NO885192L - Fremgangsmaate for fremstilling av jodiserte substituerte aromatiske forbindelser. - Google Patents

Fremgangsmaate for fremstilling av jodiserte substituerte aromatiske forbindelser.

Info

Publication number: NO885192L
Authority: NO; Norway
Prior art keywords: aromatic compound; iodine; zeolite; aromatic compounds; catalyst
Prior art date: 1987-03-25

Application number

NO885192A

Other languages

English (en)

Norwegian (no)

Other versions

NO885192D0 (no

Inventor

Mark Rule

Gerald Charles Tustin

Donald Wayne Lane

Thomas Hassell Larkins Jr

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-03-25

Filing date

1988-11-22

Publication date

1988-11-22

1988-11-22 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1988-11-22 Publication of NO885192D0 publication Critical patent/NO885192D0/no

1988-11-22 Publication of NO885192L publication Critical patent/NO885192L/no

Links

150000001491 aromatic compounds Chemical class 0.000 title claims description 44
238000000034 method Methods 0.000 title claims description 36
238000002360 preparation method Methods 0.000 title description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 45
239000010457 zeolite Substances 0.000 claims description 37
239000003054 catalyst Substances 0.000 claims description 36
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 26
229910021536 Zeolite Inorganic materials 0.000 claims description 26
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 26
239000011630 iodine Substances 0.000 claims description 26
229910052740 iodine Inorganic materials 0.000 claims description 26
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 17
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
239000001301 oxygen Substances 0.000 claims description 14
229910052760 oxygen Inorganic materials 0.000 claims description 14
230000002378 acidificating effect Effects 0.000 claims description 13
230000026045 iodination Effects 0.000 claims description 7
238000006192 iodination reaction Methods 0.000 claims description 7
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
150000001768 cations Chemical class 0.000 claims description 6
150000001555 benzenes Chemical class 0.000 claims description 5
150000002790 naphthalenes Chemical class 0.000 claims description 5
FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 claims description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 4
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 4
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 4
229910052792 caesium Inorganic materials 0.000 claims description 4
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 4
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 4
229910052700 potassium Inorganic materials 0.000 claims description 4
239000011591 potassium Substances 0.000 claims description 4
229910052701 rubidium Inorganic materials 0.000 claims description 4
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 4
235000010290 biphenyl Nutrition 0.000 claims description 3
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
125000001424 substituent group Chemical group 0.000 claims description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
239000003513 alkali Substances 0.000 claims description 2
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
239000012965 benzophenone Substances 0.000 claims description 2
239000004305 biphenyl Substances 0.000 claims description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
229910052794 bromium Inorganic materials 0.000 claims description 2
239000000460 chlorine Chemical group 0.000 claims description 2
229910052801 chlorine Inorganic materials 0.000 claims description 2
125000004093 cyano group Chemical group *C#N 0.000 claims description 2
229910052731 fluorine Inorganic materials 0.000 claims description 2
239000011737 fluorine Substances 0.000 claims description 2
229930192474 thiophene Natural products 0.000 claims description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims 2
KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims 2
YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 claims 1
LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 claims 1
125000001153 fluoro group Chemical group F* 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 19
-1 rare earth cations Chemical class 0.000 description 11
239000007795 chemical reaction product Substances 0.000 description 10
239000007789 gas Substances 0.000 description 10
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
229910052782 aluminium Inorganic materials 0.000 description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
