PL412427A1 - Sposób kompleksowej utylizacji fosfogipsów - Google Patents
Sposób kompleksowej utylizacji fosfogipsówInfo
- Publication number
- PL412427A1 PL412427A1 PL412427A PL41242715A PL412427A1 PL 412427 A1 PL412427 A1 PL 412427A1 PL 412427 A PL412427 A PL 412427A PL 41242715 A PL41242715 A PL 41242715A PL 412427 A1 PL412427 A1 PL 412427A1
- Authority
- PL
- Poland
- Prior art keywords
- precipitate
- metals
- calcium
- phosphogypsum
- sulfate
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 title abstract 3
- 239000002244 precipitate Substances 0.000 abstract 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 150000002739 metals Chemical class 0.000 abstract 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 3
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 abstract 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/19—Fluorine; Hydrogen fluoride
- C01B7/191—Hydrogen fluoride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/468—Purification of calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/32—Phosphates of magnesium, calcium, strontium, or barium
- C01B25/324—Preparation from a reaction solution obtained by acidifying with an acid other than orthophosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/32—Alkali metal silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/24—Sulfates of ammonium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/36—Nitrates
- C01F11/38—Preparation with nitric acid or nitrogen oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B11/00—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes
- C05B11/04—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid
- C05B11/08—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid using sulfuric acid
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
- C05C5/04—Fertilisers containing other nitrates containing calcium nitrate
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/14—Obtaining zirconium or hafnium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Fertilizers (AREA)
- Removal Of Specific Substances (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Sposób kompleksowej utylizacji fosfogipsów polega na rozdrabnianiu fosfogipsów, a następnie płukaniu ich roztworem kwasu siarkowego o stężeniu od 2 - 15% i mieszaniu w temperaturze od 50 - 80°C, po czym powstałą mieszaninę poddaje się rozdzieleniu na frakcje płynną i osad w większości zawierający siarczan wapnia. Sposób charakteryzuje się tym, że z frakcji płynnej strąca się metale, głównie lantanowce, fosforany i siarczany metali rozpuszczalnych w rozcieńczonym kwasie siarkowym, zaś osad zawierający w większości siarczan wapnia konwertuje się w obecności wody amoniakalnej i dwutlenku węgla do siarczanu amonu i węglanu wapnia, po czym przefiltrowany i osuszony osad w postaci węglanu wapnia rozpuszcza się w roztworze kwasu azotowego o stężeniu od 15 - 30% stale mieszając, a następnie powstały w trakcie reakcji CO2 zawraca się i wykorzystuje w procesie konwersji pierwszej fazy osadu, a powstałą mieszaninę poddaje się rozdzielaniu na roztwór azotanu wapnia z rozpuszczonymi w nim metalami oraz na osad fluorków i krzemianów z metalami wtrąconymi.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL412427A PL412427A1 (pl) | 2015-05-20 | 2015-05-20 | Sposób kompleksowej utylizacji fosfogipsów |
| EP16726674.1A EP3297975B1 (en) | 2015-05-20 | 2016-04-25 | Method for complex treatment of phosphogypsum |
| AU2016264722A AU2016264722A1 (en) | 2015-05-20 | 2016-04-25 | Method for complex treatment of phosphogypsum |
| CA2986282A CA2986282A1 (en) | 2015-05-20 | 2016-04-25 | Method for complex treatment of phosphogypsum |
