SE435399B - Sett och bad for cyanidfri zinkelektropletering - Google Patents

Sett och bad for cyanidfri zinkelektropletering

Info

Publication number: SE435399B
Authority: SE; Sweden
Prior art keywords: bath; quaternary; zinc; alkyl; leveling agent
Prior art date: 1978-01-16

Application number

SE7900338A

Other languages

English (en)

Swedish (sv)

Other versions

SE7900338L (sv

Inventor

H G Creutz

S Martin

D J Saez

R W Herr

Original Assignee

Oxy Metal Industries Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-01-16

Filing date

1979-01-15

Publication date

1984-09-24

1978-01-16 Priority claimed from US05/869,967 external-priority patent/US4170526A/en

1979-01-15 Application filed by Oxy Metal Industries Corp filed Critical Oxy Metal Industries Corp

1979-07-17 Publication of SE7900338L publication Critical patent/SE7900338L/xx

1984-09-24 Publication of SE435399B publication Critical patent/SE435399B/sv

Links

HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 33
229910052725 zinc Inorganic materials 0.000 title claims abstract description 33
239000011701 zinc Substances 0.000 title claims abstract description 33
-1 alkyl arene Chemical class 0.000 claims abstract description 19
150000001875 compounds Chemical class 0.000 claims abstract description 16
238000009713 electroplating Methods 0.000 claims abstract description 14
239000003795 chemical substances by application Substances 0.000 claims abstract description 13
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims abstract description 12
238000007747 plating Methods 0.000 claims abstract description 12
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims abstract description 10
150000002391 heterocyclic compounds Chemical class 0.000 claims abstract description 9
PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 claims abstract description 8
KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 claims abstract description 8
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 8
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims abstract description 8
239000002168 alkylating agent Substances 0.000 claims abstract description 7
229940100198 alkylating agent Drugs 0.000 claims abstract description 7
238000000034 method Methods 0.000 claims abstract description 7
230000007935 neutral effect Effects 0.000 claims abstract description 5
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims abstract description 5
VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 claims abstract description 4
MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims abstract description 4
CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims abstract description 3
238000005282 brightening Methods 0.000 claims abstract 3
239000000203 mixture Substances 0.000 claims description 15
238000000576 coating method Methods 0.000 claims description 14
239000011248 coating agent Substances 0.000 claims description 12
239000000654 additive Substances 0.000 claims description 8
230000000996 additive effect Effects 0.000 claims description 8
239000000853 adhesive Substances 0.000 claims description 8
230000001070 adhesive effect Effects 0.000 claims description 8
AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 claims description 6
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 5
229920002557 polyglycidol polymer Polymers 0.000 claims description 5
150000008050 dialkyl sulfates Chemical class 0.000 claims description 4
