JPS6236899A - Manufacturing method for single-sided through-hole wiring board - Google Patents
Manufacturing method for single-sided through-hole wiring boardInfo
- Publication number
- JPS6236899A JPS6236899A JP17653785A JP17653785A JPS6236899A JP S6236899 A JPS6236899 A JP S6236899A JP 17653785 A JP17653785 A JP 17653785A JP 17653785 A JP17653785 A JP 17653785A JP S6236899 A JPS6236899 A JP S6236899A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- hole
- copper
- sided
- plating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000003054 catalyst Substances 0.000 claims description 30
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 28
- 238000007747 plating Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 14
- 239000011889 copper foil Substances 0.000 claims description 12
- 238000007772 electroless plating Methods 0.000 claims description 11
- 238000005530 etching Methods 0.000 claims description 10
- 238000005553 drilling Methods 0.000 claims description 7
- 238000009740 moulding (composite fabrication) Methods 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 description 16
- 239000010949 copper Substances 0.000 description 16
- 229910000679 solder Inorganic materials 0.000 description 10
- 238000005476 soldering Methods 0.000 description 6
- 239000000976 ink Substances 0.000 description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- FHKNFXAIEAYRKQ-UHFFFAOYSA-N [Cu].[Ir] Chemical compound [Cu].[Ir] FHKNFXAIEAYRKQ-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000275 quality assurance Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Landscapes
- Printing Elements For Providing Electric Connections Between Printed Circuits (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 (産業上の利用分野) 本発明は、片面スルーホール配線板の製造法に関する。[Detailed description of the invention] (Industrial application field) The present invention relates to a method for manufacturing a single-sided through-hole wiring board.
(従来の技術)
民生用電子機器のラジオ、TV、VTRなどに主として
使用される片面プリント配線板は、片面の銅張積)鋤板
′f:使用し、その銅箔をエツチング(2て所袈のパタ
ーンを形成するとともに、バンチングに1っで部品取付
用の部品リード線挿入穴(スルーホール)および外形を
加工して作成する。そのようにしで作成した配線板に、
電子部品を取り付けた一例全第2図に示した。(Prior art) Single-sided printed wiring boards, which are mainly used in consumer electronic equipment such as radios, TVs, and VTRs, are made by using one-sided copper-clad plating board'f: and etching the copper foil (in two places). In addition to forming the pattern of the shank, the parts lead wire insertion hole (through hole) for mounting the parts in one piece and the external shape are processed on the bunching.On the wiring board created in this way,
An example with electronic components attached is shown in Figure 2.
第2図に於て、21は絶縁層、22は回路パターン、2
5はバット、24はスルーホール、25は電子部品、2
6は半田である。電子部品25は、そのリード縁を配糾
板の部品面よシ穴(スルーホール)24に通し、半田デ
ィツプ面のバット25とリード線全半田揚げによって取
付けられる。In FIG. 2, 21 is an insulating layer, 22 is a circuit pattern, 2
5 is a bat, 24 is a through hole, 25 is an electronic component, 2
6 is solder. The electronic component 25 is attached by passing its lead edge through a through hole 24 on the component surface of the wiring board and soldering the entire lead wire to the butt 25 on the solder dip surface.
この片面プリント配線板では、電子部品25はリード線
ヲバット23部分のみで半田付けすることにより固定す
るものであるため、半田付信頼性に開局が残る。半田付
信頼性に優れるものとして、第5図に示すような片面ス
ルーホール配線板がおる。In this single-sided printed wiring board, since the electronic component 25 is fixed by soldering only at the lead wire 23 portion, there remains a problem in soldering reliability. A single-sided through-hole wiring board as shown in FIG. 5 has excellent soldering reliability.
片面スルーホール配線板は、穴(スルーホール)34内
壁に銅めっきが施されており、そtによシミ子部品35
は、そのリード線が半田54揚げによってパット63の
みでなく、穴内にも半田34が充填され、強固に取り付
けられる。The single-sided through-hole wiring board has copper plating applied to the inner wall of the hole (through-hole) 34, and the smudge component 35 is placed on the other side.
By applying the solder 54 to the lead wire, not only the pad 63 but also the hole is filled with the solder 34, and the lead wire is firmly attached.
したがって半田付信頼性が一段と向上し、品質保証上非
常に好ましい。第3図に於て、51は絶縁層、52け回
路パターンである。Therefore, soldering reliability is further improved, which is very desirable in terms of quality assurance. In FIG. 3, 51 is an insulating layer and 52 circuit patterns.
特に振動の激しい状態で使用する場什には、片面スルー
ホール配線板の効果が強く表われる。Particularly when used under conditions of severe vibration, the effect of a single-sided through-hole wiring board is particularly evident.