239000000047 product Substances 0.000 description 7
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
239000011148 porous material Substances 0.000 description 6
229910052710 silicon Inorganic materials 0.000 description 6
239000010703 silicon Substances 0.000 description 6
239000000126 substance Substances 0.000 description 6
125000003118 aryl group Chemical group 0.000 description 5
229910002092 carbon dioxide Inorganic materials 0.000 description 5
238000002485 combustion reaction Methods 0.000 description 5
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
SNHMUERNLJLMHN-UHFFFAOYSA-N iodobenzene Chemical compound IC1=CC=CC=C1 SNHMUERNLJLMHN-UHFFFAOYSA-N 0.000 description 4
LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 4
239000007800 oxidant agent Substances 0.000 description 4
230000003647 oxidation Effects 0.000 description 4
238000007254 oxidation reaction Methods 0.000 description 4
229910052761 rare earth metal Inorganic materials 0.000 description 4
238000007792 addition Methods 0.000 description 3
YCOXTKKNXUZSKD-UHFFFAOYSA-N as-o-xylenol Natural products CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 description 3
JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
150000002910 rare earth metals Chemical class 0.000 description 3
IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
150000001351 alkyl iodides Chemical class 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
239000012071 phase Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
229910052814 silicon oxide Inorganic materials 0.000 description 2
239000007858 starting material Substances 0.000 description 2
229910052712 strontium Inorganic materials 0.000 description 2
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
MEIFVWINIHKENC-UHFFFAOYSA-N (2-iodophenyl)-phenylmethanone Chemical class IC1=CC=CC=C1C(=O)C1=CC=CC=C1 MEIFVWINIHKENC-UHFFFAOYSA-N 0.000 description 1
BBOLNFYSRZVALD-UHFFFAOYSA-N 1,2-diiodobenzene Chemical compound IC1=CC=CC=C1I BBOLNFYSRZVALD-UHFFFAOYSA-N 0.000 description 1
NKKJDIIBHHRNAG-UHFFFAOYSA-N 1-chloro-2,3-diiodobenzene Chemical class ClC1=CC=CC(I)=C1I NKKJDIIBHHRNAG-UHFFFAOYSA-N 0.000 description 1
MPEOPBCQHNWNFB-UHFFFAOYSA-N 1-chloro-2-iodobenzene Chemical compound ClC1=CC=CC=C1I MPEOPBCQHNWNFB-UHFFFAOYSA-N 0.000 description 1
JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 1
LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical class C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
AMNAGCDWTIMWRF-UHFFFAOYSA-N 2-chloro-1-iodonaphthalene Chemical class C1=CC=CC2=C(I)C(Cl)=CC=C21 AMNAGCDWTIMWRF-UHFFFAOYSA-N 0.000 description 1
JDDAFHUEOVUDFJ-UHFFFAOYSA-N 2-iodobenzonitrile Chemical compound IC1=CC=CC=C1C#N JDDAFHUEOVUDFJ-UHFFFAOYSA-N 0.000 description 1
KQDJTBPASNJQFQ-UHFFFAOYSA-N 2-iodophenol Chemical compound OC1=CC=CC=C1I KQDJTBPASNJQFQ-UHFFFAOYSA-N 0.000 description 1
BGARPMGQRREXLN-UHFFFAOYSA-N 3-iodobenzonitrile Chemical compound IC1=CC=CC(C#N)=C1 BGARPMGQRREXLN-UHFFFAOYSA-N 0.000 description 1
XOKDXPVXJWTSRM-UHFFFAOYSA-N 4-iodobenzonitrile Chemical compound IC1=CC=C(C#N)C=C1 XOKDXPVXJWTSRM-UHFFFAOYSA-N 0.000 description 1
VSMDINRNYYEDRN-UHFFFAOYSA-N 4-iodophenol Chemical compound OC1=CC=C(I)C=C1 VSMDINRNYYEDRN-UHFFFAOYSA-N 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000003570 air Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
XDFCIPNJCBUZJN-UHFFFAOYSA-N barium(2+) Chemical compound [Ba+2] XDFCIPNJCBUZJN-UHFFFAOYSA-N 0.000 description 1
125000006267 biphenyl group Chemical group 0.000 description 1
XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
150000001987 diarylethers Chemical class 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
QFWPJPIVLCBXFJ-UHFFFAOYSA-N glymidine Chemical compound N1=CC(OCCOC)=CN=C1NS(=O)(=O)C1=CC=CC=C1 QFWPJPIVLCBXFJ-UHFFFAOYSA-N 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
229940071870 hydroiodic acid Drugs 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
150000005755 iodopyridines Chemical class 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
239000000203 mixture Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000007420 reactivation Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B39/00—Halogenation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/158—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of halogenated hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)
Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
Pyridine Compounds (AREA)
Quinoline Compounds (AREA)
Other In-Based Heterocyclic Compounds (AREA)

