PL429042A1 - Symmetrical imines based on a terthiophene core and method of their preparation - Google Patents
Symmetrical imines based on a terthiophene core and method of their preparationInfo
- Publication number
- PL429042A1 PL429042A1 PL429042A PL42904219A PL429042A1 PL 429042 A1 PL429042 A1 PL 429042A1 PL 429042 A PL429042 A PL 429042A PL 42904219 A PL42904219 A PL 42904219A PL 429042 A1 PL429042 A1 PL 429042A1
- Authority
- PL
- Poland
- Prior art keywords
- core
- formula
- terthiophene
- preparation
- tertiophene
- Prior art date
Links
- 150000002466 imines Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- KXSFECAJUBPPFE-UHFFFAOYSA-N 2,2':5',2''-terthiophene Chemical group C1=CSC(C=2SC(=CC=2)C=2SC=CC=2)=C1 KXSFECAJUBPPFE-UHFFFAOYSA-N 0.000 title 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical class N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 abstract 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Photovoltaic Devices (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Przedmiotem wynalazku są symetryczne iminy z rdzeniem tertiofenowym o wzorze 1, w którym jako ugrupowania boczne (R) zawierają pochodne fenylowe lub benzotizowe, znajdujące zastosowanie w wytwarzaniu urządzeń fotowoltaicznych, w szczególności, w ogniwach słonecznych, w postaci warstwy zawierającej te związki. Zgłoszenie obejmuje także sposób otrzymywania symetrycznych imin z rdzeniem tertiofenowym o wzorze 1, charakteryzujący się tym, że w atmosferze gazu inertnego, korzystnie azotu lub argonu, dodaje się związku 2,2': 5',2"-tertiofen-5,5"-, korzystnie w postaci dialdehydu, do związku o wzorze R, korzystnie w postaci aminy, w obecności katalizatora kwasowego i prowadzi się reakcję w przedziale temperatur (140 ÷ 200)°C, w okresie od 24 godzin do 168 godzin. Otrzymany osad poreakcyjny rozpuszcza się w dimetylacetamidu. Powstałą mieszaninę wlewa się do wody, a otrzymany surowy osad przemywa się kolejno etanolem i acetonem. Następnie osad ten poddaje się procesowi suszenia.The subject of the invention is symmetrical imines with a tertiophene core of the formula I in which the side groups (R) contain phenyl or benzothisic derivatives which are used in the production of photovoltaic devices, in particular in solar cells, in the form of a layer containing these compounds. The application also covers a process for the preparation of symmetrical imines with a tertiophene core of formula I, characterized in that 2.2 ': 5', 2 "-terthiophene-5.5" is added under an inert gas atmosphere, preferably nitrogen or argon. , preferably in the form of a dialdehyde, to a compound of formula R, preferably in the form of an amine, in the presence of an acid catalyst and the reaction is carried out in the temperature range (140-200) ° C for a period of 24 hours to 168 hours. The obtained reaction precipitate is dissolved in dimethylacetamide. The resulting mixture is poured into water and the resulting crude solid is washed successively with ethanol and acetone. The sludge is then subjected to a drying process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL429042A PL237522B1 (en) | 2019-02-25 | 2019-02-25 | Symmetrical imines based on a terthiophene core and method of their preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL429042A PL237522B1 (en) | 2019-02-25 | 2019-02-25 | Symmetrical imines based on a terthiophene core and method of their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL429042A1 true PL429042A1 (en) | 2020-09-07 |
| PL237522B1 PL237522B1 (en) | 2021-04-19 |
Family
ID=72291404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL429042A PL237522B1 (en) | 2019-02-25 | 2019-02-25 | Symmetrical imines based on a terthiophene core and method of their preparation |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL237522B1 (en) |
-
2019
- 2019-02-25 PL PL429042A patent/PL237522B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL237522B1 (en) | 2021-04-19 |
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