LU86284A1 - Procede d'obtention d'ethylene a partir d'ethanol - Google Patents

Procede d'obtention d'ethylene a partir d'ethanol Download PDF

Info

Publication number: LU86284A1
Authority: LU; Luxembourg
Prior art keywords: catalyst; zeolite; ethanol; ethylene; weight
Prior art date: 1986-01-30

Application number

LU86284A

Other languages

English (en)

French (fr)

Inventor

Jacobs Julia

Tastenhoye Paul

Jacobs Pierre

Jan B Uytterhoeven

Original Assignee

Belge Etat

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-01-30

Filing date

1986-01-30

Publication date

1987-09-03

1986-01-30 Application filed by Belge Etat filed Critical Belge Etat

1986-01-30 Priority to LU86284A priority Critical patent/LU86284A1/fr

1987-01-29 Priority to EP87870013A priority patent/EP0231163B1/de

1987-01-29 Priority to AT87870013T priority patent/ATE52074T1/de

1987-01-29 Priority to DE8787870013T priority patent/DE3762334D1/de

1987-01-29 Priority to ES87870013T priority patent/ES2014331B3/es

1987-01-30 Priority to US07/008,728 priority patent/US4727214A/en

1987-01-30 Priority to BR8700422A priority patent/BR8700422A/pt

1987-09-03 Publication of LU86284A1 publication Critical patent/LU86284A1/fr

Links

LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 132
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 42
239000005977 Ethylene Substances 0.000 title claims abstract description 42
238000000034 method Methods 0.000 title claims abstract description 24
239000003054 catalyst Substances 0.000 claims abstract description 110
239000010457 zeolite Substances 0.000 claims abstract description 91
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 87
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 75
238000006243 chemical reaction Methods 0.000 claims description 38
239000000203 mixture Substances 0.000 claims description 18
229910001657 ferrierite group Inorganic materials 0.000 claims description 16
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
229910052675 erionite Inorganic materials 0.000 claims description 12
238000011282 treatment Methods 0.000 claims description 12
UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims description 11
229910052676 chabazite Inorganic materials 0.000 claims description 11
239000011148 porous material Substances 0.000 claims description 11
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
229910052799 carbon Inorganic materials 0.000 claims description 9
238000005342 ion exchange Methods 0.000 claims description 9
125000004430 oxygen atom Chemical group O* 0.000 claims description 9
239000007789 gas Substances 0.000 claims description 7
JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 6
229910001603 clinoptilolite Inorganic materials 0.000 claims description 6
238000000855 fermentation Methods 0.000 claims description 6
230000004151 fermentation Effects 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 3
239000002028 Biomass Substances 0.000 claims description 2
230000015572 biosynthetic process Effects 0.000 claims description 2
239000003245 coal Substances 0.000 claims description 2
229910052677 heulandite Inorganic materials 0.000 claims description 2
239000003208 petroleum Substances 0.000 claims description 2
229910052678 stilbite Inorganic materials 0.000 claims description 2
238000003786 synthesis reaction Methods 0.000 claims description 2
230000001105 regulatory effect Effects 0.000 claims 1
229910000323 aluminium silicate Inorganic materials 0.000 abstract description 5
238000002360 preparation method Methods 0.000 description 23
229910001868 water Inorganic materials 0.000 description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
239000000243 solution Substances 0.000 description 17
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
238000002441 X-ray diffraction Methods 0.000 description 11
229930195733 hydrocarbon Natural products 0.000 description 11
150000002430 hydrocarbons Chemical class 0.000 description 11
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 10
230000009466 transformation Effects 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
239000000047 product Substances 0.000 description 9
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 8
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
OHBTULDTCSOWOY-UHFFFAOYSA-N [C].C=C Chemical compound [C].C=C OHBTULDTCSOWOY-UHFFFAOYSA-N 0.000 description 8
238000009826 distribution Methods 0.000 description 8
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
229910052757 nitrogen Inorganic materials 0.000 description 8
238000001354 calcination Methods 0.000 description 7
238000003756 stirring Methods 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
150000001768 cations Chemical class 0.000 description 6
229910052681 coesite Inorganic materials 0.000 description 6
229910052906 cristobalite Inorganic materials 0.000 description 6
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
229910052682 stishovite Inorganic materials 0.000 description 6
229910052905 tridymite Inorganic materials 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
235000019270 ammonium chloride Nutrition 0.000 description 5
238000006297 dehydration reaction Methods 0.000 description 5
238000010992 reflux Methods 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
-1 hydrogen ions Chemical class 0.000 description 4
239000001294 propane Substances 0.000 description 4
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
239000012265 solid product Substances 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
230000009849 deactivation Effects 0.000 description 3
238000001035 drying Methods 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
239000011707 mineral Substances 0.000 description 3
239000012071 phase Substances 0.000 description 3
239000000843 powder Substances 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
238000005406 washing Methods 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
239000002585 base Substances 0.000 description 2
239000008119 colloidal silica Substances 0.000 description 2
239000013078 crystal Substances 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229910052680 mordenite Inorganic materials 0.000 description 2
239000012074 organic phase Substances 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
229910002012 Aerosil® Inorganic materials 0.000 description 1
OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
229910004283 SiO 4 Inorganic materials 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
238000003965 capillary gas chromatography Methods 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000007850 degeneration Effects 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
235000012438 extruded product Nutrition 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
229910052747 lanthanoid Inorganic materials 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000006193 liquid solution Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910052914 metal silicate Inorganic materials 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the eroionite or offretite type, e.g. zeolite T
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

