NO800101L - Katalysator og fremgangsmaate til polymerisering av alfa-alkener i naervaer av katalysatoren - Google Patents

Katalysator og fremgangsmaate til polymerisering av alfa-alkener i naervaer av katalysatoren

Info

Publication number: NO800101L
Authority: NO; Norway
Prior art keywords: magnesium; compound; catalyst; titanium; component
Prior art date: 1979-01-17

Application number

NO800101A

Other languages

English (en)

Norwegian (no)

Inventor

Richard Ewaldus Dietz

Original Assignee

Phillips Petroleum Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-01-17

Filing date

1980-01-17

Publication date

1980-07-18

1980-01-17 Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co

1980-07-18 Publication of NO800101L publication Critical patent/NO800101L/no

Links

239000003054 catalyst Substances 0.000 title claims abstract description 59
238000000034 method Methods 0.000 title claims abstract description 20
230000000379 polymerizing effect Effects 0.000 title abstract description 4
150000001336 alkenes Chemical class 0.000 title description 2
150000001875 compounds Chemical class 0.000 claims abstract description 52
239000011777 magnesium Substances 0.000 claims abstract description 45
229910052749 magnesium Inorganic materials 0.000 claims abstract description 32
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 29
150000003609 titanium compounds Chemical class 0.000 claims abstract description 15
238000002156 mixing Methods 0.000 claims abstract description 13
150000002902 organometallic compounds Chemical class 0.000 claims abstract description 11
230000008569 process Effects 0.000 claims abstract description 7
238000006116 polymerization reaction Methods 0.000 claims description 26
239000000047 product Substances 0.000 claims description 19
239000010936 titanium Substances 0.000 claims description 19
229910052719 titanium Inorganic materials 0.000 claims description 17
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 16
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 13
-1 hydrocarbyl magnesium compound Chemical class 0.000 claims description 12
CRGZYKWWYNQGEC-UHFFFAOYSA-N magnesium;methanolate Chemical compound [Mg+2].[O-]C.[O-]C CRGZYKWWYNQGEC-UHFFFAOYSA-N 0.000 claims description 12
239000004215 Carbon black (E152) Substances 0.000 claims description 9
229930195733 hydrocarbon Natural products 0.000 claims description 9
150000002430 hydrocarbons Chemical group 0.000 claims description 9
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 9
230000000737 periodic effect Effects 0.000 claims description 8
239000007795 chemical reaction product Substances 0.000 claims description 7
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 7
229910052751 metal Inorganic materials 0.000 claims description 7
239000002184 metal Substances 0.000 claims description 7
UNCRKDFOOFDWDK-UHFFFAOYSA-N CCCCC[Mg]CCCCC Chemical compound CCCCC[Mg]CCCCC UNCRKDFOOFDWDK-UHFFFAOYSA-N 0.000 claims description 6
125000004432 carbon atom Chemical group C* 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 4
125000003710 aryl alkyl group Chemical group 0.000 claims description 4
125000003118 aryl group Chemical group 0.000 claims description 4
125000000753 cycloalkyl group Chemical group 0.000 claims description 4
125000003342 alkenyl group Chemical group 0.000 claims description 3
125000002877 alkyl aryl group Chemical group 0.000 claims description 3
238000007334 copolymerization reaction Methods 0.000 claims description 3
239000012442 inert solvent Substances 0.000 claims description 3
150000002681 magnesium compounds Chemical class 0.000 claims description 3
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 3
GPAGOVZTCBLZJP-UHFFFAOYSA-N 1-dodecoxydodecane;magnesium Chemical compound [Mg].CCCCCCCCCCCCOCCCCCCCCCCCC GPAGOVZTCBLZJP-UHFFFAOYSA-N 0.000 claims description 2
RVDLHGSZWAELAU-UHFFFAOYSA-N 5-tert-butylthiophene-2-carbonyl chloride Chemical compound CC(C)(C)C1=CC=C(C(Cl)=O)S1 RVDLHGSZWAELAU-UHFFFAOYSA-N 0.000 claims description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
SRNAPDKLNOQUCM-UHFFFAOYSA-N C(C)(C)(C)C1=CC=C(C=C1)[Mg]C1=CC=C(C=C1)C(C)(C)C Chemical compound C(C)(C)(C)C1=CC=C(C=C1)[Mg]C1=CC=C(C=C1)C(C)(C)C SRNAPDKLNOQUCM-UHFFFAOYSA-N 0.000 claims description 2
NYEVYCIEQJOVQY-UHFFFAOYSA-N C1CCCCC1[Mg]C1CCCCC1 Chemical compound C1CCCCC1[Mg]C1CCCCC1 NYEVYCIEQJOVQY-UHFFFAOYSA-N 0.000 claims description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
HYSHQEMRLCMWSH-UHFFFAOYSA-M Cl[Ti](OCCCCCCCCCCCC)(OCCCCCCCCCCCC)OCCCCCCCCCCCC Chemical compound Cl[Ti](OCCCCCCCCCCCC)(OCCCCCCCCCCCC)OCCCCCCCCCCCC HYSHQEMRLCMWSH-UHFFFAOYSA-M 0.000 claims description 2
SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 claims description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
229910052794 bromium Inorganic materials 0.000 claims description 2
DEFMLLQRTVNBOF-UHFFFAOYSA-K butan-1-olate;trichlorotitanium(1+) Chemical compound [Cl-].[Cl-].[Cl-].CCCCO[Ti+3] DEFMLLQRTVNBOF-UHFFFAOYSA-K 0.000 claims description 2
239000000460 chlorine Substances 0.000 claims description 2
229910052801 chlorine Inorganic materials 0.000 claims description 2
