PL219717B1 - Oxisalt in a three-component system of metal oxides and production method of oxisalts in a three-component system of metal oxides - Google Patents
Oxisalt in a three-component system of metal oxides and production method of oxisalts in a three-component system of metal oxidesInfo
- Publication number
- PL219717B1 PL219717B1 PL395544A PL39554411A PL219717B1 PL 219717 B1 PL219717 B1 PL 219717B1 PL 395544 A PL395544 A PL 395544A PL 39554411 A PL39554411 A PL 39554411A PL 219717 B1 PL219717 B1 PL 219717B1
- Authority
- PL
- Poland
- Prior art keywords
- metal oxides
- component system
- oxide
- ternary
- hours
- Prior art date
Links
- 229910044991 metal oxide Inorganic materials 0.000 title claims description 11
- 150000004706 metal oxides Chemical class 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- -1 copper oxide-divanadium pentoxide-iron trioxide Chemical group 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 2
- 238000000137 annealing Methods 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Compounds Of Iron (AREA)
Description
Opis wynalazkuDescription of the invention
Przedmiotem wynalazku jest oksysól w trójskładnikowym układzie tlenków metali oraz sposób wytwarzania oksysoli w trójskładnikowym układzie tlenków metali. Nowa oksysól może znaleźć zastosowanie jako składnik katalizatorów w procesach utleniania związków organicznych.The subject of the invention is oxysol in the three-component metal oxide system and the method of producing oxysols in the three-component metal oxide system. The new oxysol can find application as a component of catalysts in the oxidation of organic compounds.
Z polskiego opisu patentowego nr 191 558 znana jest nowa oksysól w trójskładnikowym układzie tlenków metali przejściowych, w którym układ trójskładnikowy oznacza tlenek kobaltu-pentatlenek diwanadu-tritlenek diżelaza o sumarycznym wzorze Co2FeV3O11.Polish patent specification No. 191 558 describes a new oxysalin in the ternary transition metal oxide system, in which the ternary system is cobalt oxide-divanadium pentoxide-iron oxide with the total formula Co2FeV3O11.
Z polskiego opisu patentowego nr 196 717 znane są nowe oksysole o sumarycznych wzorach Mg3Fe4V6O24, Zn3Fe4V6O24 i Co3Fe4V6O24 w trójskładnikowych układach tlenków metali, w których układy trójskładnikowe oznaczają odpowiednio: tlenek magnezu-pentatlenek diwanadu-tritlenek diżelaza, tlenek cynku-pentatlenek diwanadu-tritlenek diżelaza oraz tlenek kobaltu-pentatlenek diwanadutritlenek diżelaza.Polish patent specification No. 196 717 describes new oxysols with the total formulas: Mg 3 Fe 4 V 6 O 24 , Zn 3 Fe 4 V 6 O 24 and Co 3 Fe 4 V 6 O 24 in ternary metal oxide systems, in which the ternary systems are mean, respectively: magnesium oxide-diwanadu pentoxide-iron oxide, zinc oxide-diwanadu pentoxide-iron oxide, and cobalt oxide-divanadu pentoxide-iron oxide.
Znana jest z polskiego opisu patentowego nr 178 601 oksysól w trójskładnikowym układzie tlenków metali, w którym układ trójskładnikowy oznacza tritlenek diglinu-pentatlenek diwanadu-tritlenek molibdenu o sumarycznym wzorze AlVMoO7.It is known from Polish patent description No. 178 601 oxysalt in a ternary metal oxide system, in which the ternary system is aluminum oxide-divanadium pentoxide-molybdenum oxide with the total formula AlVMoO7.
W dokumentach tych opisano także sposób otrzymywania tych soli. Otrzymuje się je z tlenków metali lub z odpowiednich wanadanów poprzez ich mieszanie, ujednorodnianie, pastylkowanie i wygrzewanie otrzymanych mieszanin w odpowiednich temperaturach.These documents also describe the preparation of these salts. They are obtained from metal oxides or from suitable vanadates by mixing, homogenizing, pelleting and heating the obtained mixtures at appropriate temperatures.
