NO313875B1 - FremgangsmÕte for fremstilling av nikkelhydroksyd fra elementirt nikkel - Google Patents

FremgangsmÕte for fremstilling av nikkelhydroksyd fra elementirt nikkel Download PDF

Info

Publication number: NO313875B1
Authority: NO; Norway
Prior art keywords: nickel; aqueous solution; nickel hydroxide; hydroxide; elemental
Prior art date: 1994-03-22

Application number

NO19951078A

Other languages

English (en)

Norwegian (no)

Other versions

NO951078D0 (no

NO951078L (no

Inventor

Juraj Babjak

Victor Alexander Ettel

Original Assignee

Inco Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-03-22

Filing date

1995-03-21

Publication date

2002-12-16

1995-03-21 Application filed by Inco Ltd filed Critical Inco Ltd

1995-03-21 Publication of NO951078D0 publication Critical patent/NO951078D0/no

1995-09-25 Publication of NO951078L publication Critical patent/NO951078L/no

2002-12-16 Publication of NO313875B1 publication Critical patent/NO313875B1/no

Links

PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 147
BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 title claims description 60
229910052759 nickel Inorganic materials 0.000 title claims description 54
238000000034 method Methods 0.000 title claims description 23
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 53
238000006243 chemical reaction Methods 0.000 claims description 37
239000007864 aqueous solution Substances 0.000 claims description 28
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
239000001301 oxygen Substances 0.000 claims description 26
229910052760 oxygen Inorganic materials 0.000 claims description 26
239000000203 mixture Substances 0.000 claims description 11
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
229940075397 calomel Drugs 0.000 claims description 7
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 7
150000001450 anions Chemical class 0.000 claims description 4
239000002245 particle Substances 0.000 claims description 4
238000001556 precipitation Methods 0.000 claims description 4
238000001914 filtration Methods 0.000 claims description 2
230000003213 activating effect Effects 0.000 claims 1
239000000243 solution Substances 0.000 description 35
239000000843 powder Substances 0.000 description 21
229910021529 ammonia Inorganic materials 0.000 description 19
238000012360 testing method Methods 0.000 description 14
239000000725 suspension Substances 0.000 description 12
230000004913 activation Effects 0.000 description 9
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 9
238000007792 addition Methods 0.000 description 8
229910052921 ammonium sulfate Inorganic materials 0.000 description 8
235000011130 ammonium sulphate Nutrition 0.000 description 8
239000002002 slurry Substances 0.000 description 7
230000001105 regulatory effect Effects 0.000 description 6
239000000706 filtrate Substances 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
150000002815 nickel Chemical class 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
235000019257 ammonium acetate Nutrition 0.000 description 4
150000003863 ammonium salts Chemical class 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
229910000069 nitrogen hydride Inorganic materials 0.000 description 4
USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 3
239000005695 Ammonium acetate Substances 0.000 description 3
229910002651 NO3 Inorganic materials 0.000 description 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
229940043376 ammonium acetate Drugs 0.000 description 3
238000009835 boiling Methods 0.000 description 3
238000010586 diagram Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000012065 filter cake Substances 0.000 description 3
NPURPEXKKDAKIH-UHFFFAOYSA-N iodoimino(oxo)methane Chemical compound IN=C=O NPURPEXKKDAKIH-UHFFFAOYSA-N 0.000 description 3
239000007787 solid Substances 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000003929 acidic solution Substances 0.000 description 2
239000000908 ammonium hydroxide Substances 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000003518 caustics Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
238000009792 diffusion process Methods 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
238000013101 initial test Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000007885 magnetic separation Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
229910021508 nickel(II) hydroxide Inorganic materials 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
239000000047 product Substances 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
239000012266 salt solution Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
-1 thiosulphate anions Chemical class 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
239000004133 Sodium thiosulphate Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
239000001166 ammonium sulphate Substances 0.000 description 1
238000005349 anion exchange Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000003607 modifier Substances 0.000 description 1
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
229910001453 nickel ion Inorganic materials 0.000 description 1
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000012716 precipitator Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000004064 recycling Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
230000029219 regulation of pH Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
238000004448 titration Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/04—Oxides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Inorganic Compounds Of Heavy Metals (AREA)
Battery Electrode And Active Subsutance (AREA)
Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Powder Metallurgy (AREA)

NO19951078A 1994-03-22 1995-03-21 FremgangsmÕte for fremstilling av nikkelhydroksyd fra elementirt nikkel NO313875B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US21603694A	1994-03-22	1994-03-22
US08/402,368 US5545392A (en)	1994-03-22	1995-03-13	Process for producing nickel hydroxide from elemental nickel

