RU2194708C2 - Металлоцен, лиганд, каталитическая система, способ полимеризации - Google Patents

Металлоцен, лиганд, каталитическая система, способ полимеризации Download PDF

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Publication number: RU2194708C2
Authority: RU; Russia
Prior art keywords: zirconium dichloride; group; metallocenes; metallocene; radical
Prior art date: 1996-11-15

Application number

RU99112514/04A

Other languages

English (en)

Russian (ru)

Other versions

RU99112514A (ru

Inventor

Джон А. ИВЕН

Майкл Дж. ЭЛДЕР

Роберт Л. Мл. ДЖОУНС

Юрий А. Дубицкий

Original Assignee

Монтелл Текнолоджи Компани Б.В.

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-11-15

Filing date

1997-11-12

Publication date

2002-12-20

1997-11-12 Application filed by Монтелл Текнолоджи Компани Б.В. filed Critical Монтелл Текнолоджи Компани Б.В.

2001-04-27 Publication of RU99112514A publication Critical patent/RU99112514A/ru

2002-12-20 Application granted granted Critical

2002-12-20 Publication of RU2194708C2 publication Critical patent/RU2194708C2/ru

Links

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238000006297 dehydration reaction Methods 0.000 description 1
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical class [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 1
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000002330 electrospray ionisation mass spectrometry Methods 0.000 description 1
HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 1
BVSRWCMAJISCTD-UHFFFAOYSA-N ethyl 2-diethoxyphosphorylpropanoate Chemical compound CCOC(=O)C(C)P(=O)(OCC)OCC BVSRWCMAJISCTD-UHFFFAOYSA-N 0.000 description 1
ZGVWIHLXOVJBQE-UHFFFAOYSA-N ethyl 2-methyl-3-(5-methyl-1-phenylpyrrol-2-yl)propanoate Chemical compound CCOC(=O)C(C)CC1=CC=C(C)N1C1=CC=CC=C1 ZGVWIHLXOVJBQE-UHFFFAOYSA-N 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
FWQHNLCNFPYBCA-UHFFFAOYSA-N fluoran Chemical group C12=CC=CC=C2OC2=CC=CC=C2C11OC(=O)C2=CC=CC=C21 FWQHNLCNFPYBCA-UHFFFAOYSA-N 0.000 description 1
XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
CNUDBTRUORMMPA-UHFFFAOYSA-N formylthiophene Chemical compound O=CC1=CC=CS1 CNUDBTRUORMMPA-UHFFFAOYSA-N 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
238000007429 general method Methods 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
239000008187 granular material Substances 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229920006158 high molecular weight polymer Polymers 0.000 description 1
239000002815 homogeneous catalyst Substances 0.000 description 1
IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
239000012535 impurity Substances 0.000 description 1
125000003392 indanyl group Chemical group C1(CCC2=CC=CC=C12)* 0.000 description 1
150000002469 indenes Chemical class 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
230000036512 infertility Effects 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
239000011630 iodine Substances 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
CCZVEWRRAVASGL-UHFFFAOYSA-N lithium;2-methanidylpropane Chemical compound [Li+].CC(C)[CH2-] CCZVEWRRAVASGL-UHFFFAOYSA-N 0.000 description 1
IHLVCKWPAMTVTG-UHFFFAOYSA-N lithium;carbanide Chemical compound [Li+].[CH3-] IHLVCKWPAMTVTG-UHFFFAOYSA-N 0.000 description 1
235000011147 magnesium chloride Nutrition 0.000 description 1
229920001179 medium density polyethylene Polymers 0.000 description 1
239000004701 medium-density polyethylene Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
229940095102 methyl benzoate Drugs 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
230000000877 morphologic effect Effects 0.000 description 1
238000000465 moulding Methods 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical compound C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 description 1
CQDAMYNQINDRQC-UHFFFAOYSA-N oxatriazole Chemical compound C1=NN=NO1 CQDAMYNQINDRQC-UHFFFAOYSA-N 0.000 description 1
WYURNTSHIVDZCO-SVYQBANQSA-N oxolane-d8 Chemical compound [2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H] WYURNTSHIVDZCO-SVYQBANQSA-N 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
GUVXZFRDPCKWEM-UHFFFAOYSA-N pentalene group Chemical group C1=CC=C2C=CC=C12 GUVXZFRDPCKWEM-UHFFFAOYSA-N 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920000137 polyphosphoric acid Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
IEUQOFCUXUIBJA-UHFFFAOYSA-L prop-1-ene zirconium(2+) dichloride Chemical group C=CC.[Cl-].[Cl-].[Zr+2] IEUQOFCUXUIBJA-UHFFFAOYSA-L 0.000 description 1
229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
OSFBJERFMQCEQY-UHFFFAOYSA-N propylidene Chemical group [CH]CC OSFBJERFMQCEQY-UHFFFAOYSA-N 0.000 description 1
238000010926 purge Methods 0.000 description 1
125000004076 pyridyl group Chemical group 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
239000006188 syrup Substances 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
238000003856 thermoforming Methods 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
238000012546 transfer Methods 0.000 description 1
230000007704 transition Effects 0.000 description 1
125000004665 trialkylsilyl group Chemical group 0.000 description 1
UGFZMDADCKURLH-UHFFFAOYSA-L trimethyl-(4-phenyl-2-trimethylsilylcyclopenta[b]phosphol-6-yl)silane zirconium(2+) dichloride Chemical compound [Cl-].[Cl-].[Zr++].C[Si](C)(C)C1=PC2=C(C=C(C2=C1)c1ccccc1)[Si](C)(C)C.C[Si](C)(C)C1=PC2=C(C=C(C2=C1)c1ccccc1)[Si](C)(C)C UGFZMDADCKURLH-UHFFFAOYSA-L 0.000 description 1
JWNFLAYHMJPEQU-UHFFFAOYSA-L trimethyl-(4-phenyl-2-trimethylsilylcyclopenta[b]pyrrol-6-yl)silane zirconium(2+) dichloride Chemical compound [Cl-].[Cl-].[Zr++].C[Si](C)(C)C1=NC2=C(C=C(C2=C1)c1ccccc1)[Si](C)(C)C.C[Si](C)(C)C1=NC2=C(C=C(C2=C1)c1ccccc1)[Si](C)(C)C JWNFLAYHMJPEQU-UHFFFAOYSA-L 0.000 description 1
238000001665 trituration Methods 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
- C07D333/62—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
- C07D333/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
- C07D333/70—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 2
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
- C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D495/04—Ortho-condensed systems
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/05—Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Indole Compounds (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