例えば自動車搭載用電子機器には多く採用されている。For example, it is widely used in electronic devices installed in automobiles.
この片面スルーホール配線板は、通常第4図に示す方法
により製造される。This single-sided through-hole wiring board is usually manufactured by the method shown in FIG.
すなわち、片WJ銅張積層板41を(A)、銅箔42の
ない面金触媒処理すると無電解めっきが析出するので、
触媒が耐着しないためのレジスト45印刷をする(B)
。穴44あけ(C)、触媒45処理(DJ、レジスト4
5剥離(E)、無電解めっき、電解めっき(1次)46
(Fl、めっきレジスト47印刷(G)、vl解めっき
(2次)48、半田ぬっき49(Hl、めっきレジスト
47剥離(■)、エツチング(J)、半田レジスト5G
印刷(K)の工程にLり製造される。半田めっき49(
H)に代えて、テンティング法、水理法により回路形成
を行っても良い。That is, when the single WJ copper-clad laminate 41 (A) is subjected to the surface gold catalyst treatment without the copper foil 42, electroless plating is deposited.
Print resist 45 to prevent the catalyst from sticking (B)
. Hole 44 drilling (C), catalyst 45 treatment (DJ, resist 4
5 Peeling (E), electroless plating, electrolytic plating (primary) 46
(Fl, plating resist 47 printing (G), vl deplating (secondary) 48, soldering 49 (Hl, plating resist 47 peeling (■), etching (J), solder resist 5G
It is manufactured in the printing (K) process. Solder plating 49 (
Instead of H), the circuit may be formed by a tenting method or a hydraulic method.
(発明が解決しようとする問題点)
しかしながらこの方法は片面銅張積層板から出発するた
ぬ、一方の面のみに銅箔があり、片方の面には銅箔がな
いので、無電解鋼めっきの前処理工程である穴内の触媒
処理(D) ’に行う場合、銅箔のない絶縁板表面に触
媒が耐着しない念めの触媒耐着防止皮膜43を形成する
か、触媒処理前に皮膜を形成しておき、触媒処理後その
皮膜を除去し、絶縁板表面に触媒が耐着しないようにす
る。したがってtn箔のない片面の絶縁板表面に触媒が
耐着しないための工程が心安であり、そのために画商ス
ルーホール配線板の製造工程と比較して工程数が多くな
る。(Problem to be solved by the invention) However, this method starts from a single-sided copper-clad laminate, and since there is copper foil on only one side and no copper foil on the other side, electroless steel plating is not possible. When carrying out the catalyst treatment (D)' in the holes, which is the pretreatment process of The film is removed after the catalyst treatment to prevent the catalyst from adhering to the surface of the insulating plate. Therefore, it is safe to use a process to prevent the catalyst from adhering to the surface of the one-sided insulating plate without the TN foil, and for this reason, the number of processes is greater than that of the manufacturing process of the art dealer through-hole wiring board.
本発明は、製造工程が短縮され、高密度配線パターンの
形成に處する片面スルーホール配線板の製造法を提供す
るものである。The present invention provides a method for manufacturing a single-sided through-hole wiring board that shortens the manufacturing process and facilitates the formation of high-density wiring patterns.
(問題点を解決するための手段) 第1図により本発明を貌明する。(Means for solving problems) The present invention will be explained clearly with reference to FIG.
第1図(5)は、片面銅張積層板を示すもので、銅箔1
1、触媒入り積層板等の絶縁/i#12と非触媒絶縁層
15の57iilより形成されているものである。触媒
入りPlij層は、絶縁層内に触媒が入っており、無電
解めっきに際して触媒処理をする必要がなく銅は析出す
る。Figure 1 (5) shows a single-sided copper-clad laminate, with copper foil 1
1. It is formed from an insulating layer such as a catalyst-containing laminate/i#12 and a non-catalytic insulating layer 15 (57iil). In the catalyst-containing Plij layer, a catalyst is contained in the insulating layer, and copper is deposited without the need for catalyst treatment during electroless plating.
すなわち触媒入り絶縁板に明けられた穴内壁の表面には
、触媒が一様に分布しているので、無電解銅めっき浴に
浸ffすれば、穴内壁表面には無電解の銅が析出する。In other words, the catalyst is uniformly distributed on the surface of the inner wall of the hole drilled in the catalyst-containing insulating plate, so if the hole is immersed in an electroless copper plating bath, electroless copper will be deposited on the inner wall surface of the hole. .
しかし、一般のN!3縁層(非触媒絶縁層)には、触媒
が入っていないのて、その層の部分には全く銅が析出し
ない。However, general N! Since the third edge layer (non-catalytic insulating layer) does not contain a catalyst, no copper is deposited in that layer.
