NO791163L - Oligomere iminderivater av aluminium-hydrid - Google Patents

Oligomere iminderivater av aluminium-hydrid

Info

Publication number: NO791163L
Authority: NO; Norway
Prior art keywords: stated; substituted; aluminum; alkyl; optionally
Prior art date: 1978-04-12

Application number

NO791163A

Other languages

English (en)

Norwegian (no)

Inventor

Giovanni Dozzi

Salvatore Cucinella

Tito Salvatori

Original Assignee

Anic Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-04-12

Filing date

1979-04-06

Publication date

1979-10-15

1979-04-06 Application filed by Anic Spa filed Critical Anic Spa

1979-10-15 Publication of NO791163L publication Critical patent/NO791163L/no

Links

AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 title claims 5
238000006243 chemical reaction Methods 0.000 claims description 30
238000000034 method Methods 0.000 claims description 19
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
150000001412 amines Chemical class 0.000 claims description 13
229910052739 hydrogen Inorganic materials 0.000 claims description 11
239000001257 hydrogen Substances 0.000 claims description 11
229910052783 alkali metal Inorganic materials 0.000 claims description 10
150000001340 alkali metals Chemical class 0.000 claims description 10
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
150000001342 alkaline earth metals Chemical class 0.000 claims description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 10
239000004215 Carbon black (E152) Substances 0.000 claims description 9
229930195733 hydrocarbon Natural products 0.000 claims description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 8
150000004678 hydrides Chemical class 0.000 claims description 8
125000003118 aryl group Chemical group 0.000 claims description 7
150000003141 primary amines Chemical class 0.000 claims description 7
239000012190 activator Substances 0.000 claims description 6
239000002904 solvent Substances 0.000 claims description 6
239000007795 chemical reaction product Substances 0.000 claims description 4
150000002430 hydrocarbons Chemical class 0.000 claims description 4
150000002466 imines Chemical class 0.000 claims description 4
229910052751 metal Inorganic materials 0.000 claims description 4
239000002184 metal Substances 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims description 4
239000004210 ether based solvent Substances 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims description 3
230000000737 periodic effect Effects 0.000 claims description 3
229910052757 nitrogen Inorganic materials 0.000 claims description 2
238000003776 cleavage reaction Methods 0.000 claims 2
230000007017 scission Effects 0.000 claims 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
239000001301 oxygen Chemical group 0.000 claims 1
229910052760 oxygen Chemical group 0.000 claims 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
230000015572 biosynthetic process Effects 0.000 description 18
150000001875 compounds Chemical class 0.000 description 12
238000003786 synthesis reaction Methods 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
229910052782 aluminium Inorganic materials 0.000 description 8
239000000047 product Substances 0.000 description 8
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
-1 imine derivatives of aluminum hydride Chemical class 0.000 description 7
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
150000003254 radicals Chemical class 0.000 description 6
238000002329 infrared spectrum Methods 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
VMWJCFLUSKZZDX-UHFFFAOYSA-N n,n-dimethylmethanamine Chemical compound [CH2]N(C)C VMWJCFLUSKZZDX-UHFFFAOYSA-N 0.000 description 5
238000004949 mass spectrometry Methods 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
150000001793 charged compounds Chemical class 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000000203 mixture Substances 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
239000012265 solid product Substances 0.000 description 3
238000001228 spectrum Methods 0.000 description 3
101100037762 Caenorhabditis elegans rnh-2 gene Proteins 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
239000004411 aluminium Substances 0.000 description 2
239000002585 base Substances 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
238000001816 cooling Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
125000004005 formimidoyl group Chemical group [H]\N=C(/[H])* 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
238000011835 investigation Methods 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
238000001819 mass spectrum Methods 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000002035 prolonged effect Effects 0.000 description 2
238000000926 separation method Methods 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052723 transition metal Inorganic materials 0.000 description 2
150000003624 transition metals Chemical class 0.000 description 2
239000002879 Lewis base Substances 0.000 description 1
229910010082 LiAlH Inorganic materials 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
238000007792 addition Methods 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
229910002056 binary alloy Inorganic materials 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
230000009918 complex formation Effects 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000003446 ligand Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
WGYKZJWCGVVSQN-UHFFFAOYSA-N mono-n-propyl amine Natural products CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
150000005673 monoalkenes Chemical class 0.000 description 1
239000000178 monomer Substances 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Plural Heterocyclic Compounds (AREA)
Chemical Treatment Of Metals (AREA)

