JPS6475476A - Production of alkylbenzothiazoles - Google Patents

Production of alkylbenzothiazoles

Info

Publication number
JPS6475476A
JPS6475476A JP62234276A JP23427687A JPS6475476A JP S6475476 A JPS6475476 A JP S6475476A JP 62234276 A JP62234276 A JP 62234276A JP 23427687 A JP23427687 A JP 23427687A JP S6475476 A JPS6475476 A JP S6475476A
Authority
JP
Japan
Prior art keywords
amino
complex
alkyl
formula
halobenzene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62234276A
Other languages
Japanese (ja)
Other versions
JP2564141B2 (en
Inventor
Kentaro Takagi
Tadashi Iwachimichi
Naomi Hayama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Chemical Industrial Co Ltd
Original Assignee
Nippon Chemical Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Chemical Industrial Co Ltd filed Critical Nippon Chemical Industrial Co Ltd
Priority to JP62234276A priority Critical patent/JP2564141B2/en
Publication of JPS6475476A publication Critical patent/JPS6475476A/en
Application granted granted Critical
Publication of JP2564141B2 publication Critical patent/JP2564141B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE:To obtain the titled compound useful as a raw material for drugs, agricultural chemicals and dye through an isothioamide intermediate under a mild condition in high yield, by reacting a 1-amino-2-halobenzene with a thioamide by using a transition metal complex as a catalyst. CONSTITUTION:A 1-amino-2-halobenzene shown by formula I [X is halogen; R is OH, amino, aldehydo, acyl, carboxyl, 1-3C alkoxy, (halogenated) alkyl, halogen or H] is reacted with a thioamide shown by formula II (R<1> is alkyl or substituted alkyl) in the presence of a transition metal complex [e.g. complex of tris(dibenzylideneacetone)(chloroform)di-palladium(0) and triphenylphosphine and preferably Pd complex] to give an alkylbenzothiazole (e.g. 2- methylbenzothiazole) shown by formula III. This compound is useful as a raw material for antioxidant and polymer stabilizer.
JP62234276A 1987-09-18 1987-09-18 Method for producing alkylbenzothiazoles Expired - Fee Related JP2564141B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62234276A JP2564141B2 (en) 1987-09-18 1987-09-18 Method for producing alkylbenzothiazoles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62234276A JP2564141B2 (en) 1987-09-18 1987-09-18 Method for producing alkylbenzothiazoles

Publications (2)

Publication Number Publication Date
JPS6475476A true JPS6475476A (en) 1989-03-22
JP2564141B2 JP2564141B2 (en) 1996-12-18

Family

ID=16968432

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62234276A Expired - Fee Related JP2564141B2 (en) 1987-09-18 1987-09-18 Method for producing alkylbenzothiazoles

Country Status (1)

Country Link
JP (1) JP2564141B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1968932A (en) 2004-06-18 2007-05-23 惠氏公司 Processes for preparing 6-alkyl-5-arylsulfonyl-dihydrophenanthridines

Also Published As

Publication number Publication date
JP2564141B2 (en) 1996-12-18

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Legal Events

Date Code Title Description
LAPS Cancellation because of no payment of annual fees