PT97870A - Processo para a preparacao de 1-aril-pirrois e de composicoes pesticidas que os contem - Google Patents
Processo para a preparacao de 1-aril-pirrois e de composicoes pesticidas que os contemInfo
- Publication number
- PT97870A PT97870A PT97870A PT9787091A PT97870A PT 97870 A PT97870 A PT 97870A PT 97870 A PT97870 A PT 97870A PT 9787091 A PT9787091 A PT 9787091A PT 97870 A PT97870 A PT 97870A
- Authority
- PT
- Portugal
- Prior art keywords
- compounds
- preparation
- compositions containing
- pyrrois
- aryl
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 2
- 239000000575 pesticide Substances 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 4
- 241000239223 Arachnida Species 0.000 abstract 1
- JNCMHMUGTWEVOZ-UHFFFAOYSA-N F[CH]F Chemical compound F[CH]F JNCMHMUGTWEVOZ-UHFFFAOYSA-N 0.000 abstract 1
- 108010081348 HRT1 protein Hairy Proteins 0.000 abstract 1
- 102100021881 Hairy/enhancer-of-split related with YRPW motif protein 1 Human genes 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 abstract 1
- 241000244206 Nematoda Species 0.000 abstract 1
- 101100054666 Streptomyces halstedii sch3 gene Proteins 0.000 abstract 1
- 125000004773 chlorofluoromethyl group Chemical group [H]C(F)(Cl)* 0.000 abstract 1
- ZJULYDCRWUEPTK-UHFFFAOYSA-N dichloromethyl Chemical compound Cl[CH]Cl ZJULYDCRWUEPTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- ZBZJXHCVGLJWFG-UHFFFAOYSA-N trichloromethyl(.) Chemical compound Cl[C](Cl)Cl ZBZJXHCVGLJWFG-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/14—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D295/145—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals with the ring nitrogen atoms and the carbon atoms with three bonds to hetero atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/30—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same unsaturated acyclic carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/36—Oxygen or sulfur atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pyrrole Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/533,470 US5187185A (en) | 1988-12-09 | 1990-06-05 | Pesticidal 1-arylpyrroles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PT97870A true PT97870A (pt) | 1992-04-30 |
| PT97870B PT97870B (pt) | 1998-10-30 |
Family
ID=24126083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PT97870A PT97870B (pt) | 1990-06-05 | 1991-06-05 | Processo para a preparacao de 1-aril-pirrois e de composicoes pesticidas que os contem |
Country Status (33)
| Country | Link |
|---|---|
| US (2) | US5187185A (pt) |
| EP (1) | EP0460940B1 (pt) |
| JP (1) | JPH04244060A (pt) |
| KR (1) | KR100189790B1 (pt) |
| CN (1) | CN1039079C (pt) |
| AT (1) | ATE176224T1 (pt) |
| AU (2) | AU653722B2 (pt) |
| BG (1) | BG60083B2 (pt) |
| BR (1) | BR9102331A (pt) |
| CA (1) | CA2043955C (pt) |
| CZ (1) | CZ282471B6 (pt) |
| DE (1) | DE69130813T2 (pt) |
| DK (1) | DK0460940T3 (pt) |
| ES (1) | ES2126566T3 (pt) |
| FI (1) | FI912688A7 (pt) |
| GR (1) | GR3029804T3 (pt) |
| HU (1) | HUT58183A (pt) |
| IE (1) | IE911896A1 (pt) |
| IL (1) | IL98357A (pt) |
| MA (1) | MA22167A1 (pt) |
| MY (1) | MY110420A (pt) |
| NO (1) | NO912132L (pt) |
| NZ (2) | NZ238386A (pt) |
| OA (1) | OA09360A (pt) |
| PL (1) | PL167087B1 (pt) |
| PT (1) | PT97870B (pt) |
| RO (1) | RO111077B1 (pt) |
| RU (1) | RU2092479C1 (pt) |
| SK (1) | SK278954B6 (pt) |
| TR (1) | TR25427A (pt) |
| UA (1) | UA41248C2 (pt) |
| ZA (1) | ZA914284B (pt) |
| ZW (1) | ZW6691A1 (pt) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2716453B1 (fr) * | 1994-02-22 | 1996-03-29 | Rhone Poulenc Agrochimie | Procédé de sulfinylation de composés hétérocycliques. |
