PL419509A1 - Bis-ammonium salts with alkyl-1,X-bis(decyldimethylammonium) cation and acesulfamate anion, method for obtaining them and application as food deterrents - Google Patents
Bis-ammonium salts with alkyl-1,X-bis(decyldimethylammonium) cation and acesulfamate anion, method for obtaining them and application as food deterrentsInfo
- Publication number
- PL419509A1 PL419509A1 PL419509A PL41950916A PL419509A1 PL 419509 A1 PL419509 A1 PL 419509A1 PL 419509 A PL419509 A PL 419509A PL 41950916 A PL41950916 A PL 41950916A PL 419509 A1 PL419509 A1 PL 419509A1
- Authority
- PL
- Poland
- Prior art keywords
- bis
- acesulfamate
- alkyl
- decyldimethylammonium
- anion
- Prior art date
Links
- 150000001450 anions Chemical class 0.000 title abstract 4
- 150000001768 cations Chemical class 0.000 title abstract 3
- YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 title abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 abstract 1
- SNZVFZOTUOUVDQ-UHFFFAOYSA-N [Br-].C[NH+](CCCCCCCCCC)C.C[NH+](CCCCCCCCCC)C.[Br-] Chemical compound [Br-].C[NH+](CCCCCCCCCC)C.C[NH+](CCCCCCCCCC)C.[Br-] SNZVFZOTUOUVDQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 229910017053 inorganic salt Inorganic materials 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem zgłoszenia są bisamoniowe sole z kationem alkilo-1,X-bis(decylodimetyloamoniowym) oraz anionem acesulfamianowym, o wzorze ogólnym 1, gdzie R oznacza łącznik alkilowy od czterech do dwunastu atomów węgla, A- oznacza anion: acesulfamianowy o wzorze ogólnym 3. Przedmiotem zgłoszenia jest też sposób ich otrzymywania, który polega na tym, że dibromek alkilo-1,X-bis(decylodimetyloamoniowy), o wzorze ogólnym 2, poddaje się reakcji wymiany z acesulfamianem potasu, w stosunku molowym soli do dibromku bisamoniowego 2 : 1 w temperaturze od 25 do 60°C, korzystnie 25°C, w rozpuszczalnikach takich jak: metanol lub toluen, lub aceton, następnie odsącza się produkt uboczny w postaci soli nieorganicznej i odparowuje rozpuszczalnik, a produkt końcowy suszy się w temperaturze 70°C. Zgłoszenie zawiera też zastosowanie bisamoniowych soli z kationem alkilo-1,X-bis(decylodimetyloamoniowym) oraz anionem acesulfamianowym jako deterenty pokarmowe.The subject of the application are bisammonium salts with an alkyl-1, X-bis (decyldimethylammonium) cation and an acesulfamate anion of general formula 1, where R is an alkyl linker from four to twelve carbon atoms, A- means anion: acesulfamate of general formula 3. applications are also obtained, which consists in the fact that the alkyl-1, X-bis (decyldimethylammonium) dibromide, of general formula 2, is subjected to an exchange reaction with potassium acesulfamate, in a molar ratio of 2: 1 bisammonium dibromide at a temperature of from 25 to 60 ° C, preferably 25 ° C, in solvents such as methanol or toluene or acetone, then the by-product in the form of inorganic salt is filtered off and the solvent is evaporated, and the final product is dried at 70 ° C. The application also contains the use of bisammonium salts with an alkyl-1, X-bis (decyldimethylammonium) cation and acesulfamate anion as food detectors.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL419509A PL231632B1 (en) | 2016-11-18 | 2016-11-18 | Bis-ammonium salts with alkyl-1,X-bis(decyldimethylammonium) cation and acesulfamate anion, method for obtaining them and application as food deterrents |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL419509A PL231632B1 (en) | 2016-11-18 | 2016-11-18 | Bis-ammonium salts with alkyl-1,X-bis(decyldimethylammonium) cation and acesulfamate anion, method for obtaining them and application as food deterrents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL419509A1 true PL419509A1 (en) | 2018-05-21 |
| PL231632B1 PL231632B1 (en) | 2019-03-29 |
Family
ID=62142533
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL419509A PL231632B1 (en) | 2016-11-18 | 2016-11-18 | Bis-ammonium salts with alkyl-1,X-bis(decyldimethylammonium) cation and acesulfamate anion, method for obtaining them and application as food deterrents |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL231632B1 (en) |
