NO753473L - - Google Patents

Info

Publication number: NO753473L
Authority: NO; Norway
Prior art keywords: phosphoric acid; coating; amount; mixture; polymerization
Prior art date: 1974-10-28

Application number

NO753473A

Other languages

English (en)

Norwegian (no)

Inventor

K Ogawa

K Kurimoto

Y Eguchi

S Kuwata

Original Assignee

Shinetsu Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-10-28

Filing date

1975-10-15

Publication date

1976-04-29

1975-10-15 Application filed by Shinetsu Chemical Co filed Critical Shinetsu Chemical Co

1976-04-29 Publication of NO753473L publication Critical patent/NO753473L/no

Links

239000000178 monomer Substances 0.000 claims description 46
238000000034 method Methods 0.000 claims description 42
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 39
238000000576 coating method Methods 0.000 claims description 37
-1 phosphoric acid compound Chemical class 0.000 claims description 36
239000011248 coating agent Substances 0.000 claims description 33
238000006116 polymerization reaction Methods 0.000 claims description 33
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 25
239000000203 mixture Substances 0.000 claims description 24
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
150000002148 esters Chemical class 0.000 claims description 16
229920000137 polyphosphoric acid Polymers 0.000 claims description 12
238000012662 bulk polymerization Methods 0.000 claims description 11
229910052783 alkali metal Inorganic materials 0.000 claims description 9
239000003112 inhibitor Substances 0.000 claims description 8
150000003014 phosphoric acid esters Chemical class 0.000 claims description 8
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 6
IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 6
IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 6
YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 6
235000002949 phytic acid Nutrition 0.000 claims description 6
229940068041 phytic acid Drugs 0.000 claims description 6
239000000467 phytic acid Substances 0.000 claims description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
239000002253 acid Substances 0.000 claims description 4
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical group C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 4
150000003016 phosphoric acids Chemical class 0.000 claims description 4
229910052708 sodium Inorganic materials 0.000 claims description 4
239000011734 sodium Substances 0.000 claims description 4
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 3
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
150000001299 aldehydes Chemical class 0.000 claims description 3
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 3
229910052744 lithium Inorganic materials 0.000 claims description 3
239000002904 solvent Substances 0.000 claims description 3
239000000600 sorbitol Substances 0.000 claims description 3
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
229940084778 1,4-sorbitan Drugs 0.000 claims description 2
GIXFALHDORQSOQ-UHFFFAOYSA-N 2,4,6,8-tetrahydroxy-1,3,5,7,2$l^{5},4$l^{5},6$l^{5},8$l^{5}-tetraoxatetraphosphocane 2,4,6,8-tetraoxide Chemical compound OP1(=O)OP(O)(=O)OP(O)(=O)OP(O)(=O)O1 GIXFALHDORQSOQ-UHFFFAOYSA-N 0.000 claims description 2
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 2
229930195725 Mannitol Natural products 0.000 claims description 2
229930192627 Naphthoquinone Natural products 0.000 claims description 2
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 claims description 2
MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 claims description 2
AZSFNUJOCKMOGB-UHFFFAOYSA-N cyclotriphosphoric acid Chemical compound OP1(=O)OP(O)(=O)OP(O)(=O)O1 AZSFNUJOCKMOGB-UHFFFAOYSA-N 0.000 claims description 2
XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 2
GSXOAOHZAIYLCY-HSUXUTPPSA-N keto-D-fructose 6-phosphate Chemical compound OCC(=O)[C@@H](O)[C@H](O)[C@H](O)COP(O)(O)=O GSXOAOHZAIYLCY-HSUXUTPPSA-N 0.000 claims description 2
239000000594 mannitol Substances 0.000 claims description 2
235000010355 mannitol Nutrition 0.000 claims description 2
150000002791 naphthoquinones Chemical class 0.000 claims description 2
159000000001 potassium salts Chemical class 0.000 claims description 2
229940005657 pyrophosphoric acid Drugs 0.000 claims description 2
WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 claims description 2
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 claims description 2
229940048102 triphosphoric acid Drugs 0.000 claims description 2
WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical group COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 claims 1
235000019441 ethanol Nutrition 0.000 description 23
229920000642 polymer Polymers 0.000 description 20
150000001875 compounds Chemical class 0.000 description 19
150000001298 alcohols Chemical class 0.000 description 10
