JPS6411211B2 - - Google Patents
Info
- Publication number
- JPS6411211B2 JPS6411211B2 JP59261920A JP26192084A JPS6411211B2 JP S6411211 B2 JPS6411211 B2 JP S6411211B2 JP 59261920 A JP59261920 A JP 59261920A JP 26192084 A JP26192084 A JP 26192084A JP S6411211 B2 JPS6411211 B2 JP S6411211B2
- Authority
- JP
- Japan
- Prior art keywords
- copolyester
- formula
- carbonate
- diol
- diester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000002947 alkylene group Chemical group 0.000 claims description 12
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 6
- 125000001118 alkylidene group Chemical group 0.000 claims description 4
- 150000002430 hydrocarbons Chemical group 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 30
- 229920005989 resin Polymers 0.000 description 27
- 239000011347 resin Substances 0.000 description 27
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 18
- 229930185605 Bisphenol Natural products 0.000 description 16
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 15
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 15
- -1 derivatives of aromatic hydroxycarboxylic acids Chemical class 0.000 description 15
- 125000003118 aryl group Chemical group 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 10
- 150000002009 diols Chemical class 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical group ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 239000000376 reactant Substances 0.000 description 8
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 235000014489 Cinnamomum aromaticum Nutrition 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000012695 Interfacial polymerization Methods 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- IUPJSFOHUQGEDR-UHFFFAOYSA-N 1,3-dioxetanedione Chemical class O=C1OC(=O)O1 IUPJSFOHUQGEDR-UHFFFAOYSA-N 0.000 description 3
- 241000522254 Cassia Species 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-M 4-hydroxybenzoate Chemical compound OC1=CC=C(C([O-])=O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-M 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 239000000370 acceptor Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 229940106691 bisphenol a Drugs 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- 125000005587 carbonate group Chemical group 0.000 description 2
- 150000007942 carboxylates Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229920005668 polycarbonate resin Polymers 0.000 description 2
- 239000004431 polycarbonate resin Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- LDXJRKWFNNFDSA-UHFFFAOYSA-N 2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound C1CN(CC2=NNN=C21)CC(=O)N3CCN(CC3)C4=CN=C(N=C4)NCC5=CC(=CC=C5)OC(F)(F)F LDXJRKWFNNFDSA-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- AWFYPPSBLUWMFQ-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(1,4,6,7-tetrahydropyrazolo[4,3-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=C2 AWFYPPSBLUWMFQ-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- RKSBPFMNOJWYSB-UHFFFAOYSA-N 3,3-Bis(4-hydroxyphenyl)pentane Chemical compound C=1C=C(O)C=CC=1C(CC)(CC)C1=CC=C(O)C=C1 RKSBPFMNOJWYSB-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- KSYGTCNPCHQRKM-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KSYGTCNPCHQRKM-UHFFFAOYSA-N 0.000 description 1
- BGKMFFFXZCKKGJ-UHFFFAOYSA-N 4-[3-(4-hydroxyphenyl)propyl]phenol Chemical compound C1=CC(O)=CC=C1CCCC1=CC=C(O)C=C1 BGKMFFFXZCKKGJ-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- 150000005168 4-hydroxybenzoic acids Chemical class 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 244000037364 Cinnamomum aromaticum Species 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- MOIPGXQKZSZOQX-UHFFFAOYSA-N carbonyl bromide Chemical compound BrC(Br)=O MOIPGXQKZSZOQX-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- VZWXIQHBIQLMPN-UHFFFAOYSA-N chromane Chemical compound C1=CC=C2CCCOC2=C1 VZWXIQHBIQLMPN-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- NLCKLZIHJQEMCU-UHFFFAOYSA-N cyano prop-2-enoate Chemical class C=CC(=O)OC#N NLCKLZIHJQEMCU-UHFFFAOYSA-N 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 150000005165 hydroxybenzoic acids Chemical class 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 239000011968 lewis acid catalyst Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- KSCKTBJJRVPGKM-UHFFFAOYSA-N octan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-] KSCKTBJJRVPGKM-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Description
çºæã®èæ¯
ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã¯ããã®å€
ãã®æå©ãªæ©æ¢°çããã³ç©ççç¹æ§ã®ããã«ç±å¯
塿§ãšã³ãžãã¢ãªã³ã°ææãšããŠã®çšéãå¢å€§ã
ãŠãã匷éãªç±å¯å¡æ§æš¹èé¡ã«å±ããããããã³
ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã¯ãããšãã°é
æ§ã坿æ§ãè¡æåŒ·ããå åŠçéææ§ããã³é«ã
ç±å€åœ¢æž©åºŠãšãã€ãåªããç¹æ§ã瀺ããåŸæ¥ã®ã³
ããªãšã¹ãã«âã«ãŒãããŒãã¯ãäºäŸ¡ããšããŒ
ã«ããžã«ã«ãã³é žãŸãã¯ãã®ãšã¹ãã«åœ¢ææ§ã®å
å¿æ§èªå°äœãããã³ã«ãŒãããŒãåé§äœã®åæå
å¿ã«ãã€ãŠè£œé ãåŸãããããåŸæ¥ã®ã³ããªãšã¹
ãã«âã«ãŒãããŒããªãã³ã«ãããã®è£œé æ¹æ³
ã¯ãç¹ã«ç±³åœç¹èš±ç¬¬3169121å·ã«é瀺ãããŠããã ããã«ãããããåŸæ¥ã®ã³ããªãšã¹ãã«âã«ãŒ
ãããŒãã¯å å·¥ãå€å°å°é£ã§ããããããã€ãŠã
å€ãã®ç¹ã§åŸæ¥ã®ã³ããªãšã¹ãã«âã«ãŒãããŒã
ãšã»ãŒåãã§ãã€ãŠããããå å·¥æ§ãåªããŠãã
ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èãåŸãããšã¯
倧倿ãŸããããšã§ããã ããã§ãæ¬çºæã®ç®çã¯ãå å·¥æ§ãæ¹è¯ããã
ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èãæäŸããã
ãšã§ããã çºæã®æŠèŠ æ¬çºæã¯ãåŒïŒ ã®ç¹°ãè¿ãæ§é åäœãåŒ ã®ç¹°ãè¿ãæ§é åäœããã³åŒ ã®ç¹°ãè¿ãæ§é åäœ ãåŒäžãã¯ãã©ããšãã¬ã³åºãR1ã¯åŒ ââââ ïŒåŒäžãã¯ã·ã¯ãã¢ã«ãã¬ã³åºã§ïŒ¹ã¯ã¢ã«ãã¬
ã³åºã§ããïŒã§è¡šããããäºäŸ¡ã®åºãR2ã¯åŒïŒ ïŒåŒäžãã¯äºäŸ¡ã®çåæ°ŽçŽ åºãââãâ
âã âââã
ãã®æå©ãªæ©æ¢°çããã³ç©ççç¹æ§ã®ããã«ç±å¯
塿§ãšã³ãžãã¢ãªã³ã°ææãšããŠã®çšéãå¢å€§ã
