NO330700B1 - Anvendelse av stannylener og germylener som polymerisasjonskatalysatorer for heterocykler - Google Patents

Anvendelse av stannylener og germylener som polymerisasjonskatalysatorer for heterocykler Download PDF

Info

Publication number: NO330700B1
Authority: NO; Norway
Prior art keywords: sub; formula; atom; independently represent; group
Prior art date: 2000-05-15

Application number

NO20025410A

Other languages

English (en)

Norwegian (no)

Other versions

NO20025410L (no

NO20025410D0 (no

Inventor

Jean-Bernard Cazaux

Guy Bertrand

Blanca Martin-Vaca

Didier Bourissou

Anca Dumitrescu

Heinz Gornitzka

Original Assignee

Centre Nat Rech Scient

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-05-15

Filing date

2002-11-12

Publication date

2011-06-14

2002-11-12 Application filed by Centre Nat Rech Scient filed Critical Centre Nat Rech Scient

2002-11-12 Publication of NO20025410L publication Critical patent/NO20025410L/no

2002-11-12 Publication of NO20025410D0 publication Critical patent/NO20025410D0/no

2011-06-14 Publication of NO330700B1 publication Critical patent/NO330700B1/no

Links

-1 stannylenes Chemical class 0.000 title claims abstract description 25
125000000623 heterocyclic group Chemical group 0.000 title claims abstract description 14
239000002685 polymerization catalyst Substances 0.000 title claims abstract description 9
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 6
125000000217 alkyl group Chemical group 0.000 claims description 19
150000001875 compounds Chemical class 0.000 claims description 17
238000006116 polymerization reaction Methods 0.000 claims description 15
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 12
125000003118 aryl group Chemical group 0.000 claims description 10
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
125000004122 cyclic group Chemical group 0.000 claims description 7
125000000753 cycloalkyl group Chemical group 0.000 claims description 7
229920000642 polymer Polymers 0.000 claims description 7
125000001424 substituent group Chemical group 0.000 claims description 7
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
229910052710 silicon Inorganic materials 0.000 claims description 6
238000007334 copolymerization reaction Methods 0.000 claims description 5
229910052718 tin Inorganic materials 0.000 claims description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
125000005843 halogen group Chemical group 0.000 claims description 4
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
150000002924 oxiranes Chemical class 0.000 claims description 4
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
125000004093 cyano group Chemical group *C#N 0.000 claims description 3
235000014655 lactic acid Nutrition 0.000 claims description 3
239000004310 lactic acid Substances 0.000 claims description 3
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
229910052732 germanium Inorganic materials 0.000 claims description 2
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
125000004430 oxygen atom Chemical group O* 0.000 claims description 2
125000004437 phosphorous atom Chemical group 0.000 claims description 2
229910052698 phosphorus Inorganic materials 0.000 claims description 2
229910052717 sulfur Inorganic materials 0.000 claims description 2
125000004434 sulfur atom Chemical group 0.000 claims description 2
JEVCWSUVFOYBFI-UHFFFAOYSA-N cyanyl Chemical compound N#[C] JEVCWSUVFOYBFI-UHFFFAOYSA-N 0.000 claims 1
150000004292 cyclic ethers Chemical class 0.000 claims 1
229920006395 saturated elastomer Polymers 0.000 abstract description 3
241000208152 Geranium Species 0.000 abstract description 2
RKDVKSZUMVYZHH-UHFFFAOYSA-N 1,4-dioxane-2,5-dione Chemical compound O=C1COC(=O)CO1 RKDVKSZUMVYZHH-UHFFFAOYSA-N 0.000 description 26
229920001577 copolymer Polymers 0.000 description 26
239000000203 mixture Substances 0.000 description 14
JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 13
JJTUDXZGHPGLLC-IMJSIDKUSA-N 4511-42-6 Chemical compound C[C@@H]1OC(=O)[C@H](C)OC1=O JJTUDXZGHPGLLC-IMJSIDKUSA-N 0.000 description 12
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 11
239000000178 monomer Substances 0.000 description 10
229920002521 macromolecule Polymers 0.000 description 9
238000004458 analytical method Methods 0.000 description 8
238000002360 preparation method Methods 0.000 description 8
238000003756 stirring Methods 0.000 description 8
238000005481 NMR spectroscopy Methods 0.000 description 7
239000011541 reaction mixture Substances 0.000 description 7
229910052786 argon Inorganic materials 0.000 description 6
229920000747 poly(lactic acid) Polymers 0.000 description 6
239000002904 solvent Substances 0.000 description 5
AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 4
125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 4
238000000034 method Methods 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
229920001400 block copolymer Polymers 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
239000000539 dimer Substances 0.000 description 2
239000003446 ligand Substances 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
239000000758 substrate Substances 0.000 description 2
NUMQCACRALPSHD-UHFFFAOYSA-N tert-butyl ethyl ether Chemical compound CCOC(C)(C)C NUMQCACRALPSHD-UHFFFAOYSA-N 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
UQRONKZLYKUEMO-UHFFFAOYSA-N 4-methyl-1-(2,4,6-trimethylphenyl)pent-4-en-2-one Chemical group CC(=C)CC(=O)Cc1c(C)cc(C)cc1C UQRONKZLYKUEMO-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
125000002015 acyclic group Chemical group 0.000 description 1
150000003998 acyclic ketones Chemical class 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
150000008365 aromatic ketones Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
238000006065 biodegradation reaction Methods 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000007810 chemical reaction solvent Substances 0.000 description 1
125000002592 cumenyl group Chemical group C1(=C(C=CC=C1)*)C(C)C 0.000 description 1
CFBGXYDUODCMNS-UHFFFAOYSA-N cyclobutene Chemical compound C1CC=C1 CFBGXYDUODCMNS-UHFFFAOYSA-N 0.000 description 1
125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexediene Natural products C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
239000003999 initiator Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000003951 lactams Chemical class 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
239000004973 liquid crystal related substance Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000012528 membrane Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000002950 monocyclic group Chemical group 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
125000005561 phenanthryl group Chemical group 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
125000003367 polycyclic group Chemical group 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000004781 supercooling Methods 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
230000001225 therapeutic effect Effects 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
238000012795 verification Methods 0.000 description 1
125000005023 xylyl group Chemical group 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0252—Nitrogen containing compounds with a metal-nitrogen link, e.g. metal amides, metal guanidides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Polyesters Or Polycarbonates (AREA)
Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Polymerization Catalysts (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Biological Depolymerization Polymers (AREA)
Polyethers (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