| US5286742A (en) * | 1992-11-03 | 1994-02-15 | American Cyanamid Company | Pyrrole thiocarboxamide insecticidal and acaricidal agents |
| US5453277A (en) * | 1993-01-05 | 1995-09-26 | Mccoy; Paul E. | Method of controlling soil pests |
| FR2712144B1 (fr) * | 1993-11-04 | 1997-07-18 | Rhone Poulenc Agrochimie | Association d'un fongicide à groupe azole avec un insecticide à groupe pyrazole, pyrrole ou phénylimidazole. |
| DE4404702A1 (de) * | 1994-02-15 | 1995-08-31 | Hoechst Schering Agrevo Gmbh | Wasserdispergierbare Granulate auf der Basis lebender Organismen |
| US5662897A (en) * | 1994-07-27 | 1997-09-02 | U. Of Ga Research Foundation | Insect viruses, sequences, insecticidal compositions and methods of use |
| US6271392B1 (en) * | 1994-10-07 | 2001-08-07 | Rhone-Poulenc Inc. | Intermediates useful for the synthesis of 1-arylpyrrole pesticides |
| FR2729825A1 (fr) * | 1995-01-30 | 1996-08-02 | Rhone Poulenc Agrochimie | Associations insecticides comprenant un insecticide de la famille des chloronicotinyls et un insecticide a groupe pyrazole,pyrrole ou phenylimidazole pour traiter les semences ou le sol |
| US5696144A (en) * | 1995-05-01 | 1997-12-09 | Rhone-Poulenc Inc. | Protection of corn |
| US6060502A (en) * | 1995-06-05 | 2000-05-09 | Rhone-Poulenc Agrochimie | Pesticidal sulfur compounds |
| US6136983A (en) * | 1995-06-05 | 2000-10-24 | Rhone-Poulenc Agrochimie | Pesticidal sulfur compounds |
| US6060495A (en) * | 1995-06-05 | 2000-05-09 | Rhone-Poulenc Agrochimie | Pesticidal sulfur compounds |
| FR2737085B1 (fr) * | 1995-07-26 | 1997-08-22 | Rhone Poulenc Agrochimie | Associations insecticides d'un oxime carbamate avec un insecticide a groupe pyrazole ou phenylimidazole |
| ES2179254T3 (es) * | 1996-11-04 | 2003-01-16 | Bayer Cropscience Sa | 1-poliarilpirazoles plaguicidas. |
| US5935990A (en) * | 1996-12-10 | 1999-08-10 | G.D. Searle & Co. | Substituted pyrrolyl compounds for the treatment of inflammation |
| ZA981934B (en) * | 1997-03-10 | 1999-09-06 | Rhone Poulenc Agrochimie | Pesticidal 1-aryl-3-iminopyrazoles. |
| ZA981776B (en) * | 1997-03-10 | 1998-09-03 | Rhone Poulenc Agrochimie | Pesticidal 1-arylpyrazoles |
| GB9810354D0 (en) | 1998-05-14 | 1998-07-15 | Pfizer Ltd | Heterocycles |
| FR2805971B1 (fr) | 2000-03-08 | 2004-01-30 | Aventis Cropscience Sa | Procedes de traitement et/ou de protection des cultures contre les arthropodes et compositions utiles pour de tels procedes |
| EP1765774B1 (en) * | 2004-06-26 | 2012-10-24 | Merial Limited | Pesticidal agents on the basis of 1-aryl-aminopyrrol |
| MX2007000159A (es) * | 2004-06-26 | 2007-10-10 | Bayer Cropscience Sa | Derivados de n-fenilpirazol pesticidas. |
| WO2007069254A2 (en) | 2005-12-14 | 2007-06-21 | Makhteshim Chemical Works Ltd. | POLYMORPHS AND AMORPHOUS FORMS OF 5-AMINO-l-[2,6- DICHLORO-4-(TRIFLUOROMETHYL)PHENYL]-4- [(TRIFLUOROMETHYL)SULFINYL]-IH-PYRAZOLE-3-CARBONITRILE |
| JP5931322B2 (ja) | 2006-11-10 | 2016-06-08 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | フィプロニルの結晶変態 |
| US8791046B2 (en) | 2006-11-10 | 2014-07-29 | Basf Se | Crystalline modification of fipronil |
| BRPI0718717A2 (pt) | 2006-11-10 | 2013-11-26 | Basf Se | Modificação cristalina ii de fipronil, fipronil sólido, processo para preparar a modificação cristalina ii, mistura pesticida ou parasiticida sinergística, composição pesticida ou parasiticida, uso da modificação cristalina ii, ou do fipronil sólido, ou da mistura, ou da composição, métodos para controlar pragas, para proteger uma planta da infestação e ataque por pragas, para proteger semente, e para tratar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas, semente, uso da modificação cristalina ii, ou do fipronil sólido, ou da mistura, ou da composição, e, processo para a preparação de uma composição para trtar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas |
