MA27829A1 - Materiau rigidifiant s'utilisant dans la fabrication de chaussures et procede de production correspondant - Google Patents

Materiau rigidifiant s'utilisant dans la fabrication de chaussures et procede de production correspondant

Info

Publication number
MA27829A1
MA27829A1 MA28533A MA28533A MA27829A1 MA 27829 A1 MA27829 A1 MA 27829A1 MA 28533 A MA28533 A MA 28533A MA 28533 A MA28533 A MA 28533A MA 27829 A1 MA27829 A1 MA 27829A1
Authority
MA
Morocco
Prior art keywords
adhesive
production
filler
mvr
din
Prior art date
Application number
MA28533A
Other languages
English (en)
Inventor
Emil Wilding
Markus Fath
Stefan Frey
Original Assignee
Bk Giulini Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bk Giulini Gmbh filed Critical Bk Giulini Gmbh
Publication of MA27829A1 publication Critical patent/MA27829A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/42—Filling materials located between the insole and outer sole; Stiffening materials
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
    • A43B23/08—Heel stiffeners; Toe stiffeners
    • A43B23/081—Toe stiffeners
    • A43B23/086—Toe stiffeners made of impregnated fabrics, plastics or the like
    • A43B23/087—Toe stiffeners made of impregnated fabrics, plastics or the like made of plastics
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
    • A43B23/08—Heel stiffeners; Toe stiffeners
    • A43B23/16—Heel stiffeners; Toe stiffeners made of impregnated fabrics, plastics or the like
    • A43B23/17—Heel stiffeners; Toe stiffeners made of impregnated fabrics, plastics or the like made of plastics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/20—Compositions for hot melt adhesives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/90—Compositions for adhesives used in footwear
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/16—Solid spheres
    • C08K7/18—Solid spheres inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18—Spheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0853—Ethylene vinyl acetate copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/253—Cellulosic [e.g., wood, paper, cork, rayon, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

L'invention concerne un nouveau matériau rigidifiant thermoplastique s'utilisant dans la fabrication de chaussures et de parties de chaussures, ainsi qu'un procédé écophile permettant de le produire. Ledit matériau se présente sous forme de composite à base de colle thermofusible/de charge et se caractérise en ce qu'il comprend une ou plusieurs colles thermofusibles et dune ou de plusieurs charges, dans des quantités comprises entre 50 et 15 % en poids, ne se dissolvant pas dans la colle thermofusible. Le composite à base de colle thermofusible/ de charge satisfait simultanément aux paramètres suivants : 1. valeur MVR comprise entre 2 et 6, de préférence entre 3 et 5 cm3/10 mn ; 2. adhésivité superficielle/adhésivité, mesurées selon DIN EN 14610 à 65 o.C, d'au moins 10 n/2 cm, de préférence 15 N/2 cm, en particulier 20 N/2 cm ; 3. valeur adhérence/résistance pelabilité vis-à-vis tige et doublure, d'au moins 30 N/5 cm, mesurées selon DIN 53357 ; 4. extension en longueur de 25 % au maximum, de préférence inférieure à 20 %, mesurée à des températures de l'ordre de 90 o.C.
MA28533A 2003-04-11 2005-10-03 Materiau rigidifiant s'utilisant dans la fabrication de chaussures et procede de production correspondant MA27829A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10316617A DE10316617A1 (de) 2003-04-11 2003-04-11 Thermoplastisches Versteifungsmaterial für die Schuhherstellung und ein Verfahren für seine Herstellung

Publications (1)

Publication Number Publication Date
MA27829A1 true MA27829A1 (fr) 2006-04-03

Family

ID=33154157

Family Applications (1)

Application Number Title Priority Date Filing Date
MA28533A MA27829A1 (fr) 2003-04-11 2005-10-03 Materiau rigidifiant s'utilisant dans la fabrication de chaussures et procede de production correspondant

Country Status (26)