ãŠãã匷éãªç±å¯å¡æ§æš¹èé¡ã«å±ããããããã³
ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã¯ãããšãã°é
æ§ã坿æ§ãè¡æåŒ·ããå åŠçéææ§ããã³é«ã
ç±å€åœ¢æž©åºŠãšãã€ãåªããç¹æ§ã瀺ããåŸæ¥ã®ã³
ããªãšã¹ãã«âã«ãŒãããŒãã¯ãäºäŸ¡ããšããŒ
ã«ããžã«ã«ãã³é žãŸãã¯ãã®ãšã¹ãã«åœ¢ææ§ã®å
å¿æ§èªå°äœãããã³ã«ãŒãããŒãåé§äœã®åæå
å¿ã«ãã€ãŠè£œé ãåŸãããããåŸæ¥ã®ã³ããªãšã¹
ãã«âã«ãŒãããŒããªãã³ã«ãããã®è£œé æ¹æ³
ã¯ãç¹ã«ç±³åœç¹èš±ç¬¬3169121å·ã«é瀺ãããŠããã ããã«ãããããåŸæ¥ã®ã³ããªãšã¹ãã«âã«ãŒ
ãããŒãã¯å å·¥ãå€å°å°é£ã§ããããããã€ãŠã
å€ãã®ç¹ã§åŸæ¥ã®ã³ããªãšã¹ãã«âã«ãŒãããŒã
ãšã»ãŒåãã§ãã€ãŠããããå å·¥æ§ãåªããŠãã
ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èãåŸãããšã¯
倧倿ãŸããããšã§ããã ããã§ãæ¬çºæã®ç®çã¯ãå å·¥æ§ãæ¹è¯ããã
ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èãæäŸããã
ãšã§ããã çºæã®æŠèŠ æ¬çºæã¯ãåŒïŒ ã®ç¹°ãè¿ãæ§é åäœãåŒ ã®ç¹°ãè¿ãæ§é åäœããã³åŒ ã®ç¹°ãè¿ãæ§é åäœ ãåŒäžãã¯ãã©ããšãã¬ã³åºãR1ã¯åŒ ââââ ïŒåŒäžãã¯ã·ã¯ãã¢ã«ãã¬ã³åºã§ïŒ¹ã¯ã¢ã«ãã¬
ã³åºã§ããïŒã§è¡šããããäºäŸ¡ã®åºãR2ã¯åŒïŒ ïŒåŒäžãã¯äºäŸ¡ã®çåæ°ŽçŽ åºãââãâ
âã âââã
ãåŒãããã³
ãåŒãããéžæãããïŒã§è¡šããããé眮æã
ã¹ããšããŒã«æ®åºããããŠR3ã¯ã¢ã«ãã¬ã³åºã§
ããããããªããæ§é åäœãããã³ããã
ãã®åèšéã«åºã¥ãããããïŒâ60ã¢ã«ïŒ ãïŒâ
40ã¢ã«ïŒ ããã³20â98ã¢ã«ïŒ æããééå¹³ååå
éã10000â150000ã®ç¯å²ã®å å·¥æ§ãæ¹åããã
ç±å¯å¡æ§ã³ããªãšã¹ãã«âã«ãŒãããŒãã«ä¿ãã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹è
ã¯ãäžè¬ã«åŸæ¥ã®ã³ããªãšã¹ãã«âã«ãŒãããŒã
æš¹èãšã»ãŒåæ§ãªç©ççããã³æ©æ¢°çç¹æ§ãå®è³ª
çãªçšåºŠã§ç€ºããšãšãã«ãè¯å¥œãªæµãé床ã«ãã€
ãŠç¹åŸŽä»ããããæ¹åãããå å·¥æ§ã瀺ãã çºæã®èª¬æ æ¬çºæã«ä¿ãã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹
èã¯ãäžè¬ã«åŸæ¥ã®ã³ããªãšã¹ãã«âã«ãŒãããŒ
ãã®æå©ãªç©ççã»æ©æ¢°çç¹æ§ãããšãã°åŒ·é
æ§ã坿æ§ãè¡æåŒ·ããå åŠçéææ§ããã³è¯å¥œ
ãªç±å€åœ¢æž©åºŠã®ã»ãšãã©ãå®è³ªçãªçšåºŠã«ç€ºãã
ãããå å·¥æ§ãåäžããŠããã åç°¡ã«ãããšãæ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒ
ãããŒãæš¹èã¯ãããªããŒé£éäžã«ã«ãŒãããŒã
åº
ããããããªããæ§é åäœãããã³ããã
ãã®åèšéã«åºã¥ãããããïŒâ60ã¢ã«ïŒ ãïŒâ
40ã¢ã«ïŒ ããã³20â98ã¢ã«ïŒ æããééå¹³ååå
éã10000â150000ã®ç¯å²ã®å å·¥æ§ãæ¹åããã
ç±å¯å¡æ§ã³ããªãšã¹ãã«âã«ãŒãããŒãã«ä¿ãã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹è
ã¯ãäžè¬ã«åŸæ¥ã®ã³ããªãšã¹ãã«âã«ãŒãããŒã
æš¹èãšã»ãŒåæ§ãªç©ççããã³æ©æ¢°çç¹æ§ãå®è³ª
çãªçšåºŠã§ç€ºããšãšãã«ãè¯å¥œãªæµãé床ã«ãã€
ãŠç¹åŸŽä»ããããæ¹åãããå å·¥æ§ã瀺ãã çºæã®èª¬æ æ¬çºæã«ä¿ãã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹
èã¯ãäžè¬ã«åŸæ¥ã®ã³ããªãšã¹ãã«âã«ãŒãããŒ
ãã®æå©ãªç©ççã»æ©æ¢°çç¹æ§ãããšãã°åŒ·é
æ§ã坿æ§ãè¡æåŒ·ããå åŠçéææ§ããã³è¯å¥œ
ãªç±å€åœ¢æž©åºŠã®ã»ãšãã©ãå®è³ªçãªçšåºŠã«ç€ºãã
ãããå å·¥æ§ãåäžããŠããã åç°¡ã«ãããšãæ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒ
ãããŒãæš¹èã¯ãããªããŒé£éäžã«ã«ãŒãããŒã
åº
ãåŒãã«ã«ããã·ã¬ãŒãåº
ãåŒãããã³è³éŠæççŽ ç°åŒåºãç¹°ãè¿ã
æããŠããããã ããã«ã«ããã·ã¬ãŒãåºã®å°ãª
ããšãããã€ããšã«ãŒãããŒãåºã®å°ãªããšãã
ãã€ãã¯è³éŠæççŽ ç°åŒåºã®ç°ççŽ ååã«çŽæ¥çµ
åããŠããã å ·äœçã«ã¯ãæ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒã
ããŒãæš¹èã¯æ¬¡ã®äžè¬åŒã§è¡šããããç¹°ãè¿ãæ§
é åäœãããªãã äžèšåŒäžããR1ãR2ããã³R3ã¯åèšå®çŸ©ã®
ãšããã§ããã R1ã®å ·äœäŸã¯ ã§ããã R2ã®åŒäžã®ïŒ·ã®äºäŸ¡ã®çåæ°ŽçŽ åºã¯ã¢ã«ãã¬
ã³åºãã·ã¯ãã¢ã«ãã¬ã³åºãã¢ã«ããªãã³åºãã
ã³ã·ã¯ãã¢ã«ããªãã³åºããéžæããã奜ãŸãã
ã¢ã«ãã¬ã³åºã¯ççŽ ååãïŒãçŽ10å嫿ããã
ã®ã§ããã奜ãŸããã¢ã«ããªãã³åºã¯ççŽ ååã
ïŒãçŽ10å嫿ãããã®ã§ããã奜ãŸããã·ã¯ã
ã¢ã«ãã¬ã³ããã³ã·ã¯ãã¢ã«ããªãã³åºã¯ç°ççŽ
ååãïŒãçŽïŒå嫿ãããã®ã§ããã é眮æãã¹ããšããŒã«æ®åºã§å¥œãŸããã®ã¯ã
ãã¢ã«ãã¬ã³ãã¢ã«ããªãã³ãã·ã¯ãã¢ã«ãã¬ã³
ããã³ã·ã¯ãã¢ã«ããªãã³åºããéžæããããã®
ã§ããã R3ã¯å¥œãŸããã¯ççŽ ååãïŒãçŽ20å嫿ã
ãã¢ã«ãã¬ã³åºã§ãããã¢ã«ãã¬ã³åºã¯çŽéã®ã¢
ã«ãã¬ã³åºã§ãåæã®ã¢ã«ãã¬ã³åºã§ãããã åŸãããæ®åºãåŒäžã®ïŒ²ãšãªãããžãšã¹ãã«
âãžãªãŒã«ã®è£œé ã«çšããããå ±åå¿äœã®ïŒã€ã§
ããè³éŠæããããã·ã«ã«ãã³é žåå¿äœã¯ã次ã®
äžè¬åŒã§è¡šããåŸãã HOââCOOH ããã§ïŒ²ã¯äžã§å®çŸ©ãããšããã§ãããããç¹
å®çã«ãããšãè³éŠæããããã·ã«ã«ãã³é žã¯æ¬¡
ã®åŒã§è¡šããããâããããã·å®æ¯éŠé žã§ã
ãã æ¬çºæã®ãžãšã¹ãã«âãžãªãŒã«ã®è£œé ã«ãã
ãŠãäžèšã®è³éŠæããããã·ã«ã«ãã³é žã®ãšã¹ã
ã«åœ¢ææ§ã®åå¿æ§èªå°äœãããç¹å®çã«ã¯ããã
ãã·å®æ¯éŠé žã®ãšã¹ãã«åœ¢ææ§ã®åå¿èªå°äœãã
é žèªäœã䜿çšãã代ããã«äœ¿çšããããšãå¯èœã§
ããã奜ãŸããããšããããã è³éŠæããããã·ã«ã«ãã³é žã®ããããšã¹ãã«
åœ¢ææ§ã®åå¿æ§èªå°äœã¯æ¬¡ã®äžè¬åŒã§è¡šããåŸ
ãã ããç¹å®çã«ã¯ãâããããã·å®æ¯éŠé žã®ãš
ã¹ãã«åœ¢ææ§ã®åå¿æ§èªå°äœã¯æ¬¡ã®äžè¬åŒã§è¡šã
ãåŸãã åŒäžãã¯ããã²ã³åºïŒå¡©çŽ ããã³èçŽ ã奜ãŸ
ããïŒããã³âOR13åºïŒããã§R13ã¯ã¢ã«ãã«
åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã¢ã«ã
ã«åºããã³ã¢ã«ã«ãªãŒã«åºããéžæãããïŒãã
éžæããããšã¹ãã«åœ¢ææ§åå¿åºã§ããã R13ã衚ãã奜ãŸããã¢ã«ãã«åºã¯ççŽ ååã
ïŒãçŽ10å嫿ãããã®ã§ããããããã«ã¯çŽé
ã®ã¢ã«ãã«åºããã³åæã®ã¢ã«ãã«åºãå å«ãã
ããR13ã§è¡šãããã奜ãŸããã·ã¯ãã¢ã«ãã«åº
ã¯ç°ççŽ ååãïŒãçŽïŒå嫿ãããã®ã§ããã
R13ã衚ãã奜ãŸããã¢ãªãŒã«åºã¯ççŽ ååãïŒ
ã12å嫿ãããã®ã§ãããããšãã«ããããšã
ã«ããã³ãããã«ãå å«ããããR13ã§è¡šããã
ã奜ãŸããã¢ã«ã¢ã«ãã«ããã³ã¢ã«ã«ãªãŒã«åºã¯
ççŽ ååãïŒãçŽ14å嫿ãããã®ã§ããã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã®
補é ã«äœ¿çšããããžãšã¹ãã«âãžãªãŒã«åå¿äœã
çæããããã«è³éŠæããããã·ã«ã«ãã³é žãŸã
ã¯ãã®ãšã¹ãã«åœ¢ææ§ã®åå¿æ§èªå°äœãšå ±åå¿ã
ãããåŸãããæ®åºãåŒäžã®R1ãšãªãããžãª
ãŒã«ã¯æ¬¡ã®äžè¬åŒã§è¡šããåŸãã HOâR1âOH ããã§R1ã¯äžèšã«å®çŸ©ãããã®ã§ããã ãžãªãŒã«ã®å ·äœäŸã¯ ã§ããã æ®åºãåŒäžã®R2ãšãªãé眮æãã¹ããšããŒ
ã«åå¿äœã®é©åãªäŸã«ã¯æ¬¡ã®ãã®ãå å«ãããã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãã
ãã³ïŒãã¹ããšããŒã«âïŒã ãã¹ïŒïŒâããããã·ããšãã«ïŒã¡ã¿ã³ã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒã·ã¯
ããããµã³ã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãšã¿
ã³ã ïŒïŒïŒâããªãžããšããŒã«ã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãã
ãã³ã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãã³
ã¿ã³ã æ®åºãåŒäžã®R3ãšãªããã¹ããããŒã¡ãŒã
åå¿äœã¯æ¬¡ã®äžè¬åŒã§è¡šããããã ããã§ãR3ã¯äžèšå®çŸ©ã®ãã®ã§ãããã¯
åã ç¬ç«ããŠããã²ã³åºããéžæããããå¡©çŽ ã
奜ãŸããã ããããã¹ããããŒã¡ãŒãã®ããã€ãã®äŸã«ã¯
次ã®ãã®ãå å«ãããã ããã³ ããã²ã³åã«ã«ããã«ã«ãŒãããŒãåé§äœã¯å¡©
åã«ã«ããã«ãèåã«ã«ããã«ããã³ãããã®æ··
åç©ããéžæãããããã¹ã²ã³ãšãããå¡©åã«ã«
ããã«ã奜ãŸããããã²ã³åã«ã«ããã«ã«ãŒãã
ãŒãåé§äœã§ããã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã補é
ããéã«ã¯ãæåã«è³éŠæããããã·ã«ã«ãã³é ž
ãŸãã¯ãã®ãšã¹ãã«åœ¢ææ§ã®åå¿æ§èªå°äœããžãª