Oksysól w trójskładnikowym układzie tlenków metali, według wynalazku charakteryzuje się tym, że układ trójskładnikowy oznacza tlenek miedzi-pentatlenek diwanadu-tritlenek diżelaza o wzorze sumarycznym Cu13Fe4V10O44.The oxy-salt in the ternary metal oxide system according to the invention is characterized in that the ternary system is copper oxide-divanadium pentoxide-iron oxide with the total formula Cu 13 Fe 4 V 10 O 44 .
Sposób wytwarzania oksysołi w trójskładnikowym układzie tlenków metali, według wynalazku, polegający na mieszaniu odpowiednich tlenków, ujednorodnianiu i wygrzewaniu otrzymanych mieszanin charakteryzuje się tym, że tlenek miedzi, pentatlenek diwanadu i tritlenek diżelaza w stosunkach molowych w % jak 65:25:10 miesza się i ujednorodnia, po czym otrzymaną mieszaninę wygrzewa się w zakresie temperatur od 560° do 720°C w ciągu 80 godzin, w czterech etapach po 20 godzin. Po każdym etapie ogrzewania próbkę schładza się do temperatury otoczenia i rozciera, otrzymując produkt o wzorze Cu13Fe4V10O44.The method of producing oxy-oxide in the three-component metal oxide system, according to the invention, consisting in mixing appropriate oxides, homogenizing and annealing the mixtures obtained, is characterized in that copper oxide, divanad pentoxide and iron trioxide in molar ratios in% 65:25:10 are mixed and homogenizing, then the obtained mixture is heated in the temperature range from 560 ° to 720 ° C for 80 hours in four steps of 20 hours. After each heating step, the sample is cooled to ambient temperature and triturated to give the product of formula Cu 13 Fe 4 V 10 O 44 .
Sposób otrzymywania nowej oksysoli przedstawia poniższy przykład.The method of obtaining new oxysols is shown in the example below.
Naważa się 65% molowych CuO, 25% molowych V2O5 i 10% molowych Fe2O3. Odważone składniki miesza się i ujednorodnia przez ucieranie. Próbkę ogrzewa się w atmosferze powietrza w czterech etapach: w pierwszym etapie próbkę wygrzewa się w temperaturze 560°C w ciągu 20 godzin, w drugim etapie próbkę wygrzewa się w temperaturze 600°C w ciągu 20 godzin, w trzecim etapie próbkę wygrzewa się w temperaturze 700°C w ciągu 20 godzin, w czwartym etapie próbkę wygrzewa się w temperaturze 720°C w ciągu 20 godzin. Po każdym etapie ogrzewania próbkę schładza się do temperatury otoczenia i rozciera. Nowa oksysól ma barwę brązową. Topi się w temperaturze 790 ± 5°C.65 mole% CuO, 25 mole% V 2 O 5 and 10 mole% Fe 2 O 3 are weighed. The weighed ingredients are mixed and homogenized by grinding. The sample is heated in the air atmosphere in four stages: in the first stage the sample is heated at 560 ° C for 20 hours, in the second stage the sample is heated at 600 ° C for 20 hours, in the third stage the sample is heated at the temperature 700 ° C for 20 hours, in the fourth step the sample is annealed at 720 ° C for 20 hours. After each heating step, the sample is cooled to ambient temperature and rubbed. The new oxysol is brown in color. It melts at a temperature of 790 ± 5 ° C.
Charakterystykę rentgenowską otrzymanej nowej oksysoli przedstawiono w tabeli.The X-ray characteristics of the obtained new oxysole are presented in the table.
