PL429044A1 - Symmetrical imines based on a triphenylamine core and the method of their preparation - Google Patents
Symmetrical imines based on a triphenylamine core and the method of their preparationInfo
- Publication number
- PL429044A1 PL429044A1 PL429044A PL42904419A PL429044A1 PL 429044 A1 PL429044 A1 PL 429044A1 PL 429044 A PL429044 A PL 429044A PL 42904419 A PL42904419 A PL 42904419A PL 429044 A1 PL429044 A1 PL 429044A1
- Authority
- PL
- Poland
- Prior art keywords
- triphenylamine
- formula
- preparation
- core
- symmetrical
- Prior art date
Links
- 150000002466 imines Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 125000006617 triphenylamine group Chemical group 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 239000002244 precipitate Substances 0.000 abstract 2
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical class N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 abstract 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Photovoltaic Devices (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem wynalazku są symetryczne iminy o wzorze 1, z rdzeniem trójfenyloaminowym i ugrupowaniami bocznymi (R) zawierającymi pochodne fenylowe lub benzotizowe, znajdujące zastosowanie w wytwarzaniu urządzeń fotowoltaicznych, w szczególności, w ogniwach słonecznych, w postaci warstwy zawierającej te związki. Zgłoszenie obejmuje także sposób otrzymywania symetrycznych imin o wzorze 1, z rdzeniem trójfenyloaminowym, w którym jako ugrupowania boczne (R) zawierają pochodne fenylowe lub benzotizowe. Sposób charakteryzuje się tym, że w atmosferze gazu inertnego, korzystnie azotu lub argonu, dodaje się związku 4,4'-trójfenyloaminy, korzystnie w postaci dialdehydu, do związku o wzorze R, korzystnie w postaci aminy, w obecności katalizatora kwasowego i prowadzi się reakcję w przedziale temperatur (140 ÷ 200)°C, w okresie od 24 godzin do 168 godzin. Następnie osad poreakcyjny rozpuszcza się w dimetylacetamidzie. Powstałą mieszaninę wlewa się do wody, a otrzymany surowy osad przemywa się kolejno etanolem i acetonem, a następnie poddaje się procesowi suszenia.The invention relates to symmetrical imines of the formula I, with a triphenylamine core and side groups (R) containing phenyl or benzotic derivatives, for use in the production of photovoltaic devices, in particular in solar cells, in the form of a layer containing these compounds. The application also covers a process for the preparation of symmetrical imines of the formula I with a triphenylamine core in which the side moieties (R) contain phenyl or benzothiside derivatives. The process is characterized in that the 4,4'-triphenylamine compound, preferably in the form of a dialdehyde, is added under an inert gas, preferably nitrogen or argon, to a compound of formula R, preferably in the form of an amine, in the presence of an acid catalyst, and the reaction is carried out. in the temperature range (140 ÷ 200) ° C, in the period from 24 hours to 168 hours. Then the reaction precipitate is dissolved in dimethylacetamide. The resulting mixture is poured into water, and the obtained crude precipitate is washed successively with ethanol and acetone, and then subjected to a drying process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL429044A PL237524B1 (en) | 2019-02-25 | 2019-02-25 | Symmetrical imines based on a triphenylamine core and the method of their preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL429044A PL237524B1 (en) | 2019-02-25 | 2019-02-25 | Symmetrical imines based on a triphenylamine core and the method of their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL429044A1 true PL429044A1 (en) | 2020-09-07 |
| PL237524B1 PL237524B1 (en) | 2021-04-19 |
Family
ID=72291406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL429044A PL237524B1 (en) | 2019-02-25 | 2019-02-25 | Symmetrical imines based on a triphenylamine core and the method of their preparation |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL237524B1 (en) |
-
2019
- 2019-02-25 PL PL429044A patent/PL237524B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL237524B1 (en) | 2021-04-19 |
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