PL108020B1 - Sposob wytwarzania wlokien polikaproamidowych uodpmethod of producing polycaproamide fibres hardenedornionych na dzialanie podwyzszonych temperatur i to the action of increased temperatures and lightswiatla - Google Patents

Sposob wytwarzania wlokien polikaproamidowych uodpmethod of producing polycaproamide fibres hardenedornionych na dzialanie podwyzszonych temperatur i to the action of increased temperatures and lightswiatla Download PDF

Info

Publication number: PL108020B1
Authority: PL; Poland
Prior art keywords: weight; parts; equivalent; copper; aging agent
Prior art date: 1977-04-13

Application number

PL19741277A

Other languages

English (en)

Polish (pl)

Other versions

PL197412A1 (pl

Inventor

Alicja Jaszczak

Zbigniew Plonka

Bronislaw Fryc

Jan Tomczyk

Stefan Kirkor

Original Assignee

Zaklady Wlokien Chem

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-04-13

Filing date

1977-04-13

Publication date

1980-03-31

1977-04-13 Application filed by Zaklady Wlokien Chem filed Critical Zaklady Wlokien Chem

1977-04-13 Priority to PL19741277A priority Critical patent/PL108020B1/pl

1978-04-13 Priority to BG039404A priority patent/BG40489A3/xx

1978-04-13 Priority to CS241278A priority patent/CS204028B2/cs

1978-10-23 Publication of PL197412A1 publication Critical patent/PL197412A1/xx

1980-03-31 Publication of PL108020B1 publication Critical patent/PL108020B1/pl

Links

239000000835 fiber Substances 0.000 title claims description 42
230000009471 action Effects 0.000 title description 4
239000004952 Polyamide Substances 0.000 claims description 37
229920002647 polyamide Polymers 0.000 claims description 37
230000003712 anti-aging effect Effects 0.000 claims description 36
239000003795 chemical substances by application Substances 0.000 claims description 33
238000000034 method Methods 0.000 claims description 31
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 29
229910052802 copper Inorganic materials 0.000 claims description 29
239000010949 copper Substances 0.000 claims description 29
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 22
229920002292 Nylon 6 Polymers 0.000 claims description 18
239000008187 granular material Substances 0.000 claims description 16
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 12
229910052740 iodine Inorganic materials 0.000 claims description 10
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 9
239000011630 iodine Substances 0.000 claims description 9
239000007788 liquid Substances 0.000 claims description 9
238000000354 decomposition reaction Methods 0.000 claims description 8
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 7
239000006193 liquid solution Substances 0.000 claims description 7
239000000203 mixture Substances 0.000 claims description 7
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
239000003112 inhibitor Substances 0.000 claims description 6
229910052749 magnesium Inorganic materials 0.000 claims description 6
239000011777 magnesium Substances 0.000 claims description 6
229910001629 magnesium chloride Inorganic materials 0.000 claims description 6
229910001510 metal chloride Inorganic materials 0.000 claims description 6
230000000737 periodic effect Effects 0.000 claims description 6
239000005749 Copper compound Substances 0.000 claims description 5
229910001516 alkali metal iodide Inorganic materials 0.000 claims description 5
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
150000001880 copper compounds Chemical class 0.000 claims description 5
239000004611 light stabiliser Substances 0.000 claims description 5
239000001301 oxygen Substances 0.000 claims description 5
229910052760 oxygen Inorganic materials 0.000 claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 claims description 4
239000011248 coating agent Substances 0.000 claims description 3
238000000576 coating method Methods 0.000 claims description 3
150000001879 copper Chemical class 0.000 claims description 3
TUTWLYPCGCUWQI-UHFFFAOYSA-N decanamide Chemical compound CCCCCCCCCC(N)=O TUTWLYPCGCUWQI-UHFFFAOYSA-N 0.000 claims description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
229920001515 polyalkylene glycol Polymers 0.000 claims description 2
150000005846 sugar alcohols Polymers 0.000 claims description 2
239000000446 fuel Substances 0.000 claims 1
239000002243 precursor Substances 0.000 claims 1
239000000126 substance Substances 0.000 description 8
230000032683 aging Effects 0.000 description 7
238000004519 manufacturing process Methods 0.000 description 6
