PL432325A1 - Kompleks rutenu i sposób prowadzenia reakcji metatezy olefin z utworzeniem wiązania wewnętrznego z zastosowaniem kompleksu rutenu jako katalizatora - Google Patents

Kompleks rutenu i sposób prowadzenia reakcji metatezy olefin z utworzeniem wiązania wewnętrznego z zastosowaniem kompleksu rutenu jako katalizatora

Info

Publication number
PL432325A1
PL432325A1 PL432325A PL43232519A PL432325A1 PL 432325 A1 PL432325 A1 PL 432325A1 PL 432325 A PL432325 A PL 432325A PL 43232519 A PL43232519 A PL 43232519A PL 432325 A1 PL432325 A1 PL 432325A1
Authority
PL
Poland
Prior art keywords
ruthenium complex
catalyst
formation
olefin metathesis
internal bond
Prior art date
Application number
PL432325A
Other languages
English (en)
Other versions
PL242934B1 (pl
Inventor
Michał CHWALBA
Anna GAWIN
Krzysztof Skowerski
Original Assignee
Apeiron Synthesis Spółka Akcyjna
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Apeiron Synthesis Spółka Akcyjna filed Critical Apeiron Synthesis Spółka Akcyjna
Priority to PL432325A priority Critical patent/PL242934B1/pl
Priority to PCT/IB2020/062079 priority patent/WO2021130622A2/en
Priority to EP20845698.8A priority patent/EP4081343A2/en
Publication of PL432325A1 publication Critical patent/PL432325A1/pl
Publication of PL242934B1 publication Critical patent/PL242934B1/pl

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Wynalazek dotyczy kompleksu rutenu o wzorze ogólnym (1) w którym R1, R2 i L mają znaczenie takie, jak podano w opisie. Ponadto, wynalazek dotyczy sposobu prowadzenia reakcji metatezy olefin z utworzeniem wiązania wewnętrznego z zastosowaniem kompleksu rutenu o wzorze ogólnym (1) jako katalizatora.
PL432325A 2019-12-23 2019-12-23 Kompleks rutenu i zastosowanie kompleksu rutenu jako katalizatora PL242934B1 (pl)

Priority Applications (3)

Application Number Priority Date Filing Date Title
PL432325A PL242934B1 (pl) 2019-12-23 2019-12-23 Kompleks rutenu i zastosowanie kompleksu rutenu jako katalizatora
PCT/IB2020/062079 WO2021130622A2 (en) 2019-12-23 2020-12-17 Ruthenium complex and method of conducting olefin metathesis reactions with formation of an internal bond using the ruthenium complex as a catalyst
EP20845698.8A EP4081343A2 (en) 2019-12-23 2020-12-17 Ruthenium complex and method of conducting olefin metathesis reactions with formation of an internal bond using the ruthenium complex as a catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL432325A PL242934B1 (pl) 2019-12-23 2019-12-23 Kompleks rutenu i zastosowanie kompleksu rutenu jako katalizatora

Publications (2)

Publication Number Publication Date
PL432325A1 true PL432325A1 (pl) 2021-06-28
PL242934B1 PL242934B1 (pl) 2023-05-22

Family

ID=74236238

Family Applications (1)

Application Number Title Priority Date Filing Date
PL432325A PL242934B1 (pl) 2019-12-23 2019-12-23 Kompleks rutenu i zastosowanie kompleksu rutenu jako katalizatora

Country Status (3)

Country Link
EP (1) EP4081343A2 (pl)
PL (1) PL242934B1 (pl)
WO (1) WO2021130622A2 (pl)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL442226A1 (pl) * 2022-09-08 2024-03-11 Uniwersytet Warszawski Nowe kompleksy rutenu, sposób ich otrzymywania, związki pośrednie stosowane w tym sposobie, sposób ich wytwarzania oraz zastosowanie nowych kompleksów rutenu w reakcjach metatezy olefin

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL238806B1 (pl) * 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
US11203679B2 (en) * 2018-04-27 2021-12-21 Arlanxeo Deutschland Gmbh Use of ruthenium and osmium catalysts for the metathesis of nitrile rubber

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL442226A1 (pl) * 2022-09-08 2024-03-11 Uniwersytet Warszawski Nowe kompleksy rutenu, sposób ich otrzymywania, związki pośrednie stosowane w tym sposobie, sposób ich wytwarzania oraz zastosowanie nowych kompleksów rutenu w reakcjach metatezy olefin

Also Published As

Publication number Publication date
WO2021130622A3 (en) 2021-08-05
EP4081343A2 (en) 2022-11-02
WO2021130622A2 (en) 2021-07-01
PL242934B1 (pl) 2023-05-22

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