-
2016
- 2016-11-18 PL PL419509A patent/PL231632B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL231632B1 (en) | 2019-03-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CU24612B1 (en) | SUBSTITUTED PYRIDAZINE DERIVATIVES USEFUL AS HERBICIDES | |
| BR112018076784A2 (en) | microbiocidal oxadiazole derivatives | |
| BR112018013821A2 (en) | microbiocidal oxadiazole derivatives | |
| CY1125319T1 (en) | IONIC COMPOUNDS OF LITHIUM ORGANIC ANION COMPOUNDS AND COMPOSITIONS | |
| BR112018069412A2 (en) | microbiocidal oxadiazole derivatives | |
| MX377235B (en) | IMPROVED PROCESS FOR PREPARING CHLORINATED BIPHENYLANILIDES AND BIPHENYLANILINES. | |
| PL416323A1 (en) | Methyl alkyl betaine 3,6-dichloro-2-methoxybenzoate, method for obtaining it and application as a herbicide | |
| PL419509A1 (en) | Bis-ammonium salts with alkyl-1,X-bis(decyldimethylammonium) cation and acesulfamate anion, method for obtaining them and application as food deterrents | |
| PL413162A1 (en) | New ammonium ionic liquids, containing dimethyldodecyl(carboxymethyl)ammonium cation, method for obtaining them and application as disinfectants | |
| PL415210A1 (en) | Method for obtaining ammonium ionic liquids with cation derivative of betaine and nonenoate anion and their application as herbicides | |
| PL417806A1 (en) | Ionic liquids with bis-ammonium cation and mandelate anion - method for obtaining them and applications as bactericides | |
| PL419507A1 (en) | New sweet bis-ammonium salts with alkyl-1,X-bis(decyldimethylammonium) cation and saccharinate anions, method for obtaining them and application as food deterrents | |
| PL413037A1 (en) | New (alkoxymethyl)ethyldimethylammonium 4-chloro-2-methylphenoxyacetates ionic liquids, method for obtaining them and their application as herbicides | |
| PL420661A1 (en) | New bis-ammonium ionic liquids with alkyl-1,X-bis(bis(2-hydroxyethyl)octadec-9-en-ammonium) cation and method for obtaining them and application as food deterrents | |
| PL417453A1 (en) | New bis-ammonium ionic liquids with alkyl-1,X-bis(bis(2-hydroxyethyl)octadec-9-en ammonium) or bis(ethane)amino-2,2'-bis(bis(2-hydroxyethyl)octadec-9-en ammonium), or butene-1,4-bis(bis(2-hydroxyethyl)octadec-9-en ammonium) cation, method for obtaining them and applications as herbicides | |
| PL410320A1 (en) | New quaternary alkoxymethyl propiconazole chlorides, method for producing them and their application as growth inhibitors of mycopathogens | |
| PL410374A1 (en) | New ammonium ionic liquids, alkoxymethyl[3-(methacryloylamino)propyl]dimetyl-ammonium 2,4-dichlorophenoxy)acetates, method for obtaining them and their application as herbicides | |
| BR112018008428A2 (en) | method for synthesizing 2-alkyl-4-trifluoromethyl-3-alkylsulfonylbenzoic acids | |
| PL419453A1 (en) | Bis-ammonium ionic liquids with alkane-1,X-bis(decyldimethylammonium) cation and trioxonitrate(V) anion, method for obtaining them and application as food deterrents | |
| PL417193A1 (en) | New bis-ammonium ionic liquids with alkane-1,X-bis(decyldimethylammonium) cation and formate anion, method for obtaining them and applications as bactericides | |
| PL422180A1 (en) | New ionic liquids with 1,1,4,7,7-pentamethyl-1,4,7-trialkyl-diethylene-triammonium cation and (4-chloro-2-methylphenoxy)acetate anion, method for obtaining them and applications as herbicides | |
| PL418890A1 (en) | Alkyl[2-(2-hydroxyethoxy)ethyl]dimethylammonium 3,6-dichloro-2-methoxybenzoates, method for obtaining them and application as herbicides | |
| PL413394A1 (en) | Arginine salts of phenoxy acids and methods for obtaining them and their application as herbicides | |
| PL410319A1 (en) | New quaternary alkoxymethyl tebuconazole chlorides, method for producing them and their application as growth inhibitors of mycelium | |
| PL410372A1 (en) | New ammonium ionic liquids, alkoxymethyl[3-(methacryloylamino)propyl]dimetyl-ammonium 4-chloro-2-methylphenoxy)acetates, method for producing them and their application as herbicides |