230000008569 process Effects 0.000 description 6
239000003381 stabilizer Substances 0.000 description 6
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 4
239000000956 alloy Substances 0.000 description 4
229910045601 alloy Inorganic materials 0.000 description 4
238000002156 mixing Methods 0.000 description 3
230000005855 radiation Effects 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
-1 copper glycols Chemical class 0.000 description 2
HXXRDHUDBAILGK-UHFFFAOYSA-L copper;2-hydroxyacetate Chemical class [Cu+2].OCC([O-])=O.OCC([O-])=O HXXRDHUDBAILGK-UHFFFAOYSA-L 0.000 description 2
230000008021 deposition Effects 0.000 description 2
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000004744 fabric Substances 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
150000002334 glycols Chemical class 0.000 description 2
239000012760 heat stabilizer Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
239000000155 melt Substances 0.000 description 2
150000007530 organic bases Chemical class 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
230000002035 prolonged effect Effects 0.000 description 2
150000003242 quaternary ammonium salts Chemical class 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
238000011069 regeneration method Methods 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
238000012360 testing method Methods 0.000 description 2
FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
QAQSNXHKHKONNS-UHFFFAOYSA-N 1-ethyl-2-hydroxy-4-methyl-6-oxopyridine-3-carboxamide Chemical compound CCN1C(O)=C(C(N)=O)C(C)=CC1=O QAQSNXHKHKONNS-UHFFFAOYSA-N 0.000 description 1
QPJCYJIZFCJYIR-UHFFFAOYSA-N 4-propylazetidin-2-one Chemical compound CCCC1CC(=O)N1 QPJCYJIZFCJYIR-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
239000004953 Aliphatic polyamide Substances 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
241000700143 Castor fiber Species 0.000 description 1
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
229920003231 aliphatic polyamide Polymers 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
MPDDDPYHTMZBMG-UHFFFAOYSA-N butyl(triethyl)azanium Chemical compound CCCC[N+](CC)(CC)CC MPDDDPYHTMZBMG-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
CMRVDFLZXRTMTH-UHFFFAOYSA-L copper;2-carboxyphenolate Chemical compound [Cu+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O CMRVDFLZXRTMTH-UHFFFAOYSA-L 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
239000000945 filler Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
230000005923 long-lasting effect Effects 0.000 description 1
230000007774 longterm Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
NQMRYBIKMRVZLB-UHFFFAOYSA-N methylamine hydrochloride Chemical compound [Cl-].[NH3+]C NQMRYBIKMRVZLB-UHFFFAOYSA-N 0.000 description 1
230000005012 migration Effects 0.000 description 1
238000013508 migration Methods 0.000 description 1
QAVGBPNRNXPFKY-UHFFFAOYSA-N n-cyclohexylcyclohexanamine;hydroiodide Chemical class I.C1CCCCC1NC1CCCCC1 QAVGBPNRNXPFKY-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000000575 pesticide Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000010791 quenching Methods 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910000679 solder Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000010959 steel Substances 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
239000004753 textile Substances 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
239000003017 thermal stabilizer Substances 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000027 toxicology Toxicity 0.000 description 1

Landscapes

Artificial Filaments (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Compositions Of Macromolecular Compounds (AREA)

PL19741277A 1977-04-13 1977-04-13 Sposob wytwarzania wlokien polikaproamidowych uodpmethod of producing polycaproamide fibres hardenedornionych na dzialanie podwyzszonych temperatur i to the action of increased temperatures and lightswiatla PL108020B1 (pl)

Priority Applications (3)

Application Number	Priority Date	Filing Date	Title
PL19741277A PL108020B1 (pl)	1977-04-13	1977-04-13	Sposob wytwarzania wlokien polikaproamidowych uodpmethod of producing polycaproamide fibres hardenedornionych na dzialanie podwyzszonych temperatur i to the action of increased temperatures and lightswiatla
BG039404A BG40489A3 (en)	1977-04-13	1978-04-13	Method for manufacture of polycaproamidic fibres
CS241278A CS204028B2 (cs)	1977-04-13	1978-04-13	Způsob výroby polykaproamidových vláken, majících zvýšenou odolnost vůči působení tepla a záření

