PL410320A1 - New quaternary alkoxymethyl propiconazole chlorides, method for producing them and their application as growth inhibitors of mycopathogens - Google Patents
New quaternary alkoxymethyl propiconazole chlorides, method for producing them and their application as growth inhibitors of mycopathogensInfo
- Publication number
- PL410320A1 PL410320A1 PL410320A PL41032014A PL410320A1 PL 410320 A1 PL410320 A1 PL 410320A1 PL 410320 A PL410320 A PL 410320A PL 41032014 A PL41032014 A PL 41032014A PL 410320 A1 PL410320 A1 PL 410320A1
- Authority
- PL
- Poland
- Prior art keywords
- propiconazole
- alkoxymethyl
- chlorides
- new quaternary
- growth inhibitors
- Prior art date
Links
- 239000005822 Propiconazole Substances 0.000 title abstract 5
- -1 alkoxymethyl propiconazole chlorides Chemical class 0.000 title abstract 3
- 239000003966 growth inhibitor Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 230000002538 fungal effect Effects 0.000 abstract 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Przedmiotem wynalazku są nowe czwartorzędowe alkoksymetylowe chlorki propikonazolu o wzorze ogólnym 1, w którym R oznacza podstawnik alkilowy zawierający od 3 do 18 atomów węgla, sposób ich wytwarzania oraz zastosowanie jako inhibitorów wzrostu patogenów grzybowych. Sposób otrzymywania nowych czwartorzędowych alkoksymetylowych chlorków propikonazolu polega na tym, że propikonazol poddaje się reakcji z eterem chlorometylowoalkilowym w stosunku molowym propikonazolu do eteru równym 1:1-1,5 w środowisku bezwodnego rozpuszczalnika organicznego w temperaturze od 25°C do 120° w czasie od 1 do 24 godzin, po czym powstały produkt reakcji odsącza się pod obniżonym ciśnieniem, dalej przemywa bezwodnym rozpuszczalnikiem organicznym, a następnie suszy się pod obniżonym ciśnieniem w temperaturze od 40°C do 80°C, korzystnie 50°C, w czasie od 8 do 24 godzin.The present invention relates to new quaternary alkoxymethyl chlorides of propiconazole of general formula 1, wherein R is an alkyl substituent containing from 3 to 18 carbon atoms, the method of their preparation and the use as fungal growth inhibitors. The method of obtaining new quaternary alkoxymethyl chlorides of propiconazole is that propiconazole is reacted with chloromethylalkyl ether in a molar ratio of propiconazole to ether of 1: 1-1.5 in an anhydrous organic solvent medium at a temperature from 25 ° C to 120 ° C from 1 to 24 hours, after which the resulting reaction product is filtered off under reduced pressure, further washed with anhydrous organic solvent, and then dried under reduced pressure at a temperature of 40 ° C to 80 ° C, preferably 50 ° C, for a period of 8 to 24 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL410320A PL229169B1 (en) | 2014-12-01 | 2014-12-01 | New quaternary alkoxymethyl propiconazole chlorides, method for producing them and their application as growth inhibitors of mycopathogens |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL410320A PL229169B1 (en) | 2014-12-01 | 2014-12-01 | New quaternary alkoxymethyl propiconazole chlorides, method for producing them and their application as growth inhibitors of mycopathogens |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL410320A1 true PL410320A1 (en) | 2016-06-06 |
| PL229169B1 PL229169B1 (en) | 2018-06-29 |
Family
ID=56086932
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL410320A PL229169B1 (en) | 2014-12-01 | 2014-12-01 | New quaternary alkoxymethyl propiconazole chlorides, method for producing them and their application as growth inhibitors of mycopathogens |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL229169B1 (en) |
-
2014
- 2014-12-01 PL PL410320A patent/PL229169B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL229169B1 (en) | 2018-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NZ726356A (en) | Processes for preparing antiviral compounds | |
| CY1121395T1 (en) | TETRAHYDROPYRIDOPYRAZINES-FORMERS TOY GPR6 | |
| EA201890522A1 (en) | METHOD OF OBTAINING ANTI-FIBER CONNECTIONS | |
| CO7141404A2 (en) | Processes to produce certain 2 (pyridin 3 il) thiazoles | |
| CO7141403A2 (en) | Processes to produce certain 2 (pyridin 3 il) thiazoles | |
| CR20160098A (en) | SYK INHIBITORS POLYMORPH | |
| BR112016029333A2 (en) | synthesis of polycyclic carbamoylpyridone compounds | |
| PH12017500833A1 (en) | Synthesis of copanlisib and its dihydrochloride salt | |
| MY194307A (en) | Pyridone derivative having tetrahydropyranylmethyl group | |
| MX394835B (en) | Methods for the preparation of 1,3-benzodioxole heterocyclic compounds | |
| HK1223367A1 (en) | Novel dgat2 inhibitors | |
| MX2017003238A (en) | Method for preparing 2'-o-fucosyllactose. | |
| JO3487B1 (en) | Synthesis of copanlisib and its dihydrochloride salt | |
| CO7141402A2 (en) | Processes to produce certain 2 (pyridin 3 il) thiazoles | |
| WO2016038628A3 (en) | A process for preparing olodaterol and intermediates thereof | |
| PH12014501712A1 (en) | Novel morpholinyl derivatives useful as mogat-2-inhibitors | |
| EA201490998A1 (en) | METHOD OF OBTAINING COMPLEX ETHERS (5-FLUOR-2-METHYL-3-QUINOLIN-2-ILMETHIL-INDOL-1-IL) -CATTY ACID | |
| MX367267B (en) | Process of preparing 3-(3-(4-(1-aminocyclobutyl)phenyl)-5-phenyl- 3h-imidazo[4,5-b]pyridin-2-yl)pyridin-2-amine. | |
| PL410423A1 (en) | Alkoxymethyl bis(2-hydroxyethyl)methylammonium 4-chloro-2-methylphenoxyacetates, method for obtaining them and application as plant pesticides | |
| PL410320A1 (en) | New quaternary alkoxymethyl propiconazole chlorides, method for producing them and their application as growth inhibitors of mycopathogens | |
| PL410319A1 (en) | New quaternary alkoxymethyl tebuconazole chlorides, method for producing them and their application as growth inhibitors of mycelium | |
| UA80249U (en) | Process for the preparation of 6-n-substituted derivatives of 1,3-dimethyluracil-5-carbaldehydes | |
| PL415067A1 (en) | Quaternary dialkyldimethylamonium gluconates, method for obtaining them and application as surfactants | |
| UA93929U (en) | METHOD OF PREPARATION OF 1-METHYL-3-aryl-1,2-DIGIDRO-2-HINOLONE | |
| PL419509A1 (en) | Bis-ammonium salts with alkyl-1,X-bis(decyldimethylammonium) cation and acesulfamate anion, method for obtaining them and application as food deterrents |