PL99572B1 - Sposob wytwarzania soli sodowej kwasu itakonowego - Google Patents
Sposob wytwarzania soli sodowej kwasu itakonowego Download PDFInfo
- Publication number
- PL99572B1 PL99572B1 PL1974170923A PL17092374A PL99572B1 PL 99572 B1 PL99572 B1 PL 99572B1 PL 1974170923 A PL1974170923 A PL 1974170923A PL 17092374 A PL17092374 A PL 17092374A PL 99572 B1 PL99572 B1 PL 99572B1
- Authority
- PL
- Poland
- Prior art keywords
- itaconic acid
- making
- sodium salt
- sodium
- reactions
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 title description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 title description 2
- NOJNFULGOQGBKB-UHFFFAOYSA-M sodium;3-[3-tert-butylsulfanyl-1-[[4-(6-ethoxypyridin-3-yl)phenyl]methyl]-5-[(5-methylpyridin-2-yl)methoxy]indol-2-yl]-2,2-dimethylpropanoate Chemical compound [Na+].C1=NC(OCC)=CC=C1C(C=C1)=CC=C1CN1C2=CC=C(OCC=3N=CC(C)=CC=3)C=C2C(SC(C)(C)C)=C1CC(C)(C)C([O-])=O NOJNFULGOQGBKB-UHFFFAOYSA-M 0.000 title 1
- 238000000034 method Methods 0.000 claims description 10
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- SYXYWTXQFUUWLP-UHFFFAOYSA-N sodium;butan-1-olate Chemical compound [Na+].CCCC[O-] SYXYWTXQFUUWLP-UHFFFAOYSA-N 0.000 claims description 3
- UMTVCEDYAZNYBU-UHFFFAOYSA-N 2-methylidenebutanedioic acid;sodium Chemical compound [Na].OC(=O)CC(=C)C(O)=O UMTVCEDYAZNYBU-UHFFFAOYSA-N 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Przedmiotem wynalazku jest sposób wytwarza¬ nia soli sodowej kwasu itakonowego.Znany jest sposób wytwarzania kwasu itakono¬ wego oraz jego pochodnych metoda fermentacyj¬ na, która jednak z przemyslowego punktu widze¬ nia jest niedogodna ze wzgledu na niska wydaj¬ nosc i znaczny koszt instalacji.Znane sa takze zastosowania pochodnych kwa¬ su itakowego, np. jako manomerów, które poli¬ meryzuje sie z innymi waznymi monomerami, ta¬ kimi jak akrylonitryl, styren, estry kwasu akry¬ lowego, a otrzymane polimery odznaczaja sie cha¬ rakterystycznymi wlasciwosciami (przyczepnosc barwnika).Sposób wedlug wynalazku zapewnia proste i ta¬ nie wytwarzanie soli sodowej kwasu itakowego z latwo dostepnych surowców. Sposób wedlug wy¬ nalazku polega na tym, ze poddaje sie reakcji trio- ksan z bursztynianem dwuetylowym. Reakcje te prowadzi sie w fazie cieklej w roztworze rozpusz¬ czalnika alkoholowego w obecnosci alkoholanu, takiego jak III rz. butanolan sodu w temperaturze i pod cisnieniem zdolnym do utrzymania fazy cie¬ klej.Nizej podany przyklad ilustruje przedmiot wy¬ nalazku.Przyklad. W autoklawie o pojemnosci 500 ml, wyposazonym w mieszadlo, umieszcza sie 63,3 ¦ g bursztynianiu dwuetylu i 10 g trioksanu, a na¬ stepnie w atmosferze azotu, dodaje sie roztwór III rz. butanolanu sodu w III. rz. butanolu, otrzy¬ many z 13 g sodu rozpuszczonego w 200 ml III. rz. butanolu. Mieszanine ogrzewa sie do temperatury 65—85°C i z roztworu na drodze hydrolizy wydzie¬ la sie sól sodowa kwasu itakowego z wydajnoscia 70%. PL
Claims (3)
1. Zastrzezenia patent oxw e 18 1. Sposób wytwarzania soli sodowej kwasu ita¬ konowego, znamienny tym, ze bursztynian dwue- tylowy poddaje sie reakcji z trioksanem w obecno¬ sci III rz. butanolanu sodu.