NO791163A 1978-04-12 1979-04-06 Oligomere iminderivater av aluminium-hydrid NO791163L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT22221/78A IT1095573B (it)	1978-04-12	1978-04-12	Derivati imminici oligomerici dell'idruro di alluminio e processi per la loro preparazione

Publications (1)

Publication Number	Publication Date
NO791163L true NO791163L (no)	1979-10-15

Family

ID=11193242

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO791163A NO791163L (no)	1978-04-12	1979-04-06	Oligomere iminderivater av aluminium-hydrid

Country Status (12)

Country	Link
US (1)	US4239692A (da)
BE (1)	BE875464A (da)
CS (1)	CS222657B2 (da)
DE (1)	DE2914496C3 (da)
DK (1)	DK147282C (da)
ES (1)	ES480209A1 (da)
FR (1)	FR2422669A1 (da)
GB (1)	GB2018763B (da)
IT (1)	IT1095573B (da)
NL (1)	NL180667C (da)
NO (1)	NO791163L (da)
SE (1)	SE7903260L (da)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4665207A (en) *	1985-10-02	1987-05-12	Ethyl Corporation	Preparation of amine alane complexes

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1002067B (it) *	1973-11-29	1976-05-20	Snam Progetti	Processo per la preparazione di poli n alchilimminoalani
IT1015583B (it) *	1974-07-01	1977-05-20	Snam Progetti	Derivati oligomerici dell idruro di alluminio e processo per la lo ro preparazione
IT1019678B (it) *	1974-07-01	1977-11-30	Snam Progetti	N-6-alchil-iminoalani-oligomerici e processo per la loro preparazione
US4128567A (en) *	1974-07-01	1978-12-05	Snamprogetti, S.P.A.	Aluminium polymeric compounds of polyimine nature
IE42334B1 (en) *	1974-08-02	1980-07-16	Snam Progetti	Improvements in or relating to the production of polyminoalanes
CH630926A5 (it) *	1976-01-09	1982-07-15	Snam Progetti	Procedimento per la preparazione di organo-alluminio immidi e prodotti cosi ottenuti.

1978
- 1978-04-12 IT IT22221/78A patent/IT1095573B/it active
1979
- 1979-03-15 US US06/020,837 patent/US4239692A/en not_active Expired - Lifetime
- 1979-03-30 GB GB7911290A patent/GB2018763B/en not_active Expired
- 1979-04-05 DK DK140679A patent/DK147282C/da active
- 1979-04-06 NO NO791163A patent/NO791163L/no unknown
- 1979-04-10 ES ES480209A patent/ES480209A1/es not_active Expired
- 1979-04-10 DE DE2914496A patent/DE2914496C3/de not_active Expired
- 1979-04-10 FR FR7909086A patent/FR2422669A1/fr active Granted
- 1979-04-10 BE BE0/194513A patent/BE875464A/xx not_active IP Right Cessation
- 1979-04-11 SE SE7903260A patent/SE7903260L/ not_active Application Discontinuation
- 1979-04-12 NL NLAANVRAGE7902925,A patent/NL180667C/xx not_active IP Right Cessation
- 1979-04-12 CS CS792520A patent/CS222657B2/cs unknown