NO20025410A 2000-05-15 2002-11-12 Anvendelse av stannylener og germylener som polymerisasjonskatalysatorer for heterocykler NO330700B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP00401309		2000-05-15
PCT/FR2001/001405 WO2001088014A1 (fr)	2000-05-15	2001-05-10	Utilisation de stannylenes et germylenes comme catalyseurs de polymerisation d'heterocycles

Publications (3)

Publication Number	Publication Date
NO20025410L NO20025410L (no)	2002-11-12
NO20025410D0 NO20025410D0 (no)	2002-11-12
NO330700B1 true NO330700B1 (no)	2011-06-14

Family

ID=8173676

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO20025410A NO330700B1 (no)	2000-05-15	2002-11-12	Anvendelse av stannylener og germylener som polymerisasjonskatalysatorer for heterocykler

Country Status (13)

Country	Link
US (1)	US7084237B2 (cs)
EP (1)	EP1290062B1 (cs)
JP (1)	JP5276760B2 (cs)
AT (1)	ATE528335T1 (cs)
AU (1)	AU2001260388A1 (cs)
CA (1)	CA2408394C (cs)
CZ (1)	CZ304547B6 (cs)
ES (1)	ES2375218T3 (cs)
HU (1)	HU229198B1 (cs)
NO (1)	NO330700B1 (cs)
PL (1)	PL215002B1 (cs)
RU (1)	RU2282640C2 (cs)
WO (1)	WO2001088014A1 (cs)

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2525235C1 (ru) *	2013-05-20	2014-08-10	Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт"	Способ получения катализатора полимеризации лактонов или поликонденсации альфа-оксикислот

