NO951848L - Indenylforbindelser og katalysatorkomponenter for polymerisasjon av olefiner - Google Patents
Indenylforbindelser og katalysatorkomponenter for polymerisasjon av olefinerInfo
- Publication number
- NO951848L NO951848L NO951848A NO951848A NO951848L NO 951848 L NO951848 L NO 951848L NO 951848 A NO951848 A NO 951848A NO 951848 A NO951848 A NO 951848A NO 951848 L NO951848 L NO 951848L
- Authority
- NO
- Norway
- Prior art keywords
- olefins
- polymerization
- catalyst components
- indenyl compounds
- indenyl
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL9201970A NL9201970A (nl) | 1992-11-11 | 1992-11-11 | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
| PCT/NL1993/000229 WO1994011406A1 (en) | 1992-11-11 | 1993-11-03 | Indenyl compounds and catalyst components for the polymerization of olefins |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO951848D0 NO951848D0 (no) | 1995-05-10 |
| NO951848L true NO951848L (no) | 1995-07-11 |
| NO306782B1 NO306782B1 (no) | 1999-12-20 |
Family
ID=19861509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO951848A NO306782B1 (no) | 1992-11-11 | 1995-05-10 | Indenylforbindelser og katalysatorkomponenter for polymerisasjon av olefiner |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US5646322A (no) |
| EP (1) | EP0668865B1 (no) |
| JP (1) | JP3419456B2 (no) |
| CN (1) | CN1088212A (no) |
| AU (1) | AU677026B2 (no) |
| BR (1) | BR9307420A (no) |
| CA (1) | CA2149026A1 (no) |
| DE (1) | DE69333114T2 (no) |
| ES (1) | ES2203621T3 (no) |
| FI (1) | FI114798B (no) |
| MY (1) | MY130143A (no) |
| NL (1) | NL9201970A (no) |
| NO (1) | NO306782B1 (no) |
| RU (1) | RU2128183C1 (no) |
| WO (1) | WO1994011406A1 (no) |
Families Citing this family (71)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| NL9201970A (nl) * | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
| WO1995016716A1 (en) * | 1993-12-14 | 1995-06-22 | Exxon Chemical Patents Inc. | Process for producing elastomers with an indenyl metallocene catalyst system |
| US5491207A (en) * | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
| US5594080A (en) * | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
| NL9400758A (nl) * | 1994-05-06 | 1995-12-01 | Dsm Nv | Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen. |
| US5541272A (en) * | 1994-06-03 | 1996-07-30 | Phillips Petroleum Company | High activity ethylene selective metallocenes |
| IT1273662B (it) | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propiline' |
| EP0693502B1 (en) * | 1994-07-22 | 1997-11-05 | Mitsubishi Chemical Corporation | Catalyst component for the polymerization of alpha-olefins and a process for preparing alpha-olefin polymers with use of same |
| ES2116188B1 (es) * | 1994-12-30 | 1999-04-01 | Repsol Quimica Sa | Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales. |
| IT1275408B (it) | 1995-05-30 | 1997-08-05 | Spherilene Spa | Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| US5780659A (en) * | 1996-03-29 | 1998-07-14 | Phillips Petroleum Company | Substituted indenyl unbridged metallocenes |
| US6329541B1 (en) * | 1997-01-08 | 2001-12-11 | Phillips Petroleum Company | Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds |
| FI971565A7 (fi) | 1997-04-14 | 1998-10-15 | Borealis As | Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä |
| NL1006346C2 (nl) * | 1997-06-18 | 1998-12-21 | Dsm Nv | Werkwijze voor de bereiding van polyolefines bij hoge temperatuur met behulp van Zr-metallocenen. |
| DE19809160A1 (de) * | 1998-03-04 | 1999-09-09 | Bayer Ag | Ataktische Propylen-(Co)Polymere |
| DE19809159A1 (de) * | 1998-03-04 | 1999-09-09 | Bayer Ag | Metallorganische Verbindungen |