2. Sposób wedlug zastrz. 1, znamienny tym, ze 20 reakcje prowadzi sie w alkoholu.
3. Sposób wedlug zastrz. 1 albo 2, znamienny tym, ze reakcje prowadzi sie w temperaturze i pod cisnieniem zdolnym do utrzymania fazy cie¬ klej. M572 PL
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT23862/73A IT987221B (it) | 1973-05-09 | 1973-05-09 | Processo per la preparazione dell acido itaconico e di suoi derivati |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL99572B1 true PL99572B1 (pl) | 1978-07-31 |
Family
ID=11210488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1974170923A PL99572B1 (pl) | 1973-05-09 | 1974-05-08 | Sposob wytwarzania soli sodowej kwasu itakonowego |
Country Status (26)
| Country | Link |
|---|---|
| JP (1) | JPS5013319A (pl) |
| AR (1) | AR209749A1 (pl) |
| AT (1) | AT332368B (pl) |
| BE (1) | BE814616A (pl) |
| BG (1) | BG25205A3 (pl) |
| BR (1) | BR7403403D0 (pl) |
| CH (1) | CH603529A5 (pl) |
| CS (1) | CS184765B2 (pl) |
| DD (1) | DD111365A5 (pl) |
| DE (1) | DE2422375A1 (pl) |
| EG (1) | EG11957A (pl) |
| ES (1) | ES426245A1 (pl) |
| FR (1) | FR2228760B1 (pl) |
| GB (1) | GB1418451A (pl) |
| HU (1) | HU169262B (pl) |
| IE (1) | IE39754B1 (pl) |
| IN (1) | IN140247B (pl) |
| IT (1) | IT987221B (pl) |
| LU (1) | LU70019A1 (pl) |
| MW (1) | MW1574A1 (pl) |
| NL (1) | NL7406207A (pl) |
| PL (1) | PL99572B1 (pl) |
| RO (1) | RO63044A (pl) |
| SE (1) | SE425732B (pl) |
| ZA (1) | ZA742522B (pl) |
| ZM (1) | ZM7074A1 (pl) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4480125A (en) * | 1981-11-16 | 1984-10-30 | Polaroid Corporation | Itaconamide compounds and method of preparation |
| GB201506308D0 (en) | 2015-04-14 | 2015-05-27 | Lucite Int Uk Ltd | A process for the production of ethylenically unsaturated carboxylic acids or esters |
-
1973
- 1973-05-09 IT IT23862/73A patent/IT987221B/it active
-
1974
- 1974-04-19 ZA ZA00742522A patent/ZA742522B/xx unknown
- 1974-04-22 RO RO7400078518A patent/RO63044A/ro unknown
- 1974-04-24 EG EG138/74D patent/EG11957A/xx active
- 1974-04-25 BR BR3403/74A patent/BR7403403D0/pt unknown
- 1974-04-26 MW MW15/74*UA patent/MW1574A1/xx unknown
- 1974-04-29 FR FR7414888A patent/FR2228760B1/fr not_active Expired
- 1974-04-30 ZM ZM70/74A patent/ZM7074A1/xx unknown
- 1974-05-01 GB GB1919574A patent/GB1418451A/en not_active Expired
- 1974-05-02 IE IE939/74A patent/IE39754B1/xx unknown
- 1974-05-06 BE BE143982A patent/BE814616A/xx unknown
- 1974-05-07 AR AR253632A patent/AR209749A1/es active
- 1974-05-07 ES ES426245A patent/ES426245A1/es not_active Expired
- 1974-05-08 CS CS7400003334A patent/CS184765B2/cs unknown
- 1974-05-08 PL PL1974170923A patent/PL99572B1/pl unknown
- 1974-05-08 CH CH627574A patent/CH603529A5/xx not_active IP Right Cessation
- 1974-05-08 AT AT379674A patent/AT332368B/de not_active IP Right Cessation
- 1974-05-08 HU HUSA2640A patent/HU169262B/hu unknown
- 1974-05-08 NL NL7406207A patent/NL7406207A/xx not_active Application Discontinuation
- 1974-05-08 LU LU70019A patent/LU70019A1/xx unknown
- 1974-05-08 DD DD178371A patent/DD111365A5/xx unknown
- 1974-05-09 SE SE7406232A patent/SE425732B/xx unknown
- 1974-05-09 BG BG026640A patent/BG25205A3/xx unknown
- 1974-05-09 DE DE2422375A patent/DE2422375A1/de active Pending
- 1974-05-09 JP JP49050798A patent/JPS5013319A/ja active Pending
- 1974-05-09 IN IN1034/CAL/74A patent/IN140247B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL7406207A (pl) | 1974-11-12 |
| BE814616A (fr) | 1974-09-02 |
| BG25205A3 (en) | 1978-08-10 |
| EG11957A (en) | 1978-06-30 |
| SE425732B (sv) | 1982-11-01 |
| ATA379674A (de) | 1976-01-15 |
| ES426245A1 (es) | 1976-07-01 |
| MW1574A1 (en) | 1975-05-13 |
| FR2228760B1 (pl) | 1978-03-31 |
| ZM7074A1 (en) | 1974-12-20 |
| AU6814174A (en) | 1975-10-23 |
| IE39754B1 (en) | 1978-12-20 |
| DE2422375A1 (de) | 1974-11-28 |
| CS184765B2 (en) | 1978-09-15 |
| IE39754L (en) | 1974-11-09 |
| RO63044A (fr) | 1978-05-15 |
| DD111365A5 (pl) | 1975-02-12 |
| CH603529A5 (pl) | 1978-08-15 |
| FR2228760A1 (pl) | 1974-12-06 |
| BR7403403D0 (pt) | 1974-12-03 |
| AT332368B (de) | 1976-09-27 |
| AR209749A1 (es) | 1977-05-31 |
| GB1418451A (en) | 1975-12-17 |
| LU70019A1 (pl) | 1974-10-01 |
| IN140247B (pl) | 1976-10-02 |
| HU169262B (pl) | 1976-10-28 |
| IT987221B (it) | 1975-02-20 |
| ZA742522B (en) | 1975-06-25 |
| JPS5013319A (pl) | 1975-02-12 |
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