125000000623 heterocyclic group Chemical group 0.000 claims description 4
CTLCGTSTPNMYCX-UHFFFAOYSA-N S(=O)(=O)(OCCC)OCCC.C(CC)OC(C1=CC=NC=C1)=O Chemical compound S(=O)(=O)(OCCC)OCCC.C(CC)OC(C1=CC=NC=C1)=O CTLCGTSTPNMYCX-UHFFFAOYSA-N 0.000 claims description 3
230000002378 acidificating effect Effects 0.000 claims description 3
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 3
MEDWIOBRSFCGBY-UHFFFAOYSA-N diethyl sulfate;isoquinoline Chemical compound CCOS(=O)(=O)OCC.C1=NC=CC2=CC=CC=C21 MEDWIOBRSFCGBY-UHFFFAOYSA-N 0.000 claims description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
WKGDGOODXPYEAW-UHFFFAOYSA-N diethyl sulfate;2-methylquinoline Chemical compound CCOS(=O)(=O)OCC.C1=CC=CC2=NC(C)=CC=C21 WKGDGOODXPYEAW-UHFFFAOYSA-N 0.000 claims description 2
PXVBFVXUHIYAGT-UHFFFAOYSA-N dimethyl sulfate;1h-imidazole Chemical compound C1=CNC=N1.COS(=O)(=O)OC PXVBFVXUHIYAGT-UHFFFAOYSA-N 0.000 claims description 2
DOTICPBDAASLOF-UHFFFAOYSA-N dimethyl sulfate;pyridine-3-carboxamide Chemical compound COS(=O)(=O)OC.NC(=O)C1=CC=CN=C1 DOTICPBDAASLOF-UHFFFAOYSA-N 0.000 claims description 2
238000009499 grossing Methods 0.000 claims description 2
239000000758 substrate Substances 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
238000000151 deposition Methods 0.000 claims 1
MQNYSKWKUZYFEB-UHFFFAOYSA-N diethyl sulfate;pyrimidine Chemical compound C1=CN=CN=C1.CCOS(=O)(=O)OCC MQNYSKWKUZYFEB-UHFFFAOYSA-N 0.000 claims 1
WIPCMBDEWMKHCR-UHFFFAOYSA-N dimethyl sulfate;phenazine Chemical compound COS(=O)(=O)OC.C1=CC=CC2=NC3=CC=CC=C3N=C21 WIPCMBDEWMKHCR-UHFFFAOYSA-N 0.000 claims 1
DNQINBAHVGVBEH-UHFFFAOYSA-N dimethyl sulfate;pyridine Chemical compound C1=CC=NC=C1.COS(=O)(=O)OC DNQINBAHVGVBEH-UHFFFAOYSA-N 0.000 claims 1
238000004070 electrodeposition Methods 0.000 claims 1
150000002989 phenols Chemical class 0.000 claims 1
229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims 1
KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 abstract description 6
DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 abstract description 6
150000003839 salts Chemical group 0.000 abstract description 6
WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 abstract description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 2
125000000217 alkyl group Chemical group 0.000 abstract description 2
PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 abstract 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 abstract 2
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 2
235000001968 nicotinic acid Nutrition 0.000 abstract 2
239000011664 nicotinic acid Substances 0.000 abstract 2
SMUQFGGVLNAIOZ-UHFFFAOYSA-N quinaldine Chemical compound C1=CC=CC2=NC(C)=CC=C21 SMUQFGGVLNAIOZ-UHFFFAOYSA-N 0.000 abstract 2
XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
239000004721 Polyphenylene oxide Substances 0.000 abstract 1
239000002253 acid Substances 0.000 abstract 1
150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
150000001350 alkyl halides Chemical class 0.000 abstract 1
235000005152 nicotinamide Nutrition 0.000 abstract 1
239000011570 nicotinamide Substances 0.000 abstract 1
229960003966 nicotinamide Drugs 0.000 abstract 1
229960003512 nicotinic acid Drugs 0.000 abstract 1
229920000570 polyether Polymers 0.000 abstract 1
229910021653 sulphate ion Inorganic materials 0.000 abstract 1
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 8
229910000831 Steel Inorganic materials 0.000 description 7
239000010959 steel Substances 0.000 description 7
