NO20060301L - Vannfri bearbeiding av metan til metansulfonsyre, metanol og andre forbindelser - Google Patents
Vannfri bearbeiding av metan til metansulfonsyre, metanol og andre forbindelserInfo
- Publication number
- NO20060301L NO20060301L NO20060301A NO20060301A NO20060301L NO 20060301 L NO20060301 L NO 20060301L NO 20060301 A NO20060301 A NO 20060301A NO 20060301 A NO20060301 A NO 20060301A NO 20060301 L NO20060301 L NO 20060301L
- Authority
- NO
- Norway
- Prior art keywords
- methane
- radicals
- msa
- reactor
- methanesulfonic acid
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C11/00—Fermentation processes for beer
- C12C11/02—Pitching yeast
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Genetics & Genomics (AREA)
- Mycology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Radikaler med uparede elektroner initierer en kjedereaksjon hvor lavere hydrokarboner som metan omdannes til oksygenerte væsker. En initiator som Marshalls syre anvendes til å danne metylradikaler. Disse radikaler kombinerer seg med svoveltrioksid og danner metylsulfonatradikaler som så fjerner hydrogen fra metan tilført i reaktoren, og det dannes stabil metansulfonsyre (MSA, HCSOH) og nye metylradikaler slik at kjedereaksjonen opprettholdes mens metan og S0tilføres kontinuerlig til reaktoren. Vannfne betingelser unngår bruk eller dannelse av vann. MSA i reaktoren øker løseligheten av metan og SOog reaksjonshastighetene. MSA kan oppvarmes for å frigjøre metanol, eller bli bearbeidet til bensin, dimetyleter, formaldehyd eller andre verdifulle væsker. Eventuelt S0frigjort ved behandlingen av MSA kan bli oksidert til SOog resirkulert i systemet. Forsøk viser svært høye utbytter og selektiviteter (over 95 %).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48018303P | 2003-06-21 | 2003-06-21 | |
| PCT/US2004/019977 WO2005069751A2 (en) | 2003-06-21 | 2004-06-21 | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO20060301L true NO20060301L (no) | 2006-03-08 |
Family
ID=34806865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20060301A NO20060301L (no) | 2003-06-21 | 2006-01-20 | Vannfri bearbeiding av metan til metansulfonsyre, metanol og andre forbindelser |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7282603B2 (no) |
| NO (1) | NO20060301L (no) |
| OA (1) | OA13183A (no) |
| WO (1) | WO2005069751A2 (no) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
| CA2504707C (en) * | 2002-11-05 | 2019-07-09 | Alan K. Richards | Anhydrous conversion of methane and other light alkanes into methanol and other derivatives, using radical pathways and chain reactions with minimal waste products |
| US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
| JP2007525477A (ja) | 2003-07-15 | 2007-09-06 | ジーアールティー インコーポレイテッド | 炭化水素の合成 |
| US20050045467A1 (en) * | 2003-09-03 | 2005-03-03 | King Fahd University Of Petroleum And Minerals | Method for the conversion of methane into hydrogen and higher hydrocarbons using UV laser |
| US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
| US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
| US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US7119226B2 (en) * | 2004-04-20 | 2006-10-10 | The Penn State Research Foundation | Process for the conversion of methane |
| SG187456A1 (en) | 2006-02-03 | 2013-02-28 | Grt Inc | Separation of light gases from halogens |
| AP2673A (en) | 2006-02-03 | 2013-05-23 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
| US20070282151A1 (en) * | 2006-05-19 | 2007-12-06 | Richards Alan K | Manufacture of higher hydrocarbons from methane, via methanesulfonic acid, sulfene, and other pathways |
