NO310935B1 - Stabiliserte polyamidfilamenter, samt fremgangsmate for og blanding for stabilisering av disse - Google Patents

Stabiliserte polyamidfilamenter, samt fremgangsmate for og blanding for stabilisering av disse Download PDF

Info

Publication number: NO310935B1
Authority: NO; Norway
Prior art keywords: copper; functionalized; mixture; polyphthalamide; synergist
Prior art date: 1993-09-16

Application number

NO19951935A

Other languages

English (en)

Norwegian (no)

Other versions

NO951935L (no

NO951935D0 (no

Inventor

Mark G Reichmann

Original Assignee

Bp Amoco Corp Law Dept

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-09-16

Filing date

1995-05-16

Publication date

2001-09-17

1995-05-16 Application filed by Bp Amoco Corp Law Dept filed Critical Bp Amoco Corp Law Dept

1995-05-16 Publication of NO951935L publication Critical patent/NO951935L/no

1995-05-16 Publication of NO951935D0 publication Critical patent/NO951935D0/no

2001-09-17 Publication of NO310935B1 publication Critical patent/NO310935B1/no

Links

239000000203 mixture Substances 0.000 title claims description 44
239000004952 Polyamide Substances 0.000 title claims description 34
229920002647 polyamide Polymers 0.000 title claims description 34
238000000034 method Methods 0.000 title claims description 22
230000000087 stabilizing effect Effects 0.000 title claims description 11
239000003381 stabilizer Substances 0.000 claims description 38
-1 copper (I) halide Chemical class 0.000 claims description 34
239000004954 Polyphthalamide Substances 0.000 claims description 28
229920006375 polyphtalamide Polymers 0.000 claims description 28
239000010949 copper Substances 0.000 claims description 26
229920000098 polyolefin Polymers 0.000 claims description 26
229910052802 copper Inorganic materials 0.000 claims description 24
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 22
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 18
229910001508 alkali metal halide Inorganic materials 0.000 claims description 11
150000008045 alkali metal halides Chemical class 0.000 claims description 11
239000004698 Polyethylene Substances 0.000 claims description 10
229920000573 polyethylene Polymers 0.000 claims description 10
229920002943 EPDM rubber Polymers 0.000 claims description 8
238000002074 melt spinning Methods 0.000 claims description 8
229920000642 polymer Polymers 0.000 claims description 8
229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 7
239000004743 Polypropylene Substances 0.000 claims description 6
229920001155 polypropylene Polymers 0.000 claims description 6
VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 claims description 5
229920001897 terpolymer Polymers 0.000 claims description 5
239000005749 Copper compound Substances 0.000 claims description 4
150000001880 copper compounds Chemical class 0.000 claims description 4
229910021595 Copper(I) iodide Inorganic materials 0.000 claims 6
LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 claims 3
238000002360 preparation method Methods 0.000 claims 1
239000000835 fiber Substances 0.000 description 17
229920005989 resin Polymers 0.000 description 12
239000011347 resin Substances 0.000 description 12
238000004519 manufacturing process Methods 0.000 description 10
238000001125 extrusion Methods 0.000 description 8
229920001577 copolymer Polymers 0.000 description 6
239000000126 substance Substances 0.000 description 6
229920002302 Nylon 6,6 Polymers 0.000 description 5
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
230000015556 catabolic process Effects 0.000 description 5
238000006731 degradation reaction Methods 0.000 description 5
239000010408 film Substances 0.000 description 5
229920003231 aliphatic polyamide Polymers 0.000 description 4
238000009987 spinning Methods 0.000 description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
FQLAJSQGBDYBAL-UHFFFAOYSA-N 3-(azepane-1-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2CCCCCC2)=C1 FQLAJSQGBDYBAL-UHFFFAOYSA-N 0.000 description 3
239000004953 Aliphatic polyamide Substances 0.000 description 3
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
230000001590 oxidative effect Effects 0.000 description 3
230000002035 prolonged effect Effects 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
229950011008 tetrachloroethylene Drugs 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 2
VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 2
230000032683 aging Effects 0.000 description 2
229920003233 aromatic nylon Polymers 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
238000005266 casting Methods 0.000 description 2
