MY103242A - Process for separating rare earths by liquid-liquid extraction - Google Patents

Process for separating rare earths by liquid-liquid extraction

Info

Publication number
MY103242A
MY103242A MYPI88000293A MYPI19880293A MY103242A MY 103242 A MY103242 A MY 103242A MY PI88000293 A MYPI88000293 A MY PI88000293A MY PI19880293 A MYPI19880293 A MY PI19880293A MY 103242 A MY103242 A MY 103242A
Authority
MY
Malaysia
Prior art keywords
earths
rare
liquid
extraction
rare earths
Prior art date
Application number
MYPI88000293A
Inventor
Sabot Jean-Louis
Delloye Thierry
Original Assignee
Rhone Poulenc Chimie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Chimie filed Critical Rhone Poulenc Chimie
Publication of MY103242A publication Critical patent/MY103242A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/382Phosphine chalcogenides, e.g. compounds of the formula R3P=X with X = O, S, Se or Te
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B59/00Obtaining rare earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00Compounds of rare earth metals
    • C01F17/10Preparation or treatment, e.g. separation or purification
    • C01F17/17Preparation or treatment, e.g. separation or purification involving a liquid-liquid extraction
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/387Cyclic or polycyclic compounds
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/40Mixtures
    • C22B3/408Mixtures using a mixture of phosphorus-based acid derivatives of different types
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)

Abstract

RARE-EARTHS CONTAINED IN AN AQUEOUS SOLUTION CONTAINING AT LEAST TWO RARE-EARTHS ARE SEPARATED BY LIQUID-LIQUID EXTRACTION BETWEEN AN AQUEOUS PHASE CONTAINING NITRATES OF THE RARE-EARTHS TO BE SEPARATED AND AN ORGANIC PHASE CONTAINING AN EXTRACTION AGENT COMPRISING AN ORGANOPHOSPHORUS COMPOUND CORRESPONDING TO THE FORMULA (I); IN WHICH EACH OF R1, R2 AND R3 REPRESENTS A HYDROGEN ATOM OR A SUBSTITUTED OR UNSUBSTITUTED, LINEAR, BRANCHED OR CYCLIC, SATURATED OR UNSATURATED HYDROCARBON RADICAL; THE SUM OF THE NUMBER OF CARBON ATOMS IN RADICALS R1, R2 AND R3 IS AT LEAST 12, AND AT LEAST TWO OF THE RADICALS R1, R2 AND R3 ARE DIFFERENT. THE PROCESS IS PARTICULARLY SUITABLE FOR SEPARATING YTTRIUM FROM OTHER YTTRIC RARE-EARTHS. IT CAN ALSO BE APPLIED TO THE SEPARATION OF TWO SUB-GROUPS OF RARE-EARTHS.
MYPI88000293A 1987-03-23 1988-03-22 Process for separating rare earths by liquid-liquid extraction MY103242A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8703959A FR2612911B1 (en) 1987-03-23 1987-03-23 PROCESS FOR SEPARATING RARE EARTH BY LIQUID-LIQUID EXTRACTION

Publications (1)

Publication Number Publication Date
MY103242A true MY103242A (en) 1993-05-29

Family

ID=9349288

Family Applications (2)

Application Number Title Priority Date Filing Date
MYPI88000293A MY103242A (en) 1987-03-23 1988-03-22 Process for separating rare earths by liquid-liquid extraction
MYPI88000294A MY103243A (en) 1987-03-23 1988-03-22 Process for separating rare earths by liquid-liquid extraction

Family Applications After (1)

Application Number Title Priority Date Filing Date
MYPI88000294A MY103243A (en) 1987-03-23 1988-03-22 Process for separating rare earths by liquid-liquid extraction

Country Status (14)