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
235000002639 sodium chloride Nutrition 0.000 description 6
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 5
239000004327 boric acid Substances 0.000 description 5
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 5
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
239000000243 solution Substances 0.000 description 4
239000011592 zinc chloride Substances 0.000 description 4
235000005074 zinc chloride Nutrition 0.000 description 4
239000011686 zinc sulphate Substances 0.000 description 4
235000009529 zinc sulphate Nutrition 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 3
230000008901 benefit Effects 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000001103 potassium chloride Substances 0.000 description 3
235000011164 potassium chloride Nutrition 0.000 description 3
150000003751 zinc Chemical class 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
235000019270 ammonium chloride Nutrition 0.000 description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
229910052921 ammonium sulfate Inorganic materials 0.000 description 2
235000011130 ammonium sulphate Nutrition 0.000 description 2
239000006172 buffering agent Substances 0.000 description 2
239000002738 chelating agent Substances 0.000 description 2
CICQKHNSTQLPCW-UHFFFAOYSA-N dimethyl sulfate;2-methylquinoline Chemical compound COS(=O)(=O)OC.C1=CC=CC2=NC(C)=CC=C21 CICQKHNSTQLPCW-UHFFFAOYSA-N 0.000 description 2
229910052943 magnesium sulfate Inorganic materials 0.000 description 2
235000019341 magnesium sulphate Nutrition 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
230000003389 potentiating effect Effects 0.000 description 2
BWLUCDLCZIUCRB-UHFFFAOYSA-N 2,3,7,9-tetramethyldec-5-yne-4,7-diol Chemical compound CC(C)CC(C)(O)C#CC(O)C(C)C(C)C BWLUCDLCZIUCRB-UHFFFAOYSA-N 0.000 description 1
NPKPKSNMIYBLFQ-UHFFFAOYSA-N 9,10,10-trimethylundec-5-yne-4,7-diol Chemical compound CCCC(O)C#CC(O)CC(C)C(C)(C)C NPKPKSNMIYBLFQ-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
CHVWVJPSOJAWAI-UHFFFAOYSA-N S(=O)(=O)(OCC)OCC.C(C1=CN=CC=C1)(=O)N Chemical compound S(=O)(=O)(OCC)OCC.C(C1=CN=CC=C1)(=O)N CHVWVJPSOJAWAI-UHFFFAOYSA-N 0.000 description 1
HEVRWDOGKYKUMR-UHFFFAOYSA-N S(O)(O)(=O)=O.S(=O)(=O)(OCC)OCC Chemical compound S(O)(O)(=O)=O.S(=O)(=O)(OCC)OCC HEVRWDOGKYKUMR-UHFFFAOYSA-N 0.000 description 1
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000005526 alkyl sulfate group Chemical group 0.000 description 1
150000008052 alkyl sulfonates Chemical class 0.000 description 1
239000001166 ammonium sulphate Substances 0.000 description 1
JWAZRIHNYRIHIV-UHFFFAOYSA-N beta-hydroxynaphthyl Natural products C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 1
238000007664 blowing Methods 0.000 description 1
ABRFJWFTGYEWIY-UHFFFAOYSA-N dimethyl sulfate;pyridine-3-carboxylic acid Chemical compound COS(=O)(=O)OC.OC(=O)C1=CC=CN=C1 ABRFJWFTGYEWIY-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
235000011147 magnesium chloride Nutrition 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
FZUJWWOKDIGOKH-UHFFFAOYSA-N sulfuric acid hydrochloride Chemical compound Cl.OS(O)(=O)=O FZUJWWOKDIGOKH-UHFFFAOYSA-N 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
239000004246 zinc acetate Substances 0.000 description 1
229960001763 zinc sulfate Drugs 0.000 description 1
229910000368 zinc sulfate Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/22—Collecting emitted gases