239000002131 composite material Substances 0.000 description 2
238000010276 construction Methods 0.000 description 2
239000013068 control sample Substances 0.000 description 2
GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 2
150000004985 diamines Chemical class 0.000 description 2
238000001035 drying Methods 0.000 description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
PZRHRDRVRGEVNW-UHFFFAOYSA-N milrinone Chemical compound N1C(=O)C(C#N)=CC(C=2C=CN=CC=2)=C1C PZRHRDRVRGEVNW-UHFFFAOYSA-N 0.000 description 2
229960003574 milrinone Drugs 0.000 description 2
238000002156 mixing Methods 0.000 description 2
229920001778 nylon Polymers 0.000 description 2
239000008188 pellet Substances 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000010998 test method Methods 0.000 description 2
DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical group NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 2
229920006345 thermoplastic polyamide Polymers 0.000 description 2
PGGROMGHWHXWJL-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 PGGROMGHWHXWJL-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
239000004956 Amodel Substances 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229920002633 Kraton (polymer) Polymers 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
229920002292 Nylon 6 Polymers 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
229920003182 Surlyn® Polymers 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000004760 aramid Substances 0.000 description 1
229920003235 aromatic polyamide Polymers 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
UGYHCIYEOPPPMT-UHFFFAOYSA-N benzene-1,3-dicarboxamide;hexanediamide Chemical compound NC(=O)CCCCC(N)=O.NC(=O)C1=CC=CC(C(N)=O)=C1 UGYHCIYEOPPPMT-UHFFFAOYSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
150000003842 bromide salts Chemical class 0.000 description 1
ODWXUNBKCRECNW-UHFFFAOYSA-M bromocopper(1+) Chemical compound Br[Cu+] ODWXUNBKCRECNW-UHFFFAOYSA-M 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
239000012612 commercial material Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
RFKZUAOAYVHBOY-UHFFFAOYSA-M copper(1+);acetate Chemical compound [Cu+].CC([O-])=O RFKZUAOAYVHBOY-UHFFFAOYSA-M 0.000 description 1
FPHREELHOCEQEA-UHFFFAOYSA-M copper(1+);octadecanoate Chemical compound [Cu+].CCCCCCCCCCCCCCCCCC([O-])=O FPHREELHOCEQEA-UHFFFAOYSA-M 0.000 description 1
ZKXWKVVCCTZOLD-UHFFFAOYSA-N copper;4-hydroxypent-3-en-2-one Chemical compound [Cu].CC(O)=CC(C)=O.CC(O)=CC(C)=O ZKXWKVVCCTZOLD-UHFFFAOYSA-N 0.000 description 1
GSCLWPQCXDSGBU-UHFFFAOYSA-L copper;phthalate Chemical compound [Cu+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O GSCLWPQCXDSGBU-UHFFFAOYSA-L 0.000 description 1
229930003836 cresol Natural products 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
BAHZUGHIFPYDJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxamide Chemical compound NC(=O)C1(C(N)=O)CCCCC1 BAHZUGHIFPYDJT-UHFFFAOYSA-N 0.000 description 1
VDBXLXRWMYNMHL-UHFFFAOYSA-N decanediamide Chemical compound NC(=O)CCCCCCCCC(N)=O VDBXLXRWMYNMHL-UHFFFAOYSA-N 0.000 description 1
238000006114 decarboxylation reaction Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007547 defect Effects 0.000 description 1
150000001470 diamides Chemical class 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical group 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
150000004694 iodide salts Chemical class 0.000 description 1
QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
230000007774 longterm Effects 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000010128 melt processing Methods 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
JXRWDHUZHAWOLC-UHFFFAOYSA-N naphthalene-1,2-dicarboxamide Chemical compound C1=CC=CC2=C(C(N)=O)C(C(=O)N)=CC=C21 JXRWDHUZHAWOLC-UHFFFAOYSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000002530 phenolic antioxidant Substances 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical compound NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
125000004805 propylene group Chemical class [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000007017 scission Effects 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
230000035882 stress Effects 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical class NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000010409 thin film Substances 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
239000002759 woven fabric Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Artificial Filaments (AREA)
Compositions Of Macromolecular Compounds (AREA)