| EP0941997B1 (en) * | 1998-03-09 | 2002-12-18 | Basell Polyolefine GmbH | Bridged zirconocene compounds, process for their preparation, and their use as catalyst components in the polymerization of olefins |
| ES2188047T3 (es) | 1998-03-09 | 2003-06-16 | Basell Polyolefine Gmbh | Compuestos de circonoceno puenteados, procedimiento para su preparacion y su empleo como componentes catalizadores en la polimerizacion de olefinas. |
| IL137036A0 (en) | 1998-11-18 | 2001-06-14 | Montell Technology Company Bv | Bis(tetrahydro-indenyl) metallocenes as olefin-polymerisation-catalyst |
| JP2002530285A (ja) | 1998-11-18 | 2002-09-17 | バセル テクノロジー カンパニー ビー.ブイ. | オレフィン−重合−触媒成分としてのメチレン橋架けメタロセン |
| EP1066226B1 (en) * | 1999-01-21 | 2007-08-29 | Boulder Scientific Company | Synthesis and isomerization of 1,2-bis (indenyl) ethanes |
| DE19908938A1 (de) * | 1999-03-02 | 2000-09-07 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| US6342622B1 (en) | 1999-06-11 | 2002-01-29 | Dsm B.V. | Indenyl compounds for the polymerization of olefins |
| EP1059300A1 (en) * | 1999-06-11 | 2000-12-13 | Dsm N.V. | Indenyl compounds for the polymerisation of olefins |
| EP1059299B1 (en) * | 1999-06-11 | 2003-12-17 | SABIC Polypropylenes B.V. | Process for the polymerisation of olefins in the presence of indenyl compounds |
| RU2160276C1 (ru) * | 1999-06-21 | 2000-12-10 | Институт химической физики им. Н.Н. Семенова РАН | Анса-цирконоцены с непредельным циклосилановым мостиком и способ их получения |
| RU2160277C1 (ru) * | 1999-06-21 | 2000-12-10 | Институт химической физики РАН им. Н.Н. Семенова | Анса-цирконоцены, функционализированные по циклосилановому мостику, и способ их получения |
| US6482905B1 (en) * | 1999-08-16 | 2002-11-19 | Phillips Petroleum Company | Unsymmetric unbridged bis-indenyl metallocenes and their use |
| IT1314261B1 (it) * | 1999-12-03 | 2002-12-06 | Enichem Spa | Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine. |
| DE10003581A1 (de) * | 2000-01-28 | 2001-08-02 | Bayer Ag | Metallorganische Verbindungen mit anellierten Indenyl Liganden |
| DE10127926A1 (de) | 2001-06-08 | 2002-12-12 | Bayer Ag | 1,3-disubstituierte Indenkomplexe |
| US7060765B2 (en) | 2001-07-19 | 2006-06-13 | Univation Technologies, Llc | Low comonomer incorporating metallocene catalyst compounds |
| ES2361734T3 (es) * | 2001-07-19 | 2011-06-21 | Univation Technologies Llc | Películas de polietileno con propiedades físicas mejoradas. |
| JP4020862B2 (ja) * | 2001-07-19 | 2007-12-12 | ユニベーション・テクノロジーズ・エルエルシー | コモノマー少量組込み触媒とコモノマー多量組込み触媒を含有する混合メタロセン触媒系 |
| US6936675B2 (en) | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
| US6562921B1 (en) * | 2001-10-12 | 2003-05-13 | Univation Technologies, Llc | Catalyst precursor compound and olefin polymerization process using same |
| ATE361323T1 (de) * | 2004-03-12 | 2007-05-15 | Saudi Basic Ind Corp | Katalysatorzusammensetzung für die polymerisation von olefinen und polymerisationsverfahren unter dessen verwendung |
| US7226886B2 (en) | 2005-09-15 | 2007-06-05 | Chevron Phillips Chemical Company, L.P. | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
| US7312283B2 (en) * | 2005-08-22 | 2007-12-25 | Chevron Phillips Chemical Company Lp | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
| US7619047B2 (en) | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
| WO2013091836A1 (en) * | 2011-12-19 | 2013-06-27 | Saudi Basic Industries Corporation (Sabic) | Process for the preparation of metallocene complexes |
| CN104080792A (zh) * | 2011-12-19 | 2014-10-01 | 沙特基础工业公司 | 用于制备茂金属络合物的方法 |
| EP2610269A1 (en) | 2011-12-28 | 2013-07-03 | Saudi Basic Industries Corporation | Catalyst composition and method for preparing the same |
