NL1010385C2 - Bereiding van een copolyetherester. - Google Patents

Bereiding van een copolyetherester. Download PDF

Info

Publication number: NL1010385C2
Authority: NL; Netherlands
Prior art keywords: copolyether ester; glycol; copolyether; oxide glycol; ester
Prior art date: 1998-10-23

Application number

NL1010385A

Other languages

English (en)

Dutch (nl)

Inventor

Geert Imelda Valere Bonte

Gerard Hidde Werumeus Buning

Krijn Dijkstra

Jean Marie Martinus Warnier

Original Assignee

Dsm Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-10-23

Filing date

1998-10-23

Publication date

2000-04-26

1998-10-23 Application filed by Dsm Nv filed Critical Dsm Nv

1998-10-23 Priority to NL1010385A priority Critical patent/NL1010385C2/nl

1999-10-13 Priority to TW088117710A priority patent/TWI232226B/zh

1999-10-18 Priority to EP99951254A priority patent/EP1141076B1/de

1999-10-18 Priority to ES99951254T priority patent/ES2215405T3/es

1999-10-18 Priority to CN99814698A priority patent/CN1131258C/zh

1999-10-18 Priority to KR1020017005089A priority patent/KR100567123B1/ko

1999-10-18 Priority to JP2000578368A priority patent/JP4768126B2/ja

1999-10-18 Priority to PCT/NL1999/000647 priority patent/WO2000024803A1/en

1999-10-18 Priority to AT99951254T priority patent/ATE258566T1/de

1999-10-18 Priority to DE69914508T priority patent/DE69914508T2/de

1999-10-18 Priority to AU63723/99A priority patent/AU6372399A/en

1999-10-18 Priority to CA002349583A priority patent/CA2349583C/en

2000-04-26 Application granted granted Critical

2000-04-26 Publication of NL1010385C2 publication Critical patent/NL1010385C2/nl

2001-04-23 Priority to US09/839,575 priority patent/US6441125B2/en

Links

150000002148 esters Chemical class 0.000 title claims abstract description 54
238000002360 preparation method Methods 0.000 title claims abstract description 13
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 75
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 40
238000000034 method Methods 0.000 claims abstract description 30
239000010936 titanium Substances 0.000 claims abstract description 28
-1 alkylene glycol Chemical compound 0.000 claims abstract description 20
229910052751 metal Inorganic materials 0.000 claims abstract description 19
239000002184 metal Substances 0.000 claims abstract description 19
229920000233 poly(alkylene oxides) Polymers 0.000 claims abstract description 17
229910052719 titanium Inorganic materials 0.000 claims abstract description 16
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 15
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
239000003054 catalyst Substances 0.000 claims abstract description 15
150000001875 compounds Chemical class 0.000 claims abstract description 14
125000003118 aryl group Chemical group 0.000 claims abstract description 13
238000009833 condensation Methods 0.000 claims abstract description 10
229920000728 polyester Polymers 0.000 claims abstract description 5
238000006116 polymerization reaction Methods 0.000 claims abstract description 5
230000005494 condensation Effects 0.000 claims abstract description 3
239000011777 magnesium Substances 0.000 claims description 14
229910052749 magnesium Inorganic materials 0.000 claims description 5
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 3
UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 3
229940069446 magnesium acetate Drugs 0.000 claims description 3
235000011285 magnesium acetate Nutrition 0.000 claims description 3
239000011654 magnesium acetate Substances 0.000 claims description 3
238000011835 investigation Methods 0.000 claims 2
239000003795 chemical substances by application Substances 0.000 claims 1
239000000047 product Substances 0.000 claims 1
239000013589 supplement Substances 0.000 claims 1
238000006068 polycondensation reaction Methods 0.000 abstract description 25
239000007790 solid phase Substances 0.000 abstract description 10
229920001451 polypropylene glycol Polymers 0.000 abstract description 9
239000000155 melt Substances 0.000 abstract description 8
238000004904 shortening Methods 0.000 abstract 1
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 18
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
238000002474 experimental method Methods 0.000 description 12
230000000052 comparative effect Effects 0.000 description 10
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 10
WOZVHXUHUFLZGK-UHFFFAOYSA-N terephthalic acid dimethyl ester Natural products COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 9
238000005809 transesterification reaction Methods 0.000 description 9
230000000694 effects Effects 0.000 description 7