| RU2017142631A RU2017142631A (ru) | 2015-05-20 | 2016-04-25 | Способ для комплексной обработки фосфогипса |
| PCT/PL2016/000045 WO2016186527A1 (en) | 2015-05-20 | 2016-04-25 | Method for complex treatment of phosphogypsum |
| CN201680028960.6A CN108112248A (zh) | 2015-05-20 | 2016-04-25 | 复合处理磷石膏的方法 |
| US15/574,902 US10370258B2 (en) | 2015-05-20 | 2016-04-25 | Method for complex treatment of phosphogypsum |
| PL16726674T PL3297975T3 (pl) | 2015-05-20 | 2016-04-25 | Sposób kompleksowej utylizacji fosfogipsów |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL412427A PL412427A1 (pl) | 2015-05-20 | 2015-05-20 | Sposób kompleksowej utylizacji fosfogipsów |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL412427A1 true PL412427A1 (pl) | 2016-11-21 |
Family
ID=56097257
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL412427A PL412427A1 (pl) | 2015-05-20 | 2015-05-20 | Sposób kompleksowej utylizacji fosfogipsów |
| PL16726674T PL3297975T3 (pl) | 2015-05-20 | 2016-04-25 | Sposób kompleksowej utylizacji fosfogipsów |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL16726674T PL3297975T3 (pl) | 2015-05-20 | 2016-04-25 | Sposób kompleksowej utylizacji fosfogipsów |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10370258B2 (pl) |
| EP (1) | EP3297975B1 (pl) |
| CN (1) | CN108112248A (pl) |
| AU (1) | AU2016264722A1 (pl) |
| CA (1) | CA2986282A1 (pl) |
| PL (2) | PL412427A1 (pl) |
| RU (1) | RU2017142631A (pl) |
| WO (1) | WO2016186527A1 (pl) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018190737A1 (en) | 2017-04-14 | 2018-10-18 | Ferin Sp. Z.O.O. | Method for the management of phosphogypsum |
| CN118343819A (zh) * | 2024-03-29 | 2024-07-16 | 浙江大学 | 一种高效去除磷石膏中有害杂质的方法 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108796612B (zh) * | 2018-06-06 | 2024-06-14 | 湖北三宁化工股份有限公司 | 一种磷石膏循环分解制硫酸钙晶须联产硫酸铵的方法 |
| AT521253B1 (de) * | 2018-07-27 | 2019-12-15 | Saubermacher Dienstleistungs Ag | Verfahren und Anlage zum nasschemischen Gewinnen einer Wertstofffraktion aus einem Schüttgut |
| CN108975374B (zh) * | 2018-09-20 | 2020-12-18 | 秦皇岛天鼎化工有限公司 | 利用磷石膏制备硝酸钙的方法和硝酸钙 |
| CN112030003B (zh) * | 2020-03-27 | 2021-09-07 | 昆明理工大学 | 一种同时脱除湿法炼锌废电解液中多种杂质离子的方法 |
| FR3113050B1 (fr) | 2020-07-31 | 2023-04-21 | Ocp Sa | Procédé de fabrication de sulfate d’ammonium et de carbonate de calcium à partir de phosphogypse |
| CN112266191A (zh) * | 2020-09-15 | 2021-01-26 | 昆明理工大学 | 一种利用钢渣预处理磷石膏的方法 |
| MA51851B1 (fr) * | 2020-11-23 | 2022-08-31 | Mascir Morocan Foundation For Advanced Science Innovation & Res | Procédé d'obtention de sulfate d'ammonium et d'oxalate de calcium à partir de phosphogypse |
| CN112897529A (zh) * | 2021-02-01 | 2021-06-04 | 江苏一夫科技股份有限公司 | 一种从磷石膏中提取二氧化硅的方法 |
| WO2022245733A1 (en) * | 2021-05-15 | 2022-11-24 | Elixsys, Inc. | Systems and methods to recover value-added materials from gypsum |
| RU2763074C1 (ru) * | 2021-06-16 | 2021-12-27 | федеральное государственное бюджетное образовательное учреждение высшего образования «Санкт-Петербургский горный университет» | Способ комплексной переработки фосфогипса |
| CN116999892B (zh) * | 2023-06-30 | 2026-02-06 | 武汉工程大学 | 一种提取磷石膏中共晶磷的浸取剂和方法 |
| CN118004974A (zh) * | 2024-02-01 | 2024-05-10 | 中国科学院过程工程研究所 | 一种工业磷石膏和有机废盐的资源化利用系统及方法和应用 |
| CN119178765B (zh) * | 2024-11-22 | 2025-03-14 | 贵研检测科技（云南）有限公司 | 一种钯灰中钯含量的测定方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1826785A (en) * | 1927-11-28 | 1931-10-13 | Theodore V D Berdell | Process of producing fertilizers |
