MX2021007712A - Proceso para la produccion de metanol. - Google Patents
Proceso para la produccion de metanol.Info
- Publication number
- MX2021007712A MX2021007712A MX2021007712A MX2021007712A MX2021007712A MX 2021007712 A MX2021007712 A MX 2021007712A MX 2021007712 A MX2021007712 A MX 2021007712A MX 2021007712 A MX2021007712 A MX 2021007712A MX 2021007712 A MX2021007712 A MX 2021007712A
- Authority
- MX
- Mexico
- Prior art keywords
- methanol
- production
- catalyst
- converted
- directed
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- 239000002879 Lewis base Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 150000007527 lewis bases Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 230000000269 nucleophilic effect Effects 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/04—Methanol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/34—Manganese
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención está dirigida a un proceso para la reacción catalizada de CO y H2. El catalizador es un metal de transición como ion central y, cuando menos, un ligando de base de Lewis. Conjuntamente con, al menos, un promotor nucleofílico se convierten CO y H2 a metanol como producto.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102018133689.6A DE102018133689A1 (de) | 2018-12-28 | 2018-12-28 | Verfahren zur Herstellung von Methanol |
| PCT/EP2019/084355 WO2020136003A1 (en) | 2018-12-28 | 2019-12-10 | Process for producing methanol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2021007712A true MX2021007712A (es) | 2021-09-30 |
Family
ID=68887026
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2021007712A MX2021007712A (es) | 2018-12-28 | 2019-12-10 | Proceso para la produccion de metanol. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US12071398B2 (es) |
| EP (1) | EP3902781A1 (es) |
| JP (1) | JP7518834B2 (es) |
| KR (1) | KR102824691B1 (es) |
| CN (2) | CN119219470A (es) |
| AU (1) | AU2019412710B2 (es) |
| CA (1) | CA3124740A1 (es) |
| CL (1) | CL2021001695A1 (es) |
| DE (1) | DE102018133689A1 (es) |
| MA (1) | MA53694B1 (es) |
| MX (1) | MX2021007712A (es) |
| WO (1) | WO2020136003A1 (es) |
| ZA (1) | ZA202104572B (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102021006375A1 (de) * | 2021-12-28 | 2023-06-29 | CreativeQuantum GmbH | Verfahren zur kontinuierlichen Herstellung von Methanol |
| WO2023151775A1 (en) * | 2022-02-08 | 2023-08-17 | Apex Energy Teterow Gmbh | A process for reversible hydrogen storage via amino acid formate ion pairs by hydrogenation of carbon dioxide |
| CN116212965B (zh) * | 2022-12-12 | 2025-11-14 | 陕西榆能集团能源化工研究院有限公司 | 一种金属配体催化剂以及乳酸制备方法 |
| EP4488254A1 (en) | 2023-07-05 | 2025-01-08 | C1 Green Chemicals AG | Process for producing methanol |
| EP4686716A1 (en) | 2024-07-30 | 2026-02-04 | Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. | One-pot catalytic process for the preparation of alcohols using methanol as source for carbon monoxide and hydrogen |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1178608A (en) | 1981-09-30 | 1984-11-27 | Bernard D. Dombek | Process for producing alcohols |
| US4421863A (en) * | 1982-02-01 | 1983-12-20 | Texaco Inc. | Process for preparing low molecular weight oxygenated compounds from syngas using a novel catalyst system |
| JPS61204144A (ja) | 1985-03-06 | 1986-09-10 | Agency Of Ind Science & Technol | 含酸素化合物の製造法 |
| US4935395A (en) * | 1986-12-19 | 1990-06-19 | Associated Universities, Inc. | Homogeneous catalyst formulations for methanol production |
