KR960010671A - 5h- 페닐-3,13- 디설포네이토디벤조포스폴 및 이의 제조방법 - Google Patents

5h- 페닐-3,13- 디설포네이토디벤조포스폴 및 이의 제조방법 Download PDF

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KR960010671A
KR960010671A KR1019950031281A KR19950031281A KR960010671A KR 960010671 A KR960010671 A KR 960010671A KR 1019950031281 A KR1019950031281 A KR 1019950031281A KR 19950031281 A KR19950031281 A KR 19950031281A KR 960010671 A KR960010671 A KR 960010671A
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water
acid
sulfuric acid
process according
orthoboric
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KR100353332B1 (ko
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알바네세 귀도
마네츠베르거 라이너
아. 헤르만 볼프강
슈미트 로후스
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그륀, 페터스
훽스트 아크티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

본 발명은 5H-페닐-3, 13-디설포네이토디벤조포스폴 화합물 및 이의 제조방법에 관한 것이다

Description

5H-페닐-3, 13-디설포네이토디벤조포스폴 및 이의 제조 방법.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 5H-페닐-3, 13-디설포네이토디벤조포스폴 화합물.
  2. 20 내지 170℃의 온도에서 5H-페닐디벤조포스폴을, 황산과 오르토붕산의 무수 환합물과 반응시큼을 포함하는, 5H-페닐-3, 13-디설포네이토디벤조포스폴의 제조방법.
  3. 제2항에 있어서, 방응을 60내지 150℃에서 수행하는 방법.
  4. 제2항 또는 제3항에 있어서, 황산과 오르토붕산의 혼합물에 존재하는 물을 수-결합제의 도움으로 제거하는 방법.
  5. 제2항 내지 제4항 중 어느 한 항에 있어서, 사용된 수 -결합제가 삼산화황인 방법.
  6. 제5항에 있어서, 삼산화황이 올레움의 형태로 사용되는 방법.
  7. 제2항 내지 제6항 중 어느 한 항에 있어서, 무수 황산 중의 용액으로서의 5H-페닐디벤조포스폴이 황산과 오르토붕산의 무수 혼합물내로 도입되는 방법.
  8. 제2항 내지 제7항 중 어느 한 항에 있어서, 오로토붕산이 5H-페닐디벤조포스폴을 기본으로 등몰량 이상 으로 사용되는 방법.
  9. 제2항 내지 제8항 중 어느 한 항에 있어서, 황산과 오르토붕산의 무수 혼합물을 오르토붕산으로 포화시키는 방법.
  10. 제2항 내지 제9항 중 어느 한 항에 있어서, 설폰화 반응 종료후, 반응 혼합물을 존재하는 황산을 0.5내지 50중량%로 희석시키는데 요구되는 양의 물과 혼합하고, 생성된 수용액을 수-불용성 유기 용매 중의 수-불용성 아민 용액(여기서, 아민은 설폰산의 화학적 당량당 0.5내지 3몰이 사용된다)으로 추출하고 유기상을 분리하여 수성 염기 용액과 즉시 접촉시킨 후, 수성상을 분리하며 이로부터 설폰화된 아릴포스핀을 분리시키는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950031281A 1994-09-30 1995-09-22 5h-페닐-3,13-디설포네이토디벤조포스폴및이의제조방법 Expired - Fee Related KR100353332B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4435171A DE4435171A1 (de) 1994-09-30 1994-09-30 5-H-Phenyl(di-3,13-sulfonato)dibenzophosphol und ein Verfahren zu seiner Herstellung
DEP4435171.2 1994-09-30

Publications (2)

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KR960010671A true KR960010671A (ko) 1996-04-20
KR100353332B1 KR100353332B1 (ko) 2002-12-16

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KR1019950031281A Expired - Fee Related KR100353332B1 (ko) 1994-09-30 1995-09-22 5h-페닐-3,13-디설포네이토디벤조포스폴및이의제조방법

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Country Link
US (1) US5637762A (ko)
EP (1) EP0704452B1 (ko)
JP (1) JP2812449B2 (ko)
KR (1) KR100353332B1 (ko)
CN (1) CN1050607C (ko)
AT (1) ATE187457T1 (ko)
DE (2) DE4435171A1 (ko)
ES (1) ES2141876T3 (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19918284C1 (de) * 1999-04-22 2000-12-14 Celanese Chem Europe Gmbh Verfahren zur Herstellung von sulfonierten Arylphosphinen
CN1075509C (zh) * 1999-09-09 2001-11-28 北京化工大学 亚膦化合物
CN116178647B (zh) * 2023-02-10 2025-02-14 中国石油大学(华东) 一种基于环戊二烯钴的共价有机框架材料、制备方法及其应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3235030A1 (de) * 1982-09-22 1984-03-22 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von sulfonierten arylphosphinen
FR2550202B1 (fr) * 1983-08-03 1986-03-21 Rhone Poulenc Rech Procede de preparation de tri(m-sulfophenyl) phosphine
DE4220267A1 (de) * 1992-06-20 1993-12-23 Hoechst Ag 3,4-Dimethyl-2,5,6-tris(p-sulfonatophenyl)-1-phosphanor-bornadien, Verfahren zu seiner Herstellung und Verfahren zur Hydroformylierung von olefinisch ungesättigten Verbindungen

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DE59507378D1 (de) 2000-01-13
EP0704452A1 (de) 1996-04-03
US5637762A (en) 1997-06-10
DE4435171A1 (de) 1996-04-04
JPH08198887A (ja) 1996-08-06
EP0704452B1 (de) 1999-12-08
KR100353332B1 (ko) 2002-12-16
ATE187457T1 (de) 1999-12-15
CN1129221A (zh) 1996-08-21
CN1050607C (zh) 2000-03-22
ES2141876T3 (es) 2000-04-01
JP2812449B2 (ja) 1998-10-22

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