NO744558L - - Google Patents

Info

Publication number: NO744558L
Authority: NO; Norway
Prior art keywords: stands; titanium; reaction product; weight; parts
Prior art date: 1973-12-21

Application number

NO744558A

Other languages

English (en)

Norwegian (no)

Inventor

E Kolk

H Frielingsdorf

G Schweier

W Gruber

H Mueller-Tamm

Original Assignee

Basf Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-12-21

Filing date

1974-12-17

Publication date

1975-07-21

1974-12-17 Application filed by Basf Ag filed Critical Basf Ag

1975-07-21 Publication of NO744558L publication Critical patent/NO744558L/no

Links

239000010936 titanium Substances 0.000 claims description 121
229910052719 titanium Inorganic materials 0.000 claims description 118
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 108
239000003054 catalyst Substances 0.000 claims description 106
239000007795 chemical reaction product Substances 0.000 claims description 106
229910052751 metal Inorganic materials 0.000 claims description 54
239000002184 metal Substances 0.000 claims description 54
239000000725 suspension Substances 0.000 claims description 41
238000006116 polymerization reaction Methods 0.000 claims description 40
-1 aluminum compound Chemical class 0.000 claims description 35
238000004519 manufacturing process Methods 0.000 claims description 33
239000007790 solid phase Substances 0.000 claims description 25
238000000034 method Methods 0.000 claims description 23
229910052782 aluminium Inorganic materials 0.000 claims description 22
239000001257 hydrogen Substances 0.000 claims description 19
229910052739 hydrogen Inorganic materials 0.000 claims description 19
150000001875 compounds Chemical class 0.000 claims description 18
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 17
239000005977 Ethylene Substances 0.000 claims description 17
150000002148 esters Chemical class 0.000 claims description 14
150000003839 salts Chemical class 0.000 claims description 14
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
239000000460 chlorine Substances 0.000 claims description 13
125000000217 alkyl group Chemical group 0.000 claims description 12
238000002156 mixing Methods 0.000 claims description 12
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 11
239000002253 acid Substances 0.000 claims description 11
229910052801 chlorine Inorganic materials 0.000 claims description 11
125000004432 carbon atom Chemical group C* 0.000 claims description 10
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 9
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 9
229910052794 bromium Inorganic materials 0.000 claims description 9
150000002430 hydrocarbons Chemical group 0.000 claims description 9
229910052740 iodine Inorganic materials 0.000 claims description 9
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 8
239000011630 iodine Substances 0.000 claims description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
229920001519 homopolymer Polymers 0.000 claims description 7
229910052749 magnesium Inorganic materials 0.000 claims description 7
239000011777 magnesium Substances 0.000 claims description 7
239000012071 phase Substances 0.000 claims description 7
125000005037 alkyl phenyl group Chemical group 0.000 claims description 6
239000004411 aluminium Substances 0.000 claims description 6
150000002431 hydrogen Chemical class 0.000 claims description 6
150000002739 metals Chemical class 0.000 claims description 6
239000000178 monomer Substances 0.000 claims description 6
150000002894 organic compounds Chemical class 0.000 claims description 6
125000003884 phenylalkyl group Chemical group 0.000 claims description 6
229920001577 copolymer Polymers 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
150000002736 metal compounds Chemical class 0.000 claims description 3
239000011701 zinc Substances 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 2
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 2
229910052748 manganese Inorganic materials 0.000 claims 2
239000011572 manganese Substances 0.000 claims 2
125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 82
238000002360 preparation method Methods 0.000 description 28
238000006243 chemical reaction Methods 0.000 description 18
238000003756 stirring Methods 0.000 description 15
159000000003 magnesium salts Chemical class 0.000 description 13
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 11
229920000642 polymer Polymers 0.000 description 9
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 8
239000000047 product Substances 0.000 description 8
VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 8
238000001816 cooling Methods 0.000 description 7
239000002904 solvent Substances 0.000 description 7
238000010438 heat treatment Methods 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
238000010992 reflux Methods 0.000 description 5
239000004698 Polyethylene Substances 0.000 description 4
XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 4
229920000573 polyethylene Polymers 0.000 description 4
239000007787 solid Substances 0.000 description 4
LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 4
RFONJRMUUALMBA-UHFFFAOYSA-N 2-methanidylpropane Chemical compound CC(C)[CH2-] RFONJRMUUALMBA-UHFFFAOYSA-N 0.000 description 3
238000009835 boiling Methods 0.000 description 3
239000000203 mixture Substances 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
QUVMSYUGOKEMPX-UHFFFAOYSA-N 2-methylpropan-1-olate;titanium(4+) Chemical compound [Ti+4].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] QUVMSYUGOKEMPX-UHFFFAOYSA-N 0.000 description 2
GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000012467 final product Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000003746 solid phase reaction Methods 0.000 description 2
239000007858 starting material Substances 0.000 description 2
239000000375 suspending agent Substances 0.000 description 2
238000010557 suspension polymerization reaction Methods 0.000 description 2
JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical compound CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
230000000877 morphologic effect Effects 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
SUSQOBVLVYHIEX-UHFFFAOYSA-N phenylacetonitrile Chemical compound N#CCC1=CC=CC=C1 SUSQOBVLVYHIEX-UHFFFAOYSA-N 0.000 description 1
230000008092 positive effect Effects 0.000 description 1
HKJYVRJHDIPMQB-UHFFFAOYSA-N propan-1-olate;titanium(4+) Chemical compound CCCO[Ti](OCCC)(OCCC)OCCC HKJYVRJHDIPMQB-UHFFFAOYSA-N 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000002040 relaxant effect Effects 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
230000007306 turnover Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

