SK11772003A3 - Vodná organická peroxidová emulzia a jej použitie - Google Patents
Vodná organická peroxidová emulzia a jej použitie Download PDFInfo
- Publication number
- SK11772003A3 SK11772003A3 SK1177-2003A SK11772003A SK11772003A3 SK 11772003 A3 SK11772003 A3 SK 11772003A3 SK 11772003 A SK11772003 A SK 11772003A SK 11772003 A3 SK11772003 A3 SK 11772003A3
- Authority
- SK
- Slovakia
- Prior art keywords
- emulsion
- emulsions
- organic peroxide
- plasticizer
- phthalate
- Prior art date
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 80
- 150000001451 organic peroxides Chemical class 0.000 title claims abstract description 44
- 238000003860 storage Methods 0.000 title abstract description 11
- 239000004014 plasticizer Substances 0.000 claims abstract description 29
- 239000000084 colloidal system Substances 0.000 claims abstract description 14
- 230000001681 protective effect Effects 0.000 claims abstract description 13
- 239000007798 antifreeze agent Substances 0.000 claims abstract description 6
- 125000004185 ester group Chemical group 0.000 claims abstract description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 5
- 239000000178 monomer Substances 0.000 claims abstract description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 21
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 claims description 15
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 239000011118 polyvinyl acetate Substances 0.000 claims description 13
- 150000002148 esters Chemical group 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- ALKCLFLTXBBMMP-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl hexanoate Chemical compound CCCCCC(=O)OC(C)(C=C)CCC=C(C)C ALKCLFLTXBBMMP-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 3
- LGBAGUMSAPUZPU-UHFFFAOYSA-N bis(9-methyldecyl) benzene-1,2-dicarboxylate Chemical compound CC(C)CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC(C)C LGBAGUMSAPUZPU-UHFFFAOYSA-N 0.000 claims description 3
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical group CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 3
- 125000005498 phthalate group Chemical group 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- SGWHIVHMTJJAGX-UHFFFAOYSA-N bis(10-methylundecyl) benzene-1,2-dicarboxylate Chemical compound CC(C)CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCC(C)C SGWHIVHMTJJAGX-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 14
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 12
- -1 trimetilalates Chemical class 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 150000002978 peroxides Chemical class 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- VNJISVYSDHJQFR-UHFFFAOYSA-N tert-butyl 4,4-dimethylpentaneperoxoate Chemical compound CC(C)(C)CCC(=O)OOC(C)(C)C VNJISVYSDHJQFR-UHFFFAOYSA-N 0.000 description 3
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 2
- QWTIJUSZMRYPIJ-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)decaneperoxoic acid Chemical compound CCCCCCCCC(C(=O)OO)C(C)(C)CC(C)(C)C QWTIJUSZMRYPIJ-UHFFFAOYSA-N 0.000 description 2
- AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 2
- FMGWHHVGOLOXQO-UHFFFAOYSA-N 2-methylbutan-2-yl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(C)(C)CC FMGWHHVGOLOXQO-UHFFFAOYSA-N 0.000 description 2
- RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 2
- KFGFVPMRLOQXNB-UHFFFAOYSA-N 3,5,5-trimethylhexanoyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(=O)CC(C)CC(C)(C)C KFGFVPMRLOQXNB-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- JWGRORXJBVUKDH-UHFFFAOYSA-N CCCCC(CC)COOC(C)(CC(C)C)CC(C)(C)C(=O)OO Chemical compound CCCCC(CC)COOC(C)(CC(C)C)CC(C)(C)C(=O)OO JWGRORXJBVUKDH-UHFFFAOYSA-N 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000007630 basic procedure Methods 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- GLYJVQDYLFAUFC-UHFFFAOYSA-N butyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCC GLYJVQDYLFAUFC-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 150000004978 peroxycarbonates Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- IFXDUNDBQDXPQZ-UHFFFAOYSA-N 2-methylbutan-2-yl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CC IFXDUNDBQDXPQZ-UHFFFAOYSA-N 0.000 description 1
