JPS63221128A - ポリ（アリーレンスルフィド）およびその製造方法 - Google Patents

ポリ（アリーレンスルフィド）およびその製造方法

Info

Publication number: JPS63221128A
Authority: JP; Japan
Prior art keywords: monomer; dihalobenzene; poly; carbon atoms; meta
Prior art date: 1987-01-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP62336718A

Other languages

English (en)

Japanese (ja)

Inventor

マイケル・デュアン・クリフトン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Phillips Petroleum Co

Original Assignee

Phillips Petroleum Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-01-02

Filing date

1987-12-28

Publication date

1988-09-14

1987-12-28 Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co

1988-09-14 Publication of JPS63221128A publication Critical patent/JPS63221128A/ja

Status Pending legal-status Critical Current

Links

-1 Poly(arylene sulfide Chemical compound 0.000 title claims description 49
238000004519 manufacturing process Methods 0.000 title claims description 8
239000000178 monomer Substances 0.000 claims description 94
229920001577 copolymer Polymers 0.000 claims description 42
238000000034 method Methods 0.000 claims description 35
229920000642 polymer Polymers 0.000 claims description 31
125000004432 carbon atom Chemical group C* 0.000 claims description 29
238000006116 polymerization reaction Methods 0.000 claims description 29
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical group CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 26
239000000203 mixture Substances 0.000 claims description 25
229920001400 block copolymer Polymers 0.000 claims description 24
125000003118 aryl group Chemical group 0.000 claims description 17
239000000126 substance Substances 0.000 claims description 15
239000000155 melt Substances 0.000 claims description 14
229910052977 alkali metal sulfide Inorganic materials 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical group ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims description 11
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 claims description 10
239000003495 polar organic solvent Substances 0.000 claims description 9
125000000753 cycloalkyl group Chemical group 0.000 claims description 8
238000006243 chemical reaction Methods 0.000 claims description 7
150000002367 halogens Chemical group 0.000 claims description 7
ZPQOPVIELGIULI-UHFFFAOYSA-N 1,3-dichlorobenzene Chemical group ClC1=CC=CC(Cl)=C1 ZPQOPVIELGIULI-UHFFFAOYSA-N 0.000 claims description 6
125000003710 aryl alkyl group Chemical group 0.000 claims description 6
239000001257 hydrogen Substances 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
125000002877 alkyl aryl group Chemical group 0.000 claims description 5
125000000217 alkyl group Chemical group 0.000 claims description 5
KZHZSALFKRDIBQ-UHFFFAOYSA-N 1,4-dibromo-2-ethyl-5-propan-2-ylbenzene Chemical compound CCC1=CC(Br)=C(C(C)C)C=C1Br KZHZSALFKRDIBQ-UHFFFAOYSA-N 0.000 claims description 3
WKDOCYUWLREIQL-UHFFFAOYSA-N 1,4-dichloro-2-(3-methylcyclopentyl)-5-octylbenzene Chemical compound C1=C(Cl)C(CCCCCCCC)=CC(Cl)=C1C1CC(C)CC1 WKDOCYUWLREIQL-UHFFFAOYSA-N 0.000 claims description 3
NHDODQWIKUYWMW-UHFFFAOYSA-N 1-bromo-4-chlorobenzene Chemical compound ClC1=CC=C(Br)C=C1 NHDODQWIKUYWMW-UHFFFAOYSA-N 0.000 claims description 3
GWQSENYKCGJTRI-UHFFFAOYSA-N 1-chloro-4-iodobenzene Chemical compound ClC1=CC=C(I)C=C1 GWQSENYKCGJTRI-UHFFFAOYSA-N 0.000 claims description 3
ZXONXKTYRSSVKY-UHFFFAOYSA-N 2-benzyl-1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C(CC=2C=CC=CC=2)=C1 ZXONXKTYRSSVKY-UHFFFAOYSA-N 0.000 claims description 3
150000003857 carboxamides Chemical class 0.000 claims description 3
239000000463 material Substances 0.000 claims description 3
229910052979 sodium sulfide Inorganic materials 0.000 claims description 3
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical group [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 3