Country Link
US (1) US7786193B2 (fr)
EP (1) EP1525284B1 (fr)
JP (1) JP4838584B2 (fr)
KR (1) KR100919093B1 (fr)
CN (1) CN1328347C (fr)
AT (1) ATE364669T1 (fr)
AU (1) AU2004227055B2 (fr)
BR (1) BRPI0405227A (fr)
CA (1) CA2488119C (fr)
DE (2) DE10316617A1 (fr)
DK (1) DK1525284T3 (fr)
EA (1) EA008431B1 (fr)
ES (1) ES2289502T3 (fr)
GE (1) GEP20084288B (fr)
IL (1) IL171255A (fr)
MA (1) MA27829A1 (fr)
MX (1) MXPA05002866A (fr)
NO (1) NO332989B1 (fr)
NZ (1) NZ542771A (fr)
PL (1) PL1525284T3 (fr)
PT (1) PT1525284E (fr)
SI (1) SI1525284T1 (fr)
TN (1) TNSN05228A1 (fr)
UA (1) UA77334C2 (fr)
WO (1) WO2004090061A1 (fr)
ZA (1) ZA200409142B (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010511082A (ja) * 2006-11-29 2010-04-08 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン ホットメルト接着剤からの成形品
DE102006056660A1 (de) * 2006-11-29 2008-06-05 Henkel Kgaa Formteile aus Schmelzklebstoffen
DE102009020036A1 (de) * 2009-05-05 2010-11-11 Bk Giulini Gmbh Thermoplastische Versteifungsmaterialien
GB2474015B (en) * 2009-09-24 2012-07-04 Han-Ching Wu Method for manufacturing environmental protection insole
DE102010030437A1 (de) * 2010-06-23 2011-12-29 Henkel Ag & Co. Kgaa TPU-Kaschierklebstoff
DE102012013432B4 (de) 2012-07-05 2015-05-07 Bk Giulini Gmbh Füllstoffmischung und deren Verwendung für die Herstellung von thermoplastischen Schuhversteifungsmaterialien
CN104594065B (zh) * 2015-02-04 2017-03-22 安安(中国)有限公司 一种花布伦合成革的生产方法
CN104927381A (zh) * 2015-06-18 2015-09-23 福建师范大学泉港石化研究院 一种聚氨酯增韧pe木塑复合材料的制备方法
KR102244966B1 (ko) 2015-06-19 2021-04-28 현대모비스 주식회사 핫멜트 접착제 조성물의 제조방법 및, 이에 의해 제조된 핫멜트 접착제 조성물
DE102017002070A1 (de) 2017-03-06 2018-09-06 Rhenoflex Gmbh Kunststoffzusammensetzung zur Herstellung von Versteifungsmatherialien
CN108316022A (zh) * 2018-03-16 2018-07-24 安安(中国)有限公司 一种采用真空吸花技术的超纤贾卡的生产方法
DE102019200741A1 (de) * 2019-01-22 2020-07-23 Rhenoflex Gmbh Vorrichtung zur Herstellung von Versteifungselementen aus pulverförmigem Material
US12225968B2 (en) 2021-01-20 2025-02-18 Puma SE Article of footwear having a sole plate
USD1010297S1 (en) 2021-06-30 2024-01-09 Puma SE Shoe
WO2023118181A1 (fr) 2021-12-21 2023-06-29 Rhenoflex Gmbh Matériau de renforcement pour textiles

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3778251A (en) 1971-03-17 1973-12-11 Bixby Box Toe Co Inc Shoe stiffener materials
US4717496A (en) * 1984-12-03 1988-01-05 Giulini Chemie Gmbh Stiffening material with melt-adhesive properties
DE3633777C2 (de) * 1985-10-03 1996-08-22 Mitsubishi Gas Chemical Co Hot-melt-Kleberzusammensetzung
DE3539573A1 (de) * 1985-11-08 1987-05-14 Giulini Chemie Verfahren zur herstellung dreidimensionaler versteifungsteile aus schmelzbarem kunststoffpulver und aufbringen dieser teile auf substrate, insbesondere leder
US4939036A (en) * 1987-10-14 1990-07-03 Amoco Corporation Method for preparing tufted pile carpet and adhesive therefor
GB9216775D0 (en) 1992-08-07 1992-09-23 British United Shoe Machinery Orthopaedic splinting/casting material
US5525663A (en) * 1994-08-18 1996-06-11 Minnesota Mining And Manufacturing Company Reactive hot-melt adhesive and/or sealing composition and method of using same
US20040101643A1 (en) * 1996-11-26 2004-05-27 National Starch And Chemical Limited Adhesives containing FDA approved materials
US6391380B1 (en) * 2000-08-03 2002-05-21 Stanbee Company, Inc. Stiffener material with self adhesive properties

Also Published As

Publication number Publication date
UA77334C2 (en) 2006-11-15
EA200500380A1 (ru) 2006-04-28
NO332989B1 (no) 2013-02-11
IL171255A0 (en) 2009-02-11
SI1525284T1 (sl) 2007-10-31
MXPA05002866A (es) 2006-03-16
CA2488119C (fr) 2010-12-14
IL171255A (en) 2010-11-30
ZA200409142B (en) 2006-02-22
WO2004090061A1 (fr) 2004-10-21
NO20055241L (no) 2005-11-08
ES2289502T3 (es) 2008-02-01
CN1328347C (zh) 2007-07-25
EP1525284A1 (fr) 2005-04-27
DE502004004072D1 (de) 2007-07-26
DK1525284T3 (da) 2007-10-01
KR100919093B1 (ko) 2009-09-28
JP2006515895A (ja) 2006-06-08
CN1697867A (zh) 2005-11-16
EP1525284B1 (fr) 2007-06-13
TNSN05228A1 (en) 2007-06-11
US20060154047A1 (en) 2006-07-13
ATE364669T1 (de) 2007-07-15
AU2004227055A1 (en) 2004-10-21
GEP20084288B (en) 2008-01-10
AU2004227055B2 (en) 2008-04-03
JP4838584B2 (ja) 2011-12-14
BRPI0405227A (pt) 2005-03-15
PL1525284T3 (pl) 2007-10-31
PT1525284E (pt) 2007-08-08
US7786193B2 (en) 2010-08-31
KR20060024760A (ko) 2006-03-17
CA2488119A1 (fr) 2004-10-21
DE10316617A1 (de) 2004-11-11
EA008431B1 (ru) 2007-06-29
NZ542771A (en) 2009-03-31

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