RU2128672C1 - Способ получения блочного сополимера - Google Patents

Способ получения блочного сополимера Download PDF

Info

Publication number: RU2128672C1
Authority: RU; Russia
Prior art keywords: crosslinking agent; block copolymer; polymer; copolymer; multifunctional
Prior art date: 1988-04-27

Application number

SU4742905A

Other languages

English (en)

Russian (ru)

Inventor

Ланса Эммануэль

Наво Жан

Домери Мишель

Original Assignee

Лябофина С.А.

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-04-27

Filing date

1989-04-27

Publication date

1999-04-10

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=3883380&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=RU2128672(C1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1989-04-27 Application filed by Лябофина С.А. filed Critical Лябофина С.А.

1999-04-10 Application granted granted Critical

1999-04-10 Publication of RU2128672C1 publication Critical patent/RU2128672C1/ru

Links

229920001400 block copolymer Polymers 0.000 title claims abstract description 26
238000000034 method Methods 0.000 title claims abstract description 23
239000003431 cross linking reagent Substances 0.000 claims abstract description 54
239000000203 mixture Substances 0.000 claims abstract description 23
239000003795 chemical substances by application Substances 0.000 claims abstract description 9
238000004519 manufacturing process Methods 0.000 claims abstract description 8
229920005684 linear copolymer Polymers 0.000 claims abstract 3
229920006132 styrene block copolymer Polymers 0.000 claims abstract 2
229920001577 copolymer Polymers 0.000 claims description 17
125000000217 alkyl group Chemical group 0.000 claims description 3
150000005840 aryl radicals Chemical group 0.000 claims description 3
125000000753 cycloalkyl group Chemical group 0.000 claims description 3
229910052736 halogen Inorganic materials 0.000 claims description 3
125000005843 halogen group Chemical group 0.000 claims description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 2
229910000077 silane Inorganic materials 0.000 claims 2
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 1
229910052801 chlorine Inorganic materials 0.000 claims 1
239000000460 chlorine Substances 0.000 claims 1
125000001309 chloro group Chemical group Cl* 0.000 claims 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
229920000642 polymer Polymers 0.000 abstract description 49
231100000419 toxicity Toxicity 0.000 abstract description 6
230000001988 toxicity Effects 0.000 abstract description 6
239000000126 substance Substances 0.000 abstract description 4
230000009849 deactivation Effects 0.000 abstract 4
230000001588 bifunctional effect Effects 0.000 abstract 2
230000000694 effects Effects 0.000 abstract 1
230000003993 interaction Effects 0.000 abstract 1
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 18
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 16
238000004132 cross linking Methods 0.000 description 9
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
229910003902 SiCl 4 Inorganic materials 0.000 description 7
LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 7
229910052744 lithium Inorganic materials 0.000 description 7
239000000178 monomer Substances 0.000 description 7
239000002904 solvent Substances 0.000 description 7
VIZORQUEIQEFRT-UHFFFAOYSA-N Diethyl adipate Chemical compound CCOC(=O)CCCCC(=O)OCC VIZORQUEIQEFRT-UHFFFAOYSA-N 0.000 description 6
-1 alkyl lithium Chemical compound 0.000 description 6
150000001993 dienes Chemical class 0.000 description 6
229920002554 vinyl polymer Polymers 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
238000005299 abrasion Methods 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
231100000331 toxic Toxicity 0.000 description 5
230000002588 toxic effect Effects 0.000 description 5
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 4
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
239000003054 catalyst Substances 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
239000012467 final product Substances 0.000 description 4
NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
229920005601 base polymer Polymers 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
150000002641 lithium Chemical group 0.000 description 3
238000002156 mixing Methods 0.000 description 3
PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 2
OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
239000010426 asphalt Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 description 2
FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
239000005038 ethylene vinyl acetate Substances 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
239000005055 methyl trichlorosilane Substances 0.000 description 2
JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
229920006216 polyvinyl aromatic Polymers 0.000 description 2
238000002128 reflection high energy electron diffraction Methods 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
QLJIOZSPRQUVIL-UHFFFAOYSA-N 2-ethenylnaphthalen-1-ol Chemical compound C1=CC=C2C(O)=C(C=C)C=CC2=C1 QLJIOZSPRQUVIL-UHFFFAOYSA-N 0.000 description 1
RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 1
QRLSTWVLSWCGBT-UHFFFAOYSA-N 4-((4,6-bis(octylthio)-1,3,5-triazin-2-yl)amino)-2,6-di-tert-butylphenol Chemical compound CCCCCCCCSC1=NC(SCCCCCCCC)=NC(NC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=N1 QRLSTWVLSWCGBT-UHFFFAOYSA-N 0.000 description 1
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
239000004971 Cross linker Substances 0.000 description 1
UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
244000068988 Glycine max Species 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
229920001744 Polyaldehyde Polymers 0.000 description 1
229920002732 Polyanhydride Polymers 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
229910010413 TiO 2 Inorganic materials 0.000 description 1
FYAMXEPQQLNQDM-UHFFFAOYSA-N Tris(1-aziridinyl)phosphine oxide Chemical compound C1CN1P(N1CC1)(=O)N1CC1 FYAMXEPQQLNQDM-UHFFFAOYSA-N 0.000 description 1
GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 1
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
150000004292 cyclic ethers Chemical class 0.000 description 1
FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical compound BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 description 1
IESPKCNRKMAVIB-UHFFFAOYSA-N dichloro(dicyclohexyl)silane Chemical compound C1CCCCC1[Si](Cl)(Cl)C1CCCCC1 IESPKCNRKMAVIB-UHFFFAOYSA-N 0.000 description 1
125000005594 diketone group Chemical group 0.000 description 1
FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
229960001826 dimethylphthalate Drugs 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
235000013305 food Nutrition 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229940095102 methyl benzoate Drugs 0.000 description 1
235000019808 microcrystalline wax Nutrition 0.000 description 1
239000004200 microcrystalline wax Substances 0.000 description 1
HGZAZPZCKWFXNI-UHFFFAOYSA-N naphthalene-1,4,6-tricarbaldehyde Chemical compound O=CC1=CC=C(C=O)C2=CC(C=O)=CC=C21 HGZAZPZCKWFXNI-UHFFFAOYSA-N 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
150000002900 organolithium compounds Chemical class 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920001228 polyisocyanate Polymers 0.000 description 1
239000005056 polyisocyanate Substances 0.000 description 1
229920001470 polyketone Polymers 0.000 description 1
239000000047 product Substances 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
ZOYFEXPFPVDYIS-UHFFFAOYSA-N trichloro(ethyl)silane Chemical compound CC[Si](Cl)(Cl)Cl ZOYFEXPFPVDYIS-UHFFFAOYSA-N 0.000 description 1
ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
239000005052 trichlorosilane Substances 0.000 description 1
BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Images