| UA110598C2 (uk) | 2006-11-10 | 2016-01-25 | Басф Се | Спосіб одержання кристалічної модифікації фіпронілу |
| RU2340181C1 (ru) * | 2007-03-06 | 2008-12-10 | Александр Анатольевич Хахалин | Инсектоакарицидное средство "инсектал-плюс" |
| MX2009010491A (es) * | 2007-04-11 | 2009-11-09 | Kissei Pharmaceutical | Derivado heterociclico de 5 miembros y su uso para propositos medicos. |
| JP5611535B2 (ja) * | 2008-04-17 | 2014-10-22 | 石原産業株式会社 | 有害生物防除剤組成物及び有害生物の防除方法 |
| JP2012082186A (ja) | 2010-09-15 | 2012-04-26 | Bayer Cropscience Ag | 殺虫性アリールピロリジン類 |
| AU2012100035A4 (en) | 2011-01-14 | 2012-02-09 | Keki Hormusji Gharda | Polymorphism in 5-amino-1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoro methyl sulfinyl pyrazole |
| US9212150B2 (en) | 2013-03-13 | 2015-12-15 | Dow Agrosciences Llc | Process for the preparation of certain triaryl pesticide intermediates |
| US9108932B2 (en) | 2013-03-13 | 2015-08-18 | Dow Agrosciences Llc | Preparation of haloalkoxyarylhydrazines and intermediates therefrom |
| CA2925953C (en) | 2013-10-17 | 2021-11-02 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| WO2017189348A1 (en) | 2016-04-25 | 2017-11-02 | Bayer Cropscience Lp | Formulation and method for controlling varroa mites |
| CN110325036B (zh) | 2016-12-29 | 2021-10-26 | 美国陶氏益农公司 | 用于制备杀虫化合物的方法 |
| CN107573513B (zh) * | 2017-08-28 | 2020-09-08 | 济南大学 | 一种银铜异金属簇合物及其制备方法和应用 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2779766A (en) * | 1955-04-20 | 1957-01-29 | Du Pont | Pyrroles having amino, cyano, and mercapto or substituted mercapto groups and their preparation |
| US2940977A (en) * | 1958-01-23 | 1960-06-14 | Du Pont | 5-amino-3-cyano-2-pyrrolesulfonic acid derivatives and salts thereof |
| SE337960B (pt) * | 1965-12-20 | 1971-08-23 | Bofors Ab | |
| BE757934A (fr) * | 1969-10-23 | 1971-04-23 | Bayer Ag | Nouvelles 2-phenylamino-delta 1-pyrrolines et leur application comme acaricides |
| US3950530A (en) * | 1972-05-04 | 1976-04-13 | Shell Oil Company | Pyrrolidine insect control agents |
| US3836541A (en) * | 1972-09-27 | 1974-09-17 | Upjohn Co | 3-cyano-2-pyrryl oxamic acids |
| TR18917A (tr) * | 1974-10-31 | 1977-12-09 | Ciba Geigy Ag | 1-(bis-triflormetilfenil)-2-oksopirolidin-4-karbonik asitleri ve bunlarin tuerevleri |
| JPS543866A (en) * | 1977-06-10 | 1979-01-12 | Shin Etsu Chem Co Ltd | Silicone-emulsion composition |
| US4339457A (en) * | 1980-10-20 | 1982-07-13 | Fmc Corporation | 3-(Pyrrol-1-yl)phenylmethyl esters and intermediates |
| FR2536748A1 (fr) * | 1982-11-25 | 1984-06-01 | Roussel Uclaf | Nouveaux esters derives d'acides 2,2-dimethyl cyclopropane carboxyliques et d'alcools biaryliques, leur procede de preparation et leur application a la lutte contre les parasites |
| DE3309355A1 (de) * | 1983-03-16 | 1984-09-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von pyrrolen |
| DE3545036A1 (de) * | 1985-12-19 | 1987-09-10 | Bayer Ag | 5-heterocyclyl-1-aryl-pyrazole |
| GB8713768D0 (en) * | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
| GB8531485D0 (en) * | 1985-12-20 | 1986-02-05 | May & Baker Ltd | Compositions of matter |
| ES2053579T3 (es) * | 1986-03-18 | 1994-08-01 | Sandoz Ag | Nuevas fenilureas. |
| GB2189242B (en) * | 1986-04-17 | 1990-07-25 | Ici Plc | Acrylic acid derivatives useful as fungicides |