Country Link
EP (2) EP0284504B1 (en)
JP (2) JPH0761865B2 (en)
KR (1) KR920000536B1 (en)
CN (2) CN88101566A (en)
AT (2) ATE77413T1 (en)
AU (2) AU601270B2 (en)
BR (2) BR8801283A (en)
CA (2) CA1309595C (en)
DE (2) DE3872014T2 (en)
FI (1) FI881367L (en)
FR (1) FR2612911B1 (en)
MY (2) MY103242A (en)
NO (2) NO881237L (en)
ZA (2) ZA882060B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2627478B1 (en) * 1988-02-19 1991-02-15 Rhone Poulenc Chimie PROCESS FOR THE TREATMENT OF RESIDUES CONTAINING RARE EARTH AND COBALT
FR2643911B1 (en) * 1989-03-03 1992-06-12 Rhone Poulenc Chimie PROCESS FOR TREATING RARE EARTH ORES
CN1045626C (en) * 1994-11-30 1999-10-13 中国科学院上海有机化学研究所 Method for extracting and separating yttrium with neutral phosphorus type extractant
CN103441330A (en) * 2013-08-06 2013-12-11 华为终端有限公司 Wireless communication equipment
JP5684885B1 (en) * 2013-08-12 2015-03-18 国立大学法人九州大学 Rare earth extractant and rare earth extraction method
FR3035880B1 (en) * 2015-05-07 2017-06-02 Commissariat Energie Atomique USE OF NOVEL COMPOUNDS FOR THE SELECTIVE EXTRACTION OF RARE EARTHS FROM AQUEOUS SOLUTIONS COMPRISING PHOSPHORIC ACID AND METHOD OF EXTRACTING THE SAME
US9968887B2 (en) * 2015-05-29 2018-05-15 Ut-Battelle, Llc Membrane assisted solvent extraction for rare earth element recovery
JP6576817B2 (en) * 2015-12-21 2019-09-18 三菱マテリアルテクノ株式会社 Separation method of rare earth elements
JP6775966B2 (en) * 2016-02-24 2020-10-28 持田 裕美 Rare earth element separation method
FR3055906B1 (en) * 2016-09-15 2018-09-28 Commissariat A L'energie Atomique Et Aux Energies Alternatives NOVEL EXTRACTOR USEFUL FOR EXTRACTING RARE EARTHS FROM AQUEOUS PHOSPHORIC ACID SOLUTION, AND APPLICATIONS THEREOF
CN114737056B (en) * 2021-01-08 2023-11-03 厦门稀土材料研究所 An organic extractant and its method and application for recovering metal elements
CN113584327B (en) * 2021-06-28 2022-10-28 中国恩菲工程技术有限公司 Method for purifying scandium oxide

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2515630B1 (en) * 1981-10-30 1985-10-04 Rhone Poulenc Spec Chim PROCESS FOR EXTRACTING AND SEPARATING URANIUM, THORIUM AND RARE EARTHS BY TREATING AQUEOUS CHLORIDE SOLUTIONS THEREOF
FR2562059B1 (en) * 1984-04-02 1989-12-01 Rhone Poulenc Spec Chim PROCESS FOR SEPARATING RARE EARTH BY LIQUID-LIQUID EXTRACTION
JPS61281833A (en) * 1985-06-08 1986-12-12 Seitetsu Kagaku Co Ltd Purifying method for cerium

Also Published As

Publication number Publication date
EP0284504A1 (en) 1988-09-28
AU609100B2 (en) 1991-04-26
NO881237D0 (en) 1988-03-21
ZA882063B (en) 1988-09-14
JPH0761865B2 (en) 1995-07-05
CN88101564A (en) 1988-11-02
NO881236D0 (en) 1988-03-21
FI881367A7 (en) 1988-09-24
AU1338888A (en) 1988-09-22
KR920000536B1 (en) 1992-01-16
JPH0755825B2 (en) 1995-06-14
DE3872013T2 (en) 1993-02-04
CA1309595C (en) 1992-11-03
ATE77414T1 (en) 1992-07-15
NO881237L (en) 1988-09-26
JPS6414113A (en) 1989-01-18
AU601270B2 (en) 1990-09-06
EP0284503B1 (en) 1992-06-17
CN88101566A (en) 1988-10-26
FI881367L (en) 1988-09-24
DE3872014D1 (en) 1992-07-23
AU1338788A (en) 1988-09-22
DE3872013D1 (en) 1992-07-23
JPS6428217A (en) 1989-01-30
NO881236L (en) 1988-12-22
KR880010804A (en) 1988-10-24
MY103243A (en) 1993-05-29
ATE77413T1 (en) 1992-07-15
DE3872014T2 (en) 1993-02-04
BR8801284A (en) 1988-10-25
EP0284504B1 (en) 1992-06-17
CA1309596C (en) 1992-11-03
ZA882060B (en) 1988-09-14
BR8801283A (en) 1988-10-25
FI881367A0 (en) 1988-03-22
FR2612911B1 (en) 1991-04-05
FR2612911A1 (en) 1988-09-30
EP0284503A1 (en) 1988-09-28

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