| GB310276A (en) * | 1928-06-05 | 1929-04-25 | Kunstdunger Patent Verwertungs | Method of producing a mixture of calcium nitrate and ammonium nitrate |
| US1758449A (en) * | 1928-12-24 | 1930-05-13 | Kunstdunger Patent Verwertungs | Ammonium-sulphate manufacture |
| GB512005A (en) * | 1937-05-24 | 1939-08-28 | Harold William Heiser | Improvements in or relating to methods of extracting fluorine values from fluorspar ores |
| US2640757A (en) | 1949-09-23 | 1953-06-02 | Phillips Petroleum Co | Production of ammonium sulfate and calcium carbonate |
| PL108676B2 (en) | 1977-04-05 | 1980-04-30 | Method and a device for converting phosphogypsum to chalk and ammonium sulfate solution | |
| PL157981B1 (pl) | 1989-03-09 | 1992-07-31 | Sposób biochemiczny otrzymywania metali rzadkich z fosfogipsów PL | |
| PL166137B1 (pl) | 1990-06-28 | 1995-04-28 | Politechnika Wroclawska | Sposób wytwarzania wieloskladnikowego nawozu mineralnego PL |
| US5425800A (en) * | 1993-10-26 | 1995-06-20 | Fmc Corporation | Recovery of precious metal values from refractory ores |
| PL178169B1 (pl) | 1995-02-16 | 2000-03-31 | Politechnika Szczecinska | Sposób otrzymywania roztworu pierwiastków ziem rzadkich w kwasie azotowym (V) z fosfogipsu |
| DE10230592A1 (de) * | 2002-07-06 | 2004-01-22 | Compo Gmbh & Co. Kg | Verfahren zur Herstellung von Calciumnitrat |
| CN1978420A (zh) * | 2005-12-06 | 2007-06-13 | 甘肃凯西生态环境工程有限公司 | 石膏制取柠檬酸钙 |
| CN101186318B (zh) * | 2007-12-07 | 2010-10-06 | 贵州省化工研究院 | 用硝酸分解磷矿副产物硝酸钙制造硝酸钠的方法 |
| WO2013060689A1 (fr) * | 2011-10-24 | 2013-05-02 | Prayon Sa | Procede de traitement de roches phosphatees |
| CN102674424B (zh) * | 2012-04-28 | 2014-11-05 | 浙江大学 | 一种以废石膏为钙源制备纳米碳酸钙浆料的方法、产品及应用 |
| US8758719B2 (en) | 2012-08-10 | 2014-06-24 | Sparstane Technologies LLC | Process for converting FGD gypsum to ammonium sulfate and calcium carbonate |
| RU2509724C1 (ru) * | 2012-08-13 | 2014-03-20 | Общество с ограниченной ответственностью Инженерно-производственная компания "ИНТЕРФОС" | Способ получения высокочистого углекислого кальция и азотно-сульфатного удобрения в процессе комплексной переработки фосфогипса |
| RU2526907C1 (ru) * | 2013-03-20 | 2014-08-27 | Общество с ограниченной ответственностью "МИЦ-Геосистемы" | Способ извлечения редкоземельных металлов из фосфогипса |
-
2015
- 2015-05-20 PL PL412427A patent/PL412427A1/pl unknown
-
2016
- 2016-04-25 CA CA2986282A patent/CA2986282A1/en not_active Abandoned
- 2016-04-25 RU RU2017142631A patent/RU2017142631A/ru not_active Application Discontinuation
- 2016-04-25 US US15/574,902 patent/US10370258B2/en not_active Expired - Fee Related
- 2016-04-25 CN CN201680028960.6A patent/CN108112248A/zh active Pending
- 2016-04-25 WO PCT/PL2016/000045 patent/WO2016186527A1/en not_active Ceased
- 2016-04-25 AU AU2016264722A patent/AU2016264722A1/en not_active Abandoned
- 2016-04-25 EP EP16726674.1A patent/EP3297975B1/en active Active
- 2016-04-25 PL PL16726674T patent/PL3297975T3/pl unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018190737A1 (en) | 2017-04-14 | 2018-10-18 | Ferin Sp. Z.O.O. | Method for the management of phosphogypsum |
| CN118343819A (zh) * | 2024-03-29 | 2024-07-16 | 浙江大学 | 一种高效去除磷石膏中有害杂质的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3297975B1 (en) | 2019-11-06 |
| CA2986282A1 (en) | 2016-11-24 |
| RU2017142631A (ru) | 2019-06-20 |
| WO2016186527A1 (en) | 2016-11-24 |
| CN108112248A (zh) | 2018-06-01 |
| PL3297975T3 (pl) | 2021-04-19 |
| RU2017142631A3 (pl) | 2019-10-29 |
| AU2016264722A1 (en) | 2017-12-21 |
| US20180162740A1 (en) | 2018-06-14 |
| EP3297975A1 (en) | 2018-03-28 |
| US10370258B2 (en) | 2019-08-06 |
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