| DE3718375A1 (de) * | 1987-06-02 | 1988-12-15 | Bayer Ag | Verfahren zur herstellung von 3-cyano-4-aryl-pyrrolen |
| DE3719873A1 (de) * | 1987-06-13 | 1988-12-29 | Basf Ag | Verfahren zur herstellung von itaconsaeurediestern und itaconsaeure |
| DE3724554A1 (de) * | 1987-07-24 | 1989-02-02 | Bayer Ag | Substituierte 3-arylpyrrole |
| US5010098A (en) * | 1987-07-29 | 1991-04-23 | American Cyanamid Company | Arylpyrrole insecticidal acaricidal and nematicidal agents and methods for the preparation thereof |
| US4929634A (en) * | 1987-10-23 | 1990-05-29 | American Cyanamid Company | Method of and bait compositions for controlling mollusks |
| GB8816915D0 (en) * | 1988-07-15 | 1988-08-17 | May & Baker Ltd | New compositions of matter |
| AU641905B2 (en) * | 1988-12-09 | 1993-10-07 | Rhone-Poulenc Agrochimie | 1-substituted-phenyl pyrrole derivatives as insecticides and methods for their production |
| US5019130A (en) * | 1989-11-03 | 1991-05-28 | Clairol Incorporated | Substituted N-aryl pyrroles in oxidative hair dye compositions |
-
1990
- 1990-06-05 US US07/533,470 patent/US5187185A/en not_active Expired - Lifetime
-
1991
- 1991-06-03 MA MA22439A patent/MA22167A1/fr unknown
- 1991-06-03 IL IL98357A patent/IL98357A/en not_active IP Right Cessation
- 1991-06-04 UA UA4895762A patent/UA41248C2/uk unknown
- 1991-06-04 MY MYPI91000986A patent/MY110420A/en unknown
- 1991-06-04 ZW ZW66/91A patent/ZW6691A1/xx unknown
- 1991-06-04 NZ NZ238386A patent/NZ238386A/en not_active IP Right Cessation
- 1991-06-04 RU SU914895762A patent/RU2092479C1/ru active
- 1991-06-04 NO NO91912132A patent/NO912132L/no unknown
- 1991-06-04 AU AU78179/91A patent/AU653722B2/en not_active Expired
- 1991-06-04 FI FI912688A patent/FI912688A7/fi not_active Application Discontinuation
- 1991-06-04 IE IE189691A patent/IE911896A1/en not_active Application Discontinuation
- 1991-06-04 HU HU911872A patent/HUT58183A/hu unknown
- 1991-06-04 BG BG094570A patent/BG60083B2/bg unknown
- 1991-06-05 SK SK1714-91A patent/SK278954B6/sk not_active IP Right Cessation
- 1991-06-05 DK DK91305084T patent/DK0460940T3/da active
- 1991-06-05 DE DE69130813T patent/DE69130813T2/de not_active Expired - Lifetime
- 1991-06-05 TR TR91/0600A patent/TR25427A/xx unknown
- 1991-06-05 CZ CS911714A patent/CZ282471B6/cs not_active IP Right Cessation
- 1991-06-05 KR KR1019910009350A patent/KR100189790B1/ko not_active Expired - Lifetime
- 1991-06-05 BR BR919102331A patent/BR9102331A/pt not_active IP Right Cessation
- 1991-06-05 ZA ZA914284A patent/ZA914284B/xx unknown
- 1991-06-05 RO RO147713A patent/RO111077B1/ro unknown
- 1991-06-05 PT PT97870A patent/PT97870B/pt not_active IP Right Cessation
- 1991-06-05 AT AT91305084T patent/ATE176224T1/de not_active IP Right Cessation
- 1991-06-05 OA OA60013A patent/OA09360A/xx unknown
- 1991-06-05 JP JP3230719A patent/JPH04244060A/ja active Pending
- 1991-06-05 CN CN91103902A patent/CN1039079C/zh not_active Expired - Lifetime
- 1991-06-05 EP EP91305084A patent/EP0460940B1/en not_active Expired - Lifetime
- 1991-06-05 PL PL91290546A patent/PL167087B1/pl unknown
- 1991-06-05 ES ES91305084T patent/ES2126566T3/es not_active Expired - Lifetime
- 1991-06-05 CA CA002043955A patent/CA2043955C/en not_active Expired - Lifetime
-
1993
- 1993-02-10 US US08/016,102 patent/US5506260A/en not_active Expired - Lifetime
- 1993-11-22 NZ NZ250245A patent/NZ250245A/en not_active IP Right Cessation
-
1994
- 1994-08-10 AU AU70205/94A patent/AU676343B2/en not_active Expired
-
1999
- 1999-03-26 GR GR990400893T patent/GR3029804T3/el unknown
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