239000007787 solid Substances 0.000 claims description 3
239000002904 solvent Substances 0.000 claims description 3
JSRLURSZEMLAFO-UHFFFAOYSA-N 1,3-dibromobenzene Chemical compound BrC1=CC=CC(Br)=C1 JSRLURSZEMLAFO-UHFFFAOYSA-N 0.000 claims description 2
SWJPEBQEEAHIGZ-UHFFFAOYSA-N 1,4-dibromobenzene Chemical compound BrC1=CC=C(Br)C=C1 SWJPEBQEEAHIGZ-UHFFFAOYSA-N 0.000 claims description 2
JRGGUPZKKTVKOV-UHFFFAOYSA-N 1-bromo-3-chlorobenzene Chemical compound ClC1=CC=CC(Br)=C1 JRGGUPZKKTVKOV-UHFFFAOYSA-N 0.000 claims description 2
JMLWXCJXOYDXRN-UHFFFAOYSA-N 1-chloro-3-iodobenzene Chemical compound ClC1=CC=CC(I)=C1 JMLWXCJXOYDXRN-UHFFFAOYSA-N 0.000 claims description 2
229910052783 alkali metal Inorganic materials 0.000 claims description 2
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 claims description 2
238000011084 recovery Methods 0.000 claims description 2
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 9
229920000069 polyphenylene sulfide Polymers 0.000 claims 5
229910052736 halogen Inorganic materials 0.000 claims 3
OFHDZEYCBJGZEF-UHFFFAOYSA-N 1,4-dibromo-2-(4-methylphenyl)benzene Chemical compound C1=CC(C)=CC=C1C1=CC(Br)=CC=C1Br OFHDZEYCBJGZEF-UHFFFAOYSA-N 0.000 claims 2
PTIQIITULDNGAF-UHFFFAOYSA-N 1,4-dichloro-2,3,5,6-tetramethylbenzene Chemical compound CC1=C(C)C(Cl)=C(C)C(C)=C1Cl PTIQIITULDNGAF-UHFFFAOYSA-N 0.000 claims 2
UTGSRNVBAFCOEU-UHFFFAOYSA-N 1,4-dichloro-2,5-dimethylbenzene Chemical group CC1=CC(Cl)=C(C)C=C1Cl UTGSRNVBAFCOEU-UHFFFAOYSA-N 0.000 claims 2
KFAKZJUYBOYVKA-UHFFFAOYSA-N 1,4-dichloro-2-methylbenzene Chemical compound CC1=CC(Cl)=CC=C1Cl KFAKZJUYBOYVKA-UHFFFAOYSA-N 0.000 claims 2
UCCUXODGPMAHRL-UHFFFAOYSA-N 1-bromo-4-iodobenzene Chemical compound BrC1=CC=C(I)C=C1 UCCUXODGPMAHRL-UHFFFAOYSA-N 0.000 claims 2
YDUZJJVOMVPPMD-UHFFFAOYSA-N 2,5-dichloro-1-dodecyl-3-hexylbenzene Chemical compound CCCCCCCCCCCCC1=CC(Cl)=CC(CCCCCC)=C1Cl YDUZJJVOMVPPMD-UHFFFAOYSA-N 0.000 claims 2
150000005171 halobenzenes Chemical class 0.000 claims 2
NAQWICRLNQSPPW-UHFFFAOYSA-N 1,2,3,4-tetrachloronaphthalene Chemical compound C1=CC=CC2=C(Cl)C(Cl)=C(Cl)C(Cl)=C21 NAQWICRLNQSPPW-UHFFFAOYSA-N 0.000 claims 1
YPFCYPZKFQPCOC-UHFFFAOYSA-N 1,2,3,5-tetrabromobenzene Chemical compound BrC1=CC(Br)=C(Br)C(Br)=C1 YPFCYPZKFQPCOC-UHFFFAOYSA-N 0.000 claims 1
RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical group ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 claims 1
DMFMMVMUXPAZKT-UHFFFAOYSA-N 1,2,4-tribromo-6-methylnaphthalene Chemical compound BrC1=C(Br)C=C(Br)C2=CC(C)=CC=C21 DMFMMVMUXPAZKT-UHFFFAOYSA-N 0.000 claims 1
VMNISWKTOHUZQN-UHFFFAOYSA-N 1,3,5-trichloro-2,4,6-trimethylbenzene Chemical compound CC1=C(Cl)C(C)=C(Cl)C(C)=C1Cl VMNISWKTOHUZQN-UHFFFAOYSA-N 0.000 claims 1
RCTKUIOMKBEGTG-UHFFFAOYSA-N 1,3,5-trichloro-2-methylbenzene Chemical compound CC1=C(Cl)C=C(Cl)C=C1Cl RCTKUIOMKBEGTG-UHFFFAOYSA-N 0.000 claims 1
DZHFFMWJXJBBRG-UHFFFAOYSA-N 1-bromo-3,5-dichlorobenzene Chemical compound ClC1=CC(Cl)=CC(Br)=C1 DZHFFMWJXJBBRG-UHFFFAOYSA-N 0.000 claims 1
QORAVNMWUNPXAO-UHFFFAOYSA-N 2,2',4,4'-tetrachlorobiphenyl Chemical group ClC1=CC(Cl)=CC=C1C1=CC=C(Cl)C=C1Cl QORAVNMWUNPXAO-UHFFFAOYSA-N 0.000 claims 1
SHJDOXMERQRWDJ-UHFFFAOYSA-N 4-bromo-1-chloro-2-phenylbenzene Chemical compound ClC1=CC=C(Br)C=C1C1=CC=CC=C1 SHJDOXMERQRWDJ-UHFFFAOYSA-N 0.000 claims 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
239000007864 aqueous solution Substances 0.000 claims 1
229910052799 carbon Inorganic materials 0.000 claims 1
238000001816 cooling Methods 0.000 claims 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 15
238000002474 experimental method Methods 0.000 description 14
229910052717 sulfur Inorganic materials 0.000 description 14
239000011593 sulfur Substances 0.000 description 14
