã«æŒãã(i)ã(iv)ã®æåãïŒ
åééã§æ·»å ããªãããæŽã«ã(v)ãšããŠããªâïœ
âããã«ããšããŒã«ïŒ10ééïŒ ã€ãœãããã«ã¢
ã«ã³ãŒã«æ¶²ïŒïŒmlãæ·»å ããŠå¡åžæ¶²ïŒ¥ã調液ã
ãŠãæ¯æäœçŽïŒããªããã«ã¢ã«ã³ãŒã«ãäžå¡ãã
ãæå§çŽçšåçŽïŒäžã«ãïŒm2åœãã®å¡åžééã
0.3ïœã«ãªãããã«å¡åžããŠç±çŸåæå ææ(E)ã
äœè£œããã æ¯èŒã®çºã«ç±çŸåæå ææ(A)ãäœè£œãã(E)åã³
(A)ã«å®æœäŸïŒã®é ¢é žç¶¿åç¬æº¶æ¶²ã40mlïŒm2ãšãªã
ããã«å¡åžããŠç±çŸåæå ææ(E)åã³(C)ãäœè£œ
ããå®æœäŸïŒïŒïŒãšåæ§ã®è©Šéšãè¡ã€ãã
ãè¡šã
以äžã®ããšã«ããæ¬çºæã®æåã§ãã(v)ãå±€é
å¯çã®äœçšã«æå¹ã§ããããšãå€æããã å®æœäŸ ïŒ å®æœäŸïŒã®(v)ãšããŠããã åããªâïœâããã«
ããšããŒã«ãå®æœäŸïŒãšåæ§ã«çšããŠç±çŸåæå
ææ(F)ãäœè£œããåæ§ã®æ¯èŒè©Šéšãè¡ã€ãã
å¯çã®äœçšã«æå¹ã§ããããšãå€æããã å®æœäŸ ïŒ å®æœäŸïŒã®(v)ãšããŠããã åããªâïœâããã«
ããšããŒã«ãå®æœäŸïŒãšåæ§ã«çšããŠç±çŸåæå
ææ(F)ãäœè£œããåæ§ã®æ¯èŒè©Šéšãè¡ã€ãã
ãè¡šã
å®æœäŸ ïŒ
æ¬çºæã®æå(d)ãç±çŸåæå
ææã®åçæ§èœã
æªåããããã®ã§ãªãããšã瀺ãããã«ãäžè¡šã«
å®æœäŸïŒãïŒã®ç±çŸåæå ææ(B)ã(F)ã®åçæ§èœ
ãè¡šèšããã
æªåããããã®ã§ãªãããšã瀺ãããã«ãäžè¡šã«
å®æœäŸïŒãïŒã®ç±çŸåæå ææ(B)ã(F)ã®åçæ§èœ
ãè¡šèšããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«ïŒå±€ä»¥äžã®éå±€ãæãã該éå±€ã®
ïŒå±€åã¯ïŒå±€ä»¥äžã«ããã€ãŠå°ãªããšã(a)ææ©é
å¡©ã(b)å 觊åªåã³(c)éå å€ãå«æããŠãªãç±çŸå
æå ææã«ãããŠã該éå±€ã®å°ãªããšãïŒå±€ã«(d)
äžèšäžè¬åŒã§è¡šããããåäœãæããéåäœãå«
æããããããšãç¹åŸŽãšããç±çŸåæå ææã ããã ããããã§ïŒ²ã¯æ°ŽçŽ åååã¯äœçŽã¢ã«ã
ã«åºãè¡šãããã¯æ°ŽçŽ ååãããã²ã³åååã¯
ãããåºãè¡šãããã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1634179A JPS55108654A (en) | 1979-02-15 | 1979-02-15 | Heat developable photosensitive material |
| GB8004869A GB2044475B (en) | 1979-02-15 | 1980-02-13 | Heat developable photosensitive material |
| DE19803005714 DE3005714A1 (de) | 1979-02-15 | 1980-02-15 | Hitzeentwickelbares, lichtempfindliches material |
| US06/121,855 US4291120A (en) | 1979-02-15 | 1980-02-15 | Heat developable photosensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1634179A JPS55108654A (en) | 1979-02-15 | 1979-02-15 | Heat developable photosensitive material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55108654A JPS55108654A (en) | 1980-08-21 |
| JPS6228455B2 true JPS6228455B2 (ja) | 1987-06-20 |
Family
ID=11913693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1634179A Granted JPS55108654A (en) | 1979-02-15 | 1979-02-15 | Heat developable photosensitive material |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4291120A (ja) |
| JP (1) | JPS55108654A (ja) |
| DE (1) | DE3005714A1 (ja) |
| GB (1) | GB2044475B (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2073902A (en) * | 1980-04-02 | 1981-10-21 | Fuji Photo Film Co Ltd | Photographic light-sensitive material having subbed plastics support |
| JPS58137831A (ja) * | 1982-02-10 | 1983-08-16 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææ |
| CA1329335C (en) * | 1986-12-17 | 1994-05-10 | Akihiko Nagumo | Image-forming method employing light-sensitive material |
