PL439899A1 - Method for producing modified lanolin and hardened wax - Google Patents

Method for producing modified lanolin and hardened wax

Info

Publication number
PL439899A1
PL439899A1 PL439899A PL43989921A PL439899A1 PL 439899 A1 PL439899 A1 PL 439899A1 PL 439899 A PL439899 A PL 439899A PL 43989921 A PL43989921 A PL 43989921A PL 439899 A1 PL439899 A1 PL 439899A1
Authority
PL
Poland
Prior art keywords
solvent
raw material
lanolin
precipitate
filtrate
Prior art date
Application number
PL439899A
Other languages
Polish (pl)
Other versions
PL244565B1 (en
Inventor
Stefan PTAK
Wojciech KRASODOMSKI
Artur Antosz
Zygmunt Burnus
Grażyna ŻAK
Wojciech Wilk
Iwona Rycaj
Original Assignee
Instytut Nafty I Gazu - Państwowy Instytut Badawczy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Instytut Nafty I Gazu - Państwowy Instytut Badawczy filed Critical Instytut Nafty I Gazu - Państwowy Instytut Badawczy
Priority to PL439899A priority Critical patent/PL244565B1/en
Publication of PL439899A1 publication Critical patent/PL439899A1/en
Publication of PL244565B1 publication Critical patent/PL244565B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B11/00Recovery or refining of other fatty substances, e.g. lanolin or waxes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B11/00Recovery or refining of other fatty substances, e.g. lanolin or waxes
    • C11B11/005Lanolin; Woolfat
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B15/00Solidifying fatty oils, fats, or waxes by physical processes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B7/00Separation of mixtures of fats or fatty oils into their constituents, e.g. saturated oils from unsaturated oils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Fats And Perfumes (AREA)
  • Lubricants (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób wytwarzania zmodyfikowanej lanoliny i wosku utwardzonego, który to sposób polega na tym, że będącą surowcem lanolinę, charakteryzującą się temperaturą krzepnięcia ok. 42°C poddaje się procesowi rozdzielania rozpuszczalnikowego na filtrat - roztwór zmodyfikowanej lanoliny i osad - wosk utwardzony zawierający pozostałości rozpuszczalnika, obejmującemu etap krystalizacji i etap filtracji, przy czym w etapie krystalizacji surowiec poddaje się pierwszemu rozcieńczeniu rozpuszczalnikiem zawierającym 10% - 90% (m/m) metyloetyloketonu i odpowiednio 90% - 10% (m/m) toluenu, uzyskując mieszaninę surowca i rozpuszczalnika, którą następnie oziębia się z kontrolowaną prędkością, z równoczesnym doprowadzeniem oziębionego rozpuszczalnika w 1-6 porcjach kolejnego rozcieńczenia przy szybkości schładzania w zakresie 0,15 - 6,0°C/min, aż do osiągnięcia temperatury od -10 do -30°C, przy czym stosunek sumarycznej ilości rozpuszczalnika z rozcieńczeń i przemywania do surowca zawiera się w przedziale od 1,8:1 do 9,0:1 (m/m), przy czym wielkość każdego jednostkowego rozcieńczenia wyrażona stosunkiem masowym rozpuszczalnika do surowca wynosi od 0,2:1 do 3,8:1 (m/m), po czym w zakresie temperatur od -10 do -30°C, odfiltrowuje się wydzielony osad, który przemywa się zimnym rozpuszczalnikiem o takim samym składzie jak rozpuszczalnik używany w etapie krystalizacji, stosowanym w ilości od 0,1:1 do 3,0:1 (m/m), wyrażonej stosunkiem masowym rozpuszczalnika do surowca, a następnie z roztworu filtratu oddestylowuje się rozpuszczalnik uzyskując produkt końcowy, którym jest zmodyfikowana lanolina o obniżonej temperaturze krzepnięcia od 35 do 36°C, oraz następnie z osadu oddestylowuje się rozpuszczalnik uzyskując wosk utwardzony o podwyższonej temperaturze krzepnięcia od 6 do 19°C w stosunku do wartości tych temperatur przed poddaniem surowca lanoliny procesowi rozdzielania rozpuszczalnikowego na filtrat i osad oraz oddestylowanie z nich rozpuszczalnika.The subject of the application is a method of producing modified lanolin and hardened wax, which method consists in lanolin being the raw material, characterized by a solidification point of about 42°C, being subjected to a solvent separation process into a filtrate - modified lanolin solution and precipitate - hardened wax containing residues a solvent, comprising a crystallization step and a filtration step, wherein in the crystallization step, the raw material is subjected to a first dilution with a solvent containing 10% - 90% (w/w) methyl ethyl ketone and 90% - 10% (w/w) toluene, respectively, to obtain a mixture of the raw material and of solvent, which is then cooled at a controlled rate, with simultaneous addition of chilled solvent in 1-6 portions of a further dilution at a cooling rate in the range of 0.15 - 6.0°C/min until a temperature of -10 to -30°C is reached C, where the ratio of the total amount of solvent from dilutions and washing to the raw material ranges from 1.8:1 to 9.0:1 (m/m), where the size of each unit dilution expressed as the mass ratio of the solvent to the raw material is from 0.2:1 to 3.8:1 (m/m), after which, at a temperature range of -10 to -30°C, the separated precipitate is filtered off, which is washed with a cold solvent of the same composition as the solvent used in step crystallization, used in the amount from 0.1:1 to 3.0:1 (m/m), expressed as the mass ratio of the solvent to the raw material, and then the solvent is distilled from the filtrate solution to obtain the final product, which is a modified lanolin with a reduced freezing point from 35 to 36°C, and then the solvent is distilled from the precipitate to obtain a hardened wax with an increased congealing point of 6 to 19°C in relation to the values of these temperatures before subjecting the lanolin raw material to the process of solvent separation into filtrate and precipitate and distilling the solvent from them.

PL439899A 2021-12-18 2021-12-18 Method of producing modified lanolin and hardened wax PL244565B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL439899A PL244565B1 (en) 2021-12-18 2021-12-18 Method of producing modified lanolin and hardened wax

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL439899A PL244565B1 (en) 2021-12-18 2021-12-18 Method of producing modified lanolin and hardened wax

Publications (2)

Publication Number Publication Date
PL439899A1 true PL439899A1 (en) 2023-06-19
PL244565B1 PL244565B1 (en) 2024-02-12

Family

ID=86944918

Family Applications (1)

Application Number Title Priority Date Filing Date
PL439899A PL244565B1 (en) 2021-12-18 2021-12-18 Method of producing modified lanolin and hardened wax

Country Status (1)

Country Link
PL (1) PL244565B1 (en)

Also Published As

Publication number Publication date
PL244565B1 (en) 2024-02-12

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