ãŒã«ãšåå¿ãããŠãžãšã¹ãã«âãžãªãŒã«ã圢æã
ããããç¹å®çã«ã¯ãè³éŠæããããã·ã«ã«ãã³
é žãŸãã¯ãã®ãšã¹ãã«åœ¢ææ§ã®åå¿æ§èªå°äœïŒã¢
ã«ããžãªãŒã«ïŒã¢ã«ãšåå¿ãããŠæ¬¡åŒã®ãžãšã¹ã
ã«âãžãªãŒã«ã圢æããã ããã§ãããã³R1ã¯äžèšå®çŸ©ã®ãã®ã§ããã è³éŠæããããã·ã«ã«ãã³é žãŸãã¯ãã®ãšã¹ã
ã«åœ¢ææ§ã®åå¿æ§èªå°äœãšãžãªãŒã«ãšã®åå¿ã¯ã
å®è³ªçã«ç¡æ°Žã®æ¡ä»¶äžã§å®æœãããè³éŠæããã
ãã·ã«ã«ãã³é žèªäœãŸãã¯ãã®ãšã¹ãã«èªå°äœã
ãªãã¡ãâOR13ã§ãããã®ã䜿çšããå Žåã«
ã¯ããšã¹ãã«åâãšã¹ãã«äº€æåå¿è§Šåªã®ååšäž
ã§åå¿ãè¡ãªãããã®ãããªè§Šåªã¯æ¥çã§å ¬ç¥ã§
ããããããã³é žããã³ã«ã€ã¹é žãå å«ãããã
ããã€ãã®æçšãªã«ã€ã¹é žè§Šåªãç±³åœç¹èš±ç¬¬
4045464å·ïŒåŒçšã«ããæ¬æçްæžäžã«å å«ããïŒ
ã«é瀺ãããŠãããé žããã²ã³åç©ãããªãã¡ïŒž
ãããã²ã³åºã§ãããã®ã䜿çšããå Žåã«ã¯ãé ž
ããã²ã³åç©ãšãžãªãŒã«ã®åå¿ã¯é žå容äœã®ååš
äžã§è¡ãªããšå¥œãŸããããããã®é žå容äœã¯æ¥ç
ã§åšç¥ã§ãããææ©å¡©åºããšãã°ããªãžã³ãããª
ãšãã«ã¢ãã³çããã³ç¡æ©å¡©åºããšãã°æ°Žé žåã
ããªãŠã ãæ°Žé žåã«ã«ã·ãŠã çãå å«ãããã è³éŠæããããã·ã«ã«ãã³é žãŸãã¯ãã®ãšã¹ã
ã«åœ¢ææ§ã®åå¿æ§èªå°äœãšãžãªãŒã«ãšã®åå¿äžåŒ
ã®ãžãšã¹ãã«âãžãªãŒã«çæç©ä»¥å€ã®å¯çç©ã®
çæãé¿ããŸãã¯æå°éã«æããããã«ãåŒã®
ãžãšã¹ãã«âãžãªãŒã«ãäž»çæç©ãšãªãããã«å
å¿æ¡ä»¶ããã³ïŒãŸãã¯åå¿äœãéžæãåŸããèèª
æãžãªãŒã«ã䜿çšããå Žåã«ã¯ãäž»èŠãªåå¿çæ
ç©ã¯é žãšèèªæãžãªãŒã«ãšã®åå¿çæç©ããªãã¡
ãžãšã¹ãã«âãžãªãŒã«ã§ããã®ã§ãè³éŠæããã
ãã·ã«ã«ãã³é žèªäœã®ãšã¹ãã«ãçæããããšã«
ãªãããããã·é žèªäœéã®åå¿ã¯ç¡èŠã§ããã çè«äžã¯é žãŸãã¯ãã®ãšã¹ãã«åœ¢ææ§ã®åå¿æ§
èªå°äœïŒã¢ã«ããžãªãŒã«ïŒã¢ã«ãšåå¿ããŠãžãšã¹
ãã«âãžãªãŒã«ãçæããããå®éäžã¯äžè¬ã«ãž
ãªãŒã«ïŒã¢ã«æ¯ã«ïŒã¢ã«ããå€ãã®é žã䜿çšã
ãã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã
補é ããããã«ã¯ãåŒã®ãžãšã¹ãã«âãžãªãŒ
ã«ããã¹ããšããŒã«ããã¹ããããŒã¡ãŒãããã³
ããã²ã³åã«ã«ããã«ã«ãŒãããŒãåé§äœããåŒ
ãããã³ã®ç¹°ãè¿ãæ§é åäœãããªãã³ã
ãªãšã¹ãã«âã«ãŒãããŒãæš¹èãçæããæå¹ãª
åå¿æ¡ä»¶äžã§åå¿ããããäžè¬ã«ã䜿çšãããã¹
ããããŒã¡ãŒããšããã²ã³åã«ã«ããã«ã®åèšã¢
ã«éã¯ãååšãããžãšã¹ãã«âãžãªãŒã«ãšãã¹ã
ãšããŒã«ã®åèšã¢ã«éã«å°ãªããšãçãããéåžž
ã¯å®å šãªåå¿ã確ä¿ããããã«ããã²ã³åã«ã«ã
ãã«ãéå°éã§ååšããåŸãã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã¯ã»ã°
ã¡ã³ãããªããŒã§ãã©ã³ãã ããªããŒã§ãããã
ã©ã³ãã ããªããŒãäž»ãšããŠåŸãããã«ã¯ããžãš
ã¹ãã«âãžãªãŒã«ãšãã¹ããšããŒã«ã嫿ããæ··
åç©ã«ãã¹ããããŒã¡ãŒããšããã²ã³åã«ã«ãã
ã«ãåæã«æ·»å ããã ã»ã°ã¡ã³ãããªããŒã®çæã«éããçš®ã ã®åå¿
äœã®æ·»å ããã³åå¿ã®é åºã¯äžè¬ã«çæããã»ã°
ã¡ã³ãã®ã¿ã€ãã«ãã€ãŠæ±ºãŸããããšãã°ãäžè¬
åŒïŒ ã§è¡šããããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ã
ã«âã«ãŒãããŒãã補é ããããã«ã¯ãäžè¬ã«ã
å ãçã¢ã«éã®ãžãšã¹ãã«âãžãªãŒã«ãšãã¹ãã
ããŒã¡ãŒããå ±åå¿ããããã®åŸãžãšã¹ãã«âãž
ãªãŒã«ãšãã¹ããããŒã¡ãŒãã®å ±åå¿çæç©ã«ã
ã¹ããšããŒã«ãšããã²ã³åã«ã«ããã«ãæ·»å ã
ãã äžè¬åŒïŒ ã§ç€ºãããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ãã«
âã«ãŒãããŒããåŸãããã«ã¯ããã¹ããããŒã¡
ãŒãïŒã¢ã«ããžãšã¹ãã«âãžãªãŒã«ïŒã¢ã«ãšåå¿
ããããã®åå¿çæç©ã«ãã¹ããšããŒã«ãšããã²
ã³åã«ã«ããã«ã«ãŒãããŒãåé§äœãæ·»å ããã äžè¬åŒïŒ ã§è¡šããããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ã
ã«âã«ãŒãããŒããåŸãããã«ã¯ãå ããžãšã¹ã
ã«âãžãªãŒã«ãããã²ã³åã«ã«ããã«ãšåå¿ã
ããæ¬¡ã«åŸãããåå¿çæç©ãšãã¹ããšããŒã«ã
ãã³ãã¹ããããŒã¡ãŒããšãåæã«åå¿ãããã äžè¬åŒïŒ ã§ç€ºãããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ãã«
âã«ãŒãããŒãã補é ããããã«ã¯ãäžè¬ã«ãç
ã¢ã«éã®ãã¹ããããŒã¡ãŒããšãã¹ããšããŒã«ã
åå¿ãããæ¬¡ã«ãã®åå¿çæç©ããžãšã¹ãã«âãž
ãªãŒã«ããã³ããã²ã³åã«ã«ããã«ãšåå¿ãã
ãã äžè¬åŒïŒ ã§è¡šããããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ã
ã«âã«ãŒãããŒãã補é ããããã«ã¯ããã¹ãã
ããŒã¡ãŒãïŒã¢ã«ããã¹ããšããŒã«ïŒã¢ã«ãšåå¿
ãããæ¬¡ãã§ãã®åå¿çæç©ããžãšã¹ãã«âãžãª
ãŒã«ããã³ããã²ã³åã«ã«ããã«ãšåå¿ãããã äžè¬åŒïŒ ã®ã¿ã€ãã®ã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ãã«
âã«ãŒãããŒããçæãããããã«ã¯ãå ããã¹
ããšããŒã«ãããã²ã³åã«ã«ããã«ãšå ±åå¿ã
ããæ¬¡ã«ãã®å ±åå¿çæç©ããžãšã¹ãã«âãžãªãŒ
ã«ããã³ãã¹ããããŒã¡ãŒããšåå¿ãããã äžè¬åŒïŒ ã§è¡šããããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ã
ã«âã«ãŒãããŒããåŸãããã«ã¯ããã¹ããããŒ
ã¡ãŒãïŒã¢ã«ããžãšã¹ãã«âãžãªãŒã«ïŒã¢ã«ãã
ã³ãã¹ããšããŒã«ïŒã¢ã«ãšåå¿ããããã®åå¿ç
æç©ã«ããã²ã³åã«ã«ããã«ãæ·»å ããã äžè¬åŒïŒ ã®ã¿ã€ãã®ã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ãã«
âã«ãŒãããŒããåŸãããã«ã¯ãããã²ã³åã«ã«
ããã«ããžãšã¹ãã«âãžãªãŒã«ããã³ãã¹ããšã
ãŒã«ãåæã«åå¿ãããæ¬¡ãã§ãã®åå¿çæç©ã
ãã¹ããããŒã¡ãŒããšåå¿ãããã äžè¬ã«ããã¹ããããŒã¡ãŒãããžãšã¹ãã«âãž
ãªãŒã«ããã³ãã¹ããšããŒã«ã®äœ¿çšéã¯ãå å·¥æ§
ãæ¹è¯ãããŠãããåæã«åŸæ¥ã®ã³ããªãšã¹ãã«
âã«ãŒãããŒãã®ä»ã®æå©ãªç¹æ§ã®ã»ãŒå šãŠãå®
質çãªçšåºŠã§ä¿æããŠããã³ããªãšã¹ãã«âã«ãŒ
ãããŒãæš¹èãçæããã®ã«æå¹ãªéã§ãããã
ã¹ããããŒã¡ãŒãã®å Žåãéåžžãã®éã¯ã䜿çšã
ããã¹ããããŒã¡ãŒãããžãšã¹ãã«âãžãªãŒã«ã
ãã³ãã¹ããšããŒã«ã®åèšéã«å¯ŸããçŽïŒãçŽ40
ã¢ã«ïŒ ã®ç¯å²å ã§ãããçŽïŒãçŽ30ã¢ã«ïŒ ã奜ãŸ
ããããžãšã¹ãã«âãžãªãŒã«ã®å Žåã®ãã®éã¯ã
äžè¬ã«ã䜿çšãããã¹ããããŒã¡ãŒãããžãšã¹ã
ã«âãžãªãŒã«ããã³ãã¹ããšããŒã«ã®åèšéã«å¯Ÿ
ããŠãçŽïŒãçŽ60ã¢ã«ïŒ ã®ç¯å²ã§ãããçŽïŒãçŽ
50ã¢ã«ïŒ ã®ç¯å²ã§ãããšå¥œãŸããããã¹ããšããŒ
ã«ã®éã¯éåžžãååšãããã¹ããããŒã¡ãŒãããž
ãšã¹ãã«âãžãªãŒã«ããã³ãã¹ããšããŒã«ã®åèš
éã«å¯ŸããŠãçŽ20ãçŽ98ã¢ã«ïŒ ã®ç¯å²ã§ãããçŽ
30ãçŽ90ã¢ã«ïŒ ã奜ãŸããã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èäž
ã«ååšããåŒãããã³ã®ç¹°ãè¿ãæ§é åäœ
ã®éã¯ã䜿çšãããžãšã¹ãã«âãžãªãŒã«ããã¹ã
ãããŒã¡ãŒãããã³ãã¹ããšããŒã«ã®çš®ã ã®éã«
äŸåãããããªãã¡ãããšãã°äœ¿çšãããžãšã¹ã
ã«âãžãªãŒã«ã®éãå€ãããã°ãã³ããªãšã¹ãã«
âã«ãŒãããŒãæš¹èäžã«ååšããåŒã®ç¹°ãè¿ã
æ§é åäœã®éã¯ããã ãå€ããªãã ãžãšã¹ãã«âãžãªãŒã«ããã¹ããšããŒã«ããã¹
ããããŒã¡ãŒãããã³ããã²ã³åã«ã«ããã«ããš
ãã°ãã¹ã²ã³ããæ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒ
ãããŒãã補é ããïŒã€ã®æ¹æ³ã«ã¯äžå質çé¢é
åæ³ãå«ãŸããããã®ãããªçé¢éåæ³ã¯ç±³åœç¹
蚱第3169121å·ïŒåŒçšã«ããæ¬æçްæžäžã«å å«ã
ãïŒã«èšèŒãããŠãããäžè¬ã«çé¢éåæ³ã§ã¯å
å¿äœçšã«ïŒçš®ã®äºãã«æ··åããªã溶åªç³»ã䜿çšã
ãããããã®æº¶åªç³»ã®ïŒæ¹ã¯æ°Žæ§æº¶åªç³»ã§ããã
仿¹ã¯æ°Žã«æ··åããªãææ©æº¶åªç³»ããšãã°ã¡ãã¬
ã³ã¯ãã©ã€ãã§ããããã¹ã²ã³ããã³ïŒãŸãã¯ã
ã¹ããããŒã¡ãŒããæ·»å ããéã«ã¯ãPHãå¡©åºæ§
ç¯å²ã«ä¿ã€ããã«æ°Žæ§ã¢ã«ã«ãªæº¶æ¶²ãçšããŠå¡©åº
æ§æ¡ä»¶äžã§è¡ãªããåå¿æ··åç©äžã«ã¯è§Šåªãšåå
é調ç¯å€ãååšããã 䜿çšãåŸãè§Šåªã¯ãã³ããªãšã¹ãã«âã«ãŒãã
ãŒãçæåå¿ãéãããããªãã¡ä¿é²ããåšç¥ã®
è§Šåªã®ãããã§ããããé©åœãªéåè§Šåªã«ã¯ã第
äžçŽã¢ãã³é¡ããšãã°ããªãšãã«ã¢ãã³ã第åçŽ
ã¢ã³ã¢ããŠã ååç©ããã³ç¬¬åçŽãã¹ãããŠã å
åç©ãå å«ããããããããã«éå®ãããããšã¯
ãªãã 䜿çšãããååé調ç¯å€ã¯ãé£éåæ¢æ©æ§ã«ã
