NO176764C - Fast katalysator, prepolymerpartikler, fremgangsmåter for fremstilling av katalysatoren og prepolymerpartiklene samt fremgangsmåte for polymerisasjon av olefiner - Google Patents

Fast katalysator, prepolymerpartikler, fremgangsmåter for fremstilling av katalysatoren og prepolymerpartiklene samt fremgangsmåte for polymerisasjon av olefiner

Info

Publication number: NO176764C
Authority: NO; Norway
Prior art keywords: solid catalyst; catalyst; prepolymer particles; prepolymer; solid
Prior art date: 1989-12-22

Application number

NO905440A

Other languages

English (en)

Norwegian (no)

Other versions

NO176764B (no

NO905440L (no

NO905440D0 (no

Inventor

Jean-Claude Andre Bailly

Christine Jacqueline Chabrand

Original Assignee

Bp Chem Int Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-12-22

Filing date

1990-12-17

Publication date

1995-05-24

1990-12-17 Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd

1990-12-17 Publication of NO905440D0 publication Critical patent/NO905440D0/no

1991-06-24 Publication of NO905440L publication Critical patent/NO905440L/no

1995-02-13 Publication of NO176764B publication Critical patent/NO176764B/no

1995-05-24 Publication of NO176764C publication Critical patent/NO176764C/no

Links

239000011949 solid catalyst Substances 0.000 title abstract 5
238000000034 method Methods 0.000 title abstract 4
239000002245 particle Substances 0.000 title abstract 4
150000001336 alkenes Chemical class 0.000 title abstract 3
239000003054 catalyst Substances 0.000 title abstract 2
238000006116 polymerization reaction Methods 0.000 title abstract 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
239000005977 Ethylene Substances 0.000 abstract 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 2
229920001577 copolymer Polymers 0.000 abstract 2
229910052739 hydrogen Inorganic materials 0.000 abstract 2
239000001257 hydrogen Substances 0.000 abstract 2
150000002899 organoaluminium compounds Chemical class 0.000 abstract 2
229910052726 zirconium Inorganic materials 0.000 abstract 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
150000002431 hydrogen Chemical class 0.000 abstract 1
229910001629 magnesium chloride Inorganic materials 0.000 abstract 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
230000000379 polymerizing effect Effects 0.000 abstract 1
239000000843 powder Substances 0.000 abstract 1
239000007787 solid Substances 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polyurethanes Or Polyureas (AREA)
Polyesters Or Polycarbonates (AREA)

NO905440A 1989-12-22 1990-12-17 Fast katalysator, prepolymerpartikler, fremgangsmåter for fremstilling av katalysatoren og prepolymerpartiklene samt fremgangsmåte for polymerisasjon av olefiner NO176764C (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR8917403A FR2656315B1 (fr)	1989-12-22	1989-12-22	Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.

Publications (4)

Publication Number	Publication Date
NO905440D0 NO905440D0 (no)	1990-12-17
NO905440L NO905440L (no)	1991-06-24
NO176764B NO176764B (no)	1995-02-13
NO176764C true NO176764C (no)	1995-05-24

Family

ID=9389118

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO905440A NO176764C (no)	1989-12-22	1990-12-17	Fast katalysator, prepolymerpartikler, fremgangsmåter for fremstilling av katalysatoren og prepolymerpartiklene samt fremgangsmåte for polymerisasjon av olefiner

Country Status (18)