LU86284A 1986-01-30 1986-01-30 Procede d'obtention d'ethylene a partir d'ethanol LU86284A1 (fr)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
LU86284A LU86284A1 (fr)	1986-01-30	1986-01-30	Procede d'obtention d'ethylene a partir d'ethanol
EP87870013A EP0231163B1 (de)	1986-01-30	1987-01-29	Verfahren zur Gewinnung von Äthylen aus Äthanol
AT87870013T ATE52074T1 (de)	1986-01-30	1987-01-29	Verfahren zur gewinnung von aethylen aus aethanol.
DE8787870013T DE3762334D1 (de)	1986-01-30	1987-01-29	Verfahren zur gewinnung von aethylen aus aethanol.
ES87870013T ES2014331B3 (es)	1986-01-30	1987-01-29	Procedimiento de obtencion de etileno a partir de etanol.
US07/008,728 US4727214A (en)	1986-01-30	1987-01-30	Process for obtaining ethylene from ethanol
BR8700422A BR8700422A (pt)	1986-01-30	1987-01-30	Processo para obtencao de etileno a partir de etanol anidro ou aquoso

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
LU86284		1986-01-30
LU86284A LU86284A1 (fr)	1986-01-30	1986-01-30	Procede d'obtention d'ethylene a partir d'ethanol

Publications (1)

Publication Number	Publication Date
LU86284A1 true LU86284A1 (fr)	1987-09-03

Family

ID=19730631

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
LU86284A LU86284A1 (fr)	1986-01-30	1986-01-30	Procede d'obtention d'ethylene a partir d'ethanol

Country Status (7)

Country	Link
US (1)	US4727214A (de)
EP (1)	EP0231163B1 (de)
AT (1)	ATE52074T1 (de)
BR (1)	BR8700422A (de)
DE (1)	DE3762334D1 (de)
ES (1)	ES2014331B3 (de)
LU (1)	LU86284A1 (de)