NO744558A 1973-12-21 1974-12-17 NO744558L (it)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE2363697A DE2363697C3 (de)	1973-12-21	1973-12-21	Verfahren zum Herstellen von Homopolymerisaten des Äthylens oder Copolymerisaten des Äthylens mit a -Monoolefinen BASF AG, 6700 Ludwigshafen

Publications (1)

Publication Number	Publication Date
NO744558L true NO744558L (it)	1975-07-21

Family

ID=5901474

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO744558A NO744558L (it)	1973-12-21	1974-12-17

Country Status (10)

Country	Link
JP (1)	JPS5096686A (it)
AT (1)	AT333501B (it)
AU (1)	AU498151B2 (it)
BE (1)	BE823378A (it)
DE (1)	DE2363697C3 (it)
FR (1)	FR2255318B1 (it)
GB (1)	GB1456410A (it)
IT (1)	IT1025555B (it)
NO (1)	NO744558L (it)
SE (1)	SE7416070L (it)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5274686A (en) *	1975-12-18	1977-06-22	Sumitomo Chem Co Ltd	Process for polymerizing olefins

1973
- 1973-12-21 DE DE2363697A patent/DE2363697C3/de not_active Expired
1974
- 1974-11-12 IT IT29358/74A patent/IT1025555B/it active
- 1974-12-12 AU AU76355/74A patent/AU498151B2/en not_active Expired
- 1974-12-16 BE BE151524A patent/BE823378A/xx unknown
- 1974-12-17 NO NO744558A patent/NO744558L/no unknown
- 1974-12-19 SE SE7416070A patent/SE7416070L/xx unknown
- 1974-12-19 FR FR7442037A patent/FR2255318B1/fr not_active Expired
- 1974-12-19 GB GB5485374A patent/GB1456410A/en not_active Expired
- 1974-12-20 JP JP49145800A patent/JPS5096686A/ja active Pending
- 1974-12-20 AT AT1022274A patent/AT333501B/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
AU498151B2 (en)	1979-02-15
DE2363697C3 (de)	1981-01-15
DE2363697B2 (de)	1980-04-30
FR2255318A1 (it)	1975-07-18
IT1025555B (it)	1978-08-30
DE2363697A1 (de)	1975-07-03
AT333501B (de)	1976-11-25
SE7416070L (it)	1975-06-23
AU7635574A (en)	1976-06-17
GB1456410A (en)	1976-11-24
FR2255318B1 (it)	1978-03-24
JPS5096686A (it)	1975-07-31
BE823378A (fr)	1975-06-16
ATA1022274A (de)	1976-03-15

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EP2630170B1 (en)	2015-04-22	Catalyst system for the polymerization of olefins
US2820778A (en)	1958-01-21	Production of polymerization products from olefinically unsaturated hydrocarbons
WO2002068365A1 (fr)	2002-09-06	Procede de production d'un polymere a faible teneur en $g(a)-olefine
US2922782A (en)	1960-01-26	Olefin polymerization process using catalyst obtained by mixing a reducible heavy metal compound and a reducing metal-containing compound and promoted by a boron halide
CN104250317A (zh)	2014-12-31	一种用于烯烃聚合反应的催化剂
NO180272B (no)	1996-12-09	Fremgangsmåte for fremstilling av katalysator og polymerisasjon av olefiner ved anvendelse av katalysatoren
WO2009150114A1 (en)	2009-12-17	Catalyst system for the polymerization of olefins
US4368306A (en)	1983-01-11	Process and catalyst for the polymerization of α-olefins
JP2007514026A (ja)	2007-05-31	オレフィンの重合のための液相法
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CN106543313A (zh)	2017-03-29	一种烯烃聚合催化剂体系及其应用
US3180837A (en)	1965-04-27	Polymerization catalyst containing polymeric diene-aluminum compounds
EP0584606A2 (en)	1994-03-02	Vanadium based components and catalysts for the polymerization of olefins and polymerization processes using the same
SE449495B (sv)	1987-05-04	Kontinuerligt forfarande for framstellning av eten-propen-segmentpolymerer i angfas
NO744556L (it)	1975-07-21
EA038325B1 (ru)	2021-08-10	Прокатализатор для полимеризации олефинов
NO180683B (no)	1997-02-17	Fremgangsmåte for fremstilling av en katalytisk komponent
JPS5827706A (ja)	1983-02-18	オレフイン類の重合用触媒およびその製法