- HNRUZAJDUWGXAN-UHFFFAOYSA-N 4-methylpentan-2-yl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)CC(C)C HNRUZAJDUWGXAN-UHFFFAOYSA-N 0.000 description 1
- AMEMLELAMQEAIA-UHFFFAOYSA-N 6-(tert-butyl)thieno[3,2-d]pyrimidin-4(3H)-one Chemical compound N1C=NC(=O)C2=C1C=C(C(C)(C)C)S2 AMEMLELAMQEAIA-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- NDKYEUQMPZIGFN-UHFFFAOYSA-N Butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCC NDKYEUQMPZIGFN-UHFFFAOYSA-N 0.000 description 1
- KIMQYBSXPHPYDP-UHFFFAOYSA-N CC(C)CC(C)(OO)CC(C)(C)C(=O)OO Chemical compound CC(C)CC(C)(OO)CC(C)(C)C(=O)OO KIMQYBSXPHPYDP-UHFFFAOYSA-N 0.000 description 1
- VRLGIJFBMCJBEW-UHFFFAOYSA-N CC(C)CC(C)CC(C)(C)C(=O)OO Chemical compound CC(C)CC(C)CC(C)(C)C(=O)OO VRLGIJFBMCJBEW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- JHJSICJSIOGNMW-UHFFFAOYSA-N [2-(2,2-dimethylpropanoylperoxy)-4-methylpentan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(CC(C)C)OOC(=O)C(C)(C)C JHJSICJSIOGNMW-UHFFFAOYSA-N 0.000 description 1
- NEOVVEUFSCIAGY-UHFFFAOYSA-N [2-(2-ethylhexoxycarbonylperoxy)-5-methylhexan-2-yl] 2-methylpropaneperoxoate Chemical compound CCCCC(CC)COC(=O)OOC(C)(CCC(C)C)OOC(=O)C(C)C NEOVVEUFSCIAGY-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BCSGAWBQJHXXSE-UHFFFAOYSA-N bis(11-methyldodecyl) benzene-1,2-dicarboxylate Chemical compound CC(C)CCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC(C)C BCSGAWBQJHXXSE-UHFFFAOYSA-N 0.000 description 1
- ZGPBOPXFOJBLIV-UHFFFAOYSA-N butoxycarbonyloxy butyl carbonate Chemical compound CCCCOC(=O)OOC(=O)OCCCC ZGPBOPXFOJBLIV-UHFFFAOYSA-N 0.000 description 1
- ZRNCNTSXSYXHOW-UHFFFAOYSA-N butyl decanoate Chemical compound CCCCCCCCCC(=O)OCCCC ZRNCNTSXSYXHOW-UHFFFAOYSA-N 0.000 description 1
- DHAZIUXMHRHVMP-UHFFFAOYSA-N butyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCC DHAZIUXMHRHVMP-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000007979 citrate buffer Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- GHKVUVOPHDYRJC-UHFFFAOYSA-N didodecyl hexanedioate Chemical compound CCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCC GHKVUVOPHDYRJC-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- RQIKFACUZHNEDV-UHFFFAOYSA-N dihexadecyl hexanedioate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCCCC RQIKFACUZHNEDV-UHFFFAOYSA-N 0.000 description 1
- WIYAGHSNPUBKDT-UHFFFAOYSA-N dinonyl hexanedioate Chemical compound CCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCC WIYAGHSNPUBKDT-UHFFFAOYSA-N 0.000 description 1
- OHRKDLWUOVWNLM-UHFFFAOYSA-N dipentadecyl hexanedioate Chemical compound CCCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCCC OHRKDLWUOVWNLM-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- QZQPCVVMCYMSFX-UHFFFAOYSA-N ditetradecyl hexanedioate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCC QZQPCVVMCYMSFX-UHFFFAOYSA-N 0.000 description 1
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 1
- QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- QFOJTGAPBXCVOK-UHFFFAOYSA-N hexyl 2-ethylhexaneperoxoate Chemical compound CCCCCCOOC(=O)C(CC)CCCC QFOJTGAPBXCVOK-UHFFFAOYSA-N 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229940033357 isopropyl laurate Drugs 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- FTBUKOLPOATXGV-UHFFFAOYSA-N propyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCC FTBUKOLPOATXGV-UHFFFAOYSA-N 0.000 description 1
- BEKZXQKGTDVSKX-UHFFFAOYSA-N propyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCC BEKZXQKGTDVSKX-UHFFFAOYSA-N 0.000 description 1