| JP3553740B2 (ja) | 1996-08-21 | 2004-08-11 | 財団法人石油産業活性化センター | メタノールの製造方法 |
| US6921733B2 (en) * | 2002-01-16 | 2005-07-26 | Brookhaven Science Associates, Llc | Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor |
| GB0311092D0 (en) * | 2003-05-14 | 2003-06-18 | Bp Chem Int Ltd | Process |
| TWI473785B (zh) * | 2007-06-01 | 2015-02-21 | Bp Chem Int Ltd | 使用金屬螯配位體催化劑用於醋酸之生產的羰基化方法 |
| WO2013130972A1 (en) | 2012-03-02 | 2013-09-06 | University Of Washington Through Its Center For Commercialization | Methods of converting polyols |
| CN103772142B (zh) * | 2012-10-19 | 2018-04-27 | 中国科学院上海有机化学研究所 | 钌络合物及制备甲醇和二醇的方法 |
| JP2017508722A (ja) * | 2014-01-08 | 2017-03-30 | ザ ガバニング カウンシル オブ ザ ユニバーシティ オブ トロントThe Governing Council Of The University Of Toronto | 三座配位pnpリガンドを含む鉄(ii)触媒、その合成、およびその使用 |
| WO2016038543A1 (en) * | 2014-09-11 | 2016-03-17 | King Abdullah University Of Science And Technology | Novel imines with tunable nucleophilicity and steric properties through metal coordination: applications as ligands and metalloorganocatalysts |
| EP3256250B1 (en) * | 2015-02-10 | 2020-06-24 | Council of Scientific and Industrial Research | Phenanthroline based pincer complexes useful as catalysts for the preparation of methanol from carbondioxide |
| WO2017093782A1 (en) * | 2015-12-01 | 2017-06-08 | Ecole Polytechnique Federale De Lausanne (Epfl) | Method for producing methanol from carbon dioxide and hydrogen gas in homogeneously catalyzed reactions and in an aqueous medium |
| KR20190045355A (ko) * | 2016-10-28 | 2019-05-02 | 미쯔비시 케미컬 주식회사 | 탄소섬유용 사이징제, 탄소섬유용 사이징제의 수분산액, 및 사이징제 부착 탄소섬유속 |
| JP2021131926A (ja) * | 2018-03-30 | 2021-09-09 | 株式会社村田製作所 | 二次電池 |
-
2018
- 2018-12-28 DE DE102018133689.6A patent/DE102018133689A1/de active Pending
-
2019
- 2019-12-10 CA CA3124740A patent/CA3124740A1/en active Pending
- 2019-12-10 KR KR1020217023957A patent/KR102824691B1/ko active Active
- 2019-12-10 CN CN202411338790.4A patent/CN119219470A/zh active Pending
- 2019-12-10 WO PCT/EP2019/084355 patent/WO2020136003A1/en not_active Ceased
- 2019-12-10 JP JP2021538403A patent/JP7518834B2/ja active Active
- 2019-12-10 EP EP19820714.4A patent/EP3902781A1/en active Pending
- 2019-12-10 MA MA53694A patent/MA53694B1/fr unknown
- 2019-12-10 US US17/418,262 patent/US12071398B2/en active Active
- 2019-12-10 MX MX2021007712A patent/MX2021007712A/es unknown
- 2019-12-10 AU AU2019412710A patent/AU2019412710B2/en active Active
- 2019-12-10 CN CN201980086710.1A patent/CN113825737B/zh active Active
-
2021
- 2021-06-24 CL CL2021001695A patent/CL2021001695A1/es unknown
- 2021-06-30 ZA ZA2021/04572A patent/ZA202104572B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE102018133689A1 (de) | 2020-07-02 |
| CN119219470A (zh) | 2024-12-31 |
| US12071398B2 (en) | 2024-08-27 |
| ZA202104572B (en) | 2025-09-25 |
| WO2020136003A1 (en) | 2020-07-02 |
| AU2019412710A1 (en) | 2021-07-15 |
| MA53694B1 (fr) | 2024-06-28 |
| KR20210109588A (ko) | 2021-09-06 |
| JP2022516271A (ja) | 2022-02-25 |
| JP7518834B2 (ja) | 2024-07-18 |
| MA53694A1 (fr) | 2022-02-28 |
| EP3902781A1 (en) | 2021-11-03 |
| BR112021012618A2 (pt) | 2021-09-08 |
| CA3124740A1 (en) | 2020-07-02 |
| US20220048839A1 (en) | 2022-02-17 |
| CN113825737A (zh) | 2021-12-21 |
| CN113825737B (zh) | 2024-10-01 |
| CL2021001695A1 (es) | 2022-02-11 |
| KR102824691B1 (ko) | 2025-06-24 |
| AU2019412710B2 (en) | 2024-11-21 |
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