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 5
239000008187 granular material Substances 0.000 description 5
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 4
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
238000000071 blow moulding Methods 0.000 description 3
239000006085 branching agent Substances 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
150000002009 diols Chemical class 0.000 description 3
239000011521 glass Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
DUGOZIWVEXMGBE-CHWSQXEVSA-N dexmethylphenidate Chemical compound C([C@@H]1[C@H](C(=O)OC)C=2C=CC=CC=2)CCCN1 DUGOZIWVEXMGBE-CHWSQXEVSA-N 0.000 description 2
230000032050 esterification Effects 0.000 description 2
238000005886 esterification reaction Methods 0.000 description 2
KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
229920001748 polybutylene Polymers 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
150000003609 titanium compounds Chemical class 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
JWZZKOKVBUJMES-UHFFFAOYSA-N (+-)-Isoprenaline Chemical compound CC(C)NCC(O)C1=CC=C(O)C(O)=C1 JWZZKOKVBUJMES-UHFFFAOYSA-N 0.000 description 1
WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 description 1
XKYZDQDNUKQLNY-UHFFFAOYSA-N 3,3-dihydroxypentanedioic acid Chemical compound OC(=O)CC(O)(O)CC(O)=O XKYZDQDNUKQLNY-UHFFFAOYSA-N 0.000 description 1
NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
229920001634 Copolyester Polymers 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
NIDZWWNRMZPMLN-UHFFFAOYSA-N [1,4,4-tris(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCC(CO)(CO)CC1 NIDZWWNRMZPMLN-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
239000001639 calcium acetate Substances 0.000 description 1
235000011092 calcium acetate Nutrition 0.000 description 1
229960005147 calcium acetate Drugs 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
238000001035 drying Methods 0.000 description 1
XWENCHGJOCJZQO-UHFFFAOYSA-N ethane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C(C(O)=O)C(C(O)=O)C(O)=O XWENCHGJOCJZQO-UHFFFAOYSA-N 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229940097364 magnesium acetate tetrahydrate Drugs 0.000 description 1
XKPKPGCRSHFTKM-UHFFFAOYSA-L magnesium;diacetate;tetrahydrate Chemical compound O.O.O.O.[Mg+2].CC([O-])=O.CC([O-])=O XKPKPGCRSHFTKM-UHFFFAOYSA-L 0.000 description 1
239000000463 material Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000000203 mixture Substances 0.000 description 1
ABMFBCRYHDZLRD-UHFFFAOYSA-N naphthalene-1,4-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1 ABMFBCRYHDZLRD-UHFFFAOYSA-N 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
229920001983 poloxamer Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
230000008092 positive effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyesters Or Polycarbonates (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Medicinal Preparation (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

NL1010385A 1998-10-23 1998-10-23 Bereiding van een copolyetherester. NL1010385C2 (nl)

Priority Applications (13)

Application Number	Priority Date	Filing Date	Title
NL1010385A NL1010385C2 (nl)	1998-10-23	1998-10-23	Bereiding van een copolyetherester.
TW088117710A TWI232226B (en)	1998-10-23	1999-10-13	Preparation of a copolyether ester
ES99951254T ES2215405T3 (es)	1998-10-23	1999-10-18	Preparacion de un copoli(eter ester).
CN99814698A CN1131258C (zh)	1998-10-23	1999-10-18	共聚多醚酯的制备
KR1020017005089A KR100567123B1 (ko)	1998-10-23	1999-10-18	코폴리에테르 에스테르의 제조방법
JP2000578368A JP4768126B2 (ja)	1998-10-23	1999-10-18	コポリエーテルエステルの製造法
EP99951254A EP1141076B1 (de)	1998-10-23	1999-10-18	Herstellung von copolyätherestern
PCT/NL1999/000647 WO2000024803A1 (en)	1998-10-23	1999-10-18	Preparation of a copolyether ester
AT99951254T ATE258566T1 (de)	1998-10-23	1999-10-18	Herstellung von copolyätherestern
DE69914508T DE69914508T2 (de)	1998-10-23	1999-10-18	Herstellung von copolyätherestern
AU63723/99A AU6372399A (en)	1998-10-23	1999-10-18	Preparation of a copolyether ester
CA002349583A CA2349583C (en)	1998-10-23	1999-10-18	Preparation of a copolyether ester
US09/839,575 US6441125B2 (en)	1998-10-23	2001-04-23	Preparation of a copolyether ester

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL1010385A NL1010385C2 (nl)	1998-10-23	1998-10-23	Bereiding van een copolyetherester.
NL1010385		1998-10-23

Publications (1)

Publication Number	Publication Date
NL1010385C2 true NL1010385C2 (nl)	2000-04-26

Family

ID=19768011

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL1010385A NL1010385C2 (nl)	1998-10-23	1998-10-23	Bereiding van een copolyetherester.