NO885192A 1987-03-25 1988-11-22 Fremgangsmaate for fremstilling av jodiserte substituerte aromatiske forbindelser. NO885192L (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/029,897 US4778940A (en)	1987-03-25	1987-03-25	Process for preparing iodinated substituted aromatic compounds
PCT/US1988/000800 WO1988007509A1 (fr)	1987-03-25	1988-03-16	Procede de preparation de composes aromatiques iodes substitues

Publications (2)

Publication Number	Publication Date
NO885192D0 NO885192D0 (no)	1988-11-22
NO885192L true NO885192L (no)	1988-11-22

Family

ID=21851459

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO885192A NO885192L (no)	1987-03-25	1988-11-22	Fremgangsmaate for fremstilling av jodiserte substituerte aromatiske forbindelser.

Country Status (11)

Country	Link
US (1)	US4778940A (fr)
EP (1)	EP0307447A1 (fr)
JP (1)	JPH01502819A (fr)
KR (1)	KR890700549A (fr)
CN (1)	CN88101781A (fr)
AU (1)	AU610879B2 (fr)
CA (1)	CA1314896C (fr)
DK (1)	DK656388D0 (fr)
ES (1)	ES2006391A6 (fr)
NO (1)	NO885192L (fr)
WO (1)	WO1988007509A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4855514A (en) *	1988-08-17	1989-08-08	Eastman Kodak Company	Oxidative iodination of phenol
US5026931A (en) *	1990-09-10	1991-06-25	Eastman Kodak Company	Process for preparing a product stream rich in naphthalene and 2-monoiodonaphthalene
US5138108A (en) *	1990-12-03	1992-08-11	Eastman Kodak Company	Process for regenerating a zeolite catalyst
US5386069A (en) *	1993-05-07	1995-01-31	Eastman Chemical Company	Process for preparation of difluoro-tetraiodobenzene
WO2004069772A1 (fr) *	2003-02-10	2004-08-19	Mitsubishi Gas Chemical Company, Inc.	Procede de production de composes iodes et procede de production d'acide 5-iodo-2-methilbenzoique de grande purete
JP4332702B2 (ja) *	2003-02-10	2009-09-16	三菱瓦斯化学株式会社	ヨウ素化合物の製造方法
US7642374B2 (en) *	2003-07-03	2010-01-05	Mitsubishi Gas Chemical Company, Inc.	Process for producing 5-iodo-2-methylbenzoic acid
JP4340858B2 (ja) *	2003-07-03	2009-10-07	三菱瓦斯化学株式会社	５−ヨード−２−メチル安息香酸の製造方法
CN100355710C (zh) *	2005-12-15	2007-12-19	上海交通大学	芳烃碘代物的制备方法
KR101123148B1 (ko) *	2007-12-17	2012-03-19	에스케이케미칼주식회사	방향족 요오드화 화합물의 제조 방법
KR101004369B1 (ko) *	2008-12-11	2010-12-27	에스케이케미칼주식회사	방향족 요오드화 화합물의 제조 방법

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3363010A (en) *	1961-08-02	1968-01-09	Pullman Inc	Halogenation process
US3600331A (en) *	1968-06-18	1971-08-17	Velsicol Chemical Corp	Catalyst containing copper phosphate and silver phosphate useful in the oxygenation of hydrogen halides
US3644542A (en) *	1969-06-17	1972-02-22	Hooker Chemical Corp	Benzene oxychlorination
US4240987A (en) *	1979-10-29	1980-12-23	Xerox Corporation	Chemical process
JPS5777631A (en) *	1980-10-31	1982-05-15	Kureha Chem Ind Co Ltd	Vapor-phase halogenation process
US4391785A (en) *	1981-12-21	1983-07-05	Mobil Oil Corporation	Preparation of ZSM-12 type zeolites
JPS59219241A (ja) *	1983-05-30	1984-12-10	Asahi Chem Ind Co Ltd	芳香族化合物のオキシヨウ素化法
US4513092A (en) *	1984-01-04	1985-04-23	Mobil Oil Corporation	Composite catalyst for halogenation and condensation of alkanes
IT1176856B (it) *	1984-10-05	1987-08-18	Montedipe Spa	Metodo per la sintesi di iodobenzene
IT1176981B (it) *	1984-10-16	1987-08-26	Montedipe Spa	Metodo per la sintesi di iodobenzene
US4746758A (en) *	1986-09-29	1988-05-24	Eastman Kodak Company	Processes for preparing iodinated aromatic compounds