NO19951935A 1993-09-16 1995-05-16 Stabiliserte polyamidfilamenter, samt fremgangsmate for og blanding for stabilisering av disse NO310935B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US08/122,367 US5447980A (en)	1993-09-16	1993-09-16	Stabilized polyamide fiber
PCT/US1994/009596 WO1995008011A1 (fr)	1993-09-16	1994-08-18	Fibre polyamide stabilisee

Publications (3)

Publication Number	Publication Date
NO951935L NO951935L (no)	1995-05-16
NO951935D0 NO951935D0 (no)	1995-05-16
NO310935B1 true NO310935B1 (no)	2001-09-17

Family

ID=22402286

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO19951935A NO310935B1 (no)	1993-09-16	1995-05-16	Stabiliserte polyamidfilamenter, samt fremgangsmate for og blanding for stabilisering av disse

Country Status (10)

Country	Link
US (1)	US5447980A (fr)
EP (1)	EP0668943B1 (fr)
JP (1)	JP3456483B2 (fr)
BR (1)	BR9405594A (fr)
CA (1)	CA2148487C (fr)
DE (1)	DE69415493T2 (fr)
FI (1)	FI109812B (fr)
NO (1)	NO310935B1 (fr)
SG (1)	SG79914A1 (fr)
WO (1)	WO1995008011A1 (fr)

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Publication number	Priority date	Publication date	Assignee	Title
US5585429A (en) *	1995-03-27	1996-12-17	Amoco Corporation	Polyphthalamide resin formulations
US5763561A (en) *	1996-09-06	1998-06-09	Amoco Corporation	Polyamide compositions having improved thermal stability
JP2000319508A (ja) *	1999-05-13	2000-11-21	Toyobo Co Ltd	ポリアミド樹脂組成物
EP1198520B1 (fr) *	1999-06-18	2003-12-03	Solvay Advanced Polymers, LLC	Procede et composition pour reduire la formation de depots de moulage pendant le moulage de polyamides
EP1554762B2 (fr) *	2002-10-15	2014-04-30	Solvay Specialty Polymers USA, LLC.	Compositions polymeres de polycondensation anti-jaunissement et articles associees
EP1658163B1 (fr) *	2003-08-19	2020-01-01	Solvay Specialty Polymers USA, LLC.	Corps creux en polyamide antichoc
US20050197452A1 (en) *	2004-02-27	2005-09-08	Solvay Advanced Polymers, Llc	Safety equipment comprising an aromatic polyamide composition, and aromatic polyamide composition
DE102004022963A1 (de) *	2004-05-10	2005-12-08	Ems-Chemie Ag	Thermoplastische Polyamid-Formmassen
US20070245924A1 (en) *	2006-04-20	2007-10-25	Hofmann Michael A	Reduced abrasion of titanium dioxide pigments produced from the chloride process
DE102007038578A1 (de)	2007-08-16	2009-02-19	Evonik Degussa Gmbh	Verfahren zur Dekorierung von Oberflächen
DE102010030212A1 (de) *	2010-06-17	2011-12-22	Robert Bosch Gmbh	Stabilisatorzusammensetzung für Polyamide
DE102010042131A1 (de)	2010-10-07	2012-04-12	Evonik Degussa Gmbh	Mit Polyphthalamid-Fasern verstärkter Gummikörper
DE102010051310A1 (de)	2010-11-16	2012-05-16	Thüringisches Institut für Textil- und Kunststoff-Forschung e.V.	Verfahren zur Herstellung von Polyamidzusammensetzungen mit verbesserten thermooxidativen, antibakteriellen, licht- oder energieaktiven Eigenschaften
DE102011007196A1 (de)	2011-04-12	2012-10-18	Evonik Degussa Gmbh	Verfahren zur Herstellung eines Verbundes aus einem Polyamidformteil und einem Methacrylatcopolymer-Formteil
WO2013068326A1 (fr)	2011-11-08	2013-05-16	Solvay Specialty Polymers Usa, Llc	Polyamide résistant à une chaleur élevée pour constituants de pétrole de fond de puits
JP6340375B2 (ja) *	2014-01-08	2018-06-06	旭化成株式会社	ポリアミドマルチフィラメント繊維、及び該繊維を含むタイヤコード
JP6282903B2 (ja) *	2014-03-14	2018-02-21	ユニチカ株式会社	モノフィラメント
KR102637930B1 (ko)	2015-09-09	2024-02-20	솔베이 스페셜티 폴리머즈 유에스에이, 엘.엘.씨.	폴리에스테르 조성물 및 이로 제조된 휴대용 전자 장치 성분
WO2017144279A1 (fr)	2016-02-24	2017-08-31	Solvay Specialty Polymers Usa, Llc	Compositions polymères antichoc et articles fabriqués à partir de celles-ci
CN110283311B (zh) *	2019-06-26	2021-09-24	平顶山神马帘子布发展有限公司	一种尼龙66工业丝生产中减少铜析出的生产系统及生产方法
CN112724670B (zh) *	2020-12-29	2023-03-17	上海普利特复合材料股份有限公司	一种高强度、高耐热生物基聚酰胺组合物及其制备方法