238000002474 experimental method Methods 0.000 description 10
239000000243 solution Substances 0.000 description 8
238000003756 stirring Methods 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
239000002245 particle Substances 0.000 description 5
229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
238000007792 addition Methods 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000011877 solvent mixture Substances 0.000 description 4
238000005406 washing Methods 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
241000251468 Actinopterygii Species 0.000 description 3
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
229910021538 borax Inorganic materials 0.000 description 3
BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 3
XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 3
235000010339 sodium tetraborate Nutrition 0.000 description 3
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 3
OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 description 2
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
150000001642 boronic acid derivatives Chemical class 0.000 description 2
HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
238000011010 flushing procedure Methods 0.000 description 2
239000003999 initiator Substances 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
239000012046 mixed solvent Substances 0.000 description 2
LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
238000012546 transfer Methods 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
RLLPVAHGXHCWKJ-IEBWSBKVSA-N (3-phenoxyphenyl)methyl (1s,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-IEBWSBKVSA-N 0.000 description 1
ZCJLOOJRNPHKAV-ONEGZZNKSA-N (e)-3-(furan-2-yl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CO1 ZCJLOOJRNPHKAV-ONEGZZNKSA-N 0.000 description 1
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
RJKGJBPXVHTNJL-UHFFFAOYSA-N 1-nitronaphthalene Chemical class C1=CC=C2C([N+](=O)[O-])=CC=CC2=C1 RJKGJBPXVHTNJL-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
WCASXYBKJHWFMY-NSCUHMNNSA-N 2-Buten-1-ol Chemical compound C\C=C\CO WCASXYBKJHWFMY-NSCUHMNNSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
GXGVVNFBYYEAEH-UHFFFAOYSA-N 3-methyl-4-phenylpent-3-en-2-one Chemical compound CC(=O)C(C)=C(C)C1=CC=CC=C1 GXGVVNFBYYEAEH-UHFFFAOYSA-N 0.000 description 1
JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
229930185605 Bisphenol Natural products 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
235000019445 benzyl alcohol Nutrition 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
230000001680 brushing effect Effects 0.000 description 1
NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
150000001896 cresols Chemical class 0.000 description 1
150000005675 cyclic monoalkenes Chemical class 0.000 description 1
ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical compound C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 description 1
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
XCIXKGXIYUWCLL-UHFFFAOYSA-N cyclopentanol Chemical compound OC1CCCC1 XCIXKGXIYUWCLL-UHFFFAOYSA-N 0.000 description 1
UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000010981 drying operation Methods 0.000 description 1
GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
WCASXYBKJHWFMY-UHFFFAOYSA-N gamma-methylallyl alcohol Natural products CC=CCO WCASXYBKJHWFMY-UHFFFAOYSA-N 0.000 description 1
239000008103 glucose Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical group 0.000 description 1
238000011835 investigation Methods 0.000 description 1
OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
235000020778 linoleic acid Nutrition 0.000 description 1
239000007788 liquid Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
150000004780 naphthols Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
125000005634 peroxydicarbonate group Chemical group 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229960004838 phosphoric acid Drugs 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229940079877 pyrogallol Drugs 0.000 description 1
150000004053 quinones Chemical class 0.000 description 1
239000000523 sample Substances 0.000 description 1
235000010199 sorbic acid Nutrition 0.000 description 1
239000004334 sorbic acid Substances 0.000 description 1
229940075582 sorbic acid Drugs 0.000 description 1
238000005507 spraying Methods 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
238000012360 testing method Methods 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
ACWQBUSCFPJUPN-HWKANZROSA-N trans-2-methyl-2-butenal Chemical compound C\C=C(/C)C=O ACWQBUSCFPJUPN-HWKANZROSA-N 0.000 description 1
VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 description 1
WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/004—Scale prevention in a polymerisation reactor or its auxiliary parts by a prior coating on the reactor walls

