NL7908147A - Werkwijze voor de bereiding van ketonen. - Google Patents

Werkwijze voor de bereiding van ketonen. Download PDF

Info

Publication number: NL7908147A
Authority: NL; Netherlands
Prior art keywords: carbon atoms; groups; copper; aldehyde; manganese
Prior art date: 1978-11-08

Application number

NL7908147A

Other languages

English (en)

Dutch (nl)

Original Assignee

Huels Chemische Werke Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-11-08

Filing date

1979-11-07

Publication date

1980-05-12

1979-11-07 Application filed by Huels Chemische Werke Ag filed Critical Huels Chemische Werke Ag

1980-05-12 Publication of NL7908147A publication Critical patent/NL7908147A/nl

Links

150000002576 ketones Chemical class 0.000 title claims description 11
238000000034 method Methods 0.000 title claims description 11
150000001299 aldehydes Chemical class 0.000 claims description 27
239000003054 catalyst Substances 0.000 claims description 26
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 19
125000004432 carbon atom Chemical group C* 0.000 claims description 17
239000007789 gas Substances 0.000 claims description 16
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
239000010949 copper Substances 0.000 claims description 11
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
229910052802 copper Inorganic materials 0.000 claims description 10
238000002360 preparation method Methods 0.000 claims description 10
239000011787 zinc oxide Substances 0.000 claims description 10
229910002804 graphite Inorganic materials 0.000 claims description 9
239000010439 graphite Substances 0.000 claims description 9
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
125000005842 heteroatom Chemical group 0.000 claims description 7
229910052760 oxygen Inorganic materials 0.000 claims description 7
239000001301 oxygen Substances 0.000 claims description 7
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
239000003085 diluting agent Substances 0.000 claims description 5
229910052748 manganese Inorganic materials 0.000 claims description 5
239000011572 manganese Substances 0.000 claims description 5
125000003342 alkenyl group Chemical group 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
229910044991 metal oxide Inorganic materials 0.000 claims description 4
150000004706 metal oxides Chemical class 0.000 claims description 4
125000005024 alkenyl aryl group Chemical group 0.000 claims description 3
125000002877 alkyl aryl group Chemical group 0.000 claims description 3
125000005119 alkyl cycloalkyl group Chemical group 0.000 claims description 3
210000000988 bone and bone Anatomy 0.000 claims 1
125000000392 cycloalkenyl group Chemical group 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 16
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
235000014692 zinc oxide Nutrition 0.000 description 9
229960001296 zinc oxide Drugs 0.000 description 9
230000006324 decarbonylation Effects 0.000 description 7
238000006606 decarbonylation reaction Methods 0.000 description 7
230000001590 oxidative effect Effects 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
239000000203 mixture Substances 0.000 description 6
239000000243 solution Substances 0.000 description 6
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
239000011701 zinc Substances 0.000 description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
150000001721 carbon Chemical group 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
229910052725 zinc Inorganic materials 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 3
AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 3
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
229910001431 copper ion Inorganic materials 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
239000000463 material Substances 0.000 description 3
AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 3
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
-1 alkenylcycloalkyl Chemical group 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000000969 carrier Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
229910000431 copper oxide Inorganic materials 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
LGYNIFWIKSEESD-UHFFFAOYSA-N 2-ethylhexanal Chemical compound CCCCC(CC)C=O LGYNIFWIKSEESD-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229940024548 aluminum oxide Drugs 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
230000017525 heat dissipation Effects 0.000 description 1
LGAILEFNHXWAJP-BMEPFDOTSA-N macrocycle Chemical group N([C@H]1[C@@H](C)CC)C(=O)C(N=2)=CSC=2CNC(=O)C(=C(O2)C)N=C2[C@H]([C@@H](C)CC)NC(=O)C2=CSC1=N2 LGAILEFNHXWAJP-BMEPFDOTSA-N 0.000 description 1
229940071125 manganese acetate Drugs 0.000 description 1
229910001437 manganese ion Inorganic materials 0.000 description 1
UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000008188 pellet Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
229960005196 titanium dioxide Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

NL7908147A 1978-11-08 1979-11-07 Werkwijze voor de bereiding van ketonen. NL7908147A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE2848400		1978-11-08
DE2848400A DE2848400C2 (de)	1978-11-08	1978-11-08	Verfahren zur Herstellung von Ketonen

Publications (1)

Publication Number	Publication Date
NL7908147A true NL7908147A (nl)	1980-05-12

Family

ID=6054137

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL7908147A NL7908147A (nl)	1978-11-08	1979-11-07	Werkwijze voor de bereiding van ketonen.