| MX2009012581A (es) | 2007-05-24 | 2010-03-15 | Grt Inc | Reactor de zonas que incorpora captura y liberacion de haluro de hidrogeno reversible. |
| US8026403B2 (en) | 2007-06-27 | 2011-09-27 | H R D Corporation | System and process for production of liquid product from light gas |
| US8394861B2 (en) | 2007-06-27 | 2013-03-12 | Hrd Corporation | Gasification of carbonaceous materials and gas to liquid processes |
| US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
| US8273929B2 (en) | 2008-07-18 | 2012-09-25 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
| US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
| US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
| US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
| US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
| KR101346021B1 (ko) * | 2011-12-09 | 2013-12-31 | 주식회사 엠에스씨 | 주석-은 합금 도금액의 생성방법 및 그 도금액 |
| US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
| CN105722819A (zh) | 2013-11-13 | 2016-06-29 | 格里洛凯米股份有限公司 | 由三氧化硫和烷烃制备烷基磺酸的方法 |
| MY179376A (en) * | 2013-11-18 | 2020-11-05 | Basf Se | Novel initiator for preparing alkanesulfonic acids from alkane and oleum |
| CN108602766A (zh) | 2015-11-10 | 2018-09-28 | 巴斯夫欧洲公司 | 提纯链烷磺酸的方法 |
| US9938944B2 (en) | 2015-11-25 | 2018-04-10 | General Electric Company | System including duel fuel injection engine and method of operation |
| ES2965853T3 (es) | 2016-11-28 | 2024-04-17 | Basf Se | Sulfonación de alcanos sin disolventes |
| KR20190116290A (ko) | 2017-02-07 | 2019-10-14 | 그릴로-베르케 아게 | 알칸 설폰산의 제조방법 |
| TW201841881A (zh) | 2017-04-18 | 2018-12-01 | 德商巴斯夫歐洲公司 | 純化烷烴磺酸酐的方法及使用純化的烷烴磺酸酐製造烷烴磺酸的方法 |
| EP3634597B1 (en) * | 2017-05-11 | 2023-01-11 | Arkema Inc. | Processes and systems for recovering methanesulfonic acid in purified form |
| CN110678444B (zh) * | 2017-05-30 | 2023-01-10 | 巴斯夫欧洲公司 | 生产链烷磺酸的方法 |
| TW201904938A (zh) | 2017-06-30 | 2019-02-01 | 德商葛里洛沃克股份有限公司 | 用於生產烷磺酸的調節劑 |
| CA3072213A1 (en) * | 2017-08-18 | 2019-02-21 | So3 Plus, Llc | Apparatus and method for producing hydrocarbons |
| BR112020014761B1 (pt) * | 2018-02-07 | 2022-12-20 | Basf Se | Processo para a fabricação de um ácido alcanossulfônico |
| FR3077817B1 (fr) * | 2018-02-14 | 2020-02-28 | Arkema France | Procede de synthese industrielle en continu d'acide alcane-sulfonique |
| TW201934533A (zh) | 2018-02-16 | 2019-09-01 | 德商格里洛工廠股份有限公司 | 使用異相催化自烷及三氧化硫直接合成烷磺酸 |
| TWI714964B (zh) | 2018-02-16 | 2021-01-01 | 巴斯夫歐洲公司 | 用於烷磺酸之合成的催化劑 |
| EP4159714A1 (en) | 2018-03-10 | 2023-04-05 | Veolia North America Regeneration Services, LLC | Compounds, processes, and machinery for converting methane gas into methane sulfonic acid |
| TWI799586B (zh) * | 2018-05-25 | 2023-04-21 | 德商格里洛工廠股份有限公司 | 自三氧化硫及鹵烷製備鹵代烷磺酸的方法 |
| KR20210060474A (ko) | 2018-09-25 | 2021-05-26 | 바스프 에스이 | 알칸 술폰산의 제조시 촉매로서의 양이온 |
| WO2020064573A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
| WO2020064466A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalyst for the synthesis of alkanesulfonic acids |
| WO2020126855A1 (en) | 2018-12-21 | 2020-06-25 | Basf Se | Mixture comprising methanesulfonic acid and sulfuric acid |
| ES2950933T3 (es) | 2019-04-18 | 2023-10-16 | Basf Se | Procedimiento de producción de ácido metanosulfónico anhidro a partir de metano y SO3 |
| EP3763701A1 (en) | 2019-07-10 | 2021-01-13 | Grillo-Werke AG | Improved process for the purification of methane sulfonic acid |
