PL10954B3 - A method of applying bodies with soap properties in acid baths. - Google Patents
A method of applying bodies with soap properties in acid baths. Download PDFInfo
- Publication number
- PL10954B3 PL10954B3 PL10954A PL1095427A PL10954B3 PL 10954 B3 PL10954 B3 PL 10954B3 PL 10954 A PL10954 A PL 10954A PL 1095427 A PL1095427 A PL 1095427A PL 10954 B3 PL10954 B3 PL 10954B3
- Authority
- PL
- Poland
- Prior art keywords
- bodies
- soap
- acid baths
- acid
- applying bodies
- Prior art date
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- 239000002253 acid Substances 0.000 title claims description 12
- 239000000344 soap Substances 0.000 title claims description 7
- 238000000034 method Methods 0.000 title claims description 4
- 150000007513 acids Chemical class 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- -1 acids fatty acids Chemical class 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- CRVVHBFLWWQMPT-UHFFFAOYSA-N naphthalene-1-sulfonic acid;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 CRVVHBFLWWQMPT-UHFFFAOYSA-N 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Description
Najdluzszy czas trwania patentu do 13 pazdziernika 1942 r.W patencie Nr 7933 opisano sposób sto¬ sowania mydel lub olejów tureckich i cial podobnych, ewentualnie zawieraj acych równiez sole wapnia lub magnezu, który polega na dodawaniu do nich cial utrud¬ niajacych wydzielanie sie wolnych kwa¬ sów tluszczowych lub ich soli nierozpu¬ szczalnych w kapieli kwasnej.Obecnie zauwazono, ze w sposobie po¬ wyzszym zamiast mydel, olejów tureckich i t. d, mozna stosowac równiez wolne za¬ warte w tych cialach kwasy lub inne cia¬ la organiczne, które w obecnosci wymie¬ nionych domieszek, w kapieli kwasnej sa rozpuszczalne w postaci koloidalnej i wy¬ kazuja w roztworach podobnych wlasno¬ sci mydla. Jako ciala tego rodzaju mozna przytoczyc np, zywice lub jej podobne, pochodzenia naturalnego i sztucznego, parafine i materjaly podobne, kwasy naf- tenokarbonowe, produkty rozkladu welny, tluszcz z welny, lub tluszcze podobne, woski i inne ciala organiczne o znacznym ciezarze czasteczkowym. Bardzo czesto korzystnie jest dodac ponadto organicz¬ nych rozpuszczalników, W sposobie niniejszym mozna tez z ko¬ rzyscia kwasy tluszczowe, zywicowe i po¬ dobne lub inne substancje organiczne po¬ wyzszego rodzaju rozpuscic wrozpu-szczalnikach organicznych i do roztworów tych dodac cial, które utrudniaja osadza¬ nie ,w Jfapieli? kwasnej ^a nastepnie miesza¬ nine te dodac do kapieli kwasnej i t. d.Przyklad L 1 kg oleiny rozpuszcza sie w równej jej ilosci metanolu, dodaje oko¬ lo 0,5 kg soli sodowej izopropylowanego kwasu naftalenosulfonowego i roztwór ten dokladnie miesza. Po dodaniu wody otrzy¬ muje sie ciecz przezroczysta, która rów¬ niez i po zakwaszeniu nie wykazuje osa¬ du kwasu tluszczowego i nadaje sie wy¬ smienicie jako mydlo przy pracy w ka¬ pieli kwasnej.Zamiast soli sodowej izopropylowane¬ go kwasu naftalenosulfonowego mozna równiez stosowac wolny kwas sulfonowy.Przyklad II. 50 kg butylowanego kwa¬ su naftalenosulfonowego rozpuszcza sie w wodzie, poczem do roztworu tego dodaje roztworu zawierajacego 2,5 kg kalafonji w 25 kg alkoholu butylowego. Pozostaje przezroczysty roztwór, który nawet w ka¬ pieli kwasnej posiada zdolnosc pienienia sie, oczyszczania, zwilzania i emulgowa¬ nia.Przyklad III. 10 kg butylowanego naf- talenosulfonianu sodowego rozpuszcza sie w 30 litrach wody, poczem do goracego roztworu dodaje 0,4 kg zywicznego pro¬ duktu kondensacji, otrzymanego z cyklo- heksanonu przez ogrzewanie go w obecno¬ sci alkaljów metyloalkoholowych i rozpu¬ szczonego w 4 kg produktu oleistego, po¬ wstalego przy katalitycznem uwodornia¬ niu tlenku