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Publication number	Priority date	Publication date	Assignee	Title
US3457325A (en) *	1965-03-08	1969-07-22	Du Pont	Polyamide fibers stabilized with inorganic iodides and copper phthalates
DE1595603A1 (de) *	1966-03-12	1970-05-14	Bayer Ag	Stabilisierte Polyamide
NL139548B (nl) *	1969-03-06	1973-08-15	Snia Viscosa	Werkwijze voor het bereiden van gestabiliseerde polyamiden.
US3639335A (en) *	1970-06-12	1972-02-01	Toray Industries	Thermally-stable polyamide compositions
US3917561A (en) *	1974-03-29	1975-11-04	Monsanto Co	Process for preparing melt-stable poly(dodecamethyleneterephthalamide
EP0002761B1 (fr) *	1977-12-29	1982-09-01	Bayer Ag	Masse à mouler à base de polyamide résistante aux chocs
US4346194A (en) *	1980-01-22	1982-08-24	E. I. Du Pont De Nemours And Company	Toughened polyamide blends
US4594386A (en) *	1983-08-15	1986-06-10	Copolymer Rubber & Chemical Corporation	Polyamide grafted EPM blend
US4537929A (en) *	1984-01-20	1985-08-27	Plastic Specialties And Technologies, Inc.	High impact nylon composition
CA1289686C (fr) *	1985-07-31	1991-09-24	Richard Gelles	Compositions polymeres resistant aux impacts
US5006601A (en) *	1986-09-25	1991-04-09	Shell Oil Company	Impact resistant blends of thermoplastic polyamides, polyolefins and elastomers
DE3717218A1 (de) *	1987-05-22	1989-03-23	Bayer Ag	Glasfaserverstaerkte stabilisierte polyamidformmasse
CA2013049A1 (fr) *	1989-03-28	1990-09-28	Pieter Gijsman	Composition de polyamide 4.6
US5106946A (en) *	1989-10-20	1992-04-21	E. I. Du Pont De Nemours And Company	High tenacity, high modulus polyamide yarn and process for making same
CA2051767C (fr) *	1990-09-20	2003-05-13	Ruth A. Montag	Composition a base de polyphtalamide

