SE519898C2 - Sätt att etsa koppar på kort samt anordning och elektrolyt för utförande av sättet - Google Patents
Sätt att etsa koppar på kort samt anordning och elektrolyt för utförande av sättetInfo
- Publication number
- SE519898C2 SE519898C2 SE0102994A SE0102994A SE519898C2 SE 519898 C2 SE519898 C2 SE 519898C2 SE 0102994 A SE0102994 A SE 0102994A SE 0102994 A SE0102994 A SE 0102994A SE 519898 C2 SE519898 C2 SE 519898C2
- Authority
- SE
- Sweden
- Prior art keywords
- electrolyte
- cathode
- copper
- state
- component
- Prior art date
Links
- 239000010949 copper Substances 0.000 title claims abstract description 206
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 203
- 239000003792 electrolyte Substances 0.000 title claims abstract description 201
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 200
- 238000000034 method Methods 0.000 title claims description 28
- 238000005530 etching Methods 0.000 claims abstract description 93
- 150000002500 ions Chemical class 0.000 claims abstract description 45
- 230000003647 oxidation Effects 0.000 claims abstract description 38
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 38
- 229910052751 metal Inorganic materials 0.000 claims abstract description 31
- 239000002184 metal Substances 0.000 claims abstract description 31
- 230000009467 reduction Effects 0.000 claims abstract description 31
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910001431 copper ion Inorganic materials 0.000 claims abstract description 28
- -1 fluoride ions Chemical class 0.000 claims description 16
- 230000008929 regeneration Effects 0.000 claims description 14
- 238000011069 regeneration method Methods 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 230000001172 regenerating effect Effects 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 27
- 239000004020 conductor Substances 0.000 description 20
- 238000001556 precipitation Methods 0.000 description 17
- 238000003486 chemical etching Methods 0.000 description 16
- 230000000694 effects Effects 0.000 description 15
- 230000010287 polarization Effects 0.000 description 15
- 239000012212 insulator Substances 0.000 description 14
- 229910000831 Steel Inorganic materials 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000010959 steel Substances 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 238000006479 redox reaction Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000004696 Poly ether ether ketone Substances 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- 229920002530 polyetherether ketone Polymers 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 5
- 239000012777 electrically insulating material Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000010924 continuous production Methods 0.000 description 4
- 150000001879 copper Chemical class 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 229920006332 epoxy adhesive Polymers 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 2
- 210000002837 heart atrium Anatomy 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910001172 neodymium magnet Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 238000010408 sweeping Methods 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical group NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 229910004882 Na2S2O8 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 229920006334 epoxy coating Polymers 0.000 description 1
- 229920006335 epoxy glue Polymers 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 210000004197 pelvis Anatomy 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012492 regenerant Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/06—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
- H05K3/07—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process being removed electrolytically
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F3/00—Electrolytic etching or polishing
- C25F3/02—Etching
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F7/00—Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- ing And Chemical Polishing (AREA)
- Manufacturing Of Printed Circuit Boards (AREA)
- Electrolytic Production Of Metals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Catalysts (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE0102994A SE519898C2 (sv) | 2001-09-10 | 2001-09-10 | Sätt att etsa koppar på kort samt anordning och elektrolyt för utförande av sättet |
| JP2003528080A JP4216718B2 (ja) | 2001-09-10 | 2002-09-09 | 基板への銅エッチング方法、デバイスおよびこれに用いる電解液 |
| EP02798066A EP1425948B1 (de) | 2001-09-10 | 2002-09-09 | Verfahren zum ätzen von kupfer auf karten |
| DE60226984T DE60226984D1 (de) | 2001-09-10 | 2002-09-09 | Verfahren zum ätzen von kupfer auf karten |
| AT02798066T ATE397843T1 (de) | 2001-09-10 | 2002-09-09 | Verfahren zum ätzen von kupfer auf karten |
| US10/487,745 US7767074B2 (en) | 2001-09-10 | 2002-09-09 | Method of etching copper on cards |
| CNA028176588A CN1554215A (zh) | 2001-09-10 | 2002-09-09 | 腐蚀卡上的铜的方法 |
| PCT/SE2002/001602 WO2003024172A2 (en) | 2001-09-10 | 2002-09-09 | A method of etching copper on cards |