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electroplating And Plating Baths Therefor (AREA)

SE7900338A 1978-01-16 1979-01-15 Sett och bad for cyanidfri zinkelektropletering SE435399B (sv)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/869,967 US4170526A (en)	1978-01-16	1978-01-16	Electroplating bath and process
US87219078A	1978-01-25	1978-01-25

Publications (2)

Publication Number	Publication Date
SE7900338L SE7900338L (sv)	1979-07-17
SE435399B true SE435399B (sv)	1984-09-24

Family

ID=27128141

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7900338A SE435399B (sv)	1978-01-16	1979-01-15	Sett och bad for cyanidfri zinkelektropletering

Country Status (9)

Country	Link
AR (1)	AR219787A1 (it)
AU (2)	AU523965B2 (it)
BR (2)	BR7900282A (it)
CA (1)	CA1134317A (it)
DE (1)	DE2900501C2 (it)
GB (3)	GB2062010A (it)
IT (1)	IT1114331B (it)
MX (2)	MX152135A (it)
SE (1)	SE435399B (it)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CH662583A5 (fr) *	1985-03-01	1987-10-15	Heinz Emmenegger	Bain galvanique pour le depot electrolytique d'alliages d'or-cuivre-cadmium-zinc.
US4699696A (en) *	1986-04-15	1987-10-13	Omi International Corporation	Zinc-nickel alloy electrolyte and process
ES2237003T3 (es) *	1998-09-15	2005-07-16	Lpw-Chemie Gmbh	Procedimiento para la deposicion galvanica de precipitados de cinc y/o de precipitados de aleaciones de cinc.
US6238542B1 (en)	1998-09-15	2001-05-29	Thomas Helden	Water soluble brighteners for zinc and zinc alloy electrolytes
DE10033433A1 (de) *	2000-07-10	2002-01-24	Basf Ag	Verfahren zur elektrolytischen Verzinkung aus alkansulfonsäurehaltigen Elektrolyten
WO2016105374A1 (en)	2014-12-23	2016-06-30	Colgate-Palmolive Company	Oral care implement
RU2664278C1 (ru)	2014-12-23	2018-08-15	Колгейт-Палмолив Компани	Устройство для ухода за полостью рта, содержащее многокомпонентную ручку
MX393731B (es)	2014-12-23	2025-03-24	Colgate Palmolive Co	Implemento para el cuidado bucal.
EP3223657B1 (en)	2014-12-23	2022-12-07	Colgate-Palmolive Company	Oral care implement
EP3223655B1 (en)	2014-12-23	2024-10-09	Colgate-Palmolive Company	Oral care implement
BR112017010792B1 (pt)	2014-12-23	2021-10-05	Colgate-Palmolive Company	Instrumento de higiene bucal
USD780457S1 (en)	2014-12-23	2017-03-07	Colgate-Palmolive Company	Oral care implement
US10455931B2 (en)	2014-12-23	2019-10-29	Colgate-Palmolive Company	Oral care implement
US10660430B2 (en)	2014-12-23	2020-05-26	Colgate-Palmolive Company	Oral care implement having multi-component handle
EP3995036B1 (en)	2014-12-23	2025-06-04	Colgate-Palmolive Company	Oral care implement
US11291293B2 (en)	2014-12-23	2022-04-05	Colgate-Palmolive Company	Oral care implement
US10631964B2 (en)	2017-12-12	2020-04-28	Colgate-Palmolive Company	Oral care implement
US10709533B2 (en)	2017-12-12	2020-07-14	Colgate-Palmolive Company	Oral care implement and handle and refill head thereof
USD846883S1 (en)	2017-12-12	2019-04-30	Colgate-Palmolive Company	Handle of an oral care implement
USD891784S1 (en)	2018-12-18	2020-08-04	Colgate-Palmolive Company	Electric toothbrush handle
USD960582S1 (en)	2020-12-10	2022-08-16	Colgate-Palmolive Company	Oral care refill head

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3821095A (en) *	1972-09-26	1974-06-28	M & T Chemicals Inc	Zinc electroplating process and electrolyte therefor

1978
- 1978-11-22 CA CA000316708A patent/CA1134317A/en not_active Expired
1979
- 1979-01-08 DE DE2900501A patent/DE2900501C2/de not_active Expired
- 1979-01-15 GB GB8038947A patent/GB2062010A/en not_active Withdrawn
- 1979-01-15 SE SE7900338A patent/SE435399B/sv unknown
- 1979-01-15 GB GB791398A patent/GB2012306B/en not_active Expired
- 1979-01-15 GB GB8036467A patent/GB2062009B/en not_active Expired
- 1979-01-16 BR BR7900282A patent/BR7900282A/pt unknown
- 1979-01-16 MX MX176306A patent/MX152135A/es unknown
- 1979-01-16 MX MX176305A patent/MX152015A/es unknown
- 1979-01-16 IT IT47654/79A patent/IT1114331B/it active
- 1979-01-16 AU AU43395/79A patent/AU523965B2/en not_active Ceased
- 1979-01-16 BR BR7900283A patent/BR7900283A/pt unknown
- 1979-01-16 AU AU43396/79A patent/AU521274B2/en not_active Ceased
- 1979-01-16 AR AR275188A patent/AR219787A1/es active