GCRJFBMKIMGBIY-UHFFFAOYSA-N cyclohexyloxycyclohexane;magnesium Chemical compound [Mg].C1CCCCC1OC1CCCCC1 GCRJFBMKIMGBIY-UHFFFAOYSA-N 0.000 claims description 2
KZLUHGRPVSRSHI-UHFFFAOYSA-N dimethylmagnesium Chemical compound C[Mg]C KZLUHGRPVSRSHI-UHFFFAOYSA-N 0.000 claims description 2
JFICPAADTOQAMU-UHFFFAOYSA-L ethylaluminum(2+);dibromide Chemical compound CC[Al](Br)Br JFICPAADTOQAMU-UHFFFAOYSA-L 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
150000002367 halogens Chemical class 0.000 claims description 2
WRYKIHMRDIOPSI-UHFFFAOYSA-N magnesium;benzene Chemical compound [Mg+2].C1=CC=[C-]C=C1.C1=CC=[C-]C=C1 WRYKIHMRDIOPSI-UHFFFAOYSA-N 0.000 claims description 2
KRPXAHXWPZLBKL-UHFFFAOYSA-L magnesium;diphenoxide Chemical compound [Mg+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 KRPXAHXWPZLBKL-UHFFFAOYSA-L 0.000 claims description 2
AAPWDGUQUXVEAO-UHFFFAOYSA-N magnesium;dodecane Chemical compound [Mg+2].CCCCCCCCCCC[CH2-].CCCCCCCCCCC[CH2-] AAPWDGUQUXVEAO-UHFFFAOYSA-N 0.000 claims description 2
FBAXEVHJWKHPPF-UHFFFAOYSA-N magnesium;ethanolate;methanolate Chemical compound [Mg+2].[O-]C.CC[O-] FBAXEVHJWKHPPF-UHFFFAOYSA-N 0.000 claims description 2
WCFJMDWWJOCLSJ-UHFFFAOYSA-N magnesium;methanidylbenzene Chemical compound [Mg+2].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 WCFJMDWWJOCLSJ-UHFFFAOYSA-N 0.000 claims description 2
ORPJQHHQRCLVIC-UHFFFAOYSA-N magnesium;propan-2-olate Chemical compound CC(C)O[Mg]OC(C)C ORPJQHHQRCLVIC-UHFFFAOYSA-N 0.000 claims description 2
MCWWHQMTJNSXPX-UHFFFAOYSA-N tribenzylalumane Chemical compound C=1C=CC=CC=1C[Al](CC=1C=CC=CC=1)CC1=CC=CC=C1 MCWWHQMTJNSXPX-UHFFFAOYSA-N 0.000 claims description 2
ZIYNWDQDHKSRCE-UHFFFAOYSA-N tricyclohexylalumane Chemical compound C1CCCCC1[Al](C1CCCCC1)C1CCCCC1 ZIYNWDQDHKSRCE-UHFFFAOYSA-N 0.000 claims description 2
XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 claims description 2
JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical compound C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 claims description 2
NFCLOIHFFSFVQN-UHFFFAOYSA-M Br[Ti](OC1CCCCC1)(OC1CCCCC1)OC1CCCCC1 Chemical compound Br[Ti](OC1CCCCC1)(OC1CCCCC1)OC1CCCCC1 NFCLOIHFFSFVQN-UHFFFAOYSA-M 0.000 claims 1
125000001475 halogen functional group Chemical group 0.000 claims 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 1
BCRPRYVGWGKIEQ-UHFFFAOYSA-J titanium(4+) dichloride diphenoxide Chemical compound Cl[Ti+2]Cl.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 BCRPRYVGWGKIEQ-UHFFFAOYSA-J 0.000 claims 1
150000004678 hydrides Chemical class 0.000 abstract 1
239000004711 α-olefin Substances 0.000 abstract 1
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 29
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 27
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 15
239000005977 Ethylene Substances 0.000 description 15
229920000642 polymer Polymers 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 8
239000007788 liquid Substances 0.000 description 8
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
238000010992 reflux Methods 0.000 description 6
238000003756 stirring Methods 0.000 description 6
238000002474 experimental method Methods 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
239000002002 slurry Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
238000005406 washing Methods 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 4
239000003085 diluting agent Substances 0.000 description 4
239000001282 iso-butane Substances 0.000 description 4
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000003701 inert diluent Substances 0.000 description 3
239000000725 suspension Substances 0.000 description 3
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001183 hydrocarbyl group Chemical group 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
239000011707 mineral Substances 0.000 description 2
239000000178 monomer Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000011343 solid material Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
229920000180 alkyd Polymers 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
235000006708 antioxidants Nutrition 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
238000000071 blow moulding Methods 0.000 description 1
239000001273 butane Substances 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
238000010908 decantation Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
238000003760 magnetic stirring Methods 0.000 description 1
239000012528 membrane Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000005673 monoalkenes Chemical class 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
125000002370 organoaluminium group Chemical group 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
239000008188 pellet Substances 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
238000010944 pre-mature reactiony Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000013074 reference sample Substances 0.000 description 1
239000000523 sample Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
238000013022 venting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