RU99112514/04A 1996-11-15 1997-11-12 Металлоцен, лиганд, каталитическая система, способ полимеризации RU2194708C2 (ru)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP96118369		1996-11-15
EP96118369.6		1996-11-15

Publications (2)

Publication Number	Publication Date
RU99112514A RU99112514A (ru)	2001-04-27
RU2194708C2 true RU2194708C2 (ru)	2002-12-20

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RU99112514/04A RU2194708C2 (ru)	1996-11-15	1997-11-12	Металлоцен, лиганд, каталитическая система, способ полимеризации

Country Status (21)

Country	Link
US (2)	US7238818B2 (fr)
EP (2)	EP0938491B1 (fr)
KR (1)	KR100536794B1 (fr)
CN (1)	CN1113890C (fr)
AR (1)	AR009613A1 (fr)
AU (1)	AU733813B2 (fr)
BR (1)	BR9715006B1 (fr)
CA (1)	CA2271861C (fr)
DE (2)	DE69721807T2 (fr)
ES (2)	ES2256662T3 (fr)
HU (1)	HUP9904527A2 (fr)
ID (1)	ID22443A (fr)
IL (1)	IL129600A0 (fr)
NO (1)	NO992352L (fr)
PE (1)	PE52899A1 (fr)
PL (1)	PL188107B1 (fr)
RU (1)	RU2194708C2 (fr)
TR (1)	TR199901635T2 (fr)
TW (1)	TW394779B (fr)
WO (1)	WO1998022486A1 (fr)
ZA (1)	ZA9710211B (fr)