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US383927A (en) *		1888-06-05		Lawn-mower
US3839297A (en)	1971-11-22	1974-10-01	Ethicon Inc	Use of stannous octoate catalyst in the manufacture of l(-)lactide-glycolide copolymer sutures
EP0295401A3 (de) *	1987-04-30	1990-03-21	Wacker-Chemie Gmbh	Verfahren zur Polymerisation von polaren Verbindungen
JP3164456B2 (ja) *	1993-02-22	2001-05-08	ダイセル化学工業株式会社	ラクトン重合体の製造方法
JP3098350B2 (ja) *	1993-02-26	2000-10-16	高砂香料工業株式会社	ポリ（３−ヒドロキシ酪酸）の製造方法
JPH0867748A (ja) *	1994-08-30	1996-03-12	Kanegafuchi Chem Ind Co Ltd	ポリエステル及びポリエステルカーボネートの製造方法
JP3379841B2 (ja) *	1994-10-28	2003-02-24	高砂香料工業株式会社	ブロック共重合ポリ（エステル−カーボネート）及びその製造方法
CA2253416C (fr)	1996-05-02	2006-09-19	Societe De Conseils De Recherches Et D'applications Scientifiques (S.C.R.A.S.)	Nouveaux composes possedant un element du groupe 13 lie a un ligand tridentate mono- ou di-anionique, leur procede de preparation et leur application comme catalyseurs de polymerisation
US6255515B1 (en) *	1997-01-21	2001-07-03	Mitsubishi Chemical Corporation	Processes for producing silicon- or germanium-containing organic compound, transition metal complex, catalyst for polymerization of α-olefin and α-olefin polymer
EP0890575A1 (fr) *	1997-07-08	1999-01-13	Societe De Conseils De Recherches Et D'applications Scientifiques (S.C.R.A.S.)	Nouveaux composés possédant un élément du groupe 11,12 ou 14 et un ligand tridentate, leur procédé de préparation et leur application notamment comme catalyseurs de polymérisation
JPH11116594A (ja) *	1997-10-14	1999-04-27	Takasago Internatl Corp	スズ化合物、その製法、及びこれを用いたポリ（３−ヒドロキシ酪酸）類の製造方法

2001
- 2001-05-10 ES ES01934071T patent/ES2375218T3/es not_active Expired - Lifetime
- 2001-05-10 AT AT01934071T patent/ATE528335T1/de not_active IP Right Cessation
- 2001-05-10 RU RU2002133460/04A patent/RU2282640C2/ru not_active IP Right Cessation
- 2001-05-10 EP EP01934071A patent/EP1290062B1/fr not_active Expired - Lifetime
- 2001-05-10 AU AU2001260388A patent/AU2001260388A1/en not_active Abandoned
- 2001-05-10 HU HU0302048A patent/HU229198B1/hu not_active IP Right Cessation
- 2001-05-10 CA CA2408394A patent/CA2408394C/fr not_active Expired - Lifetime
- 2001-05-10 PL PL358179A patent/PL215002B1/pl unknown
- 2001-05-10 JP JP2001585231A patent/JP5276760B2/ja not_active Expired - Fee Related
- 2001-05-10 US US10/275,332 patent/US7084237B2/en not_active Expired - Lifetime
- 2001-05-10 CZ CZ2002-3683A patent/CZ304547B6/cs not_active IP Right Cessation
- 2001-05-10 WO PCT/FR2001/001405 patent/WO2001088014A1/fr not_active Ceased
2002
- 2002-11-12 NO NO20025410A patent/NO330700B1/no not_active IP Right Cessation

Also Published As

Publication number	Publication date
HUP0302048A2 (hu)	2003-09-29
HU229198B1 (hu)	2013-09-30
ATE528335T1 (de)	2011-10-15
WO2001088014A1 (fr)	2001-11-22
HUP0302048A3 (en)	2007-09-28
NO20025410L (no)	2002-11-12
AU2001260388A1 (en)	2001-11-26
US7084237B2 (en)	2006-08-01
EP1290062B1 (fr)	2011-10-12
CA2408394C (fr)	2010-07-20
EP1290062A1 (fr)	2003-03-12
RU2282640C2 (ru)	2006-08-27
US20030153717A1 (en)	2003-08-14
ES2375218T3 (es)	2012-02-27
JP2004525193A (ja)	2004-08-19
PL358179A1 (en)	2004-08-09
CA2408394A1 (fr)	2001-11-22
JP5276760B2 (ja)	2013-08-28
CZ20023683A3 (cs)	2003-06-18
CZ304547B6 (cs)	2014-07-02
NO20025410D0 (no)	2002-11-12
PL215002B1 (pl)	2013-10-31

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NO337440B1 (no)	2016-04-11	Anvendelse av katalytisk system, samt en laktid- og glykolid- (ko)polymerisasjonsprosess.
NO330700B1 (no)	2011-06-14	Anvendelse av stannylener og germylener som polymerisasjonskatalysatorer for heterocykler
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CN109749072B (zh)	2021-09-24	利用双核胺亚胺镁配合物催化丙交酯聚合的方法
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