SE444432B - Forfarande for framstellning av blandningar av c?711 - c?714-alkanoler av syntesgas - Google Patents

Forfarande for framstellning av blandningar av c?711 - c?714-alkanoler av syntesgas

Info

Publication number
SE444432B
SE444432B SE8203800A SE8203800A SE444432B SE 444432 B SE444432 B SE 444432B SE 8203800 A SE8203800 A SE 8203800A SE 8203800 A SE8203800 A SE 8203800A SE 444432 B SE444432 B SE 444432B
Authority
SE
Sweden
Prior art keywords
ruthenium
titanium
zirconium
salt
alkanols
Prior art date
Application number
SE8203800A
Other languages
English (en)
Swedish (sv)
Other versions
SE8203800L (sv
Inventor
J F Knifton
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of SE8203800L publication Critical patent/SE8203800L/xx
Publication of SE444432B publication Critical patent/SE444432B/sv

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
    • B01J31/0288—Phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C07C29/1514—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions the solvents being characteristic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SE8203800A 1981-06-26 1982-06-18 Forfarande for framstellning av blandningar av c?711 - c?714-alkanoler av syntesgas SE444432B (sv)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/277,540 US4339545A (en) 1981-06-26 1981-06-26 Alkanols from synthesis gas

Publications (2)

Publication Number Publication Date
SE8203800L SE8203800L (sv) 1982-12-27
SE444432B true SE444432B (sv) 1986-04-14

Family

ID=23061302

Family Applications (1)

Application Number Title Priority Date Filing Date
SE8203800A SE444432B (sv) 1981-06-26 1982-06-18 Forfarande for framstellning av blandningar av c?711 - c?714-alkanoler av syntesgas

Country Status (16)

Country Link
US (1) US4339545A (ja)
JP (1) JPS58922A (ja)
KR (1) KR860000448B1 (ja)
AU (1) AU553888B2 (ja)
BE (1) BE893652A (ja)
BR (1) BR8203713A (ja)
CA (1) CA1178974A (ja)
DE (1) DE3221610A1 (ja)
ES (1) ES513408A0 (ja)
FR (1) FR2508439B1 (ja)
GB (1) GB2100725B (ja)
IT (1) IT1157282B (ja)
MX (1) MX7600E (ja)
NL (1) NL8202490A (ja)
SE (1) SE444432B (ja)
ZA (1) ZA823323B (ja)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60161933A (ja) * 1984-01-31 1985-08-23 Agency Of Ind Science & Technol 酸素含有炭化水素化合物の製造方法
FR2573999B1 (fr) * 1984-12-05 1987-01-23 Rhone Poulenc Spec Chim Procede de fabrication de supports de catalyseurs a base d'alumine dont la durabilite est amelioree
DE4109088A1 (de) * 1991-03-20 1992-09-24 Basf Ag Katalytisch wirksame salzmischungen
US7196239B2 (en) * 2003-11-19 2007-03-27 Exxonmobil Chemical Patents Inc. Methanol and ethanol production for an oxygenate to olefin reaction system
US7288689B2 (en) * 2003-11-19 2007-10-30 Exxonmobil Chemical Patents Inc. Methanol and fuel alcohol production for an oxygenate to olefin reaction system
US7199276B2 (en) * 2003-11-19 2007-04-03 Exxonmobil Chemical Patents Inc. Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion process
US20060149109A1 (en) * 2004-12-30 2006-07-06 Ruziska Philip A Converting methanol and ethanol to light olefins
EP2747885A1 (en) * 2011-08-25 2014-07-02 Eastman Chemical Company Promoted ruthenium catalyzed conversion of syngas to alcohols
US8912240B2 (en) * 2013-02-22 2014-12-16 Eastman Chemical Company Production of methanol and ethanol from CO or CO2

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4042614A (en) * 1976-04-05 1977-08-16 Exxon Research And Engineering Co. Hydrocarbon synthesis from CO and H2 using Ru supported on a titanium oxide
DE2712909A1 (de) * 1976-04-05 1977-10-13 Exxon Research Engineering Co Verfahren zur synthese von kohlenwasserstoffen
US4265828A (en) * 1979-12-31 1981-05-05 Texaco Development Corp. Manufacture of ethylene glycol from synthesis gas

Also Published As

Publication number Publication date
BE893652A (fr) 1982-12-27
ES8305294A1 (es) 1983-04-01
SE8203800L (sv) 1982-12-27
KR840000456A (ko) 1984-02-22
ZA823323B (en) 1983-09-28
IT8222058A0 (it) 1982-06-24
BR8203713A (pt) 1983-06-21
NL8202490A (nl) 1983-01-17
AU553888B2 (en) 1986-07-31
FR2508439A1 (fr) 1982-12-31
GB2100725A (en) 1983-01-06
MX7600E (es) 1990-02-20
DE3221610A1 (de) 1983-01-13
FR2508439B1 (fr) 1986-10-03
JPS58922A (ja) 1983-01-06
CA1178974A (en) 1984-12-04
KR860000448B1 (ko) 1986-04-26
GB2100725B (en) 1985-04-17
AU8518082A (en) 1983-01-06
ES513408A0 (es) 1983-04-01
IT1157282B (it) 1987-02-11
US4339545A (en) 1982-07-13

Similar Documents

Publication Publication Date Title
EP0108847B1 (en) Production of acetic acid, propionic acid and their esters
Nishiyama et al. Chiral and C2-symmetrical bis (oxazolinylpyridine) rhodium (III) complexes: effective catalysts for asymmetric hydrosilylation of ketones
JPS6021973B2 (ja) カルボン酸アルキルのヒドロカルボニル化および／またはカルボニル化法
CA1151215A (en) Manufacture of ethylene glycol from synthesis gas
US4484002A (en) Process for producing methyl acetate from methanol and carbon monoxide using a novel catalyst system
US4374285A (en) Synthesis of ethanol by homologation of methanol
US4371724A (en) Ethanol synthesis by homologation of methanol
EP0055514B1 (en) Preparation of glycols and ethers
KR860000448B1 (ko) 합성가스로부터 알칸올을 제조하는 방법
KR860000447B1 (ko) 에틸렌 글리콜의 제조방법
US4605677A (en) Process for C1 -C4 alkanol production from synthesis gas
SE444560B (sv) Sett att framstella alkanolblandningar med hog etanolhalt av syntesgas
KR101732834B1 (ko) 도데카카르보닐 트리루테늄의 제조 방법
US4409404A (en) Process for producing ethanol using said novel catalyst system
EP0048046B1 (en) Method for the manufacture of ethylidene diacetate
EP0013464A1 (en) Selective formation of ethanol from methanol, hydrogen and carbon monoxide
US4556734A (en) Process for synthesizing formamides from synthesis gas plus ammonia
CA1192226A (en) Process for preparing ethylene glycol and lower monohydric alcohols from syngas using a novel catalyst system
US4414410A (en) Process for preparing alkyl esters by homologation of the next lower alkyl ester
US4433178A (en) Process for preparing acetaldehyde from methanol and synthesis gas using a novel catalyst composition
EP0056679B1 (en) Ethanol synthesis by homologation of methanol
US4362822A (en) Process for preparing acetic and propionic acids and their esters
EP0126501B1 (en) Process for the preparation of alpha-haloalkyl esters
US20040059165A1 (en) Synthesis of aliphatic 1,3-diols utilizing reduced ligand concentration and water extraction
JP4259523B2 (ja) β−ヒドロキシエステルの製法

Legal Events

Date Code Title Description
NUG Patent has lapsed

Ref document number: 8203800-1

Effective date: 19900620

Format of ref document f/p: F