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US6451938B1 (en) †	1997-02-25	2002-09-17	Exxon Mobil Chemical Patents Inc.	Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
JP4540755B2 (ja)	1997-11-12	2010-09-08	バセルテクノロジーカンパニーベスローテンフェンノートシャップ	メタロセンおよびオレフィン重合用の触媒
WO2000018808A1 (fr)	1998-09-30	2000-04-06	Exxon Chemical Patents Inc.	Systeme catalytique cationique du groupe 3
DE19903306A1 (de) *	1999-01-28	2000-08-03	Targor Gmbh	Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
EP1074557A3 (fr) *	1999-07-31	2003-02-26	Basell Polyolefine GmbH	Complexes de métaux de transition, ligandes, catalyseurs, et leur utilisation dans la polymérisation d'oléfines
BR0014616A (pt)	1999-09-22	2002-06-18	Basell Technology Co Bv	Sistema catalìtico e processo para a polimerização de olefinas
DE60006146T2 (de)	1999-11-04	2004-09-30	Exxonmobil Chemical Patents Inc., Baytown	Propylencopolymerschäume und deren verwendung
US6444833B1 (en) *	1999-12-15	2002-09-03	Basell Technology Company Bv	Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
US6281306B1 (en)	1999-12-16	2001-08-28	Univation Technologies, Llc	Method of polymerization
MXPA02006199A (es)	1999-12-22	2003-10-15	Exxon Chemical Patents Inc	Composiciones adhesivas a base de polipropileno.
DE19962814A1 (de)	1999-12-23	2001-06-28	Targor Gmbh	Neues Katalysatorsystem und dessen Verwendung
DE19962910A1 (de)	1999-12-23	2001-07-05	Targor Gmbh	Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
EP1157046B1 (fr) *	1999-12-28	2005-12-07	Basell Polyolefine GmbH	Processus de preparation de polymeres d'ethylene
WO2001047939A1 (fr) *	1999-12-28	2001-07-05	Basell Technology Company B.V.	Composes de metallocene heterocycliques et leur utilisation dans des systemes catalytiques pour produire des polymeres d'olefines
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ES2326537T3 (es) *	2000-01-18	2009-10-14	Basell Polyolefine Gmbh	Ligando para un catalizador metaloceno para fabricar polimeros basados en propileno y metodo de obtencion del mismo.
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GB0007002D0 (en) *	2000-03-22	2000-05-10	Borealis Polymers Oy	Catalysts
DE10025412A1 (de)	2000-05-24	2001-11-29	Basell Polypropylen Gmbh	Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE10028432A1 (de)	2000-06-13	2001-12-20	Basell Polyolefine Gmbh	Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
EP1355958A2 (fr)	2000-12-22	2003-10-29	Basell Poliolefine Italia S.p.A.	Preparation de polymeres poreux et polymeres ainsi obtenus
EP1265933B1 (fr)	2000-12-22	2008-08-13	Basell Polyolefine GmbH	Composes catalytiques pour la polymerisation d'olefines
US7253292B2 (en)	2001-05-15	2007-08-07	Basell Polyolefine Gmbh	Synthesis of cyclopentadiene derivatives
DE60202524T2 (de)	2001-05-21	2005-06-30	Basell Polyolefine Gmbh	Katalysatorsystem für die polymerisierung von olefinen
DE10126265A1 (de)	2001-05-29	2002-12-05	Basell Polyolefine Gmbh	Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte
EP1446429B1 (fr)	2001-06-12	2009-10-07	Basell Polyolefine GmbH	Méthode de polymérisation de 1-butène
US7459511B2 (en)	2001-06-12	2008-12-02	Basell Polyolefine Gmbh	Process for the polymerization of 1-butene
ATE321061T1 (de)	2001-06-22	2006-04-15	Basell Polyolefine Gmbh	Metallocene, verwendung in katalysatoren für olefinpolymerisation
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Publication number	Publication date
BR9715006B1 (pt)	2011-06-28
AU5321698A (en)	1998-06-10
EP0938491B1 (fr)	2003-05-07
CA2271861A1 (fr)	1998-05-28
DE69735068T2 (de)	2006-08-24
NO992352L (no)	1999-07-08
DE69721807T2 (de)	2004-03-04
IL129600A0 (en)	2000-02-29
CN1244201A (zh)	2000-02-09
KR100536794B1 (ko)	2005-12-14
ZA9710211B (en)	1998-06-03
DE69735068D1 (de)	2006-04-06
CN1113890C (zh)	2003-07-09
JP2001504824A (ja)	2001-04-10
WO1998022486A1 (fr)	1998-05-28
ID22443A (id)	1999-10-14
ES2256662T3 (es)	2006-07-16
ES2197377T3 (es)	2004-01-01
US7238818B2 (en)	2007-07-03
EP1327636A3 (fr)	2004-01-02
CA2271861C (fr)	2007-09-04
US20050192418A1 (en)	2005-09-01
AR009613A1 (es)	2000-04-26
US7851644B2 (en)	2010-12-14
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BR9715006A (pt)	2000-12-05
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EP1327636B1 (fr)	2006-01-11
TR199901635T2 (xx)	2000-02-21
DE69721807D1 (de)	2003-06-12
PE52899A1 (es)	1999-06-09
AU733813B2 (en)	2001-05-24
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US20090286945A9 (en)	2009-11-19
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Publication	Publication Date	Title
RU2194708C2 (ru)	2002-12-20	Металлоцен, лиганд, каталитическая система, способ полимеризации
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RU2243229C2 (ru)	2004-12-27	Металлоценовое соединение, лиганд, способы получения лиганда, катализатор, способ получения полимера альфа-олефинов, гомополимер пропилена, сополимер пропилена
EP1448578B1 (fr)	2006-07-26	Composes de metallocene et procede de preparation de polymeres de propylene
CN100473669C (zh)	2009-04-01	过渡金属有机化合物、双环戊二烯基配体体系，催化剂体系和聚烯烃制备
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JP4758650B2 (ja)	2011-08-31	１−ブテンポリマーの製造方法
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KR101139268B1 (ko)	2012-07-05	유기금속 전이 금속 화합물, 비스시클로펜타디에닐 리간드계, 촉매 계 및 폴리올레핀 제조
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JP4131448B6 (ja)	2008-10-08	ヘテロ環式メタロセン類および重合触媒
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