PL428566A1 - Method of preparing pyrene derivative of ferrocenecarboxamide and method of preparing pyrene derivative of 1,1'-ferrocenedicarboxamide - Google Patents
Method of preparing pyrene derivative of ferrocenecarboxamide and method of preparing pyrene derivative of 1,1'-ferrocenedicarboxamideInfo
- Publication number
- PL428566A1 PL428566A1 PL428566A PL42856619A PL428566A1 PL 428566 A1 PL428566 A1 PL 428566A1 PL 428566 A PL428566 A PL 428566A PL 42856619 A PL42856619 A PL 42856619A PL 428566 A1 PL428566 A1 PL 428566A1
- Authority
- PL
- Poland
- Prior art keywords
- ferrocenecarboxamide
- pyrene derivative
- pyrene
- preparing
- ferrocenedicarboxamide
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 150000003220 pyrenes Chemical class 0.000 title abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- RCYFOPUXRMOLQM-UHFFFAOYSA-N pyrene-1-carbaldehyde Chemical compound C1=C2C(C=O)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 RCYFOPUXRMOLQM-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- UKJLNMAFNRKWGR-UHFFFAOYSA-N cyclohexatrienamine Chemical group NC1=CC=C=C[CH]1 UKJLNMAFNRKWGR-UHFFFAOYSA-N 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 150000002466 imines Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Sposób otrzymywania pirenowej pochodnej ferrocenokarboksyamidu o wzorze ogólnym 1, w którym R oznacza atom wodoru (H), charakteryzuje się tym, że 1-karboaldehyd pirenu poddaje się reakcji z N-(4-aminofenylo)ferrocenokarboksyamidem użytym w ilości 1 ekwiwalenta w stosunku do 1-karboaldehydu pirenu w obecności kwasu mrówkowego lub kwasu octowego w alkoholu etylowym lub alkoholu metylowym w temperaturze pokojowej a otrzymaną iminę poddaje się redukcji za pomocą cyjanotrihydroboranu użytego w ilości 5 ekwiwalentów w stosunku do 1-karboaldehydu pirenu i produkt reakcji wyodrębnia się za pomocą odsączenia mieszaniny poreakcyjnej.The method of obtaining a pyrene derivative of ferrocenecarboxamide of the general formula I, in which R is a hydrogen atom (H), is characterized in that pyrene 1-carbaldehyde is reacted with N- (4-aminophenyl) ferrocenecarboxamide used in an amount of 1 equivalent to 1 - pyrene carboxaldehyde in the presence of formic acid or acetic acid in ethyl alcohol or methyl alcohol at room temperature and the obtained imine is reduced with cyanotrihydroborate used in the amount of 5 equivalents to pyrene 1-carboxaldehyde and the reaction product is isolated by filtering the reaction mixture .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL428566A PL238252B1 (en) | 2019-01-11 | 2019-01-11 | Method of preparing pyrene derivative of ferrocenecarboxamide and method of preparing pyrene derivative of 1,1'-ferrocenedicarboxamide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL428566A PL238252B1 (en) | 2019-01-11 | 2019-01-11 | Method of preparing pyrene derivative of ferrocenecarboxamide and method of preparing pyrene derivative of 1,1'-ferrocenedicarboxamide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL428566A1 true PL428566A1 (en) | 2020-07-13 |
| PL238252B1 PL238252B1 (en) | 2021-08-02 |
Family
ID=71512429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL428566A PL238252B1 (en) | 2019-01-11 | 2019-01-11 | Method of preparing pyrene derivative of ferrocenecarboxamide and method of preparing pyrene derivative of 1,1'-ferrocenedicarboxamide |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL238252B1 (en) |
-
2019
- 2019-01-11 PL PL428566A patent/PL238252B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL238252B1 (en) | 2021-08-02 |
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