ã€ãŠã³ããªãšã¹ãã«âã«ãŒãããŒãã®ååéã調
ç¯ããåšç¥ã®ååç©ã®ãããã§ãããããããã®
ååç©ã«ã¯ããšããŒã«ãtertâããã«ããšããŒ
ã«ãã¯ããã³âçãå å«ãããã çé¢éååå¿ã«ãã€ãŠã³ããªãšã¹ãã«âã«ãŒã
ããŒãçæåå¿ãé²è¡ããæž©åºŠã¯ïŒâ以äžãã
100â以äžã«äºã€ãŠå€åãåŸããåå¿ã¯ã宀枩
ïŒ25âïŒãçŽ50âã®æž©åºŠã§æºè¶³ã«é²è¡ããã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã¯ãé
åžžçŽ10000ãçŽ150000ã®ç¯å²ã®ééå¹³åååéã
æããçŽ15000ãçŽ100000ã®ç¯å²ã§ãããšå¥œãŸã
ãã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã«ã¯å ¬
ç¥ã®é垞䜿çšãããæ·»å å€ã®ãããã®ãé©åœã«æ··
åããŠããããããšãã°ãäžæŽ»æ§å å¡«æããšãã°
ã¬ã©ã¹ãã¿ã«ã¯ã鲿¯ããã³ç²åãè¡ææ¹è³ªå€ã
玫å€ç·åžåå€ããšãã°ãã³ãŸããšãã³é¡ããã³ãŸ
ããªã¢ãŸãŒã«é¡ããã³ã·ã¢ãã¢ã¯ãªã¬ãŒãé¡ãå
æ°Žåè§£å®å®å€ããšãã°ç±³åœç¹èš±ç¬¬3489716å·ã第
4138379å·ããã³ç¬¬3839247å·ïŒãããå šãŠãåŒçš
ã«ããæ¬æçްæžäžã«å å«ããïŒã«é瀺ãããŠãã
ãšããã·ãé¡ãè²å®å®å€ããšãã°ãªã«ã¬ããã¹ã
ã¢ã€ãé¡ããªãã³ã«é£çå€ãããã ããã€ãã®ç¹ã«æçšãªé£çå€ã¯ã¹ã«ãã³é žã®ã¢
ã«ã«ãªéå±å¡©ããã³ã¢ã«ã«ãªåé¡éå±å¡©ã§ããã
ãããã®ã¿ã€ãã®é£çå€ã¯ç±³åœç¹èš±ç¬¬3933734å·ã
第3948851å·ã第3926908å·ã第3919167å·ã第
3909490å·ã第3953396å·ã第3931100å·ã第
3978025å·ã第3953399å·ã第3917599å·ã第
3951910å·ããã³ç¬¬3940366å·ïŒãããå šãŠãåŒçš
ã«ããæ¬æçްæžäžã«å å«ããïŒã«é瀺ãããŠã
ãã 奜ãŸããå ·äœäŸã®èª¬æ æ¬çºæãããè©³çŽ°ã«æçã«èª¬æããããã«ä»¥äž
ã«å®æœäŸãæããããããã®å®æœäŸã¯ãæ¬æçŽ°æž
äžã«èšèŒããã€ç¹èš±è«æ±ã®ç¯å²ã«æèšããæ¬çºæ
ãéå®ããããšãªãæ¬çºæãäŸç€ºãããã®ãšèã
ããããã以äžã®å®æœäŸäžã§ä»ã«ç¹èšããªãéã
éšããã³ïŒ ã¯å šãŠééåºæºã§ããã æ¬¡ã®ããã€ãã®å®æœäŸã¯æ¬çºæã®ãžãšã¹ãã«â
ãžãªãŒã«ã®è£œé ãäŸç€ºããã 宿œäŸ ïŒ æ¬å®æœäŸã§ã¯ïŒïŒ10âãã«ã¡ãã¬ã³âãã¹ïŒïŒ
âããããã·ãã³ãŸãšãŒãïŒã®è£œé äŸã瀺ãã ïœâããããã·å®æ¯éŠé žã¡ãã«76.1gïŒ0.5ã¢
ã«ïŒãïŒïŒ10âãã«ã³ãžãªãŒã«43.6gïŒ0.25ã¢ã«ïŒ
ããã³é žåãžããã«ã¹ãº0.3gãå åã«æ¹æããæ··
åç©ãããšã¹ãã«äº€æåå¿ã§åŸã ã«éé¢ããŠãã
ã¡ãã«ã¢ã«ã³ãŒã«ã倧æ°å§äžã§èžçããããã®èž
çããããšéæµå·åŽåšãåããåå¿ãã©ã¹ã³äž
ã§ãçŽïŒæé190ã200âã«å ç±ãããã¢ã«ã³ãŒã«
ã®éæµãçµã€ããæ°Žæµãã³ãã§æžå§ã«ããŠåŸ®éã®
ã¢ã«ã³ãŒã«ãé€å»ãããéé102.6gïŒåç99.0ïŒ ïŒ
ã®ãžãšã¹ãã«âãžãªãŒã«ãæ®æž£ãšããŠåŸãããã
ã¡ã¿ããŒã«ïŒæ°Žã§åçµæ¶ãããšèç¹154ã155âã®
çœè²çµæ¶ãåŸãããã 宿œäŸ ïŒ æ¬å®æœäŸã¯ïŒïŒïŒâããã©ã¡ãã¬ã³âãã¹ïŒïŒ
âããããã·ãã³ãŸãšãŒãïŒã®è£œé äŸã瀺ãã ïœâããããã·å®æ¯éŠé žã¡ãã«76.1gïŒ0.5ã¢
ã«ïŒãïŒïŒïŒâãã¿ã³ãžãªãŒã«22.5gïŒ0.25ã¢ã«ïŒ
ããã³ãã¿ã³é žããã©ãªã¯ãã«0.51gãå åã«æ¹
æããæ··åç©ãããšã¹ãã«äº€æåå¿ã§åŸã ã«éé¢
ããã¡ã¿ããŒã«ã倧æ°å§äžã§èžçããããã®èžç
ããããšéæµå·åŽåšãåããåå¿ãã©ã¹ã³äžã§çŽ
ïŒæé170âã«å ç±ãããã¢ã«ã³ãŒã«ã®éæµçµäº
åŸãæ°Žæµãã³ãã§æžå§ã«ããŠæ®åãã埮éã®ã¢ã«
ã³ãŒã«ãé€å»ãããã¡ã¿ããŒã«ïŒæ°Žã§åçµæ¶ãã
ãšèç¹ã182.5ã184âã®çµæ¶ãåŸãããã 宿œäŸ ïŒ ïŒïŒ10âãã«ã³ãžãªãŒã«43.6gã®ä»£ããã«ïŒïŒ
ïŒâãžã¡ãã«âïŒïŒïŒâãããã³ãžãªãŒã«0.25ã¢
ã«ã䜿çšãã以å€ã¯ã»ãŒå®æœäŸïŒã®æé ãç¹°ãè¿
ããåŸããããžãšã¹ãã«âãžãªãŒã«ã®çµæ¶ã®èç¹
ã¯156ã159âã§ããã 宿œäŸ ïŒ ïŒïŒ10âãã«ã³ãžãªãŒã«ã®ä»£ããã«ïŒâããã
ãã·ãšãã«ãšãŒãã«0.25ã¢ã«ã䜿çšããŠã»ãŒå®æœ
äŸïŒã®æé ãç¹°ãè¿ããåŸããããžãšã¹ãã«âãž
ãªãŒã«ã®çµæ¶ã¯119ã121âã®èç¹ãæããã 宿œäŸ ïŒ ïŒïŒ10âãã«ã³ãžãªãŒã«ã®ä»£ããã«ïŒïŒïŒâã·
ã¯ããããµã³ãžã¡ã¿ããŒã«ã®ã·ã¹ïŒãã©ã³ã¹æ··å
ç©ã0.25ã¢ã«ã䜿çšãã以å€ã¯ã»ãŒå®æœäŸïŒã®æ
é ãç¹°ãè¿ãã æ¬¡ã®å®æœäŸã¯ãæ¬çºæã®ç¯å²ããå€ããåŸæ¥ã®
ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã®è£œé äŸã瀺
ãããããã¯æ¯èŒã®ããã ãã®ãã®ã§ããã 宿œäŸ ïŒ è±ã€ãªã³æ°Ž10ãã¡ãã¬ã³ã¯ãã©ã€ã16ãã
ã¹ããšããŒã«âA1.910gïŒ8.36ã¢ã«ïŒãããªãšãã«
ã¢ãã³24mlãã°ã«ã³ã³é žãããªãŠã 3.4gããã³ïœ
âtertâããã«ããšããŒã«65gãæ©æ¢°çæ¹æåšã
åããåå¿å®¹åšã«å ¥ããããã®åå¿æ··åç©ãæ¹æ
ããæ¹æããåå¿æ··åç©ã«ããã¬ãã¿ãã€ã«ãžã¯
ãã©ã€ã926gãšã€ãœãã¿ãã€ã«ãžã¯ãã©ã€ã
163gãåºäœå25ééïŒ ã®ã¡ãã¬ã³ã¯ãã©ã€ã溶
æ¶²ãšããŠ15åéã«äºã€ãŠå ãããé žå¡©åç©ã®æ·»å
äžã25ïŒ æ°Žé žåãããªãŠã 氎溶液ãå ããŠPHã
8.5ã11.5ã®ç¯å²å ã«ä¿ã€ãåŸãããæ··åç©ã«æ¯
å36gã®é床ã§15åéãã¹ã²ã³ãå°å ¥ããããã®
éPHã¯æ°Žé žåãããªãŠã æ°Žæº¶æ¶²ãæ·»å ããŠ9.5ã
12ã«èª¿æŽããããã¹ã²ã³åçµäºåŸãã¡ãã¬ã³ã¯ã
ã©ã€ãïŒãå ããé å¿ã«ãããã©ã€ã³å±€ãåé¢
ããæš¹è溶液ãé žæ°Žæº¶æ¶²ã§ïŒåãæ°Žã§ïŒåæŽæµã
ããæš¹èãèžæ°ã§æ²æ®¿ãããçªçŽ æµååºä¹Ÿç¥åšäž
çŽ240âã§ä¹Ÿç¥ããã ãã®æš¹èã®ã«ã·ã€ã€ã³ããã¯ã¹ïŒKIïŒã枬å®
ããçµæãåŸæ²ã®è¡šã«ç€ºãã ã«ã·ã€ã€ã³ããã¯ã¹ïŒKIïŒã¯æš¹èã®å å·¥æ§ã®
ææšãŸãã¯å°ºåºŠã§ãããKIãäœãã»ã©æš¹èã®ã¡
ã«ããããŒã€ã³ããã¯ã¹ã倧ãããªããããã€ãŠ
å å·¥æ§ãè¯ããªããåºæ¬çã«ã«ã·ã€ã€ã³ããã¯ã¹
ã¯æš¹èã®æº¶èç²åºŠã®å°ºåºŠã§ãããã«ã·ã€ã€ã³ãã
ã¯ã¹ã®æž¬å®æ³ã¯ä»¥äžã®ãšããã§ããã125âã§æ
äœ90å也ç¥ããæš¹èãã¬ãã7gãæ¹è¯ã¿ã€ããŠ
ã¹ãŒãªã«ãŒã³ïŒTiniusâOlsenïŒT3åã¡ã«ãã€ã³
ããã¯ã¹æž¬å®åšã«æ·»å ããæž¬å®åšã®æž©åºŠã300â
ã«ä¿ã¡ãæš¹èãïŒåéãã®æž©åºŠã«å ç±ãããïŒå
åŸãååŸ0.1865ã€ã³ãã®ãã©ã³ãžã€ãŒãçšããŠå§
å17.7ãã³ãã§ååŸ0.04125ã€ã³ãã®ãªãªãã€ã¹
ãéããŠæš¹èãæŒãåºãããã©ã³ãžã€ãŒãïŒã€ã³
ãåããã®ã«èŠããæéãæž¬å®ããKIãšããŠçŸ
åã®äžç§åäœã§è¡šãããKIã倧ãããªãã°ãªã
ã»ã©æº¶èç²åºŠãé«ããªãæš¹èã®ç²æ§ãå¢ããå å·¥
æ§ãæªããªãã æ¬¡ã®å®æœäŸã¯æ¬çºæã®ç¯å²ããå€ããåŸæ¥ã®ã
ãªã«ãŒãããŒãæš¹èã®è£œé ãäŸç€ºããããã®å®æœ
äŸã¯æ¯èŒã®ããã ãã®ãã®ã§ããã 宿œäŸ ïŒ ãã¹ããšããŒã«âA57.1gïŒ0.25ã¢ã«ïŒãæ°Ž300mlã
ã¡ãã¬ã³ã¯ãã©ã€ã400mlãããšããŒã«0.6gãã
ã³ããªãšãã«ã¢ãã³0.56gã®æ··åç©äžã«ããã¹ã²
ã³31.0gã31åéãããŠåšå²æž©åºŠã§å ããããã®
éã25ïŒ æ°Žé žåãããªãŠã 氎溶液ãåæã«æ·»å ã
ãŠïŒçžç³»ã®PHãçŽ11ã«ç¶æããããã¹ã²ã³æ·»å æ
éçµäºæã«ã¯ãæ°Žæ§çžã®PHã¯11.7ã§ããããã®çž
ã®ãã¹ããšããŒã«âïŒ¡å«æçã¯çŽ«å€ç·åæã«ãã
ãš1ppmæªæºã§ããã ã¡ãã¬ã³ã¯ãã©ã€ãçžãæ°Žçžããåé¢ããéå°
ã®åžå¡©é žïŒ0.01NïŒæ°Žæº¶æ¶²ã§æŽæµããæ¬¡ãã§è±ã€
ãªã³æ°Žã§ïŒåæŽæµãããããªããŒãã¡ã¿ããŒã«ã§
æ²æŸ±ããã80âã§ä¹Ÿç¥ããã ãã®ããªã«ãŒãããŒãæš¹èã®KIãæž¬å®ããçµ
æãåŸæ²ã®è¡šã«ç€ºãã æ¬¡ã®å®æœäŸã¯æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒã
ããŒãæš¹èã®è£œé ãäŸç€ºããã 宿œäŸ ïŒ ãã¹ããšããŒã«âA54.2gïŒ0.2375ã¢ã«ïŒãããšã
ãŒã«0.5gãããªãšãã«ã¢ãã³0.5gãã¡ãã¬ã³ã¯ã
ã©ã€ã400mlããã³æ°Ž300mlã®ã¹ã©ãªãŒäžã«ã25ïŒ
æ°Žé žåãããªãŠã 氎溶液ãå åéå ããŠPHã10.5
ã«ããããã®åå¿æ··åç©ã«ïŒïŒïŒâãã¿ã³ãžãªãŒ
ã«ãã¹ã¯ããããŒã¡ãŒã10.75gïŒ0.05ã¢ã«ïŒãã¡
ãã¬ã³ã¯ãã©ã€ã50mlã«æº¶è§£ããæº¶æ¶²ã10åéã§
滎äžããŠå ããããã®éãPHã10.5ãš11ã®éã«ä¿
ã€ã次ãã§ïŒåéæ¹æãããæ¬¡ã«ã宿œäŸïŒã®æ
é ã«åŸã€ãŠè£œé ãããžãšã¹ãã«ãŒãžãªãŒã«ã4.8g
ïŒ0.0125ã¢ã«ïŒå ããåŸãæ°Žé žåãããªãŠã 氎溶
æ¶²ãå ããŠPHã11ä»è¿ã«ä¿ã¡ãªããæ¯å1gã®å²
åã§ãã¹ã²ã³ã26åéå ããããã®ãã¹ã²ã³åçµ
äºæã«ã玫å€ç·åæã«ãããšåå¿æ··åç©ã¯23ppm
ã®ãã¹ããšããŒã«âã嫿ããã ã¡ãã¬ã³ã¯ãã©ã€ãçžãæ°Žçžããåé¢ããéå°
ã®åžå¡©é žïŒ0.01NïŒæ°Žæº¶æ¶²ã§æŽæµããæ¬¡ã«è±ã€ãª