NO800101A 1979-01-17 1980-01-17 Katalysator og fremgangsmaate til polymerisering av alfa-alkener i naervaer av katalysatoren NO800101L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/004,122 US4235746A (en)	1979-01-17	1979-01-17	Polymerization of olefins

Publications (1)

Publication Number	Publication Date
NO800101L true NO800101L (no)	1980-07-18

Family

ID=21709264

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO800101A NO800101L (no)	1979-01-17	1980-01-17	Katalysator og fremgangsmaate til polymerisering av alfa-alkener i naervaer av katalysatoren

Country Status (11)

Country	Link
US (1)	US4235746A (de)
EP (1)	EP0014338B1 (de)
JP (1)	JPS5598206A (de)
AT (1)	ATE4810T1 (de)
AU (1)	AU515968B2 (de)
CA (1)	CA1132968A (de)
DE (1)	DE3064994D1 (de)
ES (1)	ES487750A0 (de)
GB (1)	GB2040965B (de)
NO (1)	NO800101L (de)
SG (1)	SG67883G (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4328121A (en) *	1980-08-04	1982-05-04	Phillips Petroleum Company	Polymerization catalyst and process
US4477586A (en) *	1982-08-27	1984-10-16	Phillips Petroleum Company	Polymerization of olefins
US5064795A (en) *	1982-08-27	1991-11-12	Phillips Petroleum Company	Polymerization of olefins
US4663403A (en) *	1983-02-04	1987-05-05	Phillips Petroleum Company	Polymerization of olefins
US4665046A (en) *	1985-10-21	1987-05-12	The Dow Chemical Company	Organoactinide polymer catalysts
US4771024A (en) *	1986-02-28	1988-09-13	Shell Oil Company	Olefin polymerization catalyst composition