| US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
| US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| KR101584350B1 (ko) * | 2013-04-08 | 2016-01-13 | 한화케미칼 주식회사 | 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법 |
| WO2014168373A1 (en) * | 2013-04-08 | 2014-10-16 | Hanwha Chemical Corporation | Metallocene catalyst system comprising antistatic agent and method for preparing polyolefin using the same |
| EP2832739A1 (en) | 2013-08-01 | 2015-02-04 | Saudi Basic Industries Corporation | Bridged metallocene complex for olefin polymerization |
| EP3039028B1 (en) | 2013-08-30 | 2017-06-21 | Saudi Basic Industries Corporation | Bridged metallocene complex for olefin polymerization |
| BR112016019334B1 (pt) * | 2014-02-11 | 2021-03-09 | Univation Technologies, Llc | método para formar uma composição de catalisador |
| BR122020005071B1 (pt) * | 2014-02-11 | 2021-06-08 | Univation Technologies, Llc | composição de catalisador |
| EP3034545B1 (en) | 2014-12-17 | 2020-11-04 | SABIC Global Technologies B.V. | A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains and the products obtained therefrom |
| EP3034546B1 (en) | 2014-12-17 | 2019-10-16 | SABIC Global Technologies B.V. | A process for the preparation of a block copolymer comprising a first polyolefin block and a second polymer block |
| EP3034547B1 (en) | 2014-12-17 | 2019-10-09 | SABIC Global Technologies B.V. | A process for the preparation of a block copolymer comprising a first polyolefin block and a second polymer block |
| EP3034544B1 (en) | 2014-12-17 | 2019-10-16 | SABIC Global Technologies B.V. | A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains |
| EP3037437A1 (en) | 2014-12-23 | 2016-06-29 | SABIC Global Technologies B.V. | Process for the preparation of a polyolefin having one or multiple end-functionalized branches. |
| EP3037438A1 (en) | 2014-12-23 | 2016-06-29 | SABIC Global Technologies B.V. | Process for the preparation of a branched polyolefin |
| KR102064412B1 (ko) | 2016-07-07 | 2020-01-09 | 주식회사 엘지화학 | 폴리올레핀 제조용 메탈로센 촉매의 제조방법 |
| CN110650978B (zh) | 2017-04-04 | 2022-09-23 | Sabic环球技术有限责任公司 | 用于烯烃聚合的二甲基-甲硅烷基-桥连的-1-取代-2-茚基茂金属复合物 |
| EP3606931B1 (en) | 2017-04-04 | 2025-08-27 | SABIC Global Technologies B.V. | Dihydrocarbyl-silyl-bridged-substituted cyclopentadienyl metallocene complexes for olefin polymerization |
| US11427608B2 (en) | 2017-04-04 | 2022-08-30 | Sabic Global Technologies B.V. | Dihydrocarbyl-silyl-bridged-1,3 disubstituted-2-indenyl metallocene complexes for olefin polymerization |
| WO2019122455A1 (en) | 2017-12-22 | 2019-06-27 | Sabic Global Technologies B.V. | Process for preparation of amorphous functionalized olefin copolymer |
| CN111511786A (zh) | 2017-12-22 | 2020-08-07 | Sabic环球技术有限责任公司 | 制备乙烯和丙烯离聚物的方法 |
| EP3743431B1 (en) | 2018-01-24 | 2025-04-16 | SABIC Global Technologies B.V. | 1,2-phenylene bridged 1-indenyl-2-indenyl metallocene complexes for olefin polymerisation |
| RU2666736C1 (ru) * | 2018-05-30 | 2018-09-12 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Способ получения синтетических высоковязких полиальфаолефиновых базовых масел |
| WO2021048030A1 (en) | 2019-09-10 | 2021-03-18 | Sabic Global Technologies B.V. | Compounds for use in catalyst compositions for the production of polyolefins |
| CN114423769B (zh) | 2019-09-20 | 2024-04-26 | Sabic环球技术有限责任公司 | 用于生产聚烯烃的催化剂组合物中的化合物 |
| WO2021173361A1 (en) * | 2020-02-24 | 2021-09-02 | Exxonmobil Chemical Patents Inc. | Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2322883A1 (fr) * | 1975-09-02 | 1977-04-01 | Michelin & Cie | Elastomeres du type e p t, et articles comportant de tels elastomeres |