weglowego. Otrzymany w ten sposób lepki roztwór daje po rozciencze¬ niu go woda roztwór przezroczysty, zupel¬ nie odporny na dzialanie kwasów i wapna, który równiez przy kwasnym odczynie po¬ siada zdolnosc oczyszczania i pienienia sie.Zamiast propylowanych lub butylowa- nych kwasów naftalenosulfonowych moz¬ na stosowac równiez inne podstawione grupa alkylowa w rdzeniu lub w odpo¬ wiednim substytuencie kwasy sulfonowe aromatyczne lub ich pochodne, które rów¬ niez moga posiadac inne grupy podsta¬ wione, lub tez mozna stosowac odpowied¬ nie sole, lugi siarczynoblonnikowe lub in¬ ne ciala dzialajace w sposób podobny. PLThe longest term of the patent until October 13, 1942 Patent No. 7933 describes the use of Turkish soaps or oils and similar bodies, possibly also containing calcium or magnesium salts, by adding to them bodies that inhibit the release of free acids fatty acids or their salts insoluble in an acid bath. It has now been observed that in the method above, instead of soaps, Turkish oils, etc., it is also possible to use free acids or other organic bodies contained in these bodies, which in the presence of the aforementioned admixtures in an acid bath are soluble in colloidal form and show similar properties of soap in solutions. Examples of such bodies are resins or the like, of natural and artificial origin, paraffin and similar materials, naphthenocarbonic acids, wool decomposition products, wool fat or similar fats, waxes and other organic bodies with a significant molecular weight. It is very often advantageous to additionally add organic solvents. In the present process, it is also possible to advantageously dissolve fatty acids, gum acids and the like or other organic substances of the above type in organic solvents and add bodies to these solutions which make it difficult to settling in Jfapiela? and then add the mixture to the acid bath, and so on. Example L 1 kg of olein is dissolved in an equal amount of methanol, about 0.5 kg of isopropylated naphthalenesulfonic acid sodium is added and the solution is mixed thoroughly. After the addition of water, a clear liquid is obtained, which, even after acidification, shows no fatty acid residue and is perfectly suitable for use in acid baths. Instead of sodium salt of isopropylated naphthalenesulfonic acid, it can also be used as a soap. use free sulfonic acid Example II. 50 kg of butylated naphthalenesulfonic acid is dissolved in water, and then a solution containing 2.5 kg of rosin in 25 kg of butyl alcohol is added to this solution. A clear solution remains, which, even in the acid bath, has the ability to foam, clean, wet and emulsify. 10 kg of sodium butylated naphthalenesulfonate are dissolved in 30 liters of water, then 0.4 kg of a resin condensation product obtained from cyclohexanone by heating in the presence of methyl alcohol alkali and dissolved in 4 kg is added to the hot solution. an oily product formed by the catalytic hydrogenation of carbon monoxide. The viscous solution obtained in this way gives, after diluting it with water, a clear solution, completely resistant to the action of acids and lime, which, even in acidic conditions, has the ability to clean and foam. Instead of propylated or butylated naphthalenesulfonic acids, it can Other substituted alkyl groups can also be used in the core or in a suitable substitute, aromatic sulfonic acids or their derivatives, which may also have other substituted groups, or it is also possible to use suitable salts, sulfite-fiber sulfites or other bodies working in a similar way. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL10954B3 true PL10954B3 (en) | 1929-09-30 |
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