1993
- 1993-09-16 US US08/122,367 patent/US5447980A/en not_active Expired - Lifetime
1994
- 1994-08-18 SG SG9608658A patent/SG79914A1/en unknown
- 1994-08-18 BR BR9405594-7A patent/BR9405594A/pt not_active IP Right Cessation
- 1994-08-18 CA CA002148487A patent/CA2148487C/fr not_active Expired - Fee Related
- 1994-08-18 DE DE69415493T patent/DE69415493T2/de not_active Expired - Lifetime
- 1994-08-18 EP EP94927951A patent/EP0668943B1/fr not_active Expired - Lifetime
- 1994-08-18 WO PCT/US1994/009596 patent/WO1995008011A1/fr not_active Ceased
- 1994-08-18 JP JP50919695A patent/JP3456483B2/ja not_active Expired - Lifetime
1995
- 1995-05-15 FI FI952356A patent/FI109812B/fi not_active IP Right Cessation
- 1995-05-16 NO NO19951935A patent/NO310935B1/no unknown

Also Published As

Publication number	Publication date
US5447980A (en)	1995-09-05
SG79914A1 (en)	2001-04-17
FI109812B (fi)	2002-10-15
CA2148487A1 (fr)	1995-03-23
FI952356L (fi)	1995-05-15
WO1995008011A1 (fr)	1995-03-23
JPH08503274A (ja)	1996-04-09
CA2148487C (fr)	2006-08-15
DE69415493T2 (de)	1999-09-02
BR9405594A (pt)	1999-09-08
NO951935L (no)	1995-05-16
NO951935D0 (no)	1995-05-16
EP0668943A1 (fr)	1995-08-30
DE69415493D1 (de)	1999-02-04
EP0668943B1 (fr)	1998-12-23
FI952356A0 (fi)	1995-05-15
JP3456483B2 (ja)	2003-10-14

Legal Events

Date	Code	Title	Description
2001-09-03	RE	Reestablishment of rights (par. 72 patents act)

Publication	Publication Date	Title
EP0668943B1 (fr)	1998-12-23	Fibre polyamide stabilisee
KR930009831B1 (ko)	1993-10-11	내연성 스테이플 섬유 배합물
AU628177B2 (en)	1992-09-10	PVP/para-aramid fibers and process for making them
CA2219551C (fr)	2007-06-26	Composition-resine de polyamide resistant au vieillissement et fibre a base de cette composition
AU725434B2 (en)	2000-10-12	Polyvinyl-alcohol-based flame retardant fiber
US5290850A (en)	1994-03-01	Processing of pigmented nylon fibers using modified polymers
JPH08506629A (ja)	1996-07-16	製紙機械フェルトのためのステープルとして有用なポリアミドファイバーを作るための方法
US5075168A (en)	1991-12-24	Polyamide filament and process for producing the same
US5135687A (en)	1992-08-04	Process for making PVP/para-aramid fibers
CA2095863C (fr)	2001-12-25	Procede pour l'obtention de fibres de polymeres pigmentes
Muskatell et al.	1997	Flame retardant polypropylene fibers with good dyeability
EP0735082B1 (fr)	2004-05-26	Compositions de résine polyphthalamide
JPH05209311A (ja)	1993-08-20	ポリプロピレン系繊維
US3573244A (en)	1971-03-30	Method for obtaining acid dye uniformity in polyamides
US3310607A (en)	1967-03-21	Bacteriostatic acrylonitrile polymers
JPS63227886A (ja)	1988-09-22	抄紙装置用ポリアミドモノフイラメント
US3471590A (en)	1969-10-07	Synthetic fiber-forming polyamides containing piperazine polyamides
US4043974A (en)	1977-08-23	Process for stabilizing polyamides
JP3657552B2 (ja)	2005-06-08	エチレン−ビニルアルコール系共重合体繊維
US2784168A (en)	1957-03-05	Polyamide solutions
KR870000747B1 (ko)	1987-04-13	흡습성 폴리아미드 섬유의 제조방법
JPH05132820A (ja)	1993-05-28	ナイロン４６フイラメントとその製造法
JPH073526A (ja)	1995-01-06	ポリアミド系繊維
HK1001191B (en)	1998-05-29	Pvp/para-aramid fibers and process for making them
JPH08269817A (ja)	1996-10-15	太物ナイロン・モノフィラメント