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DE3840506A1 (de) *	1988-12-01	1990-06-07	Linde Ag	Verfahren und vorrichtung zur luftzerlegung
US20040225164A1 (en) *	2003-05-09	2004-11-11	Conocophillips Company	Method for treating ethane
US20060149109A1 (en) *	2004-12-30	2006-07-06	Ruziska Philip A	Converting methanol and ethanol to light olefins
EP1790627A1 (de) *	2005-11-29	2007-05-30	BP Chemicals Limited	Verfahren zur Herstellung von Olefinen
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EP1792886A1 (de) *	2005-11-29	2007-06-06	BP Chemicals Limited	Verfahren zur Herstellung von Propylen
CN101104576B (zh) *	2006-07-13	2010-08-25	中国石油化工股份有限公司	一种有机含氧化合物和烃类的联合催化转化方法
CN101104571B (zh) *	2006-07-13	2010-05-12	中国石油化工股份有限公司	一种联合烃类催化转化从乙醇生产乙烯的方法
EP2090561A1 (de)	2008-02-07	2009-08-19	Total Petrochemicals Research Feluy	Dehydrierung von Alkoholen auf kristallinen Silicaten
EP2108637A1 (de)	2008-04-11	2009-10-14	Total Petrochemicals Research Feluy	Verfahren zur Herstellung von Olefinen aus Ethanol
EP2108634A1 (de)	2008-04-11	2009-10-14	Total Petrochemicals Research Feluy	Dehydrierung von Alkoholen auf Kristallsilicaten
EP2108635A1 (de)	2008-04-11	2009-10-14	Total Petrochemicals Research Feluy	Verfahren zur Herstellung von Olefinen aus Ethanol
EP2108636A1 (de)	2008-04-11	2009-10-14	Total Petrochemicals Research Feluy	Alkoholdehydrierung in Gegenwart einer inerten Komponente
EP2192101A1 (de)	2008-11-28	2010-06-02	Total Petrochemicals Research Feluy	Reinigung von Alkohol vor der Verwendung bei Vorhandensein eines Säurekatalysators
EA020426B1 (ru)	2008-11-28	2014-11-28	Тотал Петрокемикалз Ресерч Фелюи	Очистка спиртов перед их применением в присутствии кислотного катализатора
CN101747136B (zh) *	2008-12-04	2013-09-25	焦作市河阳酒精实业有限公司	乙醇经催化脱水生产乙烯的工艺
US9139929B2 (en) *	2010-01-22	2015-09-22	Total Research & Technology Feluy	Dehydration of alcohols on a crystalline silicate of low Si/Al ratio
EP2348005A1 (de)	2010-01-22	2011-07-27	Total Petrochemicals Research Feluy	Dehydrierung von Alkoholen auf kristallinem Silikat einer FER-Struktur
EP2348006A1 (de)	2010-01-26	2011-07-27	Total Petrochemicals Research Feluy	Entwässerung von Alkoholen auf einem kristallinen Silikat mit niedrigem Si/Al-Verhältnis
FR2959749B1 (fr) *	2010-05-06	2012-06-01	Inst Francais Du Petrole	Procede flexible de transformation de l'ethanol en distillats moyens.
US20140039143A1 (en)	2010-12-17	2014-02-06	Total Research & Technology Feluy	Process for producing propylene from syngas via fermentative propanol production and dehydration
WO2012143564A1 (en)	2011-04-21	2012-10-26	Shell Internationale Research Maatschappij B.V.	Process for converting a solid biomass material
EP2699646A1 (de)	2011-04-21	2014-02-26	Shell Internationale Research Maatschappij B.V.	Verfahren zur regeneration eines verkokten katalysators für katalytisches cracken
CA2833085A1 (en)	2011-04-21	2012-10-26	Shell Internationale Research Maatschappij B.V.	Process for converting a solid biomass material
JP2014511937A (ja)	2011-04-21	2014-05-19	シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ	液体燃料組成物
CA2839399C (en)	2011-06-15	2021-03-23	Ut-Battelle, Llc	Zeolitic catalytic conversion of alcohols to hydrocarbons
SG11201400355TA (en) *	2011-09-07	2014-04-28	Shell Int Research	Process for preparing ethylene and propylene from a feedstock comprising a tert - alkyl ether
CN103796975A (zh)	2011-09-07	2014-05-14	国际壳牌研究有限公司	制备乙烯和丙烯的方法
EP2594547A1 (de)	2011-11-17	2013-05-22	Solvay Sa	Verfahren zur Herstellung von mindestens einer Ethylen-Derivat-Verbindung aus Bioethanol
US8697802B2 (en)	2011-11-28	2014-04-15	Celanese International Corporation	Process for producing polyvinyl alcohol or a copolymer thereof
EP2841536A1 (de)	2012-04-23	2015-03-04	Shell Internationale Research Maatschappij B.V.	Verfahren zur umwandlung eines festen biomassematerials
US9434658B2 (en)	2013-03-06	2016-09-06	Ut-Battelle, Llc	Catalytic conversion of alcohols to hydrocarbons with low benzene content
WO2015002922A1 (en)	2013-07-02	2015-01-08	Ut-Battelle, Llc	Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock
US10696606B2 (en)	2016-06-09	2020-06-30	Ut-Battelle, Llc	Zeolitic catalytic conversion of alcohols to hydrocarbon fractions with reduced gaseous hydrocarbon content
US11053181B2 (en)	2018-08-09	2021-07-06	Ut-Battelle, Llc	Zeolitic catalytic conversion of alcohols to olefins