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
- C08G81/022—Block or graft polymers containing only sequences of polymers of C08C or C08F containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polyesters Or Polycarbonates (AREA)

SU4742905A 1988-04-27 1989-04-27 Способ получения блочного сополимера RU2128672C1 (ru)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
BE8800478		1988-04-27
BE8800478A BE1001592A3 (fr)	1988-04-27	1988-04-27	Procede de preparation de copolymeres sequences.
PCT/BE1989/000019 WO1989010378A1 (en)	1988-04-27	1989-04-27	Process for the preparation of block copolymers

Publications (1)

Publication Number	Publication Date
RU2128672C1 true RU2128672C1 (ru)	1999-04-10

Family

ID=3883380

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU4742905A RU2128672C1 (ru)	1988-04-27	1989-04-27	Способ получения блочного сополимера

Country Status (9)

Country	Link
EP (1)	EP0344140B1 (de)
JP (1)	JP2865141B2 (de)
AT (1)	ATE93242T1 (de)
BE (1)	BE1001592A3 (de)
CA (1)	CA1331494C (de)
DE (1)	DE68908475T2 (de)
ES (1)	ES2043109T3 (de)
RU (1)	RU2128672C1 (de)
WO (1)	WO1989010378A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2501731C2 (ru) *	2007-06-29	2013-12-20	Бриджстоун Корпорейшн	Однореакторный синтез наночастиц и жидкого полимера для областей применения каучуков
RU2559893C2 (ru) *	2010-05-19	2015-08-20	Эйвери Деннисон Корпорейшн	Упорядочные структуры в акриловых полимерах

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5270396A (en) *	1990-07-06	1993-12-14	Phillips Petroleum Company	Sequential coupling in formation of resinous block copolymers
CA2039379C (en) *	1990-07-06	1997-12-30	Ralph C. Farrar, Jr.	Sequential coupling in formation of resinous block copolymers
US5130354A (en) *	1991-05-13	1992-07-14	Shell Oil Company	Asphalt-diene polymer composition with improved adhesion to polar materials
US5266648A (en) *	1991-09-27	1993-11-30	Shell Oil Company	One phase melt radial polymer
US5446093A (en) *	1993-11-10	1995-08-29	Shell Oil Company	Method for producing statistically coupled asymmetric radial polymers
TW283152B (de) *	1993-11-18	1996-08-11	Shell Internat Res Schappej Bv
EP1116742A1 (de) *	2000-01-12	2001-07-18	Fina Research S.A.	S-B-S Zusammensetzungen
FR2858226B1 (fr) *	2003-07-29	2010-04-23	Oreal	Procede de traitement a partir d'une feuille dont une face comporte une couche d'un produit capable de transferer au moins partiellement sur la surface a traiter

