SE467260B - Blekning av cellulosamassa med klordioxid och ozon i ett och samma steg - Google Patents
Blekning av cellulosamassa med klordioxid och ozon i ett och samma stegInfo
- Publication number
- SE467260B SE467260B SE8904403A SE8904403A SE467260B SE 467260 B SE467260 B SE 467260B SE 8904403 A SE8904403 A SE 8904403A SE 8904403 A SE8904403 A SE 8904403A SE 467260 B SE467260 B SE 467260B
- Authority
- SE
- Sweden
- Prior art keywords
- ozone
- carbon dioxide
- added
- pulp
- separate
- Prior art date
Links
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims description 56
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title 1
- 241000276489 Merlangius merlangus Species 0.000 title 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 86
- 239000001569 carbon dioxide Substances 0.000 claims description 43
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 43
- 238000004061 bleaching Methods 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 28
- 238000005406 washing Methods 0.000 claims description 22
- 238000011282 treatment Methods 0.000 claims description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 9
- 239000012159 carrier gas Substances 0.000 claims description 8
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 8
- 239000007844 bleaching agent Substances 0.000 claims description 5
- 239000004155 Chlorine dioxide Substances 0.000 claims description 4
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 4
- 239000002657 fibrous material Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000012163 sequencing technique Methods 0.000 claims description 2
- 229920001131 Pulp (paper) Polymers 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 238000002474 experimental method Methods 0.000 description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011122 softwood Substances 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 210000003323 beak Anatomy 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000002535 acidifier Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 235000020094 liqueur Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
- D21C9/144—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites with ClO2/Cl2 and other bleaching agents in a multistage process
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8904403A SE467260B (sv) | 1989-12-29 | 1989-12-29 | Blekning av cellulosamassa med klordioxid och ozon i ett och samma steg |
| DE4039099A DE4039099C2 (de) | 1989-12-29 | 1990-12-07 | Verfahren zum Bleichen von Cellulosebrei |
| CA002031848A CA2031848C (en) | 1989-12-29 | 1990-12-10 | Method of bleaching pulp |
| AT0251990A AT396129B (de) | 1989-12-29 | 1990-12-12 | Verfahren zum bleichen von cellulosebrei |
| BR909006578A BR9006578A (pt) | 1989-12-29 | 1990-12-26 | Processo de branqueamento de polpa de material de fibra celulosica |
| FI906400A FI95291C (fi) | 1989-12-29 | 1990-12-27 | Massan valkaisutapa |
| NO905599A NO176061C (no) | 1989-12-29 | 1990-12-27 | Fremgangsmåte ved bleking av masse av celluloseinneholdende fibermateriale |
| JP2415577A JPH04289288A (ja) | 1989-12-29 | 1990-12-28 | セルロース質繊維材料のパルプの漂白方法 |
| FR9016500A FR2656634B1 (fr) | 1989-12-29 | 1990-12-28 | Procede de blanchiment d'une pate cellulosique en une seule etape par le bioxyde de chlore et l'ozone. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8904403A SE467260B (sv) | 1989-12-29 | 1989-12-29 | Blekning av cellulosamassa med klordioxid och ozon i ett och samma steg |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE8904403D0 SE8904403D0 (sv) | 1989-12-29 |
| SE8904403L SE8904403L (sv) | 1991-06-30 |
| SE467260B true SE467260B (sv) | 1992-06-22 |
Family
ID=20377904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8904403A SE467260B (sv) | 1989-12-29 | 1989-12-29 | Blekning av cellulosamassa med klordioxid och ozon i ett och samma steg |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPH04289288A (de) |
| AT (1) | AT396129B (de) |
| BR (1) | BR9006578A (de) |
| CA (1) | CA2031848C (de) |
| DE (1) | DE4039099C2 (de) |
| FI (1) | FI95291C (de) |