Publications (3)

Publication Number	Publication Date
NO951078D0 NO951078D0 (no)	1995-03-21
NO951078L NO951078L (no)	1995-09-25
NO313875B1 true NO313875B1 (no)	2002-12-16

Family

ID=26910582

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO19951078A NO313875B1 (no)	1994-03-22	1995-03-21	FremgangsmÕte for fremstilling av nikkelhydroksyd fra elementirt nikkel

Country Status (11)

Country	Link
US (1)	US5545392A (fr)
EP (1)	EP0673882B1 (fr)
JP (1)	JP2758574B2 (fr)
CN (1)	CN1041193C (fr)
AT (1)	ATE161803T1 (fr)
AU (1)	AU678097B2 (fr)
CA (1)	CA2145155C (fr)
DE (1)	DE69501348T2 (fr)
ES (1)	ES2111369T3 (fr)
FI (1)	FI107801B (fr)
NO (1)	NO313875B1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5824283A (en) *	1997-04-28	1998-10-20	Inco Limited	Process for producing nickel hydroxide from elemental nickel
US6015538A (en) *	1998-06-16	2000-01-18	Inco Limited	Methods for doping and coating nickel hydroxide
JP2001031429A (ja)	1999-07-16	2001-02-06	Matsushita Electric Ind Co Ltd	水酸化ニッケルの製造方法
US6652603B2 (en)	2001-06-29	2003-11-25	Inco Limited	Process for removing sodium sulfate from nickel hydroxide effluent streams
US6576205B2 (en) *	2001-09-04	2003-06-10	Inco Limited	Method for reducing the crystallinity of nickel hydroxide powders
JP4880909B2 (ja) *	2005-03-03	2012-02-22	大平洋金属株式会社	ニッケル化合物またはコバルト化合物から硫黄などを除去する精製方法、フェロニッケルの製造方法
JP2007103111A (ja) *	2005-10-03	2007-04-19	Matsushita Electric Ind Co Ltd	アルカリ一次電池およびオキシ水酸化ニッケルの製造方法
CA3232367A1 (fr) *	2021-09-21	2023-03-30	Sabine FRISCHHUT	Methode de fabrication de precurseurs de materiaux actifs de cathode pour batteries au lithium-ion
CN117735619A (zh) *	2023-07-20	2024-03-22	新疆大学	一种在碳载体表面原位生长过渡金属氢氧化物的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA623339A (en) *		1961-07-04	B. Beer Henri	Method of precipitating or co-precipitating metal oxides, metal hydroxides or metal salts
FR1441749A (fr) *	1965-04-30	1966-06-10	Nickel Le	Nouveau procédé de fabrication d'hydrate de nickel pur
DE3029898A1 (de) *	1980-08-07	1982-03-04	Varta Batterie Ag, 3000 Hannover	Verfahren zur herstellung von nickel (ii)-hydroxid
AU618174B2 (en) *	1989-03-17	1991-12-12	E.I. Du Pont De Nemours And Company	Polyacetal resins containing non-meltable polymer stabilizers or cellulose stabilizers
DE69009811T2 (de) *	1989-03-20	1994-09-29	Inco Ltd	Nickelhydroxyd.
US5281494A (en) *	1990-05-04	1994-01-25	Inco Limited	Nickel hydroxide
JP2673078B2 (ja) *	1992-05-27	1997-11-05	東芝電池株式会社	アルカリ二次電池用のペースト式電極
DE69313936T2 (de) *	1992-06-15	1998-04-09	Inco Ltd	Verfahren zur Herstellung von Nickelhydroxyd
DE4239295C2 (de) *	1992-11-23	1995-05-11	Starck H C Gmbh Co Kg	Verfahren zur Herstellung von reinem Nickelhydroxid sowie dessen Verwendung
JP3225129B2 (ja) *	1993-03-31	2001-11-05	東芝電池株式会社	アルカリ二次電池の製造方法
JPH06295727A (ja) *	1993-04-09	1994-10-21	Toshiba Battery Co Ltd	密閉式アルカリ蓄電池
CN1075697A (zh) *	1993-04-09	1993-09-01	河南师范大学	球形微粒氢氧化镍制造法