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US3240697A (en) *	1964-12-17	1966-03-15	Socony Mobil Oil Co Inc	Catalytic conversion with activated catalyst
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CA1196031A (en) *	1982-02-05	1985-10-29	Wooyoung Lee	Process for converting alcohols into olefins
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US4638106A (en) *	1984-07-13	1987-01-20	Exxon Research & Engineering Co.	Two stage process for improving the catalyst life of zeolites in the synthesis of lower olefins from alcohols and their ether derivatives
LU85515A1 (fr) *	1984-08-28	1986-03-11	Belge Etat	Catalyseurs pour la transformation d'ethanol en ethylene et leur utilisation
US4547616A (en) *	1984-12-28	1985-10-15	Mobil Oil Corporation	Conversion of oxygenates to lower olefins in a turbulent fluidized catalyst bed

1986
- 1986-01-30 LU LU86284A patent/LU86284A1/fr unknown
1987
- 1987-01-29 ES ES87870013T patent/ES2014331B3/es not_active Expired - Lifetime
- 1987-01-29 DE DE8787870013T patent/DE3762334D1/de not_active Expired - Fee Related
- 1987-01-29 EP EP87870013A patent/EP0231163B1/de not_active Expired - Lifetime
- 1987-01-29 AT AT87870013T patent/ATE52074T1/de active
- 1987-01-30 BR BR8700422A patent/BR8700422A/pt unknown
- 1987-01-30 US US07/008,728 patent/US4727214A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
ATE52074T1 (de)	1990-05-15
DE3762334D1 (de)	1990-05-23
US4727214A (en)	1988-02-23
EP0231163B1 (de)	1990-04-18
EP0231163A1 (de)	1987-08-05
ES2014331B3 (es)	1990-07-01
BR8700422A (pt)	1987-12-15

Publication	Publication Date	Title
LU86284A1 (fr)	1987-09-03	Procede d'obtention d'ethylene a partir d'ethanol
EP0175399B1 (de)	1988-11-30	Verfahren zur Herstellung von Äthylen aus Äthanol
JPH03503741A (ja)	1991-08-22	飽和炭化水素鎖の酸化
JP2011511037A (ja)	2011-04-07	不活性成分の存在下でのアルコールの脱水
EP3378830B1 (de)	2019-10-16	Syntheseverfahren von izm-2-zeolith in gegenwart von 1,6-bis(methylpiperidinium)hexan dibromid als strukturbildner
CA1185227A (fr)	1985-04-09	Titanoborosilicate cristallin et procede de preparation
JPS6353126B2 (de)	1988-10-21
EP3378831B1 (de)	2019-10-16	Syntheseverfahren von izm-2-zeolith in gegenwart von 1,6-bis(methylpiperidinium)hexan dihydroxid als strukturbildner
CN102227397A (zh)	2011-10-26	醇在其使用前在酸性催化剂的存在下的纯化
LU83204A1 (fr)	1981-10-30	Procede pour la preparation de silicates d'aluminium ayant une structure du genre zeolite
FR2575741A1 (fr)	1986-07-11	Obtention d'une offretite synthetique riche en silice. application a la production d'hydrocarbures riches en olefines legeres par transformation du methanol et/ou de dimethylether
JPH06508640A (ja)	1994-09-29	オレフィンの製造方法
EP0443004B1 (de)	1994-02-16	Synthese von aluminosilikat-zeolithen mit faujasitstruktur
EP0595703A1 (de)	1994-05-04	Verfahren zur Synthese von Zeolithen, die zur strukturellen Familie des Faujasits gehören
FR2542301A1 (fr)	1984-09-14	Aluminosilicate cristallin perfectionne ou zeolithe perfectionnee ayant la structure de l'offretite
EP0436713B1 (de)	1993-03-17	Synthese von gallosilikat-zeolithen mit faujasitstruktur
FR2758810A1 (fr)	1998-07-31	Zeolithe im-5 desaluminee
FR2504510A1 (fr)	1982-10-29	Compositions cristallines synthetiques de silicate et de borosilicate metalliques, leur procede de preparation et leurs applications
EP0609112A1 (de)	1994-08-03	Katalysator aufgrund modifizierter MFI Zeolite und seine Verwendung für eine aromatische C8 Fraktion
FR2472538A1 (fr)	1981-07-03	Procede de production de zeolithes cristallines
RU2310638C2 (ru)	2007-11-20	Способ удаления высших углеводородов из природного газа
CA1197498A (fr)	1985-12-03	Ferroborosilicates cristallins et procedes de leur preparation
JP2022521509A5 (de)	2022-10-04
WO1994013583A1 (fr)	1994-06-23	Procede de synthese de zeolithes du type zsm-48
FR2463746A1 (fr)	1981-02-27	Catalyseur a base de silicate de chrome, son procede de production et son application au traitement d'hydrocarbures