触媒としては、元素周期律表の第1族および第1B族に
属する金属、たとえば、ニッケル、金、銀、プラチナ、
パラジウム、ロジウム、銅イリジウム等、又はこれらの
酸化物、塩化物、臭化物、弗化物、エチルアセテート、
フルオロボレート、硝酸塩、硫酸塩、・アセテート等を
挙げることができる。特に有用なのは、パラジウム、金
、プラチナ、銅、塩化パラジウム、塩化金、塩化プラチ
ナ、酸化銅またはこれらと塩化第1錫含組合せたもので
ある。こnらの触媒をAl20s−8iCh 系の担体
に吸着させ、又、エポキシ樹脂に混合したものを熱硬化
性樹脂フェス中に分散させ、これをガラスクロス、紙等
の基材に含浸、乾燥させ触媒入りプリプレグを作る。As a catalyst, metals belonging to Groups 1 and 1B of the periodic table of elements, such as nickel, gold, silver, platinum,
Palladium, rhodium, copper iridium, etc., or their oxides, chlorides, bromides, fluorides, ethyl acetate,
Examples include fluoroborates, nitrates, sulfates, and acetates. Particularly useful are palladium, gold, platinum, copper, palladium chloride, gold chloride, platinum chloride, copper oxide or combinations thereof containing tinn chloride. These catalysts are adsorbed on an Al20s-8iCh carrier, mixed with epoxy resin and dispersed in a thermosetting resin face, and this is impregnated into a base material such as glass cloth or paper and dried. Make prepreg containing catalyst.
又触媒を混入しないで触媒なしのプリプレグを作る。触
媒入りプリプレグの必要枚数重ね合せた一方の面に触媒
なしのプリプレグの必要枚数を重ね合せ、他の面に銅箔
全型ね合せ、全体を加熱加圧一体化して片面銅張積層板
を製造する。Also, a catalyst-free prepreg is made without mixing a catalyst. Manufacture a single-sided copper-clad laminate by stacking the required number of catalyst-containing prepreg sheets on one side, laminating the required number of catalyst-free prepreg sheets on the other side, laminating all the copper foil on the other side, and integrating the whole under heat and pressure. do.
このような、無電解めっき触媒の混入した積層板と、そ
の一面の無[Mめっき触媒の混入しない所定厚積層板層
と、他面の銅箔とで構成される片面銅張積層板を使用し
て(4)、先づ耐エツチング用レジストパターンの形成
を与真あるい6一
は印刷て行い、エツチングにニジ@箔のパターン14を
形成する(B)、うそのエツチングされた銅箔パターン
の所要の箇所に穴15を明けて(C)、さらに銅箔パタ
ーンのバット以外の部分(半田付けを行う部分)に永久
1ノジスト16印絢全行なう(I))。その永久1ノジ
ストインクの表面には、無電解めっき浴に浸漬しても無
電m銅が析出しない耐めっき性のインクである。又その
永久レジストインクは、無電解ぬっき液の中に長時間浸
漬しても溶解などによりめっき液全汚染しないものであ
る。A single-sided copper-clad laminate is used, which is composed of a laminate mixed with an electroless plating catalyst, a laminate layer of a predetermined thickness on one side that is not mixed with an electroless plating catalyst, and a copper foil on the other side. (4) First, a resist pattern for etching resistance is formed by printing, and a rainbow@foil pattern 14 is formed on the etching (B). Holes 15 are made at the required locations (C), and 16 permanent nosists are injected completely on the part of the copper foil pattern other than the butt (the part to be soldered) (I)). The permanent nozzle ink is a plating-resistant ink that does not deposit electroless copper even when immersed in an electroless plating bath. Moreover, the permanent resist ink does not completely contaminate the plating solution due to dissolution even if it is immersed in the electroless plating solution for a long time.
永久レジストインクの印刷さlrした配線板全無電解め
っき浴に浸漬すると、銅箔上・触媒入り絶縁j−の表面
(穴の内壁表面)のみに銅17が析出し、その他の永久
レジストインクの表面および触媒の入っていない絶縁層
表面(非触媒絶縁層)には銅が析出しない。したがって
所要の部分のみに銅めっき17が施さし1片面スルーホ
ール配勝板をうることができる。When a wiring board printed with permanent resist ink is immersed in a total electroless plating bath, copper 17 is deposited only on the copper foil and the surface of the catalyst-containing insulation (inner wall surface of the hole), and other permanent resist inks are removed. No copper is deposited on the surface or the surface of the insulating layer that does not contain a catalyst (non-catalyst insulating layer). Therefore, it is possible to obtain a single-sided through-hole distribution plate with copper plating 17 applied only to the required portions.