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 5
238000002425 crystallisation Methods 0.000 description 5
230000008025 crystallization Effects 0.000 description 5
239000008367 deionised water Substances 0.000 description 5
229910021641 deionized water Inorganic materials 0.000 description 5
230000009257 reactivity Effects 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 4
239000001632 sodium acetate Substances 0.000 description 4
235000017281 sodium acetate Nutrition 0.000 description 4
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
239000003513 alkali Substances 0.000 description 3
150000001491 aromatic compounds Chemical class 0.000 description 3
239000000835 fiber Substances 0.000 description 3
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
239000010931 gold Substances 0.000 description 3
229910052737 gold Inorganic materials 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
238000005406 washing Methods 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
230000018044 dehydration Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
229940117389 dichlorobenzene Drugs 0.000 description 2
238000004821 distillation Methods 0.000 description 2
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
239000007789 gas Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 2
AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
XVOPLIDJHUQNRE-UHFFFAOYSA-N 1,2-dibromo-4-iodobenzene Chemical compound BrC1=CC=C(I)C=C1Br XVOPLIDJHUQNRE-UHFFFAOYSA-N 0.000 description 1
AZAMPMUEKXNYFW-UHFFFAOYSA-N 1-[2-(2-oxopyrrolidin-1-yl)ethyl]pyrrolidin-2-one Chemical compound O=C1CCCN1CCN1C(=O)CCC1 AZAMPMUEKXNYFW-UHFFFAOYSA-N 0.000 description 1
CTPUUDQIXKUAMO-UHFFFAOYSA-N 1-bromo-3-iodobenzene Chemical compound BrC1=CC=CC(I)=C1 CTPUUDQIXKUAMO-UHFFFAOYSA-N 0.000 description 1
OSOUNOBYRMOXQQ-UHFFFAOYSA-N 1-chloro-3-methylbenzene Chemical compound CC1=CC=CC(Cl)=C1 OSOUNOBYRMOXQQ-UHFFFAOYSA-N 0.000 description 1
GWCFTYITFDWLAY-UHFFFAOYSA-N 1-ethylazepan-2-one Chemical compound CCN1CCCCCC1=O GWCFTYITFDWLAY-UHFFFAOYSA-N 0.000 description 1
ZWMYTAHVFFRQTD-UHFFFAOYSA-N 2,4-dibromo-3-(2,6-dibromo-3,5-dimethylphenyl)-1,5-dimethylbenzene Chemical group CC1=CC(C)=C(Br)C(C=2C(=C(C)C=C(C)C=2Br)Br)=C1Br ZWMYTAHVFFRQTD-UHFFFAOYSA-N 0.000 description 1
KZMAWJRXKGLWGS-UHFFFAOYSA-N 2-chloro-n-[4-(4-methoxyphenyl)-1,3-thiazol-2-yl]-n-(3-methoxypropyl)acetamide Chemical compound S1C(N(C(=O)CCl)CCCOC)=NC(C=2C=CC(OC)=CC=2)=C1 KZMAWJRXKGLWGS-UHFFFAOYSA-N 0.000 description 1
ODPYDILFQYARBK-UHFFFAOYSA-N 7-thiabicyclo[4.1.0]hepta-1,3,5-triene Chemical compound C1=CC=C2SC2=C1 ODPYDILFQYARBK-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
241000251730 Chondrichthyes Species 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
IJCVBMSXIPFVLH-UHFFFAOYSA-N [C].S=O Chemical class [C].S=O IJCVBMSXIPFVLH-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000001588 bifunctional effect Effects 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000007865 diluting Methods 0.000 description 1
ADPOBOOHCUVXGO-UHFFFAOYSA-H dioxido-oxo-sulfanylidene-$l^{6}-sulfane;gold(3+) Chemical class [Au+3].[Au+3].[O-]S([O-])(=O)=S.[O-]S([O-])(=O)=S.[O-]S([O-])(=O)=S ADPOBOOHCUVXGO-UHFFFAOYSA-H 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
150000003951 lactams Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
241000894007 species Species 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
238000001308 synthesis method Methods 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
150000003556 thioamides Chemical class 0.000 description 1
150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
238000011282 treatment Methods 0.000 description 1
239000012989 trithiocarbonate Substances 0.000 description 1
238000010792 warming Methods 0.000 description 1
239000012991 xanthate Substances 0.000 description 1