| ES2966787T3 (es) | 2019-07-10 | 2024-04-24 | Basf Se | Procedimiento para reducir la concentración de SO3 en una mezcla de reacción que comprende ácido metano sulfónico y SO3 |
| EP3782981A1 (en) | 2019-08-20 | 2021-02-24 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
| WO2021063730A1 (en) | 2019-10-01 | 2021-04-08 | Basf Se | Process for manufacturing alkanesulfonic acids |
| US20220324794A1 (en) | 2021-04-07 | 2022-10-13 | Veolia North American Regeneration Services, LLC | Method for removing so3 and ch4 from mixtures which contain methane sulfonic acid |
| US11767290B2 (en) | 2021-04-07 | 2023-09-26 | Veolia North America Regeneration Services, Llc | Method for removing SO3 and CH4 from mixtures which contain methane sulfonic acid |
| EP4151774A1 (en) | 2021-09-21 | 2023-03-22 | Studiengesellschaft Kohle mbH | Process for the production of methane sulfonic acid |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2492984A (en) | 1946-05-31 | 1950-01-03 | Houdry Process Corp | Organic reactions |
| GB632820A (en) | 1946-05-31 | 1949-12-05 | Houdry Process Corp | Improvements in or relating to the production of organic compounds by chemical transformation of methane or its sulfonated and/or oxygenated derivatives |
| US2493038A (en) | 1946-05-31 | 1950-01-03 | Houdry Process Corp | Reaction of methane with sulfur trioxide |
| US2553576A (en) | 1947-03-26 | 1951-05-22 | Houdry Process Corp | Production of organic compounds from methane sulfonic acid |
| US3927189A (en) | 1974-04-12 | 1975-12-16 | Du Pont | Method for making peroxydisulfuric acid and salts thereof |
| US3969427A (en) | 1974-11-19 | 1976-07-13 | Mobil Oil Corporation | Conversion of alcohols and/or ethers to hydrocarbons |
| US5306855A (en) | 1991-02-15 | 1994-04-26 | Catalytica, Inc. | Catalytic process for converting lower alkanes to esters, alcohols, and to hydrocarbons |
| US5233113A (en) | 1991-02-15 | 1993-08-03 | Catalytica, Inc. | Process for converting lower alkanes to esters |
| DE19641483A1 (de) | 1996-10-09 | 1998-04-16 | Basf Ag | Verfahren zur Herstellung von Methansulfonsäure |
| DK128697A (da) | 1997-11-12 | 1999-05-13 | Niels J Bjerrum | Katalyseproces |
| DE19854428A1 (de) | 1998-11-25 | 2000-05-31 | Basf Ag | Verfahren zur Herstellung von Alkansulfonsäuren |
| DE19904262A1 (de) | 1999-02-03 | 2000-08-10 | Basf Ag | Verfahren zur Herstellung von Alkansulfonsäuren |
| US6538162B2 (en) | 2001-01-30 | 2003-03-25 | Exxonmobil Chemical Patents Inc. | Method for converting alkanes to oxygenates |
| US6384271B1 (en) | 2001-05-04 | 2002-05-07 | E.I. Du Pont De Nemours And Company | Sulfonation, sulfation and sulfamation |
| US6452058B1 (en) | 2001-05-21 | 2002-09-17 | Dow Global Technologies Inc. | Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons and integrated processes related thereto |
| DE10132526A1 (de) | 2001-07-09 | 2003-01-30 | Ruhrgas Ag | Verfahren zum Herstellen eines Alkanderivats |
-
2004
- 2004-06-21 US US10/873,361 patent/US7282603B2/en not_active Expired - Lifetime
- 2004-06-21 OA OA1200500373A patent/OA13183A/en unknown
- 2004-06-21 WO PCT/US2004/019977 patent/WO2005069751A2/en not_active Ceased
-
2006
- 2006-01-20 NO NO20060301A patent/NO20060301L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US7282603B2 (en) | 2007-10-16 |
| WO2005069751A3 (en) | 2006-09-21 |
| OA13183A (en) | 2006-12-13 |
| US20050070614A1 (en) | 2005-03-31 |
| WO2005069751A2 (en) | 2005-08-04 |
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| Date | Code | Title | Description |
|---|---|---|---|
| FC2A | Withdrawal, rejection or dismissal of laid open patent application |