MA53694B1 - Procédé de production de méthanol - Google Patents

Procédé de production de méthanol

Info

Publication number
MA53694B1
MA53694B1 MA53694A MA53694A MA53694B1 MA 53694 B1 MA53694 B1 MA 53694B1 MA 53694 A MA53694 A MA 53694A MA 53694 A MA53694 A MA 53694A MA 53694 B1 MA53694 B1 MA 53694B1
Authority
MA
Morocco
Prior art keywords
production process
methanol production
methanol
catalyst
converted
Prior art date
Application number
MA53694A
Other languages
English (en)
Other versions
MA53694A1 (fr
Inventor
Marek Pawel CHECINSKI
Matthias Beller
Pavel RYABCHUK
Kathrin Junge
Original Assignee
CreativeQuantum GmbH
Leibnitz-Institut für Katalyse e.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CreativeQuantum GmbH, Leibnitz-Institut für Katalyse e.V. filed Critical CreativeQuantum GmbH
Publication of MA53694A1 publication Critical patent/MA53694A1/fr
Publication of MA53694B1 publication Critical patent/MA53694B1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/04—Methanol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé de réaction catalysée de CO et de H2. Le catalyseur est un métal de transition en tant qu'ion central et au moins un ligand basique de Lewis. Conjointement avec au moins un promoteur nucléophile, CO et H2 sont convertis en méthanol en tant que produit.
MA53694A 2018-12-28 2019-12-10 Procédé de production de méthanol MA53694B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102018133689.6A DE102018133689A1 (de) 2018-12-28 2018-12-28 Verfahren zur Herstellung von Methanol
PCT/EP2019/084355 WO2020136003A1 (fr) 2018-12-28 2019-12-10 Procédé de production de méthanol

Publications (2)

Publication Number Publication Date
MA53694A1 MA53694A1 (fr) 2022-02-28
MA53694B1 true MA53694B1 (fr) 2024-06-28

Family

ID=68887026

Family Applications (1)

Application Number Title Priority Date Filing Date
MA53694A MA53694B1 (fr) 2018-12-28 2019-12-10 Procédé de production de méthanol

Country Status (13)

Country Link
US (1) US12071398B2 (fr)
EP (1) EP3902781A1 (fr)
JP (1) JP7518834B2 (fr)
KR (1) KR102824691B1 (fr)
CN (2) CN119219470A (fr)
AU (1) AU2019412710B2 (fr)
CA (1) CA3124740A1 (fr)
CL (1) CL2021001695A1 (fr)
DE (1) DE102018133689A1 (fr)
MA (1) MA53694B1 (fr)
MX (1) MX2021007712A (fr)
WO (1) WO2020136003A1 (fr)
ZA (1) ZA202104572B (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102021006375A1 (de) * 2021-12-28 2023-06-29 CreativeQuantum GmbH Verfahren zur kontinuierlichen Herstellung von Methanol
WO2023151775A1 (fr) * 2022-02-08 2023-08-17 Apex Energy Teterow Gmbh Procédé de stockage réversible d'hydrogène par l'intermédiaire de paires d'ions formiate d'acide aminé à l'aide d'hydrogénation de dioxyde de carbone
CN116212965B (zh) * 2022-12-12 2025-11-14 陕西榆能集团能源化工研究院有限公司 一种金属配体催化剂以及乳酸制备方法
EP4488254A1 (fr) 2023-07-05 2025-01-08 C1 Green Chemicals AG Procédé de production de méthanol
EP4686716A1 (fr) 2024-07-30 2026-02-04 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Procédé catalytique monotope pour la préparation d'alcools utilisant du méthanol comme source de monoxyde de carbone et d'hydrogène

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030158270A1 (en) * 2002-01-16 2003-08-21 Devinder Mahajan Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor

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CA1178608A (fr) 1981-09-30 1984-11-27 Bernard D. Dombek Procede de production d'alcools
US4421863A (en) * 1982-02-01 1983-12-20 Texaco Inc. Process for preparing low molecular weight oxygenated compounds from syngas using a novel catalyst system
JPS61204144A (ja) 1985-03-06 1986-09-10 Agency Of Ind Science & Technol 含酸素化合物の製造法
US4935395A (en) * 1986-12-19 1990-06-19 Associated Universities, Inc. Homogeneous catalyst formulations for methanol production
JP3553740B2 (ja) 1996-08-21 2004-08-11 財団法人石油産業活性化センター メタノールの製造方法
GB0311092D0 (en) * 2003-05-14 2003-06-18 Bp Chem Int Ltd Process
TWI473785B (zh) * 2007-06-01 2015-02-21 Bp Chem Int Ltd 使用金屬螯配位體催化劑用於醋酸之生產的羰基化方法
WO2013130972A1 (fr) 2012-03-02 2013-09-06 University Of Washington Through Its Center For Commercialization Procédés de conversion de polyols
CN103772142B (zh) * 2012-10-19 2018-04-27 中国科学院上海有机化学研究所 钌络合物及制备甲醇和二醇的方法
JP2017508722A (ja) * 2014-01-08 2017-03-30 ザ ガバニング カウンシル オブ ザ ユニバーシティ オブ トロントＴｈｅ Ｇｏｖｅｒｎｉｎｇ Ｃｏｕｎｃｉｌ Ｏｆ Ｔｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｔｏｒｏｎｔｏ 三座配位ｐｎｐリガンドを含む鉄（ｉｉ）触媒、その合成、およびその使用
WO2016038543A1 (fr) * 2014-09-11 2016-03-17 King Abdullah University Of Science And Technology Nouvelles imines dotées de propriétés de nucléophilicité et stériques réglables par coordination métallique : applications en tant que ligands et catalyseurs organométalliques
EP3256250B1 (fr) * 2015-02-10 2020-06-24 Council of Scientific and Industrial Research Complexes pinceurs à base de phénanthroline utiles comme catalyseurs pour la préparation de méthanol à partir de dioxyde de carbone
WO2017093782A1 (fr) * 2015-12-01 2017-06-08 Ecole Polytechnique Federale De Lausanne (Epfl) Procédé de production de méthanol à partir de dioxyde de carbone et d'hydrogène gazeux dans des réactions à catalyse homogène et dans un milieu aqueux
KR20190045355A (ko) * 2016-10-28 2019-05-02 미쯔비시 케미컬 주식회사 탄소섬유용 사이징제, 탄소섬유용 사이징제의 수분산액, 및 사이징제 부착 탄소섬유속
JP2021131926A (ja) * 2018-03-30 2021-09-09 株式会社村田製作所 二次電池

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030158270A1 (en) * 2002-01-16 2003-08-21 Devinder Mahajan Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor

Also Published As

Publication number Publication date
MX2021007712A (es) 2021-09-30
DE102018133689A1 (de) 2020-07-02
CN119219470A (zh) 2024-12-31
US12071398B2 (en) 2024-08-27
ZA202104572B (en) 2025-09-25
WO2020136003A1 (fr) 2020-07-02
AU2019412710A1 (en) 2021-07-15
KR20210109588A (ko) 2021-09-06
JP2022516271A (ja) 2022-02-25
JP7518834B2 (ja) 2024-07-18
MA53694A1 (fr) 2022-02-28
EP3902781A1 (fr) 2021-11-03
BR112021012618A2 (pt) 2021-09-08
CA3124740A1 (fr) 2020-07-02
US20220048839A1 (en) 2022-02-17
CN113825737A (zh) 2021-12-21
CN113825737B (zh) 2024-10-01
CL2021001695A1 (es) 2022-02-11
KR102824691B1 (ko) 2025-06-24
AU2019412710B2 (en) 2024-11-21

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