Landscapes

Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

JP62336718A 1987-01-02 1987-12-28 ポリ（アリーレンスルフィド）およびその製造方法 Pending JPS63221128A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US272		1979-10-12
US27287A	1987-01-02	1987-01-02

Publications (1)

Publication Number	Publication Date
JPS63221128A true JPS63221128A (ja)	1988-09-14

Family

ID=21690747

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP62336718A Pending JPS63221128A (ja)	1987-01-02	1987-12-28	ポリ（アリーレンスルフィド）およびその製造方法

Country Status (2)

Country	Link
JP (1)	JPS63221128A (fr)
CA (1)	CA1336729C (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH02269126A (ja) *	1988-12-29	1990-11-02	Phillips Petroleum Co	フィルムまたは繊維に有用なアリーレンスルフィド樹脂

1987
- 1987-12-14 CA CA000554198A patent/CA1336729C/fr not_active Expired - Fee Related
- 1987-12-28 JP JP62336718A patent/JPS63221128A/ja active Pending

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH02269126A (ja) *	1988-12-29	1990-11-02	Phillips Petroleum Co	フィルムまたは繊維に有用なアリーレンスルフィド樹脂

Also Published As

Publication number	Publication date
CA1336729C (fr)	1995-08-15

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US4116947A (en)	1978-09-26	Branched arylene sulfide polymer production
US3869434A (en)	1975-03-04	Soluble arylene sulfide polymers
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EP0403534B1 (fr)	1993-11-24	Procede de preparation de (copoly)arylene sulfure
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US5200499A (en)	1993-04-06	Removal of water by venting during the polymerization of phenylene sulfide polymers with sulfur source/polar organic compound molar ratio being at least 0.36/1
JP2648270B2 (ja)	1997-08-27	ポリ（フェニレンスルフィド）ポリマーの調製方法
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JPH04202363A (ja)	1992-07-23	ポリアリ―レンサルファイド樹脂組成物
US4882416A (en)	1989-11-21	Preparation of poly arylene sulfide with specified ratio of sulfur source to cyclic organic amide
CA2027409C (fr)	1999-10-05	Copolymere de sulfure de polyphenylene facilement instalisable et preparation a base de celle-ci

JPS63221128A - ポリ（アリーレンスルフィド）およびその製造方法 - Google Patents

Info

Links

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=21690747

Family Applications (1)

Country Status (2)

Cited By (1)

Cited By (1)

Also Published As

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