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1049584B (de) *	1955-07-29	1959-01-29	Hercules Powder Company,Wilmington, Del. (V. St. A.)	Verfahren zur Polymerisation olefinisch ungesättigter Kohlenwasserstoffe
US3050471A (en) *	1959-07-21	1962-08-21	Du Pont	Polymerization catalyst
NL128168C (de) *	1965-02-10
NL153555B (nl) *	1968-05-15	1977-06-15	Stamicarbon	Werkwijze ter bereiding van alkeenpolymeren.
BG17623A3 (bg) *	1968-06-27	1973-11-10	Hoechst Aktiengesellschaft	Метод за полимеризация на алфаолефини
US3644318A (en) *	1968-08-21	1972-02-22	Hoechst Ag	Process for the polymerization of olefins
NL136668C (de) *	1969-01-24
BE765033R (fr) *	1970-04-06	1971-09-30	Inst Francais Du Petrole	Nouveau procede d'hydrogenation et catalyseurs d'hydrogenation correspondants
GB1367460A (en) *	1970-12-22	1974-09-18	Int Synthetic Rubber	Polymerisation catalyst
BE785673A (fr) *	1971-06-30	1973-01-02	Naphtachimie Sa	Catalyseurs de polymerisation des olefines prepares a partir decomposesorganomagnesiens
US3801558A (en) *	1971-09-30	1974-04-02	Shell Oil Co	Olefin polymerization
BE791676A (fr) *	1971-12-08	1973-05-21	Solvay	Procédé pour la polymérisation des oléfines
US3859231A (en) *	1972-10-13	1975-01-07	Gulf Research Development Co	Simplified process for manufacture of catalyst component
US4006101A (en) *	1973-02-09	1977-02-01	Nippon Oil Company Ltd.	Polymerization of olefins and catalysts therefor
GB1492174A (en) *	1973-12-13	1977-11-16	British Petroleum Co	Polymerisation catalyst
IT1052079B (it) *	1975-01-10	1981-06-20	Nippon Oil Co Ltd	Procedimento per la produzione di poliolefine
US4021599A (en) *	1975-08-04	1977-05-03	Gulf Research & Development Company	Olefin polymerization process and catalyst
US4133824A (en) *	1977-08-17	1979-01-09	Texas Alkyls, Inc.	Organo-magnesium complexes and process for their preparation

1979
- 1979-01-17 US US05/004,122 patent/US4235746A/en not_active Expired - Lifetime
- 1979-12-17 CA CA342,053A patent/CA1132968A/en not_active Expired
- 1979-12-19 AU AU54019/79A patent/AU515968B2/en not_active Ceased
1980
- 1980-01-11 JP JP201880A patent/JPS5598206A/ja active Pending
- 1980-01-15 DE DE8080100182T patent/DE3064994D1/de not_active Expired
- 1980-01-15 EP EP80100182A patent/EP0014338B1/de not_active Expired
- 1980-01-15 AT AT80100182T patent/ATE4810T1/de not_active IP Right Cessation
- 1980-01-16 ES ES487750A patent/ES487750A0/es active Granted
- 1980-01-16 GB GB8001426A patent/GB2040965B/en not_active Expired
- 1980-01-17 NO NO800101A patent/NO800101L/no unknown
1983
- 1983-11-08 SG SG67883A patent/SG67883G/en unknown

Also Published As

Publication number	Publication date
EP0014338B1 (de)	1983-09-28
GB2040965B (en)	1983-03-09
EP0014338A1 (de)	1980-08-20
ATE4810T1 (de)	1983-10-15
GB2040965A (en)	1980-09-03
ES8100315A1 (es)	1980-11-01
SG67883G (en)	1984-07-27
AU515968B2 (en)	1981-05-14
DE3064994D1 (en)	1983-11-03
US4235746A (en)	1980-11-25
CA1132968A (en)	1982-10-05
ES487750A0 (es)	1980-11-01
AU5401979A (en)	1980-07-24
JPS5598206A (en)	1980-07-26

Publication	Publication Date	Title
US3281375A (en)	1966-10-25	Polymerization catalyst
EP0197166B1 (de)	1990-01-24	Aus einer Organomagnesium-Verbindung hergestellter Katalysator, eine organische Hydroxylverbindung, eine reduzierende Halogenquelle und eine Übergangsmetallverbindung und alpha-Olefinpolymerisationsverfahren mit diesem Katalysator
DK150148B (da)	1986-12-15	Fremgangsmaade til polymerisation eller copolymerisation af alfa-olefiner med 2 - 6 carbonatomer samt katalytisk komplex til brug ved fremgangsmaaden
NO158943B (no)	1988-08-08	Fremgangsmaate til fremstilling av en katalysator til polymerisasjon av alkener, katalysatorsystemer for polymerisasjon av alkener og anvendelse av dette katalysatorsystem.
SU424360A3 (ru)	1974-04-15	Способ получения полиолефинов
NO178732B (no)	1996-02-12	Katalysator, fremstilling av denne og fremgangsmåte til polymerisasjon av alkener
US4426316A (en)	1984-01-17	Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4284748A (en)	1981-08-18	Olefin polymerization
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