| FR (1) | FR2656634B1 (de) |
| NO (1) | NO176061C (de) |
| SE (1) | SE467260B (de) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5322598A (en) * | 1990-02-06 | 1994-06-21 | Olin Corporation | Chlorine dioxide generation using inert load of sodium perchlorate |
| FI925558A7 (fi) | 1992-04-22 | 1993-10-23 | Andritz Oy | Menetelmä ja laitteisto massan valkaisemiseksi |
| US5387317A (en) * | 1993-01-28 | 1995-02-07 | The Mead Corporation | Oxygen/ozone/peracetic aicd delignification and bleaching of cellulosic pulps |
| US6248209B1 (en) | 1995-08-10 | 2001-06-19 | Sanyo Chemical Industries, Ltd. | Process for bleaching cellulose pulp with a bleaching assistant having the formula R1-O-{[(C2H4O)m/(AO)n}]-H |
| FR2743094B1 (fr) * | 1995-12-27 | 1998-02-13 | Centre Tech Ind Papier | Procede de blanchiment des pates a papier chimiques |
| ID23571A (id) * | 1997-08-25 | 2000-05-04 | Praxair Technology Inc | Metoda penerapan ozon dalam pemutihan ecf |
| US6174409B1 (en) | 1997-09-19 | 2001-01-16 | American Air Liquide Inc. | Method to improve final bleached pulp strength properties by adjusting the CI02:03 ration within a single (D/Z) stage of the bleaching process |
| WO2000008251A1 (en) * | 1998-07-31 | 2000-02-17 | Asia Pulp & Paper Co. Ltd. | An improved method for bleaching pulp |
| JP2002069879A (ja) * | 2000-09-04 | 2002-03-08 | Nippon Paper Industries Co Ltd | セルロース質繊維材料のパルプの漂白方法 |
| SE532470C2 (sv) * | 2008-05-13 | 2010-02-02 | Metso Paper Inc | Slutblekning av oxygendelignifierad massa med ozon, klordioxid och peroxid |
| JP5987223B2 (ja) * | 2012-03-06 | 2016-09-07 | 愛媛県 | セルロース溶液の製造方法、セルロースの製造方法、セルロースの糖化方法 |
| CN111979823A (zh) * | 2020-08-07 | 2020-11-24 | 齐鲁工业大学 | 一种硫酸盐木浆短程序ecf漂白工艺x/d-z-p(x/z-d-p) |
| CN111979818A (zh) * | 2020-08-07 | 2020-11-24 | 齐鲁工业大学 | 一种硫酸盐木浆短程序ecf漂白工艺x/z/d-eop-d或x/d/z-eop-d |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1298875B (de) * | 1965-01-09 | 1969-07-03 | Gunnar Alexander Dipl Ing | Verfahren zum Bleichen von Zellstoff im chlorhaltigen Bleichbad und mit Ozon |
| US4080249A (en) * | 1976-06-02 | 1978-03-21 | International Paper Company | Delignification and bleaching of a lignocellulosic pulp slurry with ozone |
| US4902381A (en) * | 1988-12-09 | 1990-02-20 | Kamyr, Inc. | Method of bleaching pulp with ozone-chlorine mixtures |
| US4959124A (en) * | 1989-05-05 | 1990-09-25 | International Paper Company | Method of bleaching kraft pulp in a DZED sequence |
| FI89516B (fi) * | 1989-05-10 | 1993-06-30 | Ahlstroem Oy | Foerfarande foer blekning av cellulosamassa med otson |
-
1989
- 1989-12-29 SE SE8904403A patent/SE467260B/sv unknown
-
1990
- 1990-12-07 DE DE4039099A patent/DE4039099C2/de not_active Expired - Fee Related
- 1990-12-10 CA CA002031848A patent/CA2031848C/en not_active Expired - Lifetime
- 1990-12-12 AT AT0251990A patent/AT396129B/de not_active IP Right Cessation
- 1990-12-26 BR BR909006578A patent/BR9006578A/pt not_active IP Right Cessation
- 1990-12-27 FI FI906400A patent/FI95291C/fi active IP Right Grant
- 1990-12-27 NO NO905599A patent/NO176061C/no not_active IP Right Cessation
- 1990-12-28 FR FR9016500A patent/FR2656634B1/fr not_active Expired - Fee Related
- 1990-12-28 JP JP2415577A patent/JPH04289288A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BR9006578A (pt) | 1991-10-01 |
| FI95291C (fi) | 1996-01-10 |
| NO176061B (no) | 1994-10-17 |
| CA2031848A1 (en) | 1991-06-30 |
| FR2656634A1 (fr) | 1991-07-05 |
| DE4039099A1 (de) | 1991-07-04 |
| FI95291B (fi) | 1995-09-29 |
| NO905599D0 (no) | 1990-12-27 |
| JPH04289288A (ja) | 1992-10-14 |
| NO176061C (no) | 1995-01-25 |
| FR2656634B1 (fr) | 1996-07-26 |
| CA2031848C (en) | 1995-11-21 |
| SE8904403D0 (sv) | 1989-12-29 |
| DE4039099C2 (de) | 1994-01-27 |
| FI906400A0 (fi) | 1990-12-27 |
| AT396129B (de) | 1993-06-25 |
| ATA251990A (de) | 1992-10-15 |
| FI906400L (fi) | 1991-06-30 |
| NO905599L (no) | 1991-07-01 |
| SE8904403L (sv) | 1991-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NAL | Patent in force |
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