Also Published As

Publication number	Publication date
AR219787A1 (es)	1980-09-15
IT1114331B (it)	1986-01-27
MX152135A (es)	1985-05-31
AU521274B2 (en)	1982-03-25
AU4339579A (en)	1979-07-26
AU523965B2 (en)	1982-08-26
GB2062009B (en)	1982-09-08
GB2062009A (en)	1981-05-20
CA1134317A (en)	1982-10-26
IT7947654A0 (it)	1979-01-16
DE2900501A1 (de)	1979-08-02
BR7900283A (pt)	1979-08-14
AU4339679A (en)	1979-07-26
BR7900282A (pt)	1979-08-14
MX152015A (es)	1985-05-24
GB2012306B (en)	1982-08-04
SE7900338L (sv)	1979-07-17
GB2062010A (en)	1981-05-20
DE2900501C2 (de)	1982-10-21
GB2012306A (en)	1979-07-25

Publication	Publication Date	Title
SE435399B (sv)	1984-09-24	Sett och bad for cyanidfri zinkelektropletering
US4038161A (en)	1977-07-26	Acid copper plating and additive composition therefor
US4139425A (en)	1979-02-13	Composition, plating bath, and method for electroplating tin and/or lead
US10006135B2 (en)	2018-06-26	Electroplating bath and method for producing dark chromium layers
US4582576A (en)	1986-04-15	Plating bath and method for electroplating tin and/or lead
US4169772A (en)	1979-10-02	Acid zinc plating baths, compositions useful therein, and methods for electrodepositing bright zinc deposits
US11274373B2 (en)	2022-03-15	Method for the production of a metal strip coated with a coating of chromium and chromium oxide using an electrolyte solution with a trivalent chromium compound
US20120217168A1 (en)	2012-08-30	High speed tin plating process
US4543166A (en)	1985-09-24	Zinc-alloy electrolyte and process
US4599149A (en)	1986-07-08	Process for electroplating tin, lead and tin-lead alloys and baths therefor
US4170526A (en)	1979-10-09	Electroplating bath and process
US4515663A (en)	1985-05-07	Acid zinc and zinc alloy electroplating solution and process
US6117301A (en)	2000-09-12	Electrolyte for the galvanic deposition of low-stress, crack-resistant ruthenium layers
US4207150A (en)	1980-06-10	Electroplating bath and process
US4923576A (en)	1990-05-08	Additives for electroplating compositions and methods for their use
US4071418A (en)	1978-01-31	Electrodeposition of zinc and additives therefor
KR101998605B1 (ko)	2019-07-10	아연니켈합금 전기도금액 및 이를 이용한 전기도금법
CA1162507A (en)	1984-02-21	Brightener for zinc electroplating solutions and process
EP0037634A1 (en)	1981-10-14	Zinc plating baths and additives therefor
DE2231988A1 (de)	1973-01-18	Verfahren zur galvanischen abscheidung von zinn
NO872114L (no)	1987-11-23	Surt bad for elektrolytisk belegning med gull.
US5061351A (en)	1991-10-29	Bright tin electrodeposition composition
US4496439A (en)	1985-01-29	Acidic zinc-plating bath
US4169771A (en)	1979-10-02	Ductile bright zinc electroplating bath and process and additive therefor
US4366036A (en)	1982-12-28	Additive and alkaline zinc electroplating bath and process using same