PL3740520T3 - Pianki poliizocyjanurowe o długim czasie kremowania i właściwościach szybkiego utwardzania - Google Patents

Pianki poliizocyjanurowe o długim czasie kremowania i właściwościach szybkiego utwardzania

Info

Publication number
PL3740520T3
PL3740520T3 PL18780134.5T PL18780134T PL3740520T3 PL 3740520 T3 PL3740520 T3 PL 3740520T3 PL 18780134 T PL18780134 T PL 18780134T PL 3740520 T3 PL3740520 T3 PL 3740520T3
Authority
PL
Poland
Prior art keywords
long
polyisocyanurate foams
hardening properties
fast hardening
creaming time
Prior art date
Application number
PL18780134.5T
Other languages
English (en)
Inventor
Thomas Julien Joncheray
Jacopo BERNARDINI
Gilles Jean Geumez
Jan Vandenbroeck
Original Assignee
Huntsman International Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman International Llc filed Critical Huntsman International Llc
Publication of PL3740520T3 publication Critical patent/PL3740520T3/pl

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3237—Polyamines aromatic
    • C08G18/324—Polyamines aromatic containing only one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6644—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6677—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/794—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aromatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/125—Water, e.g. hydrated salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/10—Water or water-releasing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
PL18780134.5T 2018-01-16 2018-10-05 Pianki poliizocyjanurowe o długim czasie kremowania i właściwościach szybkiego utwardzania PL3740520T3 (pl)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP18151903 2018-01-16
PCT/EP2018/077085 WO2019141389A1 (en) 2018-01-16 2018-10-05 Polyisocyanurate comprising foams with long cream time and snap-cure behaviour

Publications (1)

Publication Number Publication Date
PL3740520T3 true PL3740520T3 (pl) 2023-08-14

Family

ID=60997379

Family Applications (1)

Application Number Title Priority Date Filing Date
PL18780134.5T PL3740520T3 (pl) 2018-01-16 2018-10-05 Pianki poliizocyjanurowe o długim czasie kremowania i właściwościach szybkiego utwardzania

Country Status (11)

Country Link
US (1) US11292865B2 (pl)
EP (1) EP3740520B1 (pl)
JP (2) JP7296968B2 (pl)
KR (1) KR102756424B1 (pl)
CN (1) CN111630080B (pl)
BR (1) BR112020013119A2 (pl)
CA (1) CA3087160A1 (pl)
MX (1) MX2020007569A (pl)
PL (1) PL3740520T3 (pl)
TW (1) TWI791656B (pl)
WO (1) WO2019141389A1 (pl)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022068681A (ja) * 2020-10-22 2022-05-10 積水化学工業株式会社 難燃性ウレタン樹脂組成物及びポリウレタン発泡体

Family Cites Families (27)