Country Status (11)

Country	Link
EP (1)	EP0011098A1 (fr)
JP (1)	JPS5566526A (fr)
AT (1)	ATA713279A (fr)
BE (1)	BE879893A (fr)
DE (1)	DE2848400C2 (fr)
ES (1)	ES485791A1 (fr)
FR (1)	FR2440932A1 (fr)
GB (1)	GB2038320A (fr)
IT (1)	IT7950781A0 (fr)
NL (1)	NL7908147A (fr)
RO (1)	RO79022A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4417696A1 (de) *	1994-05-20	1995-11-23	Basf Ag	Verfahren zur Herstellung von cyclischen Etherketonen

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1133882A (en) *	1966-09-08	1968-11-20	Ici Ltd	A process for the production of ketones
FR2053423A6 (fr) *	1969-07-07	1971-04-16	Melle Bezons
US3496197A (en) *	1969-03-05	1970-02-17	Upjohn Co	Oxidation of aldehydes to ketones employing copper ions as catalysts
US3804902A (en) *	1970-11-21	1974-04-16	Daicel Ltd	Process for producing acetone
FR2265712B1 (fr) *	1974-03-29	1978-12-29	Huels Chemische Werke Ag
DE2738269C3 (de) *	1977-08-25	1980-02-21	Chemische Werke Huels Ag, 4370 Marl	Verfahren zur Herstellung von Aceton aus Isobutyraldehyd
DE2802672A1 (de) *	1978-01-21	1979-07-26	Huels Chemische Werke Ag	Verfahren zur herstellung von aceton aus isobutyraldehyd

1978
- 1978-11-08 DE DE2848400A patent/DE2848400C2/de not_active Expired
1979
- 1979-09-07 EP EP79103323A patent/EP0011098A1/fr not_active Withdrawn
- 1979-10-31 FR FR7926990A patent/FR2440932A1/fr not_active Withdrawn
- 1979-11-06 AT AT0713279A patent/ATA713279A/de unknown
- 1979-11-07 NL NL7908147A patent/NL7908147A/nl not_active Application Discontinuation
- 1979-11-07 BE BE0/198023A patent/BE879893A/fr unknown
- 1979-11-07 JP JP14343079A patent/JPS5566526A/ja active Pending
- 1979-11-07 ES ES485791A patent/ES485791A1/es not_active Expired
- 1979-11-07 GB GB7938620A patent/GB2038320A/en not_active Withdrawn
- 1979-11-08 IT IT7950781A patent/IT7950781A0/it unknown
- 1979-11-08 RO RO7999177A patent/RO79022A/fr unknown

Also Published As

Publication number	Publication date
DE2848400C2 (de)	1982-07-08
FR2440932A1 (fr)	1980-06-06
ES485791A1 (es)	1980-05-16
DE2848400A1 (de)	1980-05-14
IT7950781A0 (it)	1979-11-08
JPS5566526A (en)	1980-05-20
GB2038320A (en)	1980-07-23
BE879893A (fr)	1980-05-07
RO79022A (fr)	1982-10-11
EP0011098A1 (fr)	1980-05-28
ATA713279A (de)	1982-07-15

Legal Events

Date	Code	Title	Description
1982-07-01	BV	The patent application has lapsed

Publication	Publication Date	Title
Climent et al.	2002	Synthesis of pseudoionones by acid and base solid catalysts
JP2000515158A (ja)	2000-11-14	酢酸の選択的製造方法およびこの目的に適する触媒
US2690457A (en)	1954-09-28	Process fok the production of un
JPS5811416B2 (ja)	1983-03-02	メタクリル酸の製造法
FR2660651A1 (fr)	1991-10-11	Procede d'obtention d'au moins une olefine tertiaire par decomposition de l'ether correspondant.
US5959124A (en)	1999-09-28	Method of preparing maleic anhydride by vapor phase oxidation of hydrocarbon
US4571290A (en)	1986-02-18	Process for the selective oxidation of olefins with photochemical illumination of semiconductor powder suspensions
Radnik et al.	2005	Deactivation of Pd acetoxylation catalysts: Direct observations by XPS investigations
US3962126A (en)	1976-06-08	Reactivation of a magnesium oxide catalyst
US5550095A (en)	1996-08-27	Process for producing catalyst used for synthesis of methacrylic acid
FR2462414A1 (fr)	1981-02-13	Procede de preparation d'acides carboxyliques a partir d'aldehydes
US4165296A (en)	1979-08-21	Method for regenerating an oxidation catalyst
JP3961834B2 (ja)	2007-08-22	低級オレフィンの不飽和アルデヒドへの酸化のための触媒、その製造方法および使用方法
JP3200149B2 (ja)	2001-08-20	メタクリル酸合成用触媒の製造法
JPS588894B2 (ja)	1983-02-18	Ｎｈ↓３により製造された酸化触媒及び酸化方法
JPS62221638A (ja)	1987-09-29	ｐ−シモ−ル及び同族アルキルベンゾ−ルの製法
US3654354A (en)	1972-04-04	Process for the oxidation of unsaturated hydrocarbons
CA1076603A (fr)	1980-04-29	Preparation d'aldehydes et de cetones aromatiques
EP0005655A2 (fr)	1979-11-28	Procédé d'oxyhydrochloration non polluant
US3305587A (en)	1967-02-21	Dehydrogenation of cycloalkanols
JPH026414A (ja)	1990-01-10	イソブチレンの製造法
LI et al.	1997	A novel method for epoxidation of cyclohexene catalyzed by Fe2O3 with molecular oxygen and aldehydes
US2098842A (en)	1937-11-09	Peepabation of acetaldehyde and a
GB2038320A (en)	1980-07-23	Process for the manufacture of ketones
JPH11226412A (ja)	1999-08-24	メタクリル酸製造用触媒の製造方法およびメタクリル酸の製造方法