ã³æ°Žã§ïŒåæŽæµãããããªããŒãã¡ã¿ããŒã«ã§æ²
柱ããã也ç¥ããã åŸãããããªããŒã®åºæç²åºŠïŒIVïŒã¯25âã®
ã¡ãã¬ã³ã¯ãã©ã€ãäžã§0.606d1ïŒïœã§ãããïŒ
次ã¬ã©ã¹è»¢ç§»æž©åºŠïŒTgïŒã¯122âã§ããã ãã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã®KIãæž¬
å®ããçµæã衚ã«ç€ºãã 衚 宿œäŸ KI ïŒ 42630 ïŒ 9220 ïŒ 425 衚ã®ããŒã¿ã瀺ããŠããããã«ãæ¬çºæã®ã³
ããªãšã¹ãã«âã«ãŒãããŒãã¯åŸæ¥ã®ã³ããªãšã¹
ãã«âã«ãŒãããŒãããäœãKIã瀺ããæŽã«ã
æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã¯ãåŸæ¥
ã®ã³ããªãšã¹ãã«âã«ãŒãããŒãããäœãKIã
瀺ãã ãã§ãªããåŸæ¥ã®ããªã«ãŒãããŒãããã
äœãKIã瀺ããããªãã¡ãæ¬çºæã®ã³ããªãšã¹
ãã«âã«ãŒãããŒãã¯ãåŸæ¥ã®ã³ããªãšã¹ãã«â
ã«ãŒãããŒãã«æ¯èŒããŠå å·¥æ§ãæ¹è¯ãããŠãã
ã ãã§ãªããåŸæ¥ã®ããªã«ãŒãããŒããããè¯å¥œ
ãªå å·¥æ§ã瀺ããäžè¬ã«ããªã«ãŒãããŒãã¯ã³ã
ãªãšã¹ãã«âã«ãŒãããŒããããå å·¥ããããã®
ã§ãããããæ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãã
ãŒããããªã«ãŒãããŒãã«å¯ŸããŠæ¹è¯ãããå å·¥
æ§ã瀺ãããšã¯éåžžã®ããšã§ã¯ãªãäºæž¬ãããªã
ã€ãããšã§ããã æããã«ãäžè¿°ã®æç€ºã«ç §ãããæ¬çºæã®ä»ã®
ä¿®æ£ããã³å€åœ¢ãå¯èœã§ããããããã€ãŠãäžè¿°
ããæ¬çºæã®ç¹å®å ·äœäŸã«ãããŠãç¹èš±è«æ±ã®ç¯
å²ã«å®çŸ©ããæ¬çºæã®å åã«æå³ãããç¯å²å ã«
ãããŠå€åããªãåŸããšçè§£ããããã
ããšãããã€ããšã«ãŒãããŒãåºã®å°ãªããšãã
ãã€ãã¯è³éŠæççŽ ç°åŒåºã®ç°ççŽ ååã«çŽæ¥çµ
åããŠããã å ·äœçã«ã¯ãæ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒã
ããŒãæš¹èã¯æ¬¡ã®äžè¬åŒã§è¡šããããç¹°ãè¿ãæ§
é åäœãããªãã äžèšåŒäžããR1ãR2ããã³R3ã¯åèšå®çŸ©ã®
ãšããã§ããã R1ã®å ·äœäŸã¯ ã§ããã R2ã®åŒäžã®ïŒ·ã®äºäŸ¡ã®çåæ°ŽçŽ åºã¯ã¢ã«ãã¬
ã³åºãã·ã¯ãã¢ã«ãã¬ã³åºãã¢ã«ããªãã³åºãã
ã³ã·ã¯ãã¢ã«ããªãã³åºããéžæããã奜ãŸãã
ã¢ã«ãã¬ã³åºã¯ççŽ ååãïŒãçŽ10å嫿ããã
ã®ã§ããã奜ãŸããã¢ã«ããªãã³åºã¯ççŽ ååã
ïŒãçŽ10å嫿ãããã®ã§ããã奜ãŸããã·ã¯ã
ã¢ã«ãã¬ã³ããã³ã·ã¯ãã¢ã«ããªãã³åºã¯ç°ççŽ
ååãïŒãçŽïŒå嫿ãããã®ã§ããã é眮æãã¹ããšããŒã«æ®åºã§å¥œãŸããã®ã¯ã
ãã¢ã«ãã¬ã³ãã¢ã«ããªãã³ãã·ã¯ãã¢ã«ãã¬ã³
ããã³ã·ã¯ãã¢ã«ããªãã³åºããéžæããããã®
ã§ããã R3ã¯å¥œãŸããã¯ççŽ ååãïŒãçŽ20å嫿ã
ãã¢ã«ãã¬ã³åºã§ãããã¢ã«ãã¬ã³åºã¯çŽéã®ã¢
ã«ãã¬ã³åºã§ãåæã®ã¢ã«ãã¬ã³åºã§ãããã åŸãããæ®åºãåŒäžã®ïŒ²ãšãªãããžãšã¹ãã«
âãžãªãŒã«ã®è£œé ã«çšããããå ±åå¿äœã®ïŒã€ã§
ããè³éŠæããããã·ã«ã«ãã³é žåå¿äœã¯ã次ã®
äžè¬åŒã§è¡šããåŸãã HOââCOOH ããã§ïŒ²ã¯äžã§å®çŸ©ãããšããã§ãããããç¹
å®çã«ãããšãè³éŠæããããã·ã«ã«ãã³é žã¯æ¬¡
ã®åŒã§è¡šããããâããããã·å®æ¯éŠé žã§ã
ãã æ¬çºæã®ãžãšã¹ãã«âãžãªãŒã«ã®è£œé ã«ãã
ãŠãäžèšã®è³éŠæããããã·ã«ã«ãã³é žã®ãšã¹ã
ã«åœ¢ææ§ã®åå¿æ§èªå°äœãããç¹å®çã«ã¯ããã
ãã·å®æ¯éŠé žã®ãšã¹ãã«åœ¢ææ§ã®åå¿èªå°äœãã
é žèªäœã䜿çšãã代ããã«äœ¿çšããããšãå¯èœã§
ããã奜ãŸããããšããããã è³éŠæããããã·ã«ã«ãã³é žã®ããããšã¹ãã«
åœ¢ææ§ã®åå¿æ§èªå°äœã¯æ¬¡ã®äžè¬åŒã§è¡šããåŸ
ãã ããç¹å®çã«ã¯ãâããããã·å®æ¯éŠé žã®ãš
ã¹ãã«åœ¢ææ§ã®åå¿æ§èªå°äœã¯æ¬¡ã®äžè¬åŒã§è¡šã
ãåŸãã åŒäžãã¯ããã²ã³åºïŒå¡©çŽ ããã³èçŽ ã奜ãŸ
ããïŒããã³âOR13åºïŒããã§R13ã¯ã¢ã«ãã«
åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã¢ã«ã
ã«åºããã³ã¢ã«ã«ãªãŒã«åºããéžæãããïŒãã
éžæããããšã¹ãã«åœ¢ææ§åå¿åºã§ããã R13ã衚ãã奜ãŸããã¢ã«ãã«åºã¯ççŽ ååã
ïŒãçŽ10å嫿ãããã®ã§ããããããã«ã¯çŽé
ã®ã¢ã«ãã«åºããã³åæã®ã¢ã«ãã«åºãå å«ãã
ããR13ã§è¡šãããã奜ãŸããã·ã¯ãã¢ã«ãã«åº
ã¯ç°ççŽ ååãïŒãçŽïŒå嫿ãããã®ã§ããã
R13ã衚ãã奜ãŸããã¢ãªãŒã«åºã¯ççŽ ååãïŒ
ã12å嫿ãããã®ã§ãããããšãã«ããããšã
ã«ããã³ãããã«ãå å«ããããR13ã§è¡šããã
ã奜ãŸããã¢ã«ã¢ã«ãã«ããã³ã¢ã«ã«ãªãŒã«åºã¯
ççŽ ååãïŒãçŽ14å嫿ãããã®ã§ããã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã®
補é ã«äœ¿çšããããžãšã¹ãã«âãžãªãŒã«åå¿äœã
çæããããã«è³éŠæããããã·ã«ã«ãã³é žãŸã
ã¯ãã®ãšã¹ãã«åœ¢ææ§ã®åå¿æ§èªå°äœãšå ±åå¿ã
ãããåŸãããæ®åºãåŒäžã®R1ãšãªãããžãª
ãŒã«ã¯æ¬¡ã®äžè¬åŒã§è¡šããåŸãã HOâR1âOH ããã§R1ã¯äžèšã«å®çŸ©ãããã®ã§ããã ãžãªãŒã«ã®å ·äœäŸã¯ ã§ããã æ®åºãåŒäžã®R2ãšãªãé眮æãã¹ããšããŒ
ã«åå¿äœã®é©åãªäŸã«ã¯æ¬¡ã®ãã®ãå å«ãããã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãã
ãã³ïŒãã¹ããšããŒã«âïŒã ãã¹ïŒïŒâããããã·ããšãã«ïŒã¡ã¿ã³ã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒã·ã¯
ããããµã³ã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãšã¿
ã³ã ïŒïŒïŒâããªãžããšããŒã«ã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãã
ãã³ã ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒãã³
ã¿ã³ã æ®åºãåŒäžã®R3ãšãªããã¹ããããŒã¡ãŒã
åå¿äœã¯æ¬¡ã®äžè¬åŒã§è¡šããããã ããã§ãR3ã¯äžèšå®çŸ©ã®ãã®ã§ãããã¯
åã ç¬ç«ããŠããã²ã³åºããéžæããããå¡©çŽ ã
奜ãŸããã ããããã¹ããããŒã¡ãŒãã®ããã€ãã®äŸã«ã¯
次ã®ãã®ãå å«ãããã ããã³ ããã²ã³åã«ã«ããã«ã«ãŒãããŒãåé§äœã¯å¡©
åã«ã«ããã«ãèåã«ã«ããã«ããã³ãããã®æ··
åç©ããéžæãããããã¹ã²ã³ãšãããå¡©åã«ã«
ããã«ã奜ãŸããããã²ã³åã«ã«ããã«ã«ãŒãã
ãŒãåé§äœã§ããã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã補é
ããéã«ã¯ãæåã«è³éŠæããããã·ã«ã«ãã³é ž
ãŸãã¯ãã®ãšã¹ãã«åœ¢ææ§ã®åå¿æ§èªå°äœããžãª
ãŒã«ãšåå¿ãããŠãžãšã¹ãã«âãžãªãŒã«ã圢æã
ããããç¹å®çã«ã¯ãè³éŠæããããã·ã«ã«ãã³
é žãŸãã¯ãã®ãšã¹ãã«åœ¢ææ§ã®åå¿æ§èªå°äœïŒã¢
ã«ããžãªãŒã«ïŒã¢ã«ãšåå¿ãããŠæ¬¡åŒã®ãžãšã¹ã
ã«âãžãªãŒã«ã圢æããã ããã§ãããã³R1ã¯äžèšå®çŸ©ã®ãã®ã§ããã è³éŠæããããã·ã«ã«ãã³é žãŸãã¯ãã®ãšã¹ã
ã«åœ¢ææ§ã®åå¿æ§èªå°äœãšãžãªãŒã«ãšã®åå¿ã¯ã
å®è³ªçã«ç¡æ°Žã®æ¡ä»¶äžã§å®æœãããè³éŠæããã
ãã·ã«ã«ãã³é žèªäœãŸãã¯ãã®ãšã¹ãã«èªå°äœã
ãªãã¡ãâOR13ã§ãããã®ã䜿çšããå Žåã«
ã¯ããšã¹ãã«åâãšã¹ãã«äº€æåå¿è§Šåªã®ååšäž
ã§åå¿ãè¡ãªãããã®ãããªè§Šåªã¯æ¥çã§å ¬ç¥ã§
ããããããã³é žããã³ã«ã€ã¹é žãå å«ãããã
ããã€ãã®æçšãªã«ã€ã¹é žè§Šåªãç±³åœç¹èš±ç¬¬
4045464å·ïŒåŒçšã«ããæ¬æçްæžäžã«å å«ããïŒ
ã«é瀺ãããŠãããé žããã²ã³åç©ãããªãã¡ïŒž
ãããã²ã³åºã§ãããã®ã䜿çšããå Žåã«ã¯ãé ž
ããã²ã³åç©ãšãžãªãŒã«ã®åå¿ã¯é žå容äœã®ååš
äžã§è¡ãªããšå¥œãŸããããããã®é žå容äœã¯æ¥ç
ã§åšç¥ã§ãããææ©å¡©åºããšãã°ããªãžã³ãããª
ãšãã«ã¢ãã³çããã³ç¡æ©å¡©åºããšãã°æ°Žé žåã
ããªãŠã ãæ°Žé žåã«ã«ã·ãŠã çãå å«ãããã è³éŠæããããã·ã«ã«ãã³é žãŸãã¯ãã®ãšã¹ã
ã«åœ¢ææ§ã®åå¿æ§èªå°äœãšãžãªãŒã«ãšã®åå¿äžåŒ
ã®ãžãšã¹ãã«âãžãªãŒã«çæç©ä»¥å€ã®å¯çç©ã®
çæãé¿ããŸãã¯æå°éã«æããããã«ãåŒã®
ãžãšã¹ãã«âãžãªãŒã«ãäž»çæç©ãšãªãããã«å
å¿æ¡ä»¶ããã³ïŒãŸãã¯åå¿äœãéžæãåŸããèèª
æãžãªãŒã«ã䜿çšããå Žåã«ã¯ãäž»èŠãªåå¿çæ
ç©ã¯é žãšèèªæãžãªãŒã«ãšã®åå¿çæç©ããªãã¡
ãžãšã¹ãã«âãžãªãŒã«ã§ããã®ã§ãè³éŠæããã
ãã·ã«ã«ãã³é žèªäœã®ãšã¹ãã«ãçæããããšã«
ãªãããããã·é žèªäœéã®åå¿ã¯ç¡èŠã§ããã çè«äžã¯é žãŸãã¯ãã®ãšã¹ãã«åœ¢ææ§ã®åå¿æ§
èªå°äœïŒã¢ã«ããžãªãŒã«ïŒã¢ã«ãšåå¿ããŠãžãšã¹
ãã«âãžãªãŒã«ãçæããããå®éäžã¯äžè¬ã«ãž
ãªãŒã«ïŒã¢ã«æ¯ã«ïŒã¢ã«ããå€ãã®é žã䜿çšã
ãã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã
補é ããããã«ã¯ãåŒã®ãžãšã¹ãã«âãžãªãŒ
ã«ããã¹ããšããŒã«ããã¹ããããŒã¡ãŒãããã³