| CS216208B2 (cs) * | 1979-02-27 | 1982-10-29 | Union Carbide Corp | Způsob přípravy katalytického systému |
| SU979371A1 (ru) * | 1981-01-04 | 1982-12-07 | Предприятие П/Я В-2913 | Способ получени (со)полимеров этилена |
| CA1257863A (en) * | 1985-10-17 | 1989-07-25 | Vaclav G. Zboril | SOLUTION PROCESS FOR THE PREPARATION OF POLYMERS OF .alpha.-OLEFINS |
| EP0406912B1 (en) * | 1986-09-24 | 1994-11-30 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins |
| IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| IL89525A0 (en) * | 1988-03-21 | 1989-09-10 | Exxon Chemical Patents Inc | Silicon-bridged transition metal compounds |
| US5120867A (en) * | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5001205A (en) * | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| KR930002411B1 (ko) * | 1988-09-14 | 1993-03-30 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | 벤젠불용성 유기알루미늄 옥시화합물 및 그 제조방법 |
| DE3840772A1 (de) * | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
| WO1991002012A1 (en) * | 1989-08-03 | 1991-02-21 | Exxon Chemical Patents Inc. | Very high molecular weight polyethylene |
| US5191042A (en) * | 1989-09-06 | 1993-03-02 | Exxon Chemical Patents Inc. | Process for preparing alpha-olefin copolymers having a narrow MWD and broad compositional distribution |
| CA2027145C (en) * | 1989-10-10 | 2002-12-10 | Michael J. Elder | Metallocene catalysts with lewis acids and aluminum alkyls |
| US5098635A (en) * | 1989-11-09 | 1992-03-24 | Copolymer Rubber & Chemical Corporation | Process for manufacturing friable rubber bales |
| DE69033368T3 (de) * | 1990-01-02 | 2008-07-03 | Exxon Chemical Patents, Inc. | Ionische Metallocenkatalysatoren auf Träger für Olefinpolymerisation |
| DE69130320T2 (de) * | 1990-07-24 | 1999-04-08 | Mitsui Chemicals Inc | Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit |
| DE59107926D1 (de) * | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| ES2071888T3 (es) * | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
| DE4039451A1 (de) * | 1990-12-11 | 1992-06-17 | Hoechst Ag | Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren |
| ES2155492T3 (es) * | 1991-05-27 | 2001-05-16 | Basell Polyolefine Gmbh | Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares. |
| US5391789A (en) * | 1991-08-08 | 1995-02-21 | Hoechst Aktiengesellschaft | Bridged, chiral metallocenes, processes for their preparation and their use as catalysts |
| DE4139261A1 (de) * | 1991-11-29 | 1993-06-03 | Basf Ag | Ethylen-copolymerisate niederer dichte |
| ATE150037T1 (de) * | 1992-05-26 | 1997-03-15 | Hoechst Ag | Verfahren zur herstellung von polyolefinwachsen |
| DE59308494D1 (de) * | 1992-08-03 | 1998-06-10 | Targor Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| NL9201970A (nl) * | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
| US5372980A (en) * | 1993-06-03 | 1994-12-13 | Polysar | Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers |
| DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| DE4344688A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
-
1992
- 1992-11-11 NL NL9201970A patent/NL9201970A/nl not_active Application Discontinuation
-
1993
- 1993-11-03 DE DE69333114T patent/DE69333114T2/de not_active Expired - Lifetime
- 1993-11-03 WO PCT/NL1993/000229 patent/WO1994011406A1/en not_active Ceased
- 1993-11-03 EP EP94901064A patent/EP0668865B1/en not_active Expired - Lifetime
- 1993-11-03 ES ES94901064T patent/ES2203621T3/es not_active Expired - Lifetime
- 1993-11-03 BR BR9307420-4A patent/BR9307420A/pt not_active Application Discontinuation
- 1993-11-03 JP JP51194394A patent/JP3419456B2/ja not_active Expired - Fee Related
- 1993-11-03 RU RU95112455A patent/RU2128183C1/ru active