| EP0792477A2 (en) * | 1994-11-16 | 1997-09-03 | Imation Corp. | Photothermographic element with improved adherence between layers |
| US5928857A (en) * | 1994-11-16 | 1999-07-27 | Minnesota Mining And Manufacturing Company | Photothermographic element with improved adherence between layers |
| US5891616A (en) * | 1995-07-18 | 1999-04-06 | Agfa-Gevaert | Process for producing a suspension of particles containing an organic silver salt for use in the production of thermographic and photothermographic materials |
| JPH09311405A (ja) * | 1996-05-23 | 1997-12-02 | Fuji Photo Film Co Ltd | ç±çŸåææ |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5321646B2 (ja) * | 1973-04-27 | 1978-07-04 |
-
1979
- 1979-02-15 JP JP1634179A patent/JPS55108654A/ja active Granted
-
1980
- 1980-02-13 GB GB8004869A patent/GB2044475B/en not_active Expired
- 1980-02-15 US US06/121,855 patent/US4291120A/en not_active Expired - Lifetime
- 1980-02-15 DE DE19803005714 patent/DE3005714A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US4291120A (en) | 1981-09-22 |
| GB2044475B (en) | 1983-03-16 |
| JPS55108654A (en) | 1980-08-21 |
| GB2044475A (en) | 1980-10-15 |
| DE3005714A1 (de) | 1980-08-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4359524A (en) | Heat developable photosensitive material | |
| US4152160A (en) | Thermally developable light-sensitive material with a benzoic acid | |
| US4170480A (en) | Thermally developable light-sensitive material | |
| US4281060A (en) | Heat-developable photosensitive materials | |
| US4546075A (en) | Heat-developable photographic material | |
| US4144072A (en) | Thermally developable light-sensitive material | |
| JPH0226214B2 (ja) | ||
| US4452885A (en) | Heat-developable photographic material | |
| US6274297B1 (en) | Photothermographic recording material with in-situ and ex-situ photosensitive silver halide and a substantially light-insensitive organic salt | |
| US4291120A (en) | Heat developable photosensitive material | |
| US4267267A (en) | Thermally-developable light-sensitive elements | |
| JPS6045413B2 (ja) | ç±çŸåæå ææ | |
| GB1565043A (en) | Dry processing type recording elemnts | |
| JPH0219938B2 (ja) | ||
| US3885968A (en) | Thermally developable light-sensitive material | |
| JPS6025776B2 (ja) | ç±çŸåæå ææ | |
| US6558895B2 (en) | Photothermographic recording materials with improved stability | |
| JP4068696B2 (ja) | æå æ§ç±ççŸåå¯èœåçææã®ããã®æ床åäžèšé²æ³ | |
| JP3800885B2 (ja) | ç±çŸåæå ææ | |
| JP3731603B2 (ja) | ç±çŸåéå¡©åçæå ææåã³éç»å圢ææ¹æ³ | |
| JPS5820024B2 (ja) | ããã²ã³ãŸãŠã«ã³ã³ãŠã¶ã€ãªãšãŠ | |
| JP3731602B2 (ja) | ç±çŸåéå¡©åçæå ææåã³éç»å圢ææ¹æ³ | |
| JP3671486B2 (ja) | ç±çŸåéå¡©åçæå ææåã³ç»å圢ææ¹æ³ | |
| JPS5957233A (ja) | ç±çŸåæå ææ | |
| JPS5946641A (ja) | ç±çŸåæå ææ |