MX2021007712A - Proceso para la produccion de metanol. - Google Patents

Proceso para la produccion de metanol.

Info

Publication number
MX2021007712A
MX2021007712A MX2021007712A MX2021007712A MX2021007712A MX 2021007712 A MX2021007712 A MX 2021007712A MX 2021007712 A MX2021007712 A MX 2021007712A MX 2021007712 A MX2021007712 A MX 2021007712A MX 2021007712 A MX2021007712 A MX 2021007712A
Authority
MX
Mexico
Prior art keywords
methanol
production
catalyst
converted
directed
Prior art date
Application number
MX2021007712A
Other languages
English (en)
Inventor
Matthias Beller
Kathrin Junge
Marek Pawel Checinski
Pavel Ryabchuk
Original Assignee
CreativeQuantum GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CreativeQuantum GmbH filed Critical CreativeQuantum GmbH
Publication of MX2021007712A publication Critical patent/MX2021007712A/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02Monohydroxylic acyclic alcohols
    • C07C31/04Methanol
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/62Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0244Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/842Iron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32Manganese, technetium or rhenium
    • C07C2523/34Manganese
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La invención está dirigida a un proceso para la reacción catalizada de CO y H2. El catalizador es un metal de transición como ion central y, cuando menos, un ligando de base de Lewis. Conjuntamente con, al menos, un promotor nucleofílico se convierten CO y H2 a metanol como producto.
MX2021007712A 2018-12-28 2019-12-10 Proceso para la produccion de metanol. MX2021007712A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102018133689.6A DE102018133689A1 (de) 2018-12-28 2018-12-28 Verfahren zur Herstellung von Methanol
PCT/EP2019/084355 WO2020136003A1 (en) 2018-12-28 2019-12-10 Process for producing methanol

Publications (1)

Publication Number Publication Date
MX2021007712A true MX2021007712A (es) 2021-09-30

Family

ID=68887026

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2021007712A MX2021007712A (es) 2018-12-28 2019-12-10 Proceso para la produccion de metanol.

Country Status (13)

Country Link
US (1) US12071398B2 (es)
EP (1) EP3902781A1 (es)
JP (1) JP7518834B2 (es)
KR (1) KR102824691B1 (es)
CN (2) CN119219470A (es)
AU (1) AU2019412710B2 (es)
CA (1) CA3124740A1 (es)
CL (1) CL2021001695A1 (es)
DE (1) DE102018133689A1 (es)
MA (1) MA53694B1 (es)
MX (1) MX2021007712A (es)
WO (1) WO2020136003A1 (es)
ZA (1) ZA202104572B (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102021006375A1 (de) * 2021-12-28 2023-06-29 CreativeQuantum GmbH Verfahren zur kontinuierlichen Herstellung von Methanol
WO2023151775A1 (en) * 2022-02-08 2023-08-17 Apex Energy Teterow Gmbh A process for reversible hydrogen storage via amino acid formate ion pairs by hydrogenation of carbon dioxide
CN116212965B (zh) * 2022-12-12 2025-11-14 陕西榆能集团能源化工研究院有限公司 一种金属配体催化剂以及乳酸制备方法
EP4488254A1 (en) 2023-07-05 2025-01-08 C1 Green Chemicals AG Process for producing methanol
EP4686716A1 (en) 2024-07-30 2026-02-04 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. One-pot catalytic process for the preparation of alcohols using methanol as source for carbon monoxide and hydrogen

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1178608A (en) 1981-09-30 1984-11-27 Bernard D. Dombek Process for producing alcohols
US4421863A (en) * 1982-02-01 1983-12-20 Texaco Inc. Process for preparing low molecular weight oxygenated compounds from syngas using a novel catalyst system
JPS61204144A (ja) 1985-03-06 1986-09-10 Agency Of Ind Science & Technol 含酸素化合物の製造法
US4935395A (en) * 1986-12-19 1990-06-19 Associated Universities, Inc. Homogeneous catalyst formulations for methanol production
JP3553740B2 (ja) 1996-08-21 2004-08-11 財団法人石油産業活性化センター メタノールの製造方法
US6921733B2 (en) * 2002-01-16 2005-07-26 Brookhaven Science Associates, Llc Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor
GB0311092D0 (en) * 2003-05-14 2003-06-18 Bp Chem Int Ltd Process
TWI473785B (zh) * 2007-06-01 2015-02-21 Bp Chem Int Ltd 使用金屬螯配位體催化劑用於醋酸之生產的羰基化方法
WO2013130972A1 (en) 2012-03-02 2013-09-06 University Of Washington Through Its Center For Commercialization Methods of converting polyols
CN103772142B (zh) * 2012-10-19 2018-04-27 中国科学院上海有机化学研究所 钌络合物及制备甲醇和二醇的方法
JP2017508722A (ja) * 2014-01-08 2017-03-30 ザ ガバニング カウンシル オブ ザ ユニバーシティ オブ トロントThe Governing Council Of The University Of Toronto 三座配位pnpリガンドを含む鉄(ii)触媒、その合成、およびその使用
WO2016038543A1 (en) * 2014-09-11 2016-03-17 King Abdullah University Of Science And Technology Novel imines with tunable nucleophilicity and steric properties through metal coordination: applications as ligands and metalloorganocatalysts
EP3256250B1 (en) * 2015-02-10 2020-06-24 Council of Scientific and Industrial Research Phenanthroline based pincer complexes useful as catalysts for the preparation of methanol from carbondioxide
WO2017093782A1 (en) * 2015-12-01 2017-06-08 Ecole Polytechnique Federale De Lausanne (Epfl) Method for producing methanol from carbon dioxide and hydrogen gas in homogeneously catalyzed reactions and in an aqueous medium
KR20190045355A (ko) * 2016-10-28 2019-05-02 미쯔비시 케미컬 주식회사 탄소섬유용 사이징제, 탄소섬유용 사이징제의 수분산액, 및 사이징제 부착 탄소섬유속
JP2021131926A (ja) * 2018-03-30 2021-09-09 株式会社村田製作所 二次電池

Also Published As

Publication number Publication date
DE102018133689A1 (de) 2020-07-02
CN119219470A (zh) 2024-12-31
US12071398B2 (en) 2024-08-27
ZA202104572B (en) 2025-09-25
WO2020136003A1 (en) 2020-07-02
AU2019412710A1 (en) 2021-07-15
MA53694B1 (fr) 2024-06-28
KR20210109588A (ko) 2021-09-06
JP2022516271A (ja) 2022-02-25
JP7518834B2 (ja) 2024-07-18
MA53694A1 (fr) 2022-02-28
EP3902781A1 (en) 2021-11-03
BR112021012618A2 (pt) 2021-09-08
CA3124740A1 (en) 2020-07-02
US20220048839A1 (en) 2022-02-17
CN113825737A (zh) 2021-12-21
CN113825737B (zh) 2024-10-01
CL2021001695A1 (es) 2022-02-11
KR102824691B1 (ko) 2025-06-24
AU2019412710B2 (en) 2024-11-21

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