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

NO753473A 1974-10-28 1975-10-15 NO753473L (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP49124096A JPS5150388A (en)	1974-10-28	1974-10-28	Enkabiniruno kaijojugoho

Publications (1)

Publication Number	Publication Date
NO753473L true NO753473L (fr)	1976-04-29

Family

ID=14876810

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO753473A NO753473L (fr)	1974-10-28	1975-10-15

Country Status (26)

Country	Link
US (1)	US4016341A (fr)
JP (1)	JPS5150388A (fr)
AR (1)	AR207265A1 (fr)
AT (1)	AT349757B (fr)
AU (1)	AU501433B2 (fr)
BE (1)	BE834883A (fr)
BR (1)	BR7507036A (fr)
CA (1)	CA1085994A (fr)
DD (1)	DD121326A5 (fr)
DE (1)	DE2548056C2 (fr)
DK (1)	DK482275A (fr)
ES (1)	ES441927A1 (fr)
FI (1)	FI752991A7 (fr)
FR (1)	FR2289531A1 (fr)
GB (1)	GB1484822A (fr)
HU (1)	HU172889B (fr)
IL (1)	IL48316A (fr)
IN (1)	IN143773B (fr)
IT (1)	IT1043668B (fr)
NL (1)	NL7512473A (fr)
NO (1)	NO753473L (fr)
PL (1)	PL104360B1 (fr)
RO (1)	RO66796A (fr)
SE (1)	SE7511717L (fr)
TR (1)	TR19110A (fr)
ZA (1)	ZA756678B (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1077197A (fr) *	1975-03-24	1980-05-06	Kazuhiko Kurimoto	Methode de polymerisation en masse du chlorure de vinyle
JPS5377290A (en) *	1976-12-17	1978-07-08	Kanegafuchi Chem Ind Co Ltd	Polymerization of vinyl chloride
JPS6026402B2 (ja) *	1978-01-13	1985-06-24	三菱レイヨン株式会社	ビニル系単量体の懸濁重合法
JPS5713037U (fr) *	1980-06-26	1982-01-23
US4420591A (en) *	1982-04-05	1983-12-13	Air Products And Chemicals, Inc.	Method for reducing wall fouling in vinyl chloride polymerization
US4588613A (en) *	1984-10-10	1986-05-13	Formosa Plastics Corporation	Process for reducing polymer buildup
JPS6220509A (ja) *	1985-07-18	1987-01-29	Shin Etsu Chem Co Ltd	ビニル系単量体の重合方法
JP3317803B2 (ja) *	1994-11-15	2002-08-26	信越化学工業株式会社	重合体スケール付着防止剤及びそれを使用する重合体製造方法
ES2254204T3 (es)	1999-07-14	2006-06-16	Johnson Polymer, Inc.	Procedimiento para la produccion continua de polimeros epoxi-(met)acrilico-estireno y su uso en revestimientos.
US6548557B1 (en)	2000-02-24	2003-04-15	Walter Merton Co., Inc.	Neutralization of phosphate esters, compositions based upon and methods using same
US6417238B1 (en) *	2000-02-24	2002-07-09	Arnold W. Fogel	Neutralization of phosphate esters, compositions based upon and methods using same
US6605681B1 (en)	2000-07-12	2003-08-12	Johnson Polymer, Inc.	Process for the continuous production of epoxylated addition polymers, and powder and liquid coating applications containing epoxylated addition polymers
WO2015047021A1 (fr) *	2013-09-30	2015-04-02	(주) 엘지화학	Composition de pvc polymérisé en masse, procédé et appareil de polymérisation en masse du pvc

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2380552A (en) *	1941-10-21	1945-07-31	Goodrich Co B F	Polymerization in aqueous emulsion
US3778423A (en) *	1971-06-28	1973-12-11	Universal Pvc Resins	Method for reducing polymer deposit in polymerization of vinyl chloride
DE2141770A1 (de) *	1971-08-20	1973-03-08	Huels Chemische Werke Ag	Verfahren und vorrichtung zur herstellung von polymerisaten oder copolymerisaten von vinylchlorid durch kontinuierliche polymerisation in masse

1974
- 1974-10-28 JP JP49124096A patent/JPS5150388A/ja active Granted
1975
- 1975-01-01 AR AR260976A patent/AR207265A1/es active
- 1975-10-15 NO NO753473A patent/NO753473L/no unknown
- 1975-10-16 HU HU75SI00001491A patent/HU172889B/hu unknown
- 1975-10-17 IL IL48316A patent/IL48316A/xx unknown
- 1975-10-20 CA CA237,921A patent/CA1085994A/fr not_active Expired
- 1975-10-20 ES ES441927A patent/ES441927A1/es not_active Expired
- 1975-10-20 SE SE7511717A patent/SE7511717L/ not_active Application Discontinuation
- 1975-10-21 AT AT800875A patent/AT349757B/de not_active IP Right Cessation
- 1975-10-23 ZA ZA00756678A patent/ZA756678B/xx unknown
- 1975-10-23 US US05/625,044 patent/US4016341A/en not_active Expired - Lifetime
- 1975-10-24 NL NL7512473A patent/NL7512473A/xx not_active Application Discontinuation
- 1975-10-27 IT IT28704/75A patent/IT1043668B/it active
- 1975-10-27 AU AU86024/75A patent/AU501433B2/en not_active Expired
- 1975-10-27 TR TR19110A patent/TR19110A/xx unknown
- 1975-10-27 BR BR7507036*A patent/BR7507036A/pt unknown
- 1975-10-27 PL PL1975184288A patent/PL104360B1/pl unknown
- 1975-10-27 DK DK482275A patent/DK482275A/da unknown
- 1975-10-27 DE DE2548056A patent/DE2548056C2/de not_active Expired
- 1975-10-27 FI FI752991A patent/FI752991A7/fi not_active Application Discontinuation
- 1975-10-27 DD DD189064A patent/DD121326A5/xx unknown
- 1975-10-27 BE BE161260A patent/BE834883A/fr unknown
- 1975-10-28 GB GB44286/75A patent/GB1484822A/en not_active Expired
- 1975-10-28 FR FR7532866A patent/FR2289531A1/fr active Granted
- 1975-10-28 RO RO7583733A patent/RO66796A/fr unknown
- 1975-10-29 IN IN2081/CAL/75A patent/IN143773B/en unknown