Also Published As

Publication number	Publication date
NL180667C (nl)	1987-04-01
ES480209A1 (es)	1980-02-01
DE2914496B2 (de)	1981-01-15
DK140679A (da)	1979-10-13
DE2914496C3 (de)	1981-12-10
CS222657B2 (en)	1983-07-29
IT1095573B (it)	1985-08-10
DE2914496A1 (de)	1979-10-25
GB2018763B (en)	1982-09-22
FR2422669A1 (fr)	1979-11-09
FR2422669B1 (da)	1981-11-27
DK147282B (da)	1984-06-04
BE875464A (fr)	1979-10-10
NL180667B (nl)	1986-11-03
SE7903260L (sv)	1979-10-13
US4239692A (en)	1980-12-16
IT7822221A0 (it)	1978-04-12
NL7902925A (nl)	1979-10-16
DK147282C (da)	1985-01-02
GB2018763A (en)	1979-10-24

Publication	Publication Date	Title
Gagne et al.	1990	Organolanthanide-centered hydroamination/cyclization of aminoolefins. Expedient oxidative access to catalytic cycles
Miller et al.	1964	Chemistry of boranes. XX. Syntheses of polyhedral boranes
Astruc et al.	1979	Novel reactions of dioxygen in organometallic chemistry. Hydrogen atom abstraction vs. dimerization of the 19-electron complexes. eta. 5-cyclopentadienyliron (I). eta. 6-arene
Watt et al.	1970	Cyclopentadienyls of titanium, zirconium, and hafnium
Cucinella et al.	1974	The chemistry and the stereochemistry of poly (N-alkyl-iminoalanes): I. Synthesis and physicochemical characterization of poly (N-alkyliminoalanes)
Schüler et al.	2019	Bis (trimethylsilyl) amide complexes of s-block metals with bidentate ether and amine ligands
Hosmane et al.	1979	Linked and mercury-bridged nido-carboranes. High-yield synthesis of. mu.,. mu.'-[(CH3) 2C2B4H5] 2Hg, conversion to 5, 5'-[(CH3) 2C2B4H5] 2, cleavage, and oxidative addition of benzene. Synthesis of. mu.,. mu.'-(B5H8) 2Hg
NO791163L (no)	1979-10-15	Oligomere iminderivater av aluminium-hydrid
SU679144A3 (ru)	1979-08-05	Способ получени олигомерных производных гидрида алюмини
SU618046A3 (ru)	1978-07-30	Способ получени поли- -алкилиминоаланов
US4064153A (en)	1977-12-20	Oligomer N-alkyl-iminoalanes and process for the preparation thereof
Brown et al.	1983	Addition compounds of alkali-metal hydrides. 23. Preparation of potassium triisopropoxyborohydride in improved purity
US4325885A (en)	1982-04-20	Method for preparation of oligomeric iminic derivatives of aluminum
US2788377A (en)	1957-04-09	Method of producing dicyclopentadienylmagnesium
SU1056905A3 (ru)	1983-11-23	Способ получени катализатора полимеризации олефинов
US5852189A (en)	1998-12-22	Tertiaryaminoalkyllithium initiators and the preparation thereof
KR101417160B1 (ko)	2014-07-08	피리딘 보란 착물
Colombier et al.	1986	Studies of the pyrolysis of tetraethylammonium tetrahydroborate
Keller	1975	Reactions of lithium dimethylamide with some borane derivatives. Evidence for the displacement of lithium hydride
NL8002004A (nl)	1980-10-07	Werkwijze voor de bereiding van alkoxy alanaten van aardalkali metalen.
Brown et al.	1972	Remarkably facile and selective dehydroboration of tetramethylethylene from thexylmonoalkylboranes under the influence of triethylamine. Novel, convenient synthesis of monoalkylboranes as triethylaminates
SU1043105A1 (ru)	1983-09-23	Способ получени алюмогидридов щелочноземельных металлов
US4278611A (en)	1981-07-14	Process for synthesizing alkoxyalanates of alkaline earth metals
Richtera et al.	2003	The Reaction of Selenium Trioxide with Dialkyl Ethers
SU722915A1 (ru)	1980-03-25	Способ получени производных карбонилов металлов