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
PL19741277A PL108020B1 (pl)	1977-04-13	1977-04-13	Sposob wytwarzania wlokien polikaproamidowych uodpmethod of producing polycaproamide fibres hardenedornionych na dzialanie podwyzszonych temperatur i to the action of increased temperatures and lightswiatla

Publications (2)

Publication Number	Publication Date
PL197412A1 PL197412A1 (pl)	1978-10-23
PL108020B1 true PL108020B1 (pl)	1980-03-31

Family

ID=19981964

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PL19741277A PL108020B1 (pl)	1977-04-13	1977-04-13	Sposob wytwarzania wlokien polikaproamidowych uodpmethod of producing polycaproamide fibres hardenedornionych na dzialanie podwyzszonych temperatur i to the action of increased temperatures and lightswiatla

Country Status (3)

Country	Link
BG (1)	BG40489A3 (cs)
CS (1)	CS204028B2 (cs)
PL (1)	PL108020B1 (cs)

1977
- 1977-04-13 PL PL19741277A patent/PL108020B1/pl unknown
1978
- 1978-04-13 CS CS241278A patent/CS204028B2/cs unknown
- 1978-04-13 BG BG039404A patent/BG40489A3/xx unknown

Also Published As

Publication number	Publication date
CS204028B2 (cs)	1981-03-31
BG40489A3 (en)	1986-12-15
PL197412A1 (pl)	1978-10-23

Publication	Publication Date	Title
RU2055950C1 (ru)	1996-03-10	Нить, предназначенная для изготовления сит бумагоделательных машин, и способ ее получения
US4755335A (en)	1988-07-05	Method of improving impregnation of poly (meta-phenylene isophthalamide) fibers
JPH10130497A (ja)	1998-05-19	ポリアミド樹脂組成物
DE2645711A1 (de)	1978-04-13	Flammwidrige fasern und faeden aus linearen, thermoplastischen polyestern
EP0691426A2 (en)	1996-01-10	Fibre treatment
EP2772571B1 (en)	2020-06-03	Spun-dyed meta-type fully aromatic polyamide fiber
CA2252953A1 (en)	1999-06-04	Stabilizer formulation for thermoplastic polymers
US3003995A (en)	1961-10-10	Stabilized polycaproamide compositions
JPS6158496B2 (cs)	1986-12-11
PL108020B1 (pl)	1980-03-31	Sposob wytwarzania wlokien polikaproamidowych uodpmethod of producing polycaproamide fibres hardenedornionych na dzialanie podwyzszonych temperatur i to the action of increased temperatures and lightswiatla
Šehić et al.	2018	Influence of N-, P-and Si-based flame retardant mixtures on flammability, thermal behavior and mechanical properties of PA6 composite fibers
Adivarekar et al.	2013	Synthesis of halogen free flame retardant and its application on polypropylene
KR940002692B1 (ko)	1994-03-30	방향족 폴리아미드 섬유의 제조방법
US4115562A (en)	1978-09-19	Treated fabrics and process
DE1593750A1 (de)	1970-12-10	Substituierte Benzophenone als Lichtstabilisatoren
US3211516A (en)	1965-10-12	Thermally stabilized cellulose materials
EP2980307B1 (en)	2019-05-01	Poly(vinyl alcohol)-based fibers having excellent thermal aging resistance, and method for producing same
DE2148276A1 (de)	1972-04-06	Polyamid Form und Strangpressmassen mit verringerter Brennbarkeit
EP0281691A2 (en)	1988-09-14	Polyamide monofilaments used for papermaking apparatus
SU589933A3 (ru)	1978-01-25	Композици на основе полипропилена
KR100227221B1 (ko)	1999-11-01	발수성이 향상된 폴리프로필렌 섬유용 수지 조성물 및 이를 이용한 직물
FI64403C (fi)	1983-11-10	Svaort antaendbara polypropylenfibrer och deras framstaellningsfoerfarande
US3280052A (en)	1966-10-18	Polyamides stabilized against discoloration from carbon disulfide by the addition of copper stearate and thioacetoamides
US3440211A (en)	1969-04-22	Flame retardant nylon composition
PL87650B1 (cs)	1976-07-31