- 1993-11-03 AU AU55774/94A patent/AU677026B2/en not_active Expired - Fee Related
- 1993-11-03 CA CA002149026A patent/CA2149026A1/en not_active Abandoned
- 1993-11-10 MY MYPI93002351A patent/MY130143A/en unknown
- 1993-11-10 CN CN93112942A patent/CN1088212A/zh active Pending
-
1995
- 1995-05-10 NO NO951848A patent/NO306782B1/no not_active IP Right Cessation
- 1995-05-10 FI FI952266A patent/FI114798B/fi not_active IP Right Cessation
- 1995-05-11 US US08/439,449 patent/US5646322A/en not_active Expired - Lifetime
-
1997
- 1997-03-10 US US08/812,675 patent/US5990253A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5990253A (en) | 1999-11-23 |
| CN1088212A (zh) | 1994-06-22 |
| NL9201970A (nl) | 1994-06-01 |
| MY130143A (en) | 2007-06-29 |
| FI114798B (fi) | 2004-12-31 |
| EP0668865B1 (en) | 2003-07-23 |
| RU2128183C1 (ru) | 1999-03-27 |
| JPH08503457A (ja) | 1996-04-16 |
| DE69333114T2 (de) | 2004-06-24 |
| NO951848D0 (no) | 1995-05-10 |
| CA2149026A1 (en) | 1994-05-26 |
| ES2203621T3 (es) | 2004-04-16 |
| WO1994011406A1 (en) | 1994-05-26 |
| AU5577494A (en) | 1994-06-08 |
| AU677026B2 (en) | 1997-04-10 |
| FI952266L (fi) | 1995-05-10 |
| FI952266A0 (fi) | 1995-05-10 |
| EP0668865A1 (en) | 1995-08-30 |
| DE69333114D1 (de) | 2003-08-28 |
| JP3419456B2 (ja) | 2003-06-23 |
| NO306782B1 (no) | 1999-12-20 |
| RU95112455A (ru) | 1997-03-20 |
| US5646322A (en) | 1997-07-08 |
| BR9307420A (pt) | 1999-08-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO306782B1 (no) | Indenylforbindelser og katalysatorkomponenter for polymerisasjon av olefiner | |
| FI935550L (fi) | Komponentteja ja katalyyttejä olefiinien polymerointia varten | |
| NO960669D0 (no) | Katalysatorbestanddeler og katalysatorer for polymerisering av olefiner | |
| FI910138L (fi) | Komponentteja ja katalysaattoreita olefiinien polymerointia varten | |
| FI960343A7 (fi) | Komponentteja ja katalyyttejä olefiinien polymerisointia varten | |
| FI955734A7 (fi) | Olefiinien polymerointiin tarkoitetut komponentit ja katalysaattorit | |
| FI961036L (fi) | Komponentteja ja katalyyttejä olefiinien polymerointia varten | |
| EP0520811A3 (en) | Catalyst components for polymerization of olefins | |
| FI894626L (fi) | Komponentteja ja katalysaattoreita olefiinien polymerointia varten | |
| NO993205D0 (no) | Katalysator og fremgangsmÕte for polymerisering av olefiner | |
| NO954780D0 (no) | Bårete metallocenkatalysatorsystemer for polymerisasjon av olefiner, fremstilling og anvendelse derav | |
| FI944573L (fi) | Olefiinien polymerointiin tarkoitettuja komponentteja ja katalyyttejä | |
| FI962329A7 (fi) | Menetelmä olefiinien (ko)polymeroimiseksi | |
| FI961269A7 (fi) | Katalyyttejä ja menetelmiä olefiinien polymeroinniksi | |
| IL96870A0 (en) | Components and catalysts for the polymerization of olefins | |
| DE69308209D1 (de) | Polymerisation von alpha-olefinen | |
| NO951025D0 (no) | Metallocener og fremgangsmåte til polymerisering av olefin | |
| EP0520816A3 (en) | Catalyst components for polymerization of olefins | |
| NO301238B1 (no) | Polymerisasjon av olefiner | |
| ITMI922491A0 (it) | Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine | |
| ITMI922125A0 (it) | Catalizzatore e procedimento per la polimerizzazione di alfa-olefine | |
| NO953017D0 (no) | Katalysatorsystem og fremgangsmåte for polymerisasjon av olefiner | |
| NO973828D0 (no) | Katalysatorbestanddeler og katalysatorer for polymerisasjon av olefiner | |
| NO933792D0 (no) | Alkenpolymerisasjonskatalysator og anvendelse av katalysatoren | |
| FI953740A0 (fi) | Katalysaattori ja olefiinien polymerisointi |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |
Free format text: LAPSED IN MAY 2001 |