- BTAXGNQLYFDKEF-UHFFFAOYSA-N propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC BTAXGNQLYFDKEF-UHFFFAOYSA-N 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
- C07C407/006—Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Polymerisation Methods In General (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01201118 | 2001-03-23 | ||
| PCT/EP2002/001812 WO2002076936A1 (fr) | 2001-03-23 | 2002-02-20 | Emulsions de peroxyde organique aqueuses et stables au stockage |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK11772003A3 true SK11772003A3 (sk) | 2003-12-02 |
Family
ID=8180066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK1177-2003A SK11772003A3 (sk) | 2001-03-23 | 2002-02-20 | Vodná organická peroxidová emulzia a jej použitie |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US7214329B2 (fr) |
| EP (1) | EP1373198B2 (fr) |
| JP (1) | JP2004528436A (fr) |
| KR (1) | KR100823447B1 (fr) |
| CN (1) | CN1219762C (fr) |
| AT (1) | ATE393142T1 (fr) |
| BR (1) | BR0208184A (fr) |
| CA (1) | CA2441583A1 (fr) |
| CZ (1) | CZ20032571A3 (fr) |
| DE (1) | DE60226219T3 (fr) |
| HU (1) | HU229629B1 (fr) |
| IL (1) | IL158049A0 (fr) |
| MA (1) | MA26010A1 (fr) |
| MX (1) | MXPA03008566A (fr) |
| NO (1) | NO20034210L (fr) |
| PL (1) | PL363747A1 (fr) |
| RU (1) | RU2285011C2 (fr) |
| SK (1) | SK11772003A3 (fr) |
| WO (1) | WO2002076936A1 (fr) |
| ZA (1) | ZA200307380B (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070213247A1 (en) * | 2006-02-10 | 2007-09-13 | Gyorgyi Fenyvesi | Detergent and liquid soap compositions comprising biologically-based mono and di esters |
| CN105367688B (zh) * | 2009-08-06 | 2018-07-06 | 阿克佐诺贝尔化学国际公司 | 具有高活性氧含量的储存稳定且安全的过氧化物乳液 |
| EP2508507A1 (fr) * | 2011-04-07 | 2012-10-10 | LANXESS Deutschland GmbH | Composés acylés du glycerol et leur utilisation en tant que stabilisateurs ou flegmatisants de peroxydes et formulations contenant des peroxydes |
| EP2861688B1 (fr) * | 2012-06-15 | 2019-04-24 | Arkema, Inc. | Dispersions de peroxyde |
| FR2995906B1 (fr) * | 2012-09-21 | 2015-02-20 | Arkema France | Composition d'emulsion aqueuse de peroxyde organique |
| RU2732403C2 (ru) * | 2016-03-18 | 2020-09-16 | Акцо Нобель Кемикалз Интернэшнл Б.В. | Стабильные при хранении водные эмульсии органического пероксида |
| DE102019110214A1 (de) | 2019-04-17 | 2020-10-22 | Pergan Hilfsstoffe für industrielle Prozesse GmbH | Organische Peroxidemulsion, Verfahren zu deren Herstellung und deren Verwendung |
| EP4153641A1 (fr) * | 2020-05-20 | 2023-03-29 | Arkema France | Emulsion de peroxydicarbonate de di-sec-butyl |
| EP4545573A1 (fr) * | 2023-10-20 | 2025-04-30 | Nouryon Chemicals International B.V. | Emulsions aqueuses de peroxyde organique |
| EP4541788A1 (fr) * | 2023-10-20 | 2025-04-23 | Nouryon Chemicals International B.V. | Production continue d'emulsions aqueuses de peroxyde organique |
| CN119977862B (zh) * | 2025-04-16 | 2025-07-18 | 兰州助剂厂股份有限公司 | 一种低温稳定型有机过氧化物乳液及其安全制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US2454254A (en) | 1944-02-24 | 1948-11-16 | Buffalo Electro Chem Co | Stabilized organic peroxides |
| US2437420A (en) * | 1944-02-25 | 1948-03-09 | Prophylactic Brush Co | Vulcanizable copolymers of a vinyl aryl compound, butadiene, and vinyl ethers |
| DE1595428A1 (de) * | 1965-07-10 | 1970-03-12 | Chisso Corp | Verfahren zur Herstellung von Polyvinylchlorid mit innerer Weichmachung |
| NL132378C (fr) | 1966-06-23 | |||
| US3535422A (en) * | 1968-03-11 | 1970-10-20 | Stiefel Laboratories | Stable benzoyl peroxide composition |
| DE1922171C3 (de) | 1969-04-30 | 1979-03-01 | Peroxid-Chemie Gmbh, 8021 Hoellriegelskreuth | Verfahren zur Herstellung einer Peroxidpaste |
| JPS546263B1 (fr) | 1970-07-17 | 1979-03-27 | ||
| US4255277A (en) | 1979-01-29 | 1981-03-10 | General Electric Company | Storage stable peroxide paste composition |
| NL8000260A (nl) | 1980-01-16 | 1981-08-17 | Akzo Nv | Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties. |
