PL429043A1 - Unsymmetrical imines based on a triphenylamine core and method of their preparation - Google Patents
Unsymmetrical imines based on a triphenylamine core and method of their preparationInfo
- Publication number
- PL429043A1 PL429043A1 PL429043A PL42904319A PL429043A1 PL 429043 A1 PL429043 A1 PL 429043A1 PL 429043 A PL429043 A PL 429043A PL 42904319 A PL42904319 A PL 42904319A PL 429043 A1 PL429043 A1 PL 429043A1
- Authority
- PL
- Poland
- Prior art keywords
- unsymmetrical
- triphenylamine
- formula
- imines
- preparation
- Prior art date
Links
- 150000002466 imines Chemical class 0.000 title abstract 3
- 125000006617 triphenylamine group Chemical group 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Photovoltaic Devices (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem wynalazku są niesymetryczne iminy z rdzeniem trójfenyloaminowym o wzorze 1, w którym jako ugrupowania boczne (R) zawierają pochodne fenylowe lub benzotizowe, znajdujące zastosowanie w wytwarzaniu urządzeń fotowoltaicznych w szczególności, w ogniwach słonecznych, w postaci warstwy zawierającej te związki. Zgłoszenie obejmuje też sposób otrzymywania niesymetrycznych imin z rdzeniem trójfenyloaminowym o wzorze 1, w którym jako ugrupowania boczne (R) zawierają pochodne fenylowe lub benzotizowe. Sposób charakteryzuje się tym, że w atmosferze gazu inertnego, korzystnie azotu lub argonu, dodaje się związku 4-trójfenyloaminy, korzystnie w postaci aldehydu do związku o wzorze R, korzystnie w postaci aminy, w obecności katalizatora kwasowego i prowadzi się reakcję w przedziale temperatur (140 ÷ 200)°C, w okresie od 24 godzin do 168 godzin. Następnie osad poreakcyjny rozpuszcza się w dimetylacetamidzie. Powstałą mieszaninę wlewa się do wody, a otrzymany surowy osad przemywa się kolejno etanolem i acetonem, a następnie osad ten poddaje się etapowi suszenia.The invention relates to unsymmetrical imines with a triphenylamine core of the formula I in which the side moieties (R) contain phenyl or benzothisic derivatives which are used in the production of photovoltaic devices, in particular, in solar cells, in the form of a layer containing these compounds. The application also covers the preparation of unsymmetrical imines with a triphenylamine core of the formula I, in which the side moieties (R) contain phenyl or benzothiside derivatives. The method is characterized in that, under an inert gas atmosphere, preferably nitrogen or argon, the compound of 4-triphenylamine, preferably in the form of an aldehyde, is added to a compound of formula R, preferably in the form of an amine, in the presence of an acid catalyst and the reaction is carried out in a temperature range ( 140 ÷ 200) ° C, in the period from 24 hours to 168 hours. Then the reaction precipitate is dissolved in dimethylacetamide. The resulting mixture is poured into water, and the obtained crude solid is washed successively with ethanol and acetone, and then this solid is subjected to a drying step.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL429043A PL237523B1 (en) | 2019-02-25 | 2019-02-25 | Unsymmetrical imines based on a triphenylamine core and method of their preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL429043A PL237523B1 (en) | 2019-02-25 | 2019-02-25 | Unsymmetrical imines based on a triphenylamine core and method of their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL429043A1 true PL429043A1 (en) | 2020-09-07 |
| PL237523B1 PL237523B1 (en) | 2021-04-19 |
Family
ID=72291398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL429043A PL237523B1 (en) | 2019-02-25 | 2019-02-25 | Unsymmetrical imines based on a triphenylamine core and method of their preparation |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL237523B1 (en) |
-
2019
- 2019-02-25 PL PL429043A patent/PL237523B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL237523B1 (en) | 2021-04-19 |
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