T a b e l aT a b e l a
PL 219 717 B1 cd. tabeliPL 219 717 B1 cont. table
Zastrzeżenia patentowePatent claims
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL395544A PL219717B1 (en) | 2011-07-08 | 2011-07-08 | Oxisalt in a three-component system of metal oxides and production method of oxisalts in a three-component system of metal oxides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL395544A PL219717B1 (en) | 2011-07-08 | 2011-07-08 | Oxisalt in a three-component system of metal oxides and production method of oxisalts in a three-component system of metal oxides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL395544A1 PL395544A1 (en) | 2013-01-21 |
| PL219717B1 true PL219717B1 (en) | 2015-06-30 |
Family
ID=47624743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL395544A PL219717B1 (en) | 2011-07-08 | 2011-07-08 | Oxisalt in a three-component system of metal oxides and production method of oxisalts in a three-component system of metal oxides |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL219717B1 (en) |
-
2011
- 2011-07-08 PL PL395544A patent/PL219717B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL395544A1 (en) | 2013-01-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ni et al. | Crystallized Zn3 (VO4) 2: synthesis, characterization and optical property | |
| MX346804B (en) | Manufacture method of high efficiency non-oriented silicon steel having good magnetic performance. | |
| AU2016254966B2 (en) | Chromium-free near-infrared reflecting delafossite pigments | |
| PL219717B1 (en) | Oxisalt in a three-component system of metal oxides and production method of oxisalts in a three-component system of metal oxides | |
| Onoda et al. | Improvement of acid and base resistance of nickel phosphate pigment by the addition of lanthanum cation | |
| PL216969B1 (en) | New oxosalt in ternary system of metal oxides and process for the preparation of new method for producing a new oxosalt in ternary system of metal oxides | |
| PL209578B1 (en) | Oxisalt in a three-component system of metal oxides and production method of oxisalts in a three-component system of metal oxides | |
| PL221615B1 (en) | Oxisalt in the ternary system of transition metal oxides and manufacturing method thereof | |
| PL210261B1 (en) | New oxosalt in three-component system of metal oxides and the manner of production of new three-component system of metal oxides | |
| PL225790B1 (en) | Solid solution with unlimited range of solubility of components in the two-component system of vanadates (V) cobalt (II) and iron (III) as well as magnesium and iron (III) and methods for the production of solid solution with unlimited range of solubility of components in the two-component system of vanadates (V) cobalt (II) and iron (III) as well as magnesium and iron (III) | |
| PL219934B1 (en) | Phases of continuous solid solution type in four-component system of vanadium, iron, magnesium and zinc oxides, and process for the preparation of phases of continuous solid solution type in four-component system of vanadium, iron, magnesium and zinc oxides | |
| PL212451B1 (en) | Oxysalt in the three-component system of the metal oxides and the method of manufacturing the oxysalt in the three-component system of the metal oxides | |
| PL209576B1 (en) | New oxysalt in three-component system of transient metal-oxides and method for the manufacture of new salt in three-component system of transient metal-oxides | |
| PL222182B1 (en) | Oxisalt in the ternary system of transition metal oxides and methods for its preparation | |
| PL209577B1 (en) | Oxisalt in three-component arrangement of metal oxides and production method of oxisalts in three-component arrangement of metal oxides | |
| PL236322B1 (en) | New type phases of restricted solid solutions doped with rare-earth ions and method for producing type phases of restricted solid solutions doped with rare-earth ions | |
| PL213465B1 (en) | Oxosalt in a two-component system of cadmium molybdate (VI) and metal molybdates (VI) and process for the preparation of oxosalts in two-component system of cadmium molybdate (VI) and metal molybdates (VI) | |
| PL209574B1 (en) | Oxisalt in two-component arrangement of tungstates of metals and molybdates of metals and production method of oxisalts in two-component arrangement of tungstates of metals and molybdates of metals | |
| PL196718B1 (en) | New oxy salt in a ternary system of metal oxides and method of manufacture of new oxy salt in a ternary system of metal oxides | |
| PL222181B1 (en) | Type phase solid solutions with limited solubility of the components a four-component system metal oxide and a method for producing the phase-type solid solutions of the limited solubility of the ingredients in the four-component system metal oxide | |
| PL221618B1 (en) | Oxisalt in a two-component circuit of metal molybdates and methods for preparing the two-component system of oxisalts in a two-component circuit of metal molybdates | |
| PL196717B1 (en) | New oxy salt in a ternay system of metal oxides and method of manufacture of new oxy salt in a ternary system of metal oxides | |
| PL191558B1 (en) | Novel oxy-salt in a three-component system transient metal oxides and method of obtaining such oxy-salt | |
| PL235245B1 (en) | New type phases of restricted solid solution doped with f-electron-metal ions and method for producing new type phases of restricted solid solution doped with f-electron-metal ions | |
| PL219945B1 (en) | Oxisalt in a three-component system of metal oxides and production method of oxisalts in a three-component system of metal oxides |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LICE | Declarations of willingness to grant licence |
Free format text: RATE OF LICENCE: 10% Effective date: 20141215 |