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JPS56142058A (en) * 1980-04-07 1981-11-06 Nisshin Spinning Laminated resin foaming body and its manufacture
US5109031A (en) 1989-03-13 1992-04-28 Jim Walter Research Corp. Rigid foam with improved "K" factor by reacting a polyisocyanate and polyester polyol containing low free glycol
JPH02248419A (ja) * 1989-03-22 1990-10-04 M D Kasei Kk 耐熱性ウレタン変性ポリイソシアヌレートフォームの製法
JPH0662797B2 (ja) * 1990-04-05 1994-08-17 三洋化成工業株式会社 硬質ポリウレタンおよびポリイソシアヌレートフォームの製法
DE4028211A1 (de) * 1990-09-06 1992-03-12 Basf Ag Verfahren zur herstellung von urethangruppen oder urethan- und isocyanuratgruppen enthaltenden hartschaumstoffen
DE4421817A1 (de) * 1994-06-22 1996-01-04 Bayer Ag Verfahren zur Isolierung von Rohren
JP2584955B2 (ja) * 1994-12-07 1997-02-26 大同鋼板株式会社 変性ポリイソシアヌレート発泡体及びその製造法並びにポリオール組成物
JPH09295364A (ja) * 1996-04-30 1997-11-18 Dainippon Ink & Chem Inc 積層軽量パネル及びその製造方法
KR20000053020A (ko) 1996-11-04 2000-08-25 네바드 에드워드 죤 경질 폴리우레탄 발포체
US5847014A (en) * 1997-04-15 1998-12-08 Bayer Corporation Water blown, energy absorbing foams
SK14542000A3 (sk) 1998-04-03 2001-04-09 Huntsman Ici Chemicals Llc Reakčný systém na polyizokyanurátové peny, jeho reakčný produkt a spôsob výroby týchto pien
JP4170134B2 (ja) 2003-04-18 2008-10-22 旭有機材工業株式会社 硬質ポリウレタンフォーム用原料組成物及び硬質ポリウレタンフォームの製造方法
CN101177525B (zh) * 2006-11-08 2010-05-12 上海昊海化工有限公司 纤维增强聚氨酯改性聚异氰酸脲酯复合材料及其制备方法
JP5403898B2 (ja) * 2007-11-05 2014-01-29 東洋ゴム工業株式会社 スプレー発泡硬質ポリウレタンフォーム用ポリオール組成物及びスプレー発泡硬質ポリウレタンフォームの製造方法
CN101319039A (zh) * 2008-07-23 2008-12-10 福建省新达保温材料有限公司 B1级喷涂型聚氨酯改性聚异氰脲酸酯泡沫塑料
JP5699563B2 (ja) 2009-11-30 2015-04-15 旭硝子株式会社 硬質発泡合成樹脂の製造方法
ES2472717T3 (es) * 2010-01-18 2014-07-02 Basf Se Envoltura de espuma rígida de poliuretano para conexión de tuberías
DE102011079336A1 (de) * 2011-07-18 2013-01-24 Bayer Materialscience Aktiengesellschaft Versprühbarer, wassergetriebener PUR-/PIR-Hartschaumstoff
TR201802484T4 (tr) * 2012-03-15 2018-03-21 Dow Global Technologies Llc Düşük yoğunluklu tam su üflemeli poliüretan sert köpük.
ES2651388T3 (es) * 2012-05-25 2018-01-26 Dow Global Technologies Llc Producción de paneles de espuma de poliisocianurato
CN103571171B (zh) * 2012-07-23 2016-07-13 上海东大聚氨酯有限公司 高密度聚氨酯管托，其组合聚醚、原料组合物、制备方法
US9522973B2 (en) * 2012-10-02 2016-12-20 Covestro Llc Polyurethane and polyisocyanurate rigid foams for roofing insulation
CN103030780A (zh) * 2012-12-31 2013-04-10 南京弘诺科技有限公司 一种阻燃型聚氨酯改性聚异氰脲酸酯泡沫、其制备方法及应用
US20160115289A1 (en) 2013-06-07 2016-04-28 Covestro Deutschland Ag Elastic rigid foam having improved temperature stability
CN103665305B (zh) * 2013-12-06 2016-02-24 上海华峰新材料研发科技有限公司 高阻燃型聚异氰脲酸酯硬质泡沫及其制备方法
CN104910349B (zh) * 2015-06-11 2018-02-23 山东一诺威新材料有限公司 聚异氰脲酸酯改性喷涂型组合聚醚及其制备方法和应用
CN105461895B (zh) * 2015-12-23 2018-10-26 上海东大聚氨酯有限公司 组合聚醚、聚异氰脲酸酯泡沫及其原料组合物和制备方法

Also Published As

Publication number Publication date
US11292865B2 (en) 2022-04-05
RU2020123603A (ru) 2022-02-17
EP3740520A1 (en) 2020-11-25
JP2021510753A (ja) 2021-04-30
TWI791656B (zh) 2023-02-11
RU2020123603A3 (pl) 2022-02-17
BR112020013119A2 (pt) 2020-12-01
US20200339728A1 (en) 2020-10-29
JP2023082116A (ja) 2023-06-13
CA3087160A1 (en) 2019-07-25
CN111630080A (zh) 2020-09-04
MX2020007569A (es) 2020-09-03
KR20200108430A (ko) 2020-09-18
JP7296968B2 (ja) 2023-06-23
EP3740520B1 (en) 2023-04-19
JP7581407B2 (ja) 2024-11-12
TW201932502A (zh) 2019-08-16
WO2019141389A1 (en) 2019-07-25
KR102756424B1 (ko) 2025-01-21
CN111630080B (zh) 2023-07-14

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