以上、エツチング(B)、穴あけ(Qfflめっきレジ
スト形成(r))の場合ヲ示したがエツチング(B)、
めっきレジスト形成(1’))、穴あけ(C)、又は穴
あけ(C1、エツチング(B)、めっきレジスト形成(
L))の銅にすることも出来る。The cases of etching (B) and drilling (Qffl plating resist formation (r)) have been shown above, but etching (B),
Plating resist formation (1')), drilling (C), or drilling (C1), etching (B), plating resist formation (
L)) copper can also be used.
(発明の効果)
本発明の方法では、銅箔−触媒入り層−非触媒1−から
成りケっている片面銅張り積層板を使用するとともに、
所要の穴内壁部分のみに無電解銅めっき全析出させるも
のであるため、簡単な工程で片面スルーホール配線板を
製造することが出来る。(Effects of the Invention) In the method of the present invention, a single-sided copper-clad laminate consisting of a copper foil, a catalyst-containing layer, and a non-catalyst layer is used, and
Since electroless copper plating is entirely deposited only on the required inner wall portion of the hole, a single-sided through-hole wiring board can be manufactured with a simple process.
又、非触媒絶縁層の厚さTl を変えることにより穴内
壁の無電解めっき銅の析出する高さTl(触媒入り層の
厚みに相当する)を任意に選定できる。銅の析出高さT
l を任意に変えられることは、従来の方法を用いる
と全く不可能である。従来の法では、電気めっきによっ
て穴内の銅ぬっきを施すが、部品面(バタ・−ンのない
面)の穴出口にも銅めっきが析出して、穴の出口にもり
上がる。その影響も加わって非常に接近した穴の場合に
は、半田揚げKよって半田が穴から突出し、隣の穴と半
H]によるブリッナを発生する。Further, by changing the thickness Tl of the non-catalytic insulating layer, the height Tl (corresponding to the thickness of the catalyst-containing layer) at which electroless plated copper is deposited on the inner wall of the hole can be arbitrarily selected. Copper precipitation height T
It is completely impossible to vary l arbitrarily using conventional methods. In the conventional method, the inside of the hole is plated with copper by electroplating, but the copper plating is also deposited at the hole exit on the part surface (the side without the butterflies) and rises to the hole exit. Adding to this effect, in the case of holes that are very close to each other, the solder protrudes from the hole due to solder frying, and a blister is generated due to the neighboring hole and the half hole.
本発明では接近した穴であっても半田上りが少ないので
、半田によりブリッジが発生しない。In the present invention, even if the holes are close together, there is little solder buildup, so no bridging occurs due to solder.
穴内壁に施すめきの高さTl は、一般的に&X 10
0 % == 20〜50 %が適当である。The height Tl of the plating applied to the inner wall of the hole is generally &X 10
0%==20-50% is suitable.
第1図は本発明の方法を示す断面図、第2図、第5図は
配線板の断面図、第4図は従来の方法を示す断面図であ
る。
符号の説明
11、銅箔
12 触媒入り絶縁ノー
1五非触媒絶縁層
14、パターン
15、穴
16、永久レジスト
17、析出鋼FIG. 1 is a sectional view showing the method of the present invention, FIGS. 2 and 5 are sectional views of a wiring board, and FIG. 4 is a sectional view showing the conventional method. Explanation of symbols 11, copper foil 12, catalyst-containing insulation No. 15, non-catalytic insulation layer 14, pattern 15, hole 16, permanent resist 17, deposited steel
Claims (1)
無電解めっき触媒の混入しない所定厚みの積層板層と他
面の銅箔とで構成される片面銅張積層板を、エッチング
、穴あけ、めっきレジストの形成を行うか、又は、エッ
チング、めっきレジストの形成、穴あけを行うか、又は
、穴あけ、エッチング、めっきレジストの形成を行うか
した後、無電解めっきを行うことを特徴とする片面スル
ーホール配線板の製造法。1. Etching and drilling a single-sided copper-clad laminate consisting of a laminate mixed with an electroless plating catalyst, a laminate layer of a predetermined thickness that does not contain the electroless plating catalyst on one side, and copper foil on the other side. , one side characterized by performing electroless plating after forming a plating resist, or performing etching, forming a plating resist, and drilling, or performing drilling, etching, and forming a plating resist. A method for manufacturing through-hole wiring boards.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17653785A JPS6236899A (en) | 1985-08-10 | 1985-08-10 | Manufacturing method for single-sided through-hole wiring board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17653785A JPS6236899A (en) | 1985-08-10 | 1985-08-10 | Manufacturing method for single-sided through-hole wiring board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6236899A true JPS6236899A (en) | 1987-02-17 |
Family
ID=16015332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17653785A Pending JPS6236899A (en) | 1985-08-10 | 1985-08-10 | Manufacturing method for single-sided through-hole wiring board |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6236899A (en) |
-
1985
- 1985-08-10 JP JP17653785A patent/JPS6236899A/en active Pending
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