ããã²ã³åã«ã«ããã«ã«ãŒãããŒãåé§äœããåŒ
ãããã³ã®ç¹°ãè¿ãæ§é åäœãããªãã³ã
ãªãšã¹ãã«âã«ãŒãããŒãæš¹èãçæããæå¹ãª
åå¿æ¡ä»¶äžã§åå¿ããããäžè¬ã«ã䜿çšãããã¹
ããããŒã¡ãŒããšããã²ã³åã«ã«ããã«ã®åèšã¢
ã«éã¯ãååšãããžãšã¹ãã«âãžãªãŒã«ãšãã¹ã
ãšããŒã«ã®åèšã¢ã«éã«å°ãªããšãçãããéåžž
ã¯å®å šãªåå¿ã確ä¿ããããã«ããã²ã³åã«ã«ã
ãã«ãéå°éã§ååšããåŸãã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã¯ã»ã°
ã¡ã³ãããªããŒã§ãã©ã³ãã ããªããŒã§ãããã
ã©ã³ãã ããªããŒãäž»ãšããŠåŸãããã«ã¯ããžãš
ã¹ãã«âãžãªãŒã«ãšãã¹ããšããŒã«ã嫿ããæ··
åç©ã«ãã¹ããããŒã¡ãŒããšããã²ã³åã«ã«ãã
ã«ãåæã«æ·»å ããã ã»ã°ã¡ã³ãããªããŒã®çæã«éããçš®ã ã®åå¿
äœã®æ·»å ããã³åå¿ã®é åºã¯äžè¬ã«çæããã»ã°
ã¡ã³ãã®ã¿ã€ãã«ãã€ãŠæ±ºãŸããããšãã°ãäžè¬
åŒïŒ ã§è¡šããããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ã
ã«âã«ãŒãããŒãã補é ããããã«ã¯ãäžè¬ã«ã
å ãçã¢ã«éã®ãžãšã¹ãã«âãžãªãŒã«ãšãã¹ãã
ããŒã¡ãŒããå ±åå¿ããããã®åŸãžãšã¹ãã«âãž
ãªãŒã«ãšãã¹ããããŒã¡ãŒãã®å ±åå¿çæç©ã«ã
ã¹ããšããŒã«ãšããã²ã³åã«ã«ããã«ãæ·»å ã
ãã äžè¬åŒïŒ ã§ç€ºãããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ãã«
âã«ãŒãããŒããåŸãããã«ã¯ããã¹ããããŒã¡
ãŒãïŒã¢ã«ããžãšã¹ãã«âãžãªãŒã«ïŒã¢ã«ãšåå¿
ããããã®åå¿çæç©ã«ãã¹ããšããŒã«ãšããã²
ã³åã«ã«ããã«ã«ãŒãããŒãåé§äœãæ·»å ããã äžè¬åŒïŒ ã§è¡šããããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ã
ã«âã«ãŒãããŒããåŸãããã«ã¯ãå ããžãšã¹ã
ã«âãžãªãŒã«ãããã²ã³åã«ã«ããã«ãšåå¿ã
ããæ¬¡ã«åŸãããåå¿çæç©ãšãã¹ããšããŒã«ã
ãã³ãã¹ããããŒã¡ãŒããšãåæã«åå¿ãããã äžè¬åŒïŒ ã§ç€ºãããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ãã«
âã«ãŒãããŒãã補é ããããã«ã¯ãäžè¬ã«ãç
ã¢ã«éã®ãã¹ããããŒã¡ãŒããšãã¹ããšããŒã«ã
åå¿ãããæ¬¡ã«ãã®åå¿çæç©ããžãšã¹ãã«âãž
ãªãŒã«ããã³ããã²ã³åã«ã«ããã«ãšåå¿ãã
ãã äžè¬åŒïŒ ã§è¡šããããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ã
ã«âã«ãŒãããŒãã補é ããããã«ã¯ããã¹ãã
ããŒã¡ãŒãïŒã¢ã«ããã¹ããšããŒã«ïŒã¢ã«ãšåå¿
ãããæ¬¡ãã§ãã®åå¿çæç©ããžãšã¹ãã«âãžãª
ãŒã«ããã³ããã²ã³åã«ã«ããã«ãšåå¿ãããã äžè¬åŒïŒ ã®ã¿ã€ãã®ã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ãã«
âã«ãŒãããŒããçæãããããã«ã¯ãå ããã¹
ããšããŒã«ãããã²ã³åã«ã«ããã«ãšå ±åå¿ã
ããæ¬¡ã«ãã®å ±åå¿çæç©ããžãšã¹ãã«âãžãªãŒ
ã«ããã³ãã¹ããããŒã¡ãŒããšåå¿ãããã äžè¬åŒïŒ ã§è¡šããããã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ã
ã«âã«ãŒãããŒããåŸãããã«ã¯ããã¹ããããŒ
ã¡ãŒãïŒã¢ã«ããžãšã¹ãã«âãžãªãŒã«ïŒã¢ã«ãã
ã³ãã¹ããšããŒã«ïŒã¢ã«ãšåå¿ããããã®åå¿ç
æç©ã«ããã²ã³åã«ã«ããã«ãæ·»å ããã äžè¬åŒïŒ ã®ã¿ã€ãã®ã»ã°ã¡ã³ãã嫿ããã³ããªãšã¹ãã«
âã«ãŒãããŒããåŸãããã«ã¯ãããã²ã³åã«ã«
ããã«ããžãšã¹ãã«âãžãªãŒã«ããã³ãã¹ããšã
ãŒã«ãåæã«åå¿ãããæ¬¡ãã§ãã®åå¿çæç©ã
ãã¹ããããŒã¡ãŒããšåå¿ãããã äžè¬ã«ããã¹ããããŒã¡ãŒãããžãšã¹ãã«âãž
ãªãŒã«ããã³ãã¹ããšããŒã«ã®äœ¿çšéã¯ãå å·¥æ§
ãæ¹è¯ãããŠãããåæã«åŸæ¥ã®ã³ããªãšã¹ãã«
âã«ãŒãããŒãã®ä»ã®æå©ãªç¹æ§ã®ã»ãŒå šãŠãå®
質çãªçšåºŠã§ä¿æããŠããã³ããªãšã¹ãã«âã«ãŒ
ãããŒãæš¹èãçæããã®ã«æå¹ãªéã§ãããã
ã¹ããããŒã¡ãŒãã®å Žåãéåžžãã®éã¯ã䜿çšã
ããã¹ããããŒã¡ãŒãããžãšã¹ãã«âãžãªãŒã«ã
ãã³ãã¹ããšããŒã«ã®åèšéã«å¯ŸããçŽïŒãçŽ40
ã¢ã«ïŒ ã®ç¯å²å ã§ãããçŽïŒãçŽ30ã¢ã«ïŒ ã奜ãŸ
ããããžãšã¹ãã«âãžãªãŒã«ã®å Žåã®ãã®éã¯ã
äžè¬ã«ã䜿çšãããã¹ããããŒã¡ãŒãããžãšã¹ã
ã«âãžãªãŒã«ããã³ãã¹ããšããŒã«ã®åèšéã«å¯Ÿ
ããŠãçŽïŒãçŽ60ã¢ã«ïŒ ã®ç¯å²ã§ãããçŽïŒãçŽ
50ã¢ã«ïŒ ã®ç¯å²ã§ãããšå¥œãŸããããã¹ããšããŒ
ã«ã®éã¯éåžžãååšãããã¹ããããŒã¡ãŒãããž
ãšã¹ãã«âãžãªãŒã«ããã³ãã¹ããšããŒã«ã®åèš
éã«å¯ŸããŠãçŽ20ãçŽ98ã¢ã«ïŒ ã®ç¯å²ã§ãããçŽ
30ãçŽ90ã¢ã«ïŒ ã奜ãŸããã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èäž
ã«ååšããåŒãããã³ã®ç¹°ãè¿ãæ§é åäœ
ã®éã¯ã䜿çšãããžãšã¹ãã«âãžãªãŒã«ããã¹ã
ãããŒã¡ãŒãããã³ãã¹ããšããŒã«ã®çš®ã ã®éã«
äŸåãããããªãã¡ãããšãã°äœ¿çšãããžãšã¹ã
ã«âãžãªãŒã«ã®éãå€ãããã°ãã³ããªãšã¹ãã«
âã«ãŒãããŒãæš¹èäžã«ååšããåŒã®ç¹°ãè¿ã
æ§é åäœã®éã¯ããã ãå€ããªãã ãžãšã¹ãã«âãžãªãŒã«ããã¹ããšããŒã«ããã¹
ããããŒã¡ãŒãããã³ããã²ã³åã«ã«ããã«ããš
ãã°ãã¹ã²ã³ããæ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒ
ãããŒãã補é ããïŒã€ã®æ¹æ³ã«ã¯äžå質çé¢é
åæ³ãå«ãŸããããã®ãããªçé¢éåæ³ã¯ç±³åœç¹
蚱第3169121å·ïŒåŒçšã«ããæ¬æçްæžäžã«å å«ã
ãïŒã«èšèŒãããŠãããäžè¬ã«çé¢éåæ³ã§ã¯å
å¿äœçšã«ïŒçš®ã®äºãã«æ··åããªã溶åªç³»ã䜿çšã
ãããããã®æº¶åªç³»ã®ïŒæ¹ã¯æ°Žæ§æº¶åªç³»ã§ããã
仿¹ã¯æ°Žã«æ··åããªãææ©æº¶åªç³»ããšãã°ã¡ãã¬
ã³ã¯ãã©ã€ãã§ããããã¹ã²ã³ããã³ïŒãŸãã¯ã
ã¹ããããŒã¡ãŒããæ·»å ããéã«ã¯ãPHãå¡©åºæ§
ç¯å²ã«ä¿ã€ããã«æ°Žæ§ã¢ã«ã«ãªæº¶æ¶²ãçšããŠå¡©åº
æ§æ¡ä»¶äžã§è¡ãªããåå¿æ··åç©äžã«ã¯è§Šåªãšåå
é調ç¯å€ãååšããã 䜿çšãåŸãè§Šåªã¯ãã³ããªãšã¹ãã«âã«ãŒãã
ãŒãçæåå¿ãéãããããªãã¡ä¿é²ããåšç¥ã®
è§Šåªã®ãããã§ããããé©åœãªéåè§Šåªã«ã¯ã第
äžçŽã¢ãã³é¡ããšãã°ããªãšãã«ã¢ãã³ã第åçŽ
ã¢ã³ã¢ããŠã ååç©ããã³ç¬¬åçŽãã¹ãããŠã å
åç©ãå å«ããããããããã«éå®ãããããšã¯
ãªãã 䜿çšãããååé調ç¯å€ã¯ãé£éåæ¢æ©æ§ã«ã
ã€ãŠã³ããªãšã¹ãã«âã«ãŒãããŒãã®ååéã調
ç¯ããåšç¥ã®ååç©ã®ãããã§ãããããããã®
ååç©ã«ã¯ããšããŒã«ãtertâããã«ããšããŒ
ã«ãã¯ããã³âçãå å«ãããã çé¢éååå¿ã«ãã€ãŠã³ããªãšã¹ãã«âã«ãŒã
ããŒãçæåå¿ãé²è¡ããæž©åºŠã¯ïŒâ以äžãã
100â以äžã«äºã€ãŠå€åãåŸããåå¿ã¯ã宀枩
ïŒ25âïŒãçŽ50âã®æž©åºŠã§æºè¶³ã«é²è¡ããã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã¯ãé
åžžçŽ10000ãçŽ150000ã®ç¯å²ã®ééå¹³åååéã
æããçŽ15000ãçŽ100000ã®ç¯å²ã§ãããšå¥œãŸã
ãã æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã«ã¯å ¬
ç¥ã®é垞䜿çšãããæ·»å å€ã®ãããã®ãé©åœã«æ··
åããŠããããããšãã°ãäžæŽ»æ§å å¡«æããšãã°
ã¬ã©ã¹ãã¿ã«ã¯ã鲿¯ããã³ç²åãè¡ææ¹è³ªå€ã
玫å€ç·åžåå€ããšãã°ãã³ãŸããšãã³é¡ããã³ãŸ
ããªã¢ãŸãŒã«é¡ããã³ã·ã¢ãã¢ã¯ãªã¬ãŒãé¡ãå
æ°Žåè§£å®å®å€ããšãã°ç±³åœç¹èš±ç¬¬3489716å·ã第
4138379å·ããã³ç¬¬3839247å·ïŒãããå šãŠãåŒçš
ã«ããæ¬æçްæžäžã«å å«ããïŒã«é瀺ãããŠãã
ãšããã·ãé¡ãè²å®å®å€ããšãã°ãªã«ã¬ããã¹ã
ã¢ã€ãé¡ããªãã³ã«é£çå€ãããã ããã€ãã®ç¹ã«æçšãªé£çå€ã¯ã¹ã«ãã³é žã®ã¢
ã«ã«ãªéå±å¡©ããã³ã¢ã«ã«ãªåé¡éå±å¡©ã§ããã
ãããã®ã¿ã€ãã®é£çå€ã¯ç±³åœç¹èš±ç¬¬3933734å·ã
第3948851å·ã第3926908å·ã第3919167å·ã第
3909490å·ã第3953396å·ã第3931100å·ã第
3978025å·ã第3953399å·ã第3917599å·ã第
3951910å·ããã³ç¬¬3940366å·ïŒãããå šãŠãåŒçš
ã«ããæ¬æçްæžäžã«å å«ããïŒã«é瀺ãããŠã
ãã 奜ãŸããå ·äœäŸã®èª¬æ æ¬çºæãããè©³çŽ°ã«æçã«èª¬æããããã«ä»¥äž
ã«å®æœäŸãæããããããã®å®æœäŸã¯ãæ¬æçŽ°æž
äžã«èšèŒããã€ç¹èš±è«æ±ã®ç¯å²ã«æèšããæ¬çºæ
ãéå®ããããšãªãæ¬çºæãäŸç€ºãããã®ãšèã
ããããã以äžã®å®æœäŸäžã§ä»ã«ç¹èšããªãéã
éšããã³ïŒ ã¯å šãŠééåºæºã§ããã æ¬¡ã®ããã€ãã®å®æœäŸã¯æ¬çºæã®ãžãšã¹ãã«â
ãžãªãŒã«ã®è£œé ãäŸç€ºããã 宿œäŸ ïŒ æ¬å®æœäŸã§ã¯ïŒïŒ10âãã«ã¡ãã¬ã³âãã¹ïŒïŒ
âããããã·ãã³ãŸãšãŒãïŒã®è£œé äŸã瀺ãã ïœâããããã·å®æ¯éŠé žã¡ãã«76.1gïŒ0.5ã¢
ã«ïŒãïŒïŒ10âãã«ã³ãžãªãŒã«43.6gïŒ0.25ã¢ã«ïŒ