Country	Link
EP (1)	EP0435514B1 (fr)
JP (1)	JPH04211405A (fr)
KR (1)	KR910011921A (fr)
CN (1)	CN1053432A (fr)
AT (1)	ATE142655T1 (fr)
AU (1)	AU647430B2 (fr)
CA (1)	CA2032621A1 (fr)
DE (1)	DE69028503T2 (fr)
ES (1)	ES2091230T3 (fr)
FI (1)	FI906299L (fr)
FR (1)	FR2656315B1 (fr)
HU (1)	HU208982B (fr)
MY (1)	MY104605A (fr)
NO (1)	NO176764C (fr)
PL (1)	PL288413A1 (fr)
PT (1)	PT96344B (fr)
SG (1)	SG44342A1 (fr)
ZA (1)	ZA9010047B (fr)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2659337B1 (fr) *	1990-03-12	1992-06-05	Bp Chemicals Snc	Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2659336B1 (fr) *	1990-03-12	1993-05-07	Bp Chemicals Snc	Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
EP0578838A1 (fr) *	1992-04-29	1994-01-19	Hoechst Aktiengesellschaft	Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation
ES2101113T3 (es) *	1992-05-28	1997-07-01	Idemitsu Petrochemical Co	Procedimiento de produccion de poliolefina.
CA2127822A1 (fr) *	1993-07-13	1995-01-14	Yoshinori Morita	Procede de polymerisation en phase gazeuse d'olefine
IT1269837B (it) *	1994-05-26	1997-04-15	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione delle olefine
US6140432A (en) *	1995-07-13	2000-10-31	Exxon Chemical Patents Inc.	Polymerization catalyst systems, their production and use
DE69509403T2 (de) *	1994-10-13	1999-10-07	Exxon Chemical Patents, Inc.	Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung
KR100405100B1 (ko) *	1994-10-13	2004-02-05	엑손모빌 케미칼 패턴츠 인코포레이티드	중합촉매시스템,이의제조및용도
US6506866B2 (en)	1994-11-17	2003-01-14	Dow Global Technologies Inc.	Ethylene copolymer compositions
US6399533B2 (en) *	1995-05-25	2002-06-04	Basell Technology Company Bv	Compounds and catalysts for the polymerization of olefins
KR970015606A (ko) *	1995-09-01	1997-04-28	윤덕용	폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
JPH09309926A (ja)	1996-05-17	1997-12-02	Dow Chem Co:The	エチレン共重合体の製造方法
US6187882B1 (en) *	1997-02-21	2001-02-13	Council Of Scientific & Industrial Research	Process for polymerization of olefins
US5965477A (en) *	1997-02-21	1999-10-12	Council Of Scientific & Industrial Research	Process for the preparation of supported metallocene catalyst
EP0878484B1 (fr) *	1997-03-27	2004-12-15	Council of Scientific and Industrial Research	Procédé de préparation d'un catalyseur métallocène supporté sur un halogénure de magnésium
EP0878483B1 (fr) *	1997-03-27	2008-03-12	Council of Scientific and Industrial Research	Procédé pour la polymérisation et copolymérisation des oléfines
JP3322643B2 (ja) *	1998-10-19	2002-09-09	丸善石油化学株式会社	オレフィン重合用固体触媒およびこれを用いたオレフィン系重合体の製造方法
ATE388967T1 (de)	1998-10-27	2008-03-15	Westlake Longview Corp	Verfahren zur polymerisierung von olefine; polyethylene, und filme, und gegenstände damit hergestellt
US6291613B1 (en)	1998-10-27	2001-09-18	Eastman Chemical Company	Process for the polymerization of olefins
US6288181B1 (en) *	1999-03-30	2001-09-11	Eastman Chemical Company	Process for producing polyolefins
US6313236B1 (en)	1999-03-30	2001-11-06	Eastman Chemical Company	Process for producing polyolefins
CA2377259A1 (fr) *	1999-06-25	2001-01-04	Randal Ray Ford	Procede de polymerisation d'olefines, polyolefines, et films et articles produits a partir de celles-ci
US6288182B1 (en) *	1999-10-12	2001-09-11	Saudi Basic Industries Corporation	Supported metallocene catalyst system for olefin polymerization
DE19962129A1 (de)	1999-12-21	2001-06-28	Targor Gmbh	Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
EP1555272B1 (fr)	2002-10-23	2010-12-08	Mitsui Chemicals, Inc.	Catalyseur de polymerisation olefinique supporte
KR102019467B1 (ko)	2015-12-23	2019-11-04	주식회사 엘지화학	메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2541683B1 (fr) *	1983-02-28	1986-05-09	Ato Chimie	Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
US4659685A (en) *	1986-03-17	1987-04-21	The Dow Chemical Company	Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
FR2628110B1 (fr) *	1988-03-03	1994-03-25	Bp Chimie	Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation

1989
- 1989-12-22 FR FR8917403A patent/FR2656315B1/fr not_active Expired - Lifetime
1990
- 1990-12-13 AT AT90313570T patent/ATE142655T1/de not_active IP Right Cessation
- 1990-12-13 DE DE69028503T patent/DE69028503T2/de not_active Expired - Fee Related
- 1990-12-13 ES ES90313570T patent/ES2091230T3/es not_active Expired - Lifetime
- 1990-12-13 ZA ZA9010047A patent/ZA9010047B/xx unknown
- 1990-12-13 SG SG1995002080A patent/SG44342A1/en unknown
- 1990-12-13 EP EP90313570A patent/EP0435514B1/fr not_active Expired - Lifetime
- 1990-12-17 NO NO905440A patent/NO176764C/no unknown
- 1990-12-17 AU AU68174/90A patent/AU647430B2/en not_active Ceased
- 1990-12-18 CA CA002032621A patent/CA2032621A1/fr not_active Abandoned
- 1990-12-20 MY MYPI90002229A patent/MY104605A/en unknown
- 1990-12-20 FI FI906299A patent/FI906299L/fi not_active Application Discontinuation
- 1990-12-21 HU HU908439A patent/HU208982B/hu not_active IP Right Cessation
- 1990-12-21 PL PL28841390A patent/PL288413A1/xx unknown
- 1990-12-21 CN CN91100669A patent/CN1053432A/zh active Pending
- 1990-12-21 JP JP2419283A patent/JPH04211405A/ja active Pending
- 1990-12-21 PT PT96344A patent/PT96344B/pt not_active IP Right Cessation
- 1990-12-22 KR KR1019900021445A patent/KR910011921A/ko not_active Ceased

Also Published As

Publication number	Publication date
JPH04211405A (ja)	1992-08-03
MY104605A (en)	1994-04-30
EP0435514A2 (fr)	1991-07-03
AU6817490A (en)	1991-06-27
AU647430B2 (en)	1994-03-24
ES2091230T3 (es)	1996-11-01
NO176764B (no)	1995-02-13
PL288413A1 (en)	1992-02-10
NO905440L (no)	1991-06-24
CN1053432A (zh)	1991-07-31
ATE142655T1 (de)	1996-09-15
PT96344B (pt)	1998-06-30
FI906299A7 (fi)	1991-06-23
EP0435514B1 (fr)	1996-09-11
DE69028503D1 (de)	1996-10-17
HU908439D0 (en)	1991-07-29
EP0435514A3 (fr)	1991-07-10
CA2032621A1 (fr)	1991-06-23
FI906299A0 (fi)	1990-12-20
KR910011921A (ko)	1991-08-07
PT96344A (pt)	1991-09-30
FR2656315B1 (fr)	1992-04-17
HUT59424A (en)	1992-05-28
HU208982B (en)	1994-02-28
SG44342A1 (en)	1997-12-19
FR2656315A1 (fr)	1991-06-28
ZA9010047B (en)	1992-08-26
NO905440D0 (no)	1990-12-17
DE69028503T2 (de)	1997-01-30
FI906299L (fi)	1991-06-23

Publication	Publication Date	Title
NO176764C (no)	1995-05-24	Fast katalysator, prepolymerpartikler, fremgangsmåter for fremstilling av katalysatoren og prepolymerpartiklene samt fremgangsmåte for polymerisasjon av olefiner
NO176571C (no)	1995-04-26	Fast katalysator og prepolymer for fremstilling av polyolefiner, fremgangsmåter for fremstilling av katalysatoren og prepolymeren samt fremgangsmåte for fremstilling av polyolefiner
ZA911294B (en)	1992-10-28	Catalyst and prepolymer used for polymerising olefins,and (co-)polymer of ethylene obtainable therefrom
YU211889A (en)	1991-02-28	Process for obtaining polyethylene wax
CA2087181A1 (fr)	1992-01-14	Hydrocarbyloxydes de metaux des groupes ivb, vb et vib, avec l'alumoxane pour la polymerisation des olefines
AU622573B2 (en)	1992-04-09	Process for preparing in gas phase elastomeric copolymers of propylene
FI911214A0 (fi)	1991-03-12	Katalysator och prepolymer foer anvaendning vid polymerisation av olefiner och fraon dessa framstaellbar (ko) polymer av eten.
DE3779400D1 (de)	1992-07-02	Katalysatorbestandteile und katalysatoren fuer die polymerisation von alpha-olefinen zu stereoregularen polymeren mit beschraenkter molekulargewichtsverteilung.
JPS52150491A (en)	1977-12-14	Polymerization of ethylene of alpha-olefins