JPS63291943A - 熱可塑性樹脂組成物 - Google Patents

熱可塑性樹脂組成物

Info

Publication number: JPS63291943A
Authority: JP; Japan
Prior art keywords: weight; parts; latex; resin composition; resin
Prior art date: 1987-05-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP12907787A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0478650B2 (fr

Inventor

Hideo Goto

後藤　日出夫

Koichi Matsuda

幸一松田

Yasuyuki Hiromoto

廣本　恭之

Hiroshi Kawasaki

河崎　宏

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ube Cycon Ltd

Original Assignee

Ube Cycon Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-05-25

Filing date

1987-05-25

Publication date

1988-11-29

1987-05-25 Application filed by Ube Cycon Ltd filed Critical Ube Cycon Ltd

1987-05-25 Priority to JP12907787A priority Critical patent/JPS63291943A/ja

1988-11-29 Publication of JPS63291943A publication Critical patent/JPS63291943A/ja

1992-12-11 Publication of JPH0478650B2 publication Critical patent/JPH0478650B2/ja

Status Granted legal-status Critical Current

Links

239000011342 resin composition Substances 0.000 title abstract description 38
229920005992 thermoplastic resin Polymers 0.000 title abstract description 14
229920001577 copolymer Polymers 0.000 claims abstract description 41
239000000203 mixture Substances 0.000 claims abstract description 40
229920000126 latex Polymers 0.000 claims abstract description 31
229920002554 vinyl polymer Polymers 0.000 claims abstract description 24
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims abstract description 22
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 18
-1 aromatic vinyl compound Chemical class 0.000 claims abstract description 16
229920000578 graft copolymer Polymers 0.000 claims abstract description 13
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims abstract description 11
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 10
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims abstract description 10
239000008121 dextrose Substances 0.000 claims abstract description 10
239000011790 ferrous sulphate Substances 0.000 claims abstract description 10
235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 10
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 10
229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 10
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 10
229940048086 sodium pyrophosphate Drugs 0.000 claims abstract description 10
235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 10
239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 10
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims abstract description 7
239000000178 monomer Substances 0.000 claims description 44
238000006243 chemical reaction Methods 0.000 claims description 43
239000004816 latex Substances 0.000 claims description 27
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 22
238000006116 polymerization reaction Methods 0.000 claims description 22
239000012190 activator Substances 0.000 claims description 13
239000003995 emulsifying agent Substances 0.000 claims description 11
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
239000012986 chain transfer agent Substances 0.000 claims description 6
239000012966 redox initiator Substances 0.000 claims description 6
229920005989 resin Polymers 0.000 abstract description 44
239000011347 resin Substances 0.000 abstract description 44
230000000704 physical effect Effects 0.000 abstract description 14
238000002156 mixing Methods 0.000 abstract description 5
150000001993 dienes Chemical class 0.000 abstract description 3
229920001971 elastomer Polymers 0.000 description 24
238000000034 method Methods 0.000 description 20
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 11
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
230000000052 comparative effect Effects 0.000 description 5
238000005259 measurement Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
238000007334 copolymerization reaction Methods 0.000 description 4
238000010528 free radical solution polymerization reaction Methods 0.000 description 4
238000001746 injection moulding Methods 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
238000011156 evaluation Methods 0.000 description 3
238000002347 injection Methods 0.000 description 3
239000007924 injection Substances 0.000 description 3
239000002932 luster Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000008188 pellet Substances 0.000 description 3
OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 2
HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 2
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
238000012662 bulk polymerization Methods 0.000 description 2
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
235000013539 calcium stearate Nutrition 0.000 description 2
239000008116 calcium stearate Substances 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000007720 emulsion polymerization reaction Methods 0.000 description 2
238000004898 kneading Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
238000010557 suspension polymerization reaction Methods 0.000 description 2
QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
238000005452 bending Methods 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
239000004566 building material Substances 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
230000001112 coagulating effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
VTXVGVNLYGSIAR-UHFFFAOYSA-N decane-1-thiol Chemical compound CCCCCCCCCCS VTXVGVNLYGSIAR-UHFFFAOYSA-N 0.000 description 1
230000007423 decrease Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000010556 emulsion polymerization method Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
229920006258 high performance thermoplastic Polymers 0.000 description 1
230000006698 induction Effects 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
239000012778 molding material Substances 0.000 description 1
238000000465 moulding Methods 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 1
238000010926 purge Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)
Graft Or Block Polymers (AREA)