ããã³é žåãžããã«ã¹ãº0.3gãå åã«æ¹æããæ··
åç©ãããšã¹ãã«äº€æåå¿ã§åŸã ã«éé¢ããŠãã
ã¡ãã«ã¢ã«ã³ãŒã«ã倧æ°å§äžã§èžçããããã®èž
çããããšéæµå·åŽåšãåããåå¿ãã©ã¹ã³äž
ã§ãçŽïŒæé190ã200âã«å ç±ãããã¢ã«ã³ãŒã«
ã®éæµãçµã€ããæ°Žæµãã³ãã§æžå§ã«ããŠåŸ®éã®
ã¢ã«ã³ãŒã«ãé€å»ãããéé102.6gïŒåç99.0ïŒ ïŒ
ã®ãžãšã¹ãã«âãžãªãŒã«ãæ®æž£ãšããŠåŸãããã
ã¡ã¿ããŒã«ïŒæ°Žã§åçµæ¶ãããšèç¹154ã155âã®
çœè²çµæ¶ãåŸãããã 宿œäŸ ïŒ æ¬å®æœäŸã¯ïŒïŒïŒâããã©ã¡ãã¬ã³âãã¹ïŒïŒ
âããããã·ãã³ãŸãšãŒãïŒã®è£œé äŸã瀺ãã ïœâããããã·å®æ¯éŠé žã¡ãã«76.1gïŒ0.5ã¢
ã«ïŒãïŒïŒïŒâãã¿ã³ãžãªãŒã«22.5gïŒ0.25ã¢ã«ïŒ
ããã³ãã¿ã³é žããã©ãªã¯ãã«0.51gãå åã«æ¹
æããæ··åç©ãããšã¹ãã«äº€æåå¿ã§åŸã ã«éé¢
ããã¡ã¿ããŒã«ã倧æ°å§äžã§èžçããããã®èžç
ããããšéæµå·åŽåšãåããåå¿ãã©ã¹ã³äžã§çŽ
ïŒæé170âã«å ç±ãããã¢ã«ã³ãŒã«ã®éæµçµäº
åŸãæ°Žæµãã³ãã§æžå§ã«ããŠæ®åãã埮éã®ã¢ã«
ã³ãŒã«ãé€å»ãããã¡ã¿ããŒã«ïŒæ°Žã§åçµæ¶ãã
ãšèç¹ã182.5ã184âã®çµæ¶ãåŸãããã 宿œäŸ ïŒ ïŒïŒ10âãã«ã³ãžãªãŒã«43.6gã®ä»£ããã«ïŒïŒ
ïŒâãžã¡ãã«âïŒïŒïŒâãããã³ãžãªãŒã«0.25ã¢
ã«ã䜿çšãã以å€ã¯ã»ãŒå®æœäŸïŒã®æé ãç¹°ãè¿
ããåŸããããžãšã¹ãã«âãžãªãŒã«ã®çµæ¶ã®èç¹
ã¯156ã159âã§ããã 宿œäŸ ïŒ ïŒïŒ10âãã«ã³ãžãªãŒã«ã®ä»£ããã«ïŒâããã
ãã·ãšãã«ãšãŒãã«0.25ã¢ã«ã䜿çšããŠã»ãŒå®æœ
äŸïŒã®æé ãç¹°ãè¿ããåŸããããžãšã¹ãã«âãž
ãªãŒã«ã®çµæ¶ã¯119ã121âã®èç¹ãæããã 宿œäŸ ïŒ ïŒïŒ10âãã«ã³ãžãªãŒã«ã®ä»£ããã«ïŒïŒïŒâã·
ã¯ããããµã³ãžã¡ã¿ããŒã«ã®ã·ã¹ïŒãã©ã³ã¹æ··å
ç©ã0.25ã¢ã«ã䜿çšãã以å€ã¯ã»ãŒå®æœäŸïŒã®æ
é ãç¹°ãè¿ãã æ¬¡ã®å®æœäŸã¯ãæ¬çºæã®ç¯å²ããå€ããåŸæ¥ã®
ã³ããªãšã¹ãã«âã«ãŒãããŒãæš¹èã®è£œé äŸã瀺
ãããããã¯æ¯èŒã®ããã ãã®ãã®ã§ããã 宿œäŸ ïŒ è±ã€ãªã³æ°Ž10ãã¡ãã¬ã³ã¯ãã©ã€ã16ãã
ã¹ããšããŒã«âA1.910gïŒ8.36ã¢ã«ïŒãããªãšãã«
ã¢ãã³24mlãã°ã«ã³ã³é žãããªãŠã 3.4gããã³ïœ
âtertâããã«ããšããŒã«65gãæ©æ¢°çæ¹æåšã
åããåå¿å®¹åšã«å ¥ããããã®åå¿æ··åç©ãæ¹æ
ããæ¹æããåå¿æ··åç©ã«ããã¬ãã¿ãã€ã«ãžã¯
ãã©ã€ã926gãšã€ãœãã¿ãã€ã«ãžã¯ãã©ã€ã
163gãåºäœå25ééïŒ ã®ã¡ãã¬ã³ã¯ãã©ã€ã溶
æ¶²ãšããŠ15åéã«äºã€ãŠå ãããé žå¡©åç©ã®æ·»å
äžã25ïŒ æ°Žé žåãããªãŠã 氎溶液ãå ããŠPHã
8.5ã11.5ã®ç¯å²å ã«ä¿ã€ãåŸãããæ··åç©ã«æ¯
å36gã®é床ã§15åéãã¹ã²ã³ãå°å ¥ããããã®
éPHã¯æ°Žé žåãããªãŠã æ°Žæº¶æ¶²ãæ·»å ããŠ9.5ã
12ã«èª¿æŽããããã¹ã²ã³åçµäºåŸãã¡ãã¬ã³ã¯ã
ã©ã€ãïŒãå ããé å¿ã«ãããã©ã€ã³å±€ãåé¢
ããæš¹è溶液ãé žæ°Žæº¶æ¶²ã§ïŒåãæ°Žã§ïŒåæŽæµã
ããæš¹èãèžæ°ã§æ²æ®¿ãããçªçŽ æµååºä¹Ÿç¥åšäž
çŽ240âã§ä¹Ÿç¥ããã ãã®æš¹èã®ã«ã·ã€ã€ã³ããã¯ã¹ïŒKIïŒã枬å®
ããçµæãåŸæ²ã®è¡šã«ç€ºãã ã«ã·ã€ã€ã³ããã¯ã¹ïŒKIïŒã¯æš¹èã®å å·¥æ§ã®
ææšãŸãã¯å°ºåºŠã§ãããKIãäœãã»ã©æš¹èã®ã¡
ã«ããããŒã€ã³ããã¯ã¹ã倧ãããªããããã€ãŠ
å å·¥æ§ãè¯ããªããåºæ¬çã«ã«ã·ã€ã€ã³ããã¯ã¹
ã¯æš¹èã®æº¶èç²åºŠã®å°ºåºŠã§ãããã«ã·ã€ã€ã³ãã
ã¯ã¹ã®æž¬å®æ³ã¯ä»¥äžã®ãšããã§ããã125âã§æ
äœ90å也ç¥ããæš¹èãã¬ãã7gãæ¹è¯ã¿ã€ããŠ
ã¹ãŒãªã«ãŒã³ïŒTiniusâOlsenïŒT3åã¡ã«ãã€ã³
ããã¯ã¹æž¬å®åšã«æ·»å ããæž¬å®åšã®æž©åºŠã300â
ã«ä¿ã¡ãæš¹èãïŒåéãã®æž©åºŠã«å ç±ãããïŒå
åŸãååŸ0.1865ã€ã³ãã®ãã©ã³ãžã€ãŒãçšããŠå§
å17.7ãã³ãã§ååŸ0.04125ã€ã³ãã®ãªãªãã€ã¹
ãéããŠæš¹èãæŒãåºãããã©ã³ãžã€ãŒãïŒã€ã³
ãåããã®ã«èŠããæéãæž¬å®ããKIãšããŠçŸ
åã®äžç§åäœã§è¡šãããKIã倧ãããªãã°ãªã
ã»ã©æº¶èç²åºŠãé«ããªãæš¹èã®ç²æ§ãå¢ããå å·¥
æ§ãæªããªãã æ¬¡ã®å®æœäŸã¯æ¬çºæã®ç¯å²ããå€ããåŸæ¥ã®ã
ãªã«ãŒãããŒãæš¹èã®è£œé ãäŸç€ºããããã®å®æœ
äŸã¯æ¯èŒã®ããã ãã®ãã®ã§ããã 宿œäŸ ïŒ ãã¹ããšããŒã«âA57.1gïŒ0.25ã¢ã«ïŒãæ°Ž300mlã
ã¡ãã¬ã³ã¯ãã©ã€ã400mlãããšããŒã«0.6gãã
ã³ããªãšãã«ã¢ãã³0.56gã®æ··åç©äžã«ããã¹ã²
ã³31.0gã31åéãããŠåšå²æž©åºŠã§å ããããã®
éã25ïŒ æ°Žé žåãããªãŠã 氎溶液ãåæã«æ·»å ã
ãŠïŒçžç³»ã®PHãçŽ11ã«ç¶æããããã¹ã²ã³æ·»å æ
éçµäºæã«ã¯ãæ°Žæ§çžã®PHã¯11.7ã§ããããã®çž
ã®ãã¹ããšããŒã«âïŒ¡å«æçã¯çŽ«å€ç·åæã«ãã
ãš1ppmæªæºã§ããã ã¡ãã¬ã³ã¯ãã©ã€ãçžãæ°Žçžããåé¢ããéå°
ã®åžå¡©é žïŒ0.01NïŒæ°Žæº¶æ¶²ã§æŽæµããæ¬¡ãã§è±ã€
ãªã³æ°Žã§ïŒåæŽæµãããããªããŒãã¡ã¿ããŒã«ã§
æ²æŸ±ããã80âã§ä¹Ÿç¥ããã ãã®ããªã«ãŒãããŒãæš¹èã®KIãæž¬å®ããçµ
æãåŸæ²ã®è¡šã«ç€ºãã æ¬¡ã®å®æœäŸã¯æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒã
ããŒãæš¹èã®è£œé ãäŸç€ºããã 宿œäŸ ïŒ ãã¹ããšããŒã«âA54.2gïŒ0.2375ã¢ã«ïŒãããšã
ãŒã«0.5gãããªãšãã«ã¢ãã³0.5gãã¡ãã¬ã³ã¯ã
ã©ã€ã400mlããã³æ°Ž300mlã®ã¹ã©ãªãŒäžã«ã25ïŒ
æ°Žé žåãããªãŠã 氎溶液ãå åéå ããŠPHã10.5
ã«ããããã®åå¿æ··åç©ã«ïŒïŒïŒâãã¿ã³ãžãªãŒ
ã«ãã¹ã¯ããããŒã¡ãŒã10.75gïŒ0.05ã¢ã«ïŒãã¡
ãã¬ã³ã¯ãã©ã€ã50mlã«æº¶è§£ããæº¶æ¶²ã10åéã§
滎äžããŠå ããããã®éãPHã10.5ãš11ã®éã«ä¿
ã€ã次ãã§ïŒåéæ¹æãããæ¬¡ã«ã宿œäŸïŒã®æ
é ã«åŸã€ãŠè£œé ãããžãšã¹ãã«ãŒãžãªãŒã«ã4.8g
ïŒ0.0125ã¢ã«ïŒå ããåŸãæ°Žé žåãããªãŠã 氎溶
æ¶²ãå ããŠPHã11ä»è¿ã«ä¿ã¡ãªããæ¯å1gã®å²
åã§ãã¹ã²ã³ã26åéå ããããã®ãã¹ã²ã³åçµ
äºæã«ã玫å€ç·åæã«ãããšåå¿æ··åç©ã¯23ppm
ã®ãã¹ããšããŒã«âã嫿ããã ã¡ãã¬ã³ã¯ãã©ã€ãçžãæ°Žçžããåé¢ããéå°
ã®åžå¡©é žïŒ0.01NïŒæ°Žæº¶æ¶²ã§æŽæµããæ¬¡ã«è±ã€ãª
ã³æ°Žã§ïŒåæŽæµãããããªããŒãã¡ã¿ããŒã«ã§æ²
柱ããã也ç¥ããã åŸãããããªããŒã®åºæç²åºŠïŒIVïŒã¯25âã®
ã¡ãã¬ã³ã¯ãã©ã€ãäžã§0.606d1ïŒïœã§ãããïŒ
次ã¬ã©ã¹è»¢ç§»æž©åºŠïŒTgïŒã¯122âã§ããã ãã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã®KIãæž¬
å®ããçµæã衚ã«ç€ºãã 衚 宿œäŸ KI ïŒ 42630 ïŒ 9220 ïŒ 425 衚ã®ããŒã¿ã瀺ããŠããããã«ãæ¬çºæã®ã³
ããªãšã¹ãã«âã«ãŒãããŒãã¯åŸæ¥ã®ã³ããªãšã¹
ãã«âã«ãŒãããŒãããäœãKIã瀺ããæŽã«ã
æ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãããŒãã¯ãåŸæ¥
ã®ã³ããªãšã¹ãã«âã«ãŒãããŒãããäœãKIã
瀺ãã ãã§ãªããåŸæ¥ã®ããªã«ãŒãããŒãããã
äœãKIã瀺ããããªãã¡ãæ¬çºæã®ã³ããªãšã¹
ãã«âã«ãŒãããŒãã¯ãåŸæ¥ã®ã³ããªãšã¹ãã«â
ã«ãŒãããŒãã«æ¯èŒããŠå å·¥æ§ãæ¹è¯ãããŠãã
ã ãã§ãªããåŸæ¥ã®ããªã«ãŒãããŒããããè¯å¥œ
ãªå å·¥æ§ã瀺ããäžè¬ã«ããªã«ãŒãããŒãã¯ã³ã
ãªãšã¹ãã«âã«ãŒãããŒããããå å·¥ããããã®
ã§ãããããæ¬çºæã®ã³ããªãšã¹ãã«âã«ãŒãã
ãŒããããªã«ãŒãããŒãã«å¯ŸããŠæ¹è¯ãããå å·¥
æ§ã瀺ãããšã¯éåžžã®ããšã§ã¯ãªãäºæž¬ãããªã
ã€ãããšã§ããã æããã«ãäžè¿°ã®æç€ºã«ç §ãããæ¬çºæã®ä»ã®
ä¿®æ£ããã³å€åœ¢ãå¯èœã§ããããããã€ãŠãäžè¿°
ããæ¬çºæã®ç¹å®å ·äœäŸã«ãããŠãç¹èš±è«æ±ã®ç¯
å²ã«å®çŸ©ããæ¬çºæã®å åã«æå³ãããç¯å²å ã«
ãããŠå€åããªãåŸããšçè§£ããããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ åŒïŒ ã®ç¹°ãè¿ãæ§é åäœãåŒ ã®ç¹°ãè¿ãæ§é åäœããã³åŒ ã®ç¹°ãè¿ãæ§é åäœ ãåŒäžãã¯ãã©ããšãã¬ã³åºãR1ã¯åŒ ââââ ïŒåŒäžãã¯ã·ã¯ãã¢ã«ãã¬ã³åºã§ïŒ¹ã¯ã¢ã«ãã¬
ã³åºã§ããïŒã§è¡šããããäºäŸ¡ã®åºãR2ã¯åŒïŒ ïŒåŒäžãã¯äºäŸ¡ã®çåæ°ŽçŽ åºãââãâ
âã âââããåŒããåŒãããã³ ãåŒãããéžæãããïŒã§è¡šããããé眮æã ã¹ããšããŒã«æ®åºããããŠR3ã¯ã¢ã«ãã¬ã³åºã§
ããããããªããæ§é åäœãããã³ããã
ãã®åèšéã«åºã¥ãããããïŒâ60ã¢ã«ïŒ ãïŒâ
40ã¢ã«ïŒ ããã³20â98ã¢ã«ïŒ æããééå¹³ååå
éã10000â150000ã®ç¯å²ã®å å·¥æ§ãæ¹åããã
ç±å¯å¡æ§ã³ããªãšã¹ãã«âã«ãŒãããŒãã ïŒ ïŒ·ã§è¡šããããäºäŸ¡ã®çåæ°ŽçŽ åºãã¢ã«ãã¬
ã³åºãã·ã¯ãã¢ã«ãã¬ã³åºãã¢ã«ããªãã³åºãã