| EP0038988B1 (fr) | 1980-04-26 | 1984-07-04 | Interox Chemicals Limited | Compositions contenant des peroxydes organiques |
| JPH0635484B2 (ja) | 1985-10-14 | 1994-05-11 | 化薬アクゾ株式会社 | 有機過酸化物のエマルジヨン配合物 |
| JPH021472A (ja) | 1988-05-26 | 1990-01-05 | Kayaku Akzo Kk | パーオキサイド組成物 |
| RU2046807C1 (ru) * | 1992-09-25 | 1995-10-27 | Государственное предприятие "Капролактам" | Способ суспензионной полимеризации винилхлорида |
| US5690856A (en) | 1995-03-07 | 1997-11-25 | Akzo Nobel N.V. | Solid diacyl organic peroxide dispersions |
| BE1009969A3 (fr) | 1996-01-25 | 1997-11-04 | Solvay | Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle. |
| BE1011295A3 (fr) | 1997-07-22 | 1999-07-06 | Solvay | Solution organique de peroxydicarbonate de dialkyle, procede pour l'obtenir, preparation de polymeres halogenes a l'intervention de celle-ci et polymeres halogenes obtenus. |
| TW426707B (en) | 1997-07-24 | 2001-03-21 | Akzo Nobel Nv | Emulsions of peroxyesters |
| JPH11171914A (ja) * | 1997-12-16 | 1999-06-29 | Kayaku Akzo Corp | 有機過酸化物のエマルション配合物 |
| WO2001040372A1 (fr) * | 1999-12-03 | 2001-06-07 | Kuraray Co., Ltd. | Emulsion aqueuse et dispersant destine a une polymerisation en suspension d'un compose vinylique |
-
2002
- 2002-02-20 CA CA002441583A patent/CA2441583A1/fr not_active Abandoned
- 2002-02-20 CN CNB028071034A patent/CN1219762C/zh not_active Expired - Fee Related
- 2002-02-20 DE DE60226219.4T patent/DE60226219T3/de not_active Expired - Lifetime
- 2002-02-20 CZ CZ20032571A patent/CZ20032571A3/cs unknown
- 2002-02-20 PL PL02363747A patent/PL363747A1/xx not_active Application Discontinuation
- 2002-02-20 HU HU0303602A patent/HU229629B1/hu not_active IP Right Cessation
- 2002-02-20 AT AT02724174T patent/ATE393142T1/de not_active IP Right Cessation
- 2002-02-20 WO PCT/EP2002/001812 patent/WO2002076936A1/fr not_active Ceased
- 2002-02-20 BR BR0208184-9A patent/BR0208184A/pt not_active IP Right Cessation
- 2002-02-20 US US10/468,907 patent/US7214329B2/en not_active Expired - Fee Related
- 2002-02-20 RU RU2003131182/04A patent/RU2285011C2/ru not_active IP Right Cessation
- 2002-02-20 IL IL15804902A patent/IL158049A0/xx unknown
- 2002-02-20 JP JP2002576198A patent/JP2004528436A/ja not_active Withdrawn
- 2002-02-20 MX MXPA03008566A patent/MXPA03008566A/es active IP Right Grant
- 2002-02-20 SK SK1177-2003A patent/SK11772003A3/sk unknown
- 2002-02-20 KR KR1020037011878A patent/KR100823447B1/ko not_active Expired - Fee Related
- 2002-02-20 EP EP02724174.4A patent/EP1373198B2/fr not_active Expired - Lifetime
-
2003
- 2003-09-22 NO NO20034210A patent/NO20034210L/no not_active Application Discontinuation
- 2003-09-22 ZA ZA200307380A patent/ZA200307380B/en unknown
- 2003-09-22 MA MA27317A patent/MA26010A1/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2003131182A (ru) | 2005-02-27 |
| ATE393142T1 (de) | 2008-05-15 |
| BR0208184A (pt) | 2004-03-02 |
| ZA200307380B (en) | 2004-07-06 |
| US20040132938A1 (en) | 2004-07-08 |
| HUP0303602A2 (hu) | 2004-01-28 |
| CN1498207A (zh) | 2004-05-19 |
| WO2002076936A1 (fr) | 2002-10-03 |
| NO20034210D0 (no) | 2003-09-22 |
| CA2441583A1 (fr) | 2002-10-03 |
| KR100823447B1 (ko) | 2008-04-17 |
| DE60226219T2 (de) | 2009-05-28 |
| NO20034210L (no) | 2003-09-22 |
| EP1373198B1 (fr) | 2008-04-23 |
| CZ20032571A3 (cs) | 2004-02-18 |
| EP1373198A1 (fr) | 2004-01-02 |
| RU2285011C2 (ru) | 2006-10-10 |
| US7214329B2 (en) | 2007-05-08 |
| DE60226219T3 (de) | 2015-06-18 |
| JP2004528436A (ja) | 2004-09-16 |
| PL363747A1 (en) | 2004-11-29 |
| MXPA03008566A (es) | 2003-12-08 |
| HU229629B1 (en) | 2014-03-28 |
| HUP0303602A3 (en) | 2011-04-28 |
| EP1373198B2 (fr) | 2015-02-25 |
| DE60226219D1 (de) | 2008-06-05 |
| CN1219762C (zh) | 2005-09-21 |
| IL158049A0 (en) | 2004-03-28 |
| KR20030086300A (ko) | 2003-11-07 |
| WO2002076936A8 (fr) | 2003-11-27 |
| MA26010A1 (fr) | 2003-12-31 |
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