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3661873A (en) *	1971-01-06	1972-05-09	Firestone Tire & Rubber Co	Process and product of treating live polymers with divinyl benzene and a haloalkane
US4304886A (en) *	1981-01-22	1981-12-08	Shell Oil Company	Mixed coupling agent process

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU515569B2 (en) *	1977-11-11	1981-04-09	Phillips Petroleum Company	Coupled diene polymers
JPS61171714A (ja) *	1984-07-23	1986-08-02	Japan Synthetic Rubber Co Ltd	粘着剤組成物

1988
- 1988-04-27 BE BE8800478A patent/BE1001592A3/fr not_active IP Right Cessation
1989
- 1989-04-26 CA CA000597795A patent/CA1331494C/fr not_active Expired - Lifetime
- 1989-04-27 EP EP89870061A patent/EP0344140B1/de not_active Expired - Lifetime
- 1989-04-27 RU SU4742905A patent/RU2128672C1/ru active
- 1989-04-27 DE DE89870061T patent/DE68908475T2/de not_active Expired - Lifetime
- 1989-04-27 WO PCT/BE1989/000019 patent/WO1989010378A1/en not_active Ceased
- 1989-04-27 ES ES89870061T patent/ES2043109T3/es not_active Expired - Lifetime
- 1989-04-27 AT AT89870061T patent/ATE93242T1/de not_active IP Right Cessation
- 1989-04-27 JP JP1504420A patent/JP2865141B2/ja not_active Ceased

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3661873A (en) *	1971-01-06	1972-05-09	Firestone Tire & Rubber Co	Process and product of treating live polymers with divinyl benzene and a haloalkane
US4304886A (en) *	1981-01-22	1981-12-08	Shell Oil Company	Mixed coupling agent process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2501731C2 (ru) *	2007-06-29	2013-12-20	Бриджстоун Корпорейшн	Однореакторный синтез наночастиц и жидкого полимера для областей применения каучуков
RU2559893C2 (ru) *	2010-05-19	2015-08-20	Эйвери Деннисон Корпорейшн	Упорядочные структуры в акриловых полимерах

Also Published As

Publication number	Publication date
ATE93242T1 (de)	1993-09-15
JPH02504159A (ja)	1990-11-29
EP0344140B1 (de)	1993-08-18
BE1001592A3 (fr)	1989-12-12
JP2865141B2 (ja)	1999-03-08
ES2043109T3 (es)	1993-12-16
EP0344140A1 (de)	1989-11-29
DE68908475D1 (de)	1993-09-23
CA1331494C (fr)	1994-08-16
DE68908475T2 (de)	1994-01-13
WO1989010378A1 (en)	1989-11-02

Publication	Publication Date	Title
US5300582A (en)	1994-04-05	Coupled elastomeric block copolymers
CA1120636A (en)	1982-03-23	Coupled block copolymers with improved tack for adhesives
US5576395A (en)	1996-11-19	Low viscosity adhesive compositions containing asymmetric radial polymers
EP1470190A2 (de)	2004-10-27	Blockcopolymerzusammensetzungen mit verbesserten mechanisch- und prozess-eigenschaften
US7268184B2 (en)	2007-09-11	Blockcopolymer compositions, having improved mechanical properties and processability and styrenic blockcopolymer to be used in them
JP2865141B2 (ja)	1999-03-08	ブロックコポリマー混合物の製造方法
US5635561A (en)	1997-06-03	Star block copolymer of vinylaromatic monomer and of conjugated diene process for preparing it, and its compositions with crystal polystyrene
EP1569999A1 (de)	2005-09-07	Zusammensetzungen von styrenblockcopolymeren für die herstellung transparenter gelfreier folien
US5585443A (en)	1996-12-17	Block copolymer
US5264489A (en)	1993-11-23	Process for the preparation of block copolymers
JP2989690B2 (ja)	1999-12-13	分枝鎖状ブロックコポリマー，その製法及び用途
RU2138517C1 (ru)	1999-09-27	Способ получения привитых блоксополимеров
JPH0912898A (ja)	1997-01-14	アスファルト組成物
EP1263841B1 (de)	2005-12-21	S-b-s zusammensetzungen
US6576686B1 (en)	2003-06-10	Road marking compound comprising linear tetrablock copolymers
JP3125799B2 (ja)	2001-01-22	熱安定化ブロック共重合体組成物
EP1195407B1 (de)	2007-04-04	Blockpolymerzusammensetzung
JPH09291266A (ja)	1997-11-11	ブロック共重合体を基剤とする不織布用接着剤組成物
JPH1160661A (ja)	1999-03-02	新規なブロック共重合体の製造方法
JP2003003040A (ja)	2003-01-08	ブロック共重合体組成物

RU2128672C1 - Способ получения блочного сополимера - Google Patents

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