ã³ã·ã¯ãã¢ã«ããªãã³åºããéžæãããããšãç¹
城ãšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®ã³ããªãš
ã¹ãã«âã«ãŒãããŒãã ïŒ ïŒ·ãïŒïŒïŒâããããªãã³åºã§ããããšãç¹
城ãšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®ã³ããªãš
ã¹ãã«âã«ãŒãããŒãã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/562,273 US4504649A (en) | 1983-12-16 | 1983-12-16 | Copolyester-carbonate resins |
| US562273 | 1983-12-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60168722A JPS60168722A (ja) | 1985-09-02 |
| JPS6411211B2 true JPS6411211B2 (ja) | 1989-02-23 |
Family
ID=24245564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59261920A Granted JPS60168722A (ja) | 1983-12-16 | 1984-12-13 | ã³ããªãšã¹ãã«âã«âããâãæš¹è |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4504649A (ja) |
| EP (1) | EP0146076A3 (ja) |
| JP (1) | JPS60168722A (ja) |
| AU (1) | AU578642B2 (ja) |
| CA (1) | CA1224589A (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4476294A (en) * | 1983-12-16 | 1984-10-09 | General Electric Company | Copolyester-carbonate resins |
| US4487917A (en) * | 1983-12-21 | 1984-12-11 | General Electric Company | Copolyester-carbonate resins exhibiting improved processability |
| US4628081A (en) * | 1985-11-12 | 1986-12-09 | General Electric Company | Polycarbonate exhibiting improved impact properties |
| US4728716A (en) * | 1985-11-12 | 1988-03-01 | General Electric Company | Polycarbonate exhibiting improved impact properties containing divalent residue of polymerized alkadiene monomer |
| CA2013354A1 (en) * | 1989-07-03 | 1991-01-03 | John C. Schmidhauser | Thermoplastic polycarbonate compositions having improved oxygen barrier properties |
| JP4915750B2 (ja) * | 2008-10-29 | 2012-04-11 | å©åœŠ é«å® | å£é¢ããã«åã³ãã®å£é¢ããã«ãçšããæšé 建ç©ã®å£é¢æ§é |
| RU2621353C1 (ru) * | 2016-02-24 | 2017-06-02 | ЀеЎеÑалÑМПе гПÑÑЎаÑÑÑвеММПе бÑЎжеÑМПе ПбÑазПваÑелÑМПе ÑÑÑежЎеМОе вÑÑÑегП ПбÑÐ°Ð·ÐŸÐ²Ð°ÐœÐžÑ "ÐабаÑЎОМП-ÐалкаÑÑкОй гПÑÑЎаÑÑÑвеММÑй ÑМОвеÑÑОÑÐµÑ ÐžÐŒ. Ð¥.Ð. ÐеÑбекПва" (ÐÐÐУ) | ÐалПгеМÑПЎеÑжаÑОе блПк-ÑПпПлОÑÑОÑкаÑбПМаÑÑ |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH372841A (de) * | 1958-03-08 | 1963-10-31 | Inventa Ag | Verfahren zur Herstellung linearer Polyester der KohlensÀure |
| US3030335A (en) * | 1959-01-02 | 1962-04-17 | Gen Electric | Aromatic polycarbonate reaction products |
| US3207814A (en) * | 1961-01-03 | 1965-09-21 | Gen Electric | Carbonate-polyester copolymer resinous compositions |
| US3493534A (en) * | 1967-12-11 | 1970-02-03 | Gen Mills Inc | Polycarbonates of diols derived from dimeric fat acids |
| DE2704315C3 (de) * | 1976-02-12 | 1981-04-30 | Teijin Ltd., Osaka | Aromatische Polyestercarbonate, Verfahren zu ihrer Herstellung und deren Verwendung |
| US4381358A (en) * | 1981-10-16 | 1983-04-26 | General Electric Co. | Copolyester-carbonates containing aliphatic diol co-monomers |
| US4476294A (en) * | 1983-12-16 | 1984-10-09 | General Electric Company | Copolyester-carbonate resins |
| US4487917A (en) * | 1983-12-21 | 1984-12-11 | General Electric Company | Copolyester-carbonate resins exhibiting improved processability |
-
1983
- 1983-12-16 US US06/562,273 patent/US4504649A/en not_active Expired - Fee Related
-
1984
- 1984-11-30 CA CA000469067A patent/CA1224589A/en not_active Expired
- 1984-12-04 EP EP84114744A patent/EP0146076A3/en not_active Withdrawn
- 1984-12-12 AU AU36587/84A patent/AU578642B2/en not_active Ceased
- 1984-12-13 JP JP59261920A patent/JPS60168722A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AU578642B2 (en) | 1988-11-03 |
| EP0146076A2 (en) | 1985-06-26 |
| EP0146076A3 (en) | 1987-01-07 |
| AU3658784A (en) | 1985-06-20 |
| JPS60168722A (ja) | 1985-09-02 |
| CA1224589A (en) | 1987-07-21 |
| US4504649A (en) | 1985-03-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR940010012B1 (ko) | ìœíŽëЬìì€í 륎 칎볎ë€ìŽížì ì ì¡°ë°©ë² | |
| JPS6411210B2 (ja) | ||
| JPS59167528A (ja) | ããªã«âããâã | |
| KR101687831B1 (ko) | ìŽê°ìì± ìì§ì ì ì¡° ë°©ë², íŽëЬìì€í 륎 ìì§ ë° íŽëŠ¬ì¹Žë³Žë€ìŽíž ìì§, ê·žëŠ¬ê³ ê·žë€ì ì©ë | |
| TW201713707A (zh) | èé ¯æš¹è | |
| EP0146880B1 (en) | Copolyester-carbonate resins exhibiting improved processability | |
| EP0068014B1 (en) | Benzoate ester terminated polyester-carbonate | |
| US4002600A (en) | Linear copolyesters based on terephthalic acid and/or isophthalic acid, a process for their manufacture and their use | |
| US5274068A (en) | Catalytic, interfacial, pH controlled preparation of polyester polycarbonate | |
| JPS6411211B2 (ja) | ||
| EP0695511B1 (en) | Preparation of copolyestercarbonates by the bischloroformate process | |
| US4381358A (en) | Copolyester-carbonates containing aliphatic diol co-monomers | |
| JPS59166528A (ja) | æ¹è¯ãããèç±æ§ã瀺ãããªã«âããâã | |
| JPS59133223A (ja) | æåãã³ããªãšã¹ãã«âã«âããâãæš¹èçµæç©ãšãã®è£œæ³ | |
| EP0625521B1 (en) | Bisphosphine oxide monomers and polycarbonates prepared therefrom | |
| US6307005B1 (en) | Robust process for the synthesis of polyestercarbonates | |
| JP2003530477A (ja) | ããªã«ãŒãããŒã補é çšè§ŠåªãšããŠã®ã¢ãªãŒã«ã¹ã«ãã³é žå¡© | |
| US4576996A (en) | Polycarbonates exhibiting improved heat resistance | |
| JPH0564935B2 (ja) | ||
| US4608430A (en) | Polycarbonate exhibiting improved heat resistance from diphenol containing disubstituted phenylene radical | |
| US4526956A (en) | Copolyester-carbonates exhibiting improved processability | |
| JP2003511499A (ja) | ããªã«ãŒãããŒãåæè§ŠåªãšããŠã®ã€ãªãŠã®ãªããœé žã®ã¢ã«ã«ãªéå±å¡© | |
| US4547564A (en) | Polyester carbonate from branched chain alkylidene dihydric phenol | |
| JPS59191718A (ja) | æ¹è¯ãããèç±æ§ã瀺ãããªã«âããâã | |
| EP0362659A2 (en) | Spirobindindane copolysiloxanecarbonates and method for their preparation |