1995
- 1995-03-13 US US08/402,368 patent/US5545392A/en not_active Expired - Lifetime
- 1995-03-21 CN CN95114810A patent/CN1041193C/zh not_active Expired - Fee Related
- 1995-03-21 CA CA002145155A patent/CA2145155C/fr not_active Expired - Fee Related
- 1995-03-21 AU AU14964/95A patent/AU678097B2/en not_active Ceased
- 1995-03-21 NO NO19951078A patent/NO313875B1/no unknown
- 1995-03-21 FI FI951326A patent/FI107801B/fi not_active IP Right Cessation
- 1995-03-22 AT AT95301902T patent/ATE161803T1/de not_active IP Right Cessation
- 1995-03-22 DE DE69501348T patent/DE69501348T2/de not_active Expired - Fee Related
- 1995-03-22 EP EP95301902A patent/EP0673882B1/fr not_active Expired - Lifetime
- 1995-03-22 JP JP7063184A patent/JP2758574B2/ja not_active Expired - Fee Related
- 1995-03-22 ES ES95301902T patent/ES2111369T3/es not_active Expired - Lifetime

Also Published As

Publication number	Publication date
DE69501348D1 (de)	1998-02-12
AU678097B2 (en)	1997-05-15
CA2145155A1 (fr)	1995-09-23
AU1496495A (en)	1995-09-28
US5545392A (en)	1996-08-13
NO951078D0 (no)	1995-03-21
JP2758574B2 (ja)	1998-05-28
CA2145155C (fr)	1999-01-19
NO951078L (no)	1995-09-25
FI107801B (fi)	2001-10-15
DE69501348T2 (de)	1998-07-23
CN1041193C (zh)	1998-12-16
ES2111369T3 (es)	1998-03-01
EP0673882A1 (fr)	1995-09-27
ATE161803T1 (de)	1998-01-15
CN1112521A (zh)	1995-11-29
JPH0834618A (ja)	1996-02-06
FI951326A0 (fi)	1995-03-21
FI951326L (fi)	1995-09-23
EP0673882B1 (fr)	1998-01-07

Publication	Publication Date	Title
JP4316393B2 (ja)	2009-08-19	フッ化カルシウムの製造方法と再利用法ならびにそのリサイクル方法
CN100594180C (zh)	2010-03-17	海水提取高纯超细微粉氢氧化镁的生产方法
NO313875B1 (no)	2002-12-16	FremgangsmÕte for fremstilling av nikkelhydroksyd fra elementirt nikkel
EP0575093B1 (fr)	1997-09-17	Procédé de préparation d'hydroxyde de nickel
AU2020401568A1 (en)	2022-06-30	Process and method for refining lithium carbonate starting from an impure lithium chloride solution
JP2013212985A (ja)	2013-10-17	パラタングステン酸アンモニウム四水和物及び高純度のパラタングステン酸アンモニウム四水和物を製造する方法
US12129183B2 (en)	2024-10-29	Method for preparing basic copper carbonate
CN116534900A (zh)	2023-08-04	一种同时制备硫化锰和电池级硫酸锰的方法
CN117597308B (zh)	2025-09-30	一种对电池回收过程中产生的废弃资源进行回收的方法
US4100264A (en)	1978-07-11	Process for the preparation of calcium carbonate for use in fluorescent lamp phosphors
CN106800303A (zh)	2017-06-06	一种利用微通道反应器制备碘化钾的方法
RU2389690C2 (ru)	2010-05-20	Порошок вольфрамовой кислоты, состоящий из сферических частиц вольфрамовой кислоты, и способ его получения
KR100323880B1 (ko)	2002-08-01	니켈 원소로부터 수산화니켈 제조방법
US4337228A (en)	1982-06-29	Process for the production of sulfates
CN1040012A (zh)	1990-02-28	保险粉废液的处理及亚硫酸钠和氯化钠的回收方法
CN86102308A (zh)	1987-10-14	钨精矿制取粉状钨酸的工艺
CN113460976B (zh)	2023-11-14	一种含锡二氧化碲的提纯方法
RU2795224C1 (ru)	2023-05-02	Процесс и способ очистки карбоната лития, исходя из раствора хлорида лития с примесями
JP2000178663A (ja)	2000-06-27	アルミニウムドロスの処理方法
AU2011226890B1 (en)	2012-12-20	Continuous process for preparation of calcium thiosulfate liquid solution
JPS6350328A (ja)	1988-03-03	炭酸ニツケルの製造方法
JPH11130441A (ja)	1999-05-18	ニッケルを含有する水酸化物の製造方法
SU810844A1 (ru)	1981-03-07	Способ осаждени никел и кобальтаиз PACTBOPOB
CN118619351A (zh)	2024-09-10	一种以含杂锰液制备四氧化三锰的方法
Weiser et al.	1940	Alumina Floc X-Ray Diffraction Study