Country Status (13)

Country	Link
US (1)	US6441125B2 (de)
EP (1)	EP1141076B1 (de)
JP (1)	JP4768126B2 (de)
KR (1)	KR100567123B1 (de)
CN (1)	CN1131258C (de)
AT (1)	ATE258566T1 (de)
AU (1)	AU6372399A (de)
CA (1)	CA2349583C (de)
DE (1)	DE69914508T2 (de)
ES (1)	ES2215405T3 (de)
NL (1)	NL1010385C2 (de)
TW (1)	TWI232226B (de)
WO (1)	WO2000024803A1 (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1321270A1 (de) *	2001-12-18	2003-06-25	Dsm N.V.	Slushverfahren zur Herstellung eines Formteils
JP2006316262A (ja) *	2005-04-15	2006-11-24	Mitsubishi Chemicals Corp	ポリエーテルエステルブロック共重合体
CN101155851B (zh)	2005-04-15	2011-06-22	三菱化学株式会社	聚醚酯嵌段共聚物
JP2007277305A (ja) *	2006-04-03	2007-10-25	Mitsubishi Chemicals Corp	熱可塑性ポリエステルおよびその製造方法並びにフィルム
JP5604168B2 (ja) *	2009-12-28	2014-10-08	花王株式会社	ポリエーテルポリカーボネートの製造方法
KR101433898B1 (ko) *	2012-08-22	2014-08-27	주식회사 휴비스	열안정성이 우수한 폴리에테르 에스테르 엘라스토머 및 그 제조방법
KR101447446B1 (ko) *	2013-05-07	2014-10-10	주식회사 휴비스	영구압축 변형율이 낮은 열접착 부직포
TWI499612B (zh)	2014-04-02	2015-09-11	Far Eastern New Century Corp	製備共聚酯醚薄膜的方法及其用途
EP3583962B1 (de)	2018-06-20	2023-05-24	Fresenius Hemocare Italia S.r.l.	Blutenthnahmebehälter und herstellungsverfahren
EP4243957A1 (de)	2020-11-10	2023-09-20	Fresenius Hemocare Italia S.r.l.	Filter zur entfernung von substanzen aus blut

Citations (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2362175A1 (fr) *	1976-08-21	1978-03-17	Bayer Ag	Procede pour la preparation de polyesters de poids moleculaire eleve
US4124653A (en) *	1976-12-14	1978-11-07	E. I. Du Pont De Nemours And Company	Elastomer blend
US4452965A (en) *	1983-07-29	1984-06-05	The Goodyear Tire & Rubber Company	Random elastomeric copolyesters
EP0736560A2 (de) *	1995-04-07	1996-10-09	Zimmer Aktiengesellschaft	Titanhaltiger Katalysator und Verfahren zur Herstellung von Polyester

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- 1999-10-18 CA CA002349583A patent/CA2349583C/en not_active Expired - Fee Related
- 1999-10-18 JP JP2000578368A patent/JP4768126B2/ja not_active Expired - Fee Related
- 1999-10-18 ES ES99951254T patent/ES2215405T3/es not_active Expired - Lifetime
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Also Published As

Publication number	Publication date
CA2349583A1 (en)	2000-05-04
JP2002528579A (ja)	2002-09-03
KR20010080303A (ko)	2001-08-22
DE69914508D1 (de)	2004-03-04
AU6372399A (en)	2000-05-15
ES2215405T3 (es)	2004-10-01
DE69914508T2 (de)	2004-11-11
US20020016437A1 (en)	2002-02-07
EP1141076A1 (de)	2001-10-10
JP4768126B2 (ja)	2011-09-07
US6441125B2 (en)	2002-08-27
CA2349583C (en)	2009-12-29
EP1141076B1 (de)	2004-01-28
ATE258566T1 (de)	2004-02-15
KR100567123B1 (ko)	2006-03-31
CN1131258C (zh)	2003-12-17
WO2000024803A1 (en)	2000-05-04
TWI232226B (en)	2005-05-11
CN1331712A (zh)	2002-01-16

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2005-12-01	TD	Modifications of names of proprietors of patents	Owner name: KONINKLIJKE DSM N.V. Effective date: 20050915
2007-07-02	VD1	Lapsed due to non-payment of the annual fee	Effective date: 20070501

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