Also Published As

Publication number	Publication date
AU8602475A (en)	1977-05-05
PL104360B1 (pl)	1979-08-31
ZA756678B (en)	1976-10-27
DE2548056C2 (de)	1986-05-07
FI752991A7 (fr)	1976-04-29
AR207265A1 (es)	1976-09-22
DD121326A5 (fr)	1976-07-20
HU172889B (hu)	1978-12-28
FR2289531A1 (fr)	1976-05-28
ATA800875A (de)	1978-09-15
BE834883A (fr)	1976-02-16
AU501433B2 (en)	1979-06-21
IT1043668B (it)	1980-02-29
SE7511717L (sv)	1976-04-29
NL7512473A (nl)	1976-05-03
TR19110A (tr)	1978-05-25
ES441927A1 (es)	1977-06-16
DK482275A (da)	1976-04-29
US4016341A (en)	1977-04-05
BR7507036A (pt)	1976-08-17
AT349757B (de)	1979-04-25
IN143773B (fr)	1978-01-28
GB1484822A (en)	1977-09-08
FR2289531B1 (fr)	1978-04-07
DE2548056A1 (de)	1976-05-06
CA1085994A (fr)	1980-09-16
JPS5150388A (en)	1976-05-01
RO66796A (fr)	1982-02-26
IL48316A (en)	1978-10-31
IL48316A0 (en)	1975-12-31
JPS5137306B2 (fr)	1976-10-14

Publication	Publication Date	Title
NO753473L (fr)	1976-04-29
US3778423A (en)	1973-12-11	Method for reducing polymer deposit in polymerization of vinyl chloride
US4098972A (en)	1978-07-04	Method for bulk polymerization of vinyl chloride
US2559754A (en)	1951-07-10	Fluoroalkanephosphonic compounds
JP4506894B1 (ja)	2010-07-21	離型剤
CA1082848A (fr)	1980-07-29	Procede de polymerisation en suspension de chlorure de vinyle avec une faible accumulation de polymeres a chaine courte
JPH072937A (ja)	1995-01-06	良好な機械的特性および良好な熱化学的安定性を有するポリ弗化ビニリデンとその製造方法
DE69501349T2 (de)	1998-04-16	Verfahren zur Herstellung von thermoplastischen wasserstoffhältigen Fluorpolymeren
NO140272B (no)	1979-04-23	Fremgangsmaate for hindring av polymer-oppbygging ved fremstilling av vinylkloridpolymerer
JPH06126182A (ja)	1994-05-10	三フッ化ホウ素の回収方法
KR790001434B1 (ko)	1979-10-08	염화비닐의 괴상중합법
JPH03185007A (ja)	1991-08-13	水性懸濁媒質中での弗化ビニリデン重合中の反応器内におけるビルドアップ形成の減少方法
US20020166992A1 (en)	2002-11-14	Build-up suppressing compositions and the use thereof in polymerization processes
US4152500A (en)	1979-05-01	Suspension polymerization of vinyl chloride with polyvinylalcohol (saponification No. 300-500)
EP0081777B1 (fr)	1986-04-09	Procédé pour la production de polymères de chlorure de vinyle
Burgess	1982	Suspension polymerisation of vinyl chloride
CA1042143A (fr)	1978-11-07	Reduction de la formation de tartre de polymere dans la fabrication des pvc
EP1078934A1 (fr)	2001-02-28	Procédé pour le nettoyage des réacteurs
JP4292815B2 (ja)	2009-07-08	ペースト塩化ビニル系樹脂用スケール付着防止剤及びそれを用いたペースト塩化ビニル系樹脂の製造方法
PT93930A (pt)	1990-11-20	Processo para evitar a deposicao de incrustacao de polimero
EP0210104A1 (fr)	1987-01-28	Procédé pour empêcher la formation d'un encroûtement sur les parois d'un réacteur lors de la polymérisation de monomères insaturés
KR890003575B1 (ko)	1989-09-25	염화비닐 현탁 중합방법
CA1261542A (fr)	1989-09-26	Polymerisation d'un monomere du chlorure de vinyle en milieu aqueux
JP3697062B2 (ja)	2005-09-21	塩化ビニル系樹脂の製造方法
RU2124528C1 (ru)	1999-01-10	Способ получения суспензионного поливинилхлорида