1987
- 1987-03-25 US US07/029,897 patent/US4778940A/en not_active Expired - Fee Related
1988
- 1988-02-15 CA CA000558888A patent/CA1314896C/fr not_active Expired - Fee Related
- 1988-03-16 JP JP62507066A patent/JPH01502819A/ja active Pending
- 1988-03-16 AU AU15441/88A patent/AU610879B2/en not_active Ceased
- 1988-03-16 EP EP88903093A patent/EP0307447A1/fr not_active Withdrawn
- 1988-03-16 KR KR1019880701530A patent/KR890700549A/ko not_active Withdrawn
- 1988-03-16 WO PCT/US1988/000800 patent/WO1988007509A1/fr not_active Ceased
- 1988-03-25 CN CN198888101781A patent/CN88101781A/zh active Pending
- 1988-03-25 ES ES8800918A patent/ES2006391A6/es not_active Expired
- 1988-11-22 NO NO885192A patent/NO885192L/no unknown
- 1988-11-24 DK DK656388A patent/DK656388D0/da not_active Application Discontinuation

Also Published As

Publication number	Publication date
JPH01502819A (ja)	1989-09-28
NO885192D0 (no)	1988-11-22
AU1544188A (en)	1988-11-02
ES2006391A6 (es)	1989-04-16
CN88101781A (zh)	1988-11-02
DK656388A (da)	1988-11-24
CA1314896C (fr)	1993-03-23
WO1988007509A1 (fr)	1988-10-06
US4778940A (en)	1988-10-18
DK656388D0 (da)	1988-11-24
KR890700549A (ko)	1989-04-25
EP0307447A1 (fr)	1989-03-22
AU610879B2 (en)	1991-05-30

Publication	Publication Date	Title
US4746758A (en)	1988-05-24	Processes for preparing iodinated aromatic compounds
US4792642A (en)	1988-12-20	Process for preparing iodinated aromatic compounds
US4795737A (en)	1989-01-03	Process for the iodination of aromatic compounds over solid catalysts
EP0181790B1 (fr)	1990-08-01	Procédé pour la synthèse d'iodobenzène
NO885192L (no)	1988-11-22	Fremgangsmaate for fremstilling av jodiserte substituerte aromatiske forbindelser.
EP0183579B1 (fr)	1990-06-06	Procédé pour la synthèse d'iodobenzène
KR860001543B1 (ko)	1986-10-04	디할로겐화벤젠의 제조방법
US4754086A (en)	1988-06-28	Process for preparation of nuclear halides of monoalkylbenzenes
US4849560A (en)	1989-07-18	Process for preparation of halogenated benzene derivatives
CA1067521A (fr)	1979-12-04	Production d'hydrocarbures aromatiques chlorofluores
US4792641A (en)	1988-12-20	Process for preparing iodinated aromatic compounds
US4814525A (en)	1989-03-21	Vapor phase bromination of aromatic compounds
US4778938A (en)	1988-10-18	Processes for preparing iodinated aromatic compounds
US4777305A (en)	1988-10-11	Synthesis of 1,4-dichlorobenzene
US4806697A (en)	1989-02-21	Selective liquid phase disproportionation catalysts for iodoaromatics
US4778939A (en)	1988-10-18	Low temperature oxyiodination of aromatic compounds
EP1599448A1 (fr)	2005-11-30	Preparation de 3,6-dichloro-2-trichloromethylpyridine par chloration en phase vapeur de 6-chloro-2-trichloromethylpyridine
JPH0344061B2 (fr)	1991-07-04
US4895992A (en)	1990-01-23	Process for preparing iodinated aromatic compounds and the regeneration of catalysts used therein
JPH01502825A (ja)	1989-09-28	沃素化芳香族化合物の液相異性化
NO171311B (no)	1992-11-16	Fremgangsmaate for fremstilling av iodaromatiske forbindelser
JPS6334131B2 (fr)	1988-07-08