| AU2002334517A AU2002334517A1 (en) | 2001-09-10 | 2002-09-09 | A method of etching copper on cards |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE0102994A SE519898C2 (sv) | 2001-09-10 | 2001-09-10 | Sätt att etsa koppar på kort samt anordning och elektrolyt för utförande av sättet |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE0102994D0 SE0102994D0 (sv) | 2001-09-10 |
| SE0102994L SE0102994L (sv) | 2003-03-11 |
| SE519898C2 true SE519898C2 (sv) | 2003-04-22 |
Family
ID=20285274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE0102994A SE519898C2 (sv) | 2001-09-10 | 2001-09-10 | Sätt att etsa koppar på kort samt anordning och elektrolyt för utförande av sättet |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7767074B2 (de) |
| EP (1) | EP1425948B1 (de) |
| JP (1) | JP4216718B2 (de) |
| CN (1) | CN1554215A (de) |
| AT (1) | ATE397843T1 (de) |
| AU (1) | AU2002334517A1 (de) |
| DE (1) | DE60226984D1 (de) |
| SE (1) | SE519898C2 (de) |
| WO (1) | WO2003024172A2 (de) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005011298A1 (de) * | 2005-03-04 | 2006-09-07 | Gebr. Schmid Gmbh & Co. | Vorrichtung und Verfahren zum Ätzen von Substraten |
| FR2937054B1 (fr) | 2008-10-13 | 2010-12-10 | Commissariat Energie Atomique | Procede et dispositif de decontamination d'une surface metallique. |
| PL2508267T3 (pl) * | 2011-04-04 | 2014-11-28 | J Wagner Ag | Odwracalna dysza do materiałów powłokowych do pistoletu natryskowego do powlekania obrabianego przedmiotu materiałem powłokowym |
| KR102179814B1 (ko) * | 2013-11-08 | 2020-11-17 | 엘지전자 주식회사 | 가전기기용 외장 패널 및 그 제조방법 |
| WO2019066584A1 (ko) * | 2017-09-28 | 2019-04-04 | 주식회사 어썸리드 | 전해연마용 전극 프레임 및 이를 포함하는 전해연마 장치 |
| IT201700110569A1 (it) * | 2017-10-03 | 2019-04-03 | Univ Degli Studi Di Palermo | Apparato e metodo per il recupero di rame a partire da scarti di dispositivi elettrici ed elettronici |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1362159A (en) * | 1917-04-04 | 1920-12-14 | Jackson S Weeks | Composition for electrolytes for electrical etching |
| NL268373A (de) * | 1960-08-23 | |||
| JPS5313177B2 (de) * | 1973-06-20 | 1978-05-08 | ||
| DE2850542C2 (de) * | 1978-11-22 | 1982-07-01 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Verfahren zum Ätzen von Oberflächen aus Kupfer oder Kupferlegierungen |
| DE3020012C2 (de) * | 1980-05-24 | 1983-03-03 | Daimler-Benz Ag, 7000 Stuttgart | Verfahren zum Freilegen der Siliciumkristalle an der Oberfläche eines Körpers aus einer Aluminiumlegierung mit hohem Siliciumgehalt |
| US4973380A (en) * | 1983-10-06 | 1990-11-27 | Olin Corporation | Process for etching copper base materials |
| US5035778A (en) * | 1989-05-12 | 1991-07-30 | International Business Machines Corporation | Regeneration of spent ferric chloride etchants |
| US5302240A (en) * | 1991-01-22 | 1994-04-12 | Kabushiki Kaisha Toshiba | Method of manufacturing semiconductor device |
| US5196053A (en) * | 1991-11-27 | 1993-03-23 | Mcgean-Rohco, Inc. | Complexing agent for displacement tin plating |
| US5284554A (en) | 1992-01-09 | 1994-02-08 | International Business Machines Corporation | Electrochemical micromachining tool and process for through-mask patterning of thin metallic films supported by non-conducting or poorly conducting surfaces |
| AU4141697A (en) | 1996-09-06 | 1998-03-26 | Obducat Ab | Method for anisotropic etching of structures in conducting materials |
| US6143158A (en) * | 1997-04-25 | 2000-11-07 | Fuji Photo Film Co., Ltd. | Method for producing an aluminum support for a lithographic printing plate |
| EP0889680A3 (de) | 1997-07-01 | 2000-07-05 | Deutsche Thomson-Brandt Gmbh | Verfahren zur Entfernung und/oder Aufbringung von leitendem Material |
| JP4431203B2 (ja) | 1998-08-10 | 2010-03-10 | 義和 小林 | 塩化第二鉄エッチング液の管理装置 |
| US6638686B2 (en) * | 1999-12-09 | 2003-10-28 | Fuji Photo Film Co., Ltd. | Planographic printing plate |
-
2001
- 2001-09-10 SE SE0102994A patent/SE519898C2/sv not_active IP Right Cessation
-
2002
- 2002-09-09 WO PCT/SE2002/001602 patent/WO2003024172A2/en not_active Ceased
- 2002-09-09 AT AT02798066T patent/ATE397843T1/de not_active IP Right Cessation
- 2002-09-09 US US10/487,745 patent/US7767074B2/en not_active Expired - Fee Related
- 2002-09-09 JP JP2003528080A patent/JP4216718B2/ja not_active Expired - Fee Related
- 2002-09-09 EP EP02798066A patent/EP1425948B1/de not_active Expired - Lifetime
- 2002-09-09 AU AU2002334517A patent/AU2002334517A1/en not_active Abandoned
- 2002-09-09 DE DE60226984T patent/DE60226984D1/de not_active Expired - Lifetime
- 2002-09-09 CN CNA028176588A patent/CN1554215A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2003024172A3 (en) | 2003-06-05 |
| US7767074B2 (en) | 2010-08-03 |
| DE60226984D1 (de) | 2008-07-17 |
| JP2005502785A (ja) | 2005-01-27 |
| ATE397843T1 (de) | 2008-06-15 |
| SE0102994D0 (sv) | 2001-09-10 |
| SE0102994L (sv) | 2003-03-11 |
| WO2003024172A8 (en) | 2004-05-06 |
| WO2003024172A2 (en) | 2003-03-20 |
| JP4216718B2 (ja) | 2009-01-28 |
| CN1554215A (zh) | 2004-12-08 |
| US20050082257A1 (en) | 2005-04-21 |
| EP1425948A2 (de) | 2004-06-09 |
| AU2002334517A1 (en) | 2003-03-24 |
| EP1425948B1 (de) | 2008-06-04 |
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