JP12907787A 1987-05-25 1987-05-25 熱可塑性樹脂組成物 Granted JPS63291943A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP12907787A JPS63291943A (ja)	1987-05-25	1987-05-25	熱可塑性樹脂組成物

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP12907787A JPS63291943A (ja)	1987-05-25	1987-05-25	熱可塑性樹脂組成物

Publications (2)

Publication Number	Publication Date
JPS63291943A true JPS63291943A (ja)	1988-11-29
JPH0478650B2 JPH0478650B2 (fr)	1992-12-11

Family

ID=15000505

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP12907787A Granted JPS63291943A (ja)	1987-05-25	1987-05-25	熱可塑性樹脂組成物

Country Status (1)

Country	Link
JP (1)	JPS63291943A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5352738A (en) *	1991-03-04	1994-10-04	Ube Cycon, Ltd.	Method for production of thermoplastic resin composition and graft copolymer

1987
- 1987-05-25 JP JP12907787A patent/JPS63291943A/ja active Granted

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5352738A (en) *	1991-03-04	1994-10-04	Ube Cycon, Ltd.	Method for production of thermoplastic resin composition and graft copolymer

Also Published As

Publication number	Publication date
JPH0478650B2 (fr)	1992-12-11

Legal Events

Date	Code	Title	Description
2004-12-21	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2005-12-13	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2006-12-12	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2007-05-25	EXPY	Cancellation because of completion of term
2007-08-15	FPAY	Renewal fee payment (event date is renewal date of database)	Free format text: PAYMENT UNTIL: 20071211 Year of fee payment: 15

Publication	Publication Date	Title
US4393172A (en)	1983-07-12	High-notched-impact core-shell polymers having improved weather resistance
CN101429266A (zh)	2009-05-13	制备具有出众光泽、冲击强度和白度的热塑性树脂的方法
US5091470A (en)	1992-02-25	Molding resin
JPS6346106B2 (fr)	1988-09-13
TW202128800A (zh)	2021-08-01	丙烯酸烷酯化合物－氰乙烯化合物－芳族乙烯基化合物接枝共聚物，彼之製法，及含彼之熱塑性樹脂組成物
CA1218484A (fr)	1987-02-24	Alliage de polymere a surface matte
US4603169A (en)	1986-07-29	Thermoplastic molding compositions containing polycarbonate and a graft copolymer of resin-forming monomers on a rubber
KR100513658B1 (ko)	2005-09-07	열안정성 및 분체 특성이 뛰어난 열가소성 수지 조성물 및그 제조방법
US4594387A (en)	1986-06-10	Thermoplastic resin composition having toughness and high thermal deformation resistance
JPH02212534A (ja)	1990-08-23	重合体混合物
JPS63291943A (ja)	1988-11-29	熱可塑性樹脂組成物
JPS63132956A (ja)	1988-06-04	耐衝撃性樹脂組成物
JPH0478645B2 (fr)	1992-12-11
JPH0548779B2 (fr)	1993-07-22
JPH08874B2 (ja)	1996-01-10	熱可塑性樹脂組成物
KR19980029660A (ko)	1998-07-25	자연색상과 내충격성이 우수한 열가소성 수지 조성물의 제조방법.
KR920004212B1 (ko)	1992-05-30	열가소성수지 조성물과 그 제조방법
JPH0379366B2 (fr)	1991-12-18
JPS6235416B2 (fr)	1987-08-01
JPS6321682B2 (fr)	1988-05-09
KR100369378B1 (ko)	2003-04-10	내충격성및인장특성이우수한열가소성수지의제조방법
JPH0794593B2 (ja)	1995-10-11	熱可塑性樹脂組成物
JPH03163163A (ja)	1991-07-15	耐衝撃性熱可塑性樹脂組成物
JP3386532B2 (ja)	2003-03-17	熱可塑性樹脂組成物
JPS63304042A (ja)	1988-12-12	耐熱性熱可塑性樹脂組成物

JPS63291943A - 熱可塑